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By Williams RC

Overlying the coal deposits of the Sydney Basin are several lakes and other bodies of water. These include the Pacific Ocean, Lake Macquarie, the Tuggerah Lakes and the stored waters of the dams of the New South Wales Metropolitan Water Sewerage and Drainage Board. The coal beneath these bodies of water amounts to hundreds of millions of tons. Colliery workings have approached these areas of water and in some instances first 1"orkings of bord and pillar have taken place oi_eshh the water. he problem which now faces mine manage- and other interested authorities involves the determination of the maximum ;mount of coal which can be safely extracted from beneath the water. There are many factors to be considered including the depth of cover, seam thickness, geological details and strata movements.

Jan 1, 1972

By F Melcher, M Wiedicke, A Wittenberg

Ferromanganese nodules form a specific category of widespread marine mineral deposits. The tremendous increase in metal prices during the last decade raised new economic interest in their exploration. The German Federal Institute for Geosciences and Natural Resources (BGR), which had been engaged in nodule research in the 1970s and 1980s, renewed its activities on this subject based on an exploration contract with the International Seabed Authority, signed in 2006. BGRÆs licence area û comprising 75 000 km2 û is located between the Clarion and the Clipperton Fracture Zones. In this so-called nodule belt north of the equator the sea floor reaches water depths of >4000 m. About 900 million tonnes of manganese nodules are expected there. In this study the fine-scale distribution of important elements in manganese nodules and crusts from a variety of locations was investigated. Besides 11 samples from the RV SONNE cruise SO-25, numerous samples from additional locations were included in this study for comparison. In general, the sample suite includes two genetic types of precipitates, manganese nodules and Co-rich crusts. A detailed characterisation of the distribution of major, minor and important trace elements in manganese nodules based on in situ microenergy dispersive X-ray fluorescence (¦-EDXRF) analysis is presented here. The data are compared with bulk major, minor and trace element data as well as with quantitative electron probe microanalysis (EMPA) data sets. The element distribution maps and profiles produced by ¦-EDXRF analysis with short or extended (in case of profiles) counting times, allow precise selection of æregions of interestÆ for further detailed investigation using high spatial resolution techniques (eg scanning electron microscope (SEM)-EDAX; laser ablation-inductively coupled plasma mass spectroscopy (LA-ICPMS); isotopic studies).

Jan 1, 2008

By Walker G. S

Infrared and Raman spectroscopy have been used to study a range of solid state and aqueous solution species which are of interest in extractive metallurgy. In the solid state new Cu(II)/CN'/NH3 complexes have been detected, iron impurities in kaolin characterised, aluminium substitution in hematite and goethite quantified, and the crystallinity and orientation of zircon determined in heterogeneous crystals. In aqueous solution metal cyanide complexes and equilibria were readily characterised, the thermal decomposition of SO2 monitored and products identified, and complexation of AI(III) by hydroxycarboxylates observed. Attempts to monitor the early stages of the gelling of silicate solutions were less successful, with only changes in the gel being detected. However, the degradation of 12-tungstosilicic acid was readily monitored as a function of both time and pH.

Jan 1, 1996

To enable AN-FO .tòo' be used on an equal .weight basis wish Nitro Gl reerin.e expl3oòsives r smaller diameter bore holes became necessary With consequent modifications to drill steel and burden on holes, De't'onation of AN-FO "in small diameter holes proved successful' both with 'and without primer charges but some altorat-ions were required to. adopt Anolodeòr.s to the smaller -holes, Important factors in training all operators In the new charging method were the retention of imp-,cved, fragmentat'ion, avoidance of excel ive ove:break and keeping wall rock dilution 'to an absoluato mi. iArurle ò The ò successful storage of Ammonium 14t-rate in c"!ime.tic conditions 'with daily'.-' temperature fluctuationc above and below the critical' 90¦F, has. been "achieved,

Jan 1, 1964

ALTHOUGH discovered as long ago as 1817, by Strohmeyer, the use of cadmium did not become in anyway general for nearly a century. Its properties, although well known, did not recommend it to users of metals generally, and it was, on the whole, regarded more in the light of a nuisance to zinc producers than anything else. Its real value was not appreciated until both the United States of America and Germany, who are entirely dependent on outside sources for their supplies of tin, were faced with the unpleasant fact that their tin stocks were being rapidly depleted, with practically no prospect of having them replenished. This resulted in serious efforts being made in the UnIted States of America to conserve what tin was available, and, as a consequence, several metals were tried in the hope that they would prove satisfactory substitutes for tin. Among these was cadmium, and it was found that cadmium could replace tin in a manner sufficiently satisfactory to permit of its use in many directions where tin had been used before.It is on this ability of cadmium to replace tin that its use became in any way general at first; but since then new avenues of development have been opened up in which its physical and chemical properties are proving their value. It is highly probable that its use will extend very considerably as time goes on. OCCURRENCE OF CADMIUM.There are several cadmium minerals known, but none of them occur in profitable quantities as ores. The cadmium of commerce is derived almost entirely from zinc minerals and ores in which it is almost invariably present in proportions which are usually very small. Cadmium behaves metallurgically almost the same as zinc, and hence constitutes a fraction of 1% of almost all spelter.

Jan 1, 1923

The Middleback Ranges are a series of parallel northsouth ridges on the eastern side of the Eyre Peninsula, South Australia, about 20 miles inland from the Spencer Gulf, as shown in Fig. 1. They extend for some 20 miles across the centre of the County of York. North of them, on the same line of strike, in, the County of Manchester, is a disconnected series of lesser which ends in the Iron Monarch-Iron Knob ridge, the principal iron ore locality. These ridges are referred to in the following pages as an integral part of the Middleback Ranges.The deposits of hematite which outcrop in these ranges (Fig. 1) form the most important group of iron ore bodies in Australia, and are exploited by the Broken Hill Proprietary Company. The largest of them is the Iron Monarch (Fig. 6) .H: The next largest are the Iron Duke, the Iron Prince and Iron Baron. The Iron Knob, Iron Duchess, the North and South Iron Knights, Iron Queen, and the small body south of it, the Kimba Lease, and the deposits in the Cook's and Ash Leases, are all smaller.Numerous small lens-like bodies of hematite occur throughout the ridges, but are not of sufficient size to be of commercial use. At present only the Iron Monarch and the Iron Prince bodies are being worked. The Iron Knob was quarried previously, but its remaining supply is held in reserve.*Published by permission of the Council for Scientific and Industrial Research.

Jan 1, 1936

The difficulty of successfully imple menting a landscape policy is almost incom- prehensible. Landscape design is recognised as an essential component in the integration of engineering and architectural projects into the landscape, but the factors which prevent the achievement of a successful result are rarely recognised or assessed. In many cases these prohibiting factors are due to a lack of understanding of the effect of major planning decisions on the existing landscape, the importance of the landscape plan and the significance of appro- priate specified techniques to prevent un- necessary damage and to ensure retention of existing vegetation in a healthy condition. The role of the landscape architect in incorporating new land uses into the landscape provides the background against which factors which inhibit policy achievement can be con- sidered.

Jan 1, 1976

By Elpatyevskaya VP, Arzhanova VS

Main geochemical problems concerning the environment and mining industry interrelation are connected with the transformation of natural water chemistry by mining wastes. The investigation of many mines in Primorye, the southern part of the Russian Far East, showed that their mining waters have high concentrations of heavy metals and aluminium. Water acidity is primarily connected with the amount of acid-forming sulphide minerals in ores and also depends on the neutralising capacity of rocks. Considerable quantity of metals occur in the waters in dissolved form. Metal concentrations in mining waters exceeds the natural levels by 2-5 orders of magnitude and can't be reduced to the background levels even after multiple dilution. It is necessary to develop and put into practice new technologies so that to reduce the geochemical impact upon the environment.

Jan 1, 1995

By C Tukel

Copper sulfate is traditionally used to activate various types of sulfide minerals. The list of users includes Falconbridge Sudbury operations, where copper sulfate solution is added to the pyrrhotite/pentlandite middlings at the scavenging stage. Results from some batch tests reported in the literature suggested that copper activation is helpful for the improvement of pentlandite recovery, especially in the difficult to float fine particle range. Any improvement in pentlandite recovery is important since it is the main nickel bearing sulfide mineral. The impact of copper sulfate for this function has been investigated. Since the focus of current investigation was the flotation behaviour of minerals at the scavenger stage, rougher flotation was kept as constant as possible at two different weight recoveries, namely 13.2 per cent and 15.5 per cent that is relevant to industrial practice. Samples taken during batch testing were extracted using DETA and flotation products from selected tests were analysed to determine the recovery by size behaviour in relation to the use of copper sulfate. Results provide significant evidence that the addition of copper sulfate to these middlings does not yield greater nickel recovery, either on an overall or specific particle size basis. It is concluded that copper sulfate is wasted in the process and that self activation behaviour of the ore at a slightly reduced pH is sufficiently significant to maintain the scavenger recovery of pyrrhotite and pentlandite at desirable levels. Results obtained from limited circuit trials have shown supporting evidence for this conclusion.

Jan 1, 2005

By Y Wei, H-B Mnhlhaus

Particles are by far the easiest objects to simulate, because their dynamics is simple. Determining the motion of particles and their interaction, a wide variety of deformable structures can be constructed by connecting particles that have mass, position, and velocity, and that respond to forces. Starting from this simple idea we have derived what we call the particle-lattice method for the solutions of boundary value problems of deformation and fracture of solid mass. The problem of rock breaking by blasting operations as well as fracture and flow of rocks fragments involve momentum transfer between solid and fluid; gas flow and reactive mass transfer. In this paper we outline the method and describe briefly the salient features of the algorithm. We derive relationships between the contact properties for the discrete model and the properties of the underlying continuum and fluid flow coupling procedure. Finally we illustrate the potential of the method by means of example solutions related to the dynamic fracture and flow in jointed rock by blasting.

Jan 1, 1999

By G King, Q Shu, W Cao, F Gyakwaa, H Singh, S Wang, M Huttula, T Fabritius

Metallurgical slag, such as refining slag, is essential to enhance or promote steel cleanliness. The CaO–MgO–Al2O3–SiO2 system is the primary source of oxides-based inclusions. It plays a vital role in applications in various pyrometallurgical processes. Numerous thermodynamic databases and physicochemical properties of slag studies mainly focus on quenched samples and measurements at room temperature. Consequently, the present study explored the physicochemical, structural properties and crystallisation evolution for CaO–MgO–Al2O3–SiO2 glassy slags via in situ hightemperature Raman spectroscopy and synchrotron X-ray diffraction. The study was carried out by synthesising CaO–MgO–Al2O3–SiO2 slag with varying Al2O3/SiO2 ratios. The results from the in situ high-temperature measurement demonstrated a pattern showing a transformation of a broad peak from the glassy matrix to crystalline peaks. The study showed crystallisation of dominant phases such as Ca2SiO4, Ca2Al2SiO7 and CaAl2O4 that correspond and are attributable to changes of structural units during in situ high-temperature measurements. The results further showed a correlation between an increase and transformation in crystalline phases observed from the spectra obtained from non-isothermal heating of the samples.

Jun 19, 2024

By Gilligan P

The Selwyn gold-copper operation is wholly owned and operated by the Arimco mining group. The mine is located 150 kilometres south-east of Mount Isa. The primary extraction method for the gold-copper 251 orebody is by sub level open stoping. Secondary extraction is from the mass blasting of the remaining crown and rib pillars. The final mass blast of the 251 orebody occurred in December 1993. This paper details the design and execution of that firing.

Jan 1, 1994

By M Simpson, K Brodie, J L. Mauk

Subaqueous water-rock reactions that occur at the pit wall/lake water interface can affect the pH of pit lakes. Many pit lake water chemistry models neglect subaqueous reactions, which may create inaccurate predictions over time. A mineral quantification method is presented that defines the wall rock mineralogy of active open pit mines, using samples collected from the Martha Mine, a low-sulfidation epithermal Au-Ag deposit in Waihi, New Zealand. The mineral quantification method has five components: field observations and sampling, X-ray diffraction analyses, selection of representative samples, geochemical analyses, and mineral accounting. Predicted mineral concentrations closely match observed mineral concentrations visually estimated using petrographic techniques. Results of the method can be incorporated into a geochemical model of long-range pit lake water quality resulting from subaqueous water-rock reactions.

Jan 1, 2003

By Johnstone RD, Rattenbury MS

RACE Quartz-calcite veins containing Au, As, W, Cu, Pb, Zn and Fe cross-cut Alpine Fault- related structures in the Alpine Schist of South Island, New Zealand. These veins, and some other related veins have been deposited by metamorphic fluids at 250¦C to >320¦C at pressures of a few hundred bars. The fluids were very variable in composition, with 0 to 50 mole % CO2 and 2 to 18 wt. % NaCl equivalent. Penetration of hot metamorphic fluids to shallow levels in the crust was facilitated by rapid uplift of hot rocks at a compressive plate margin. Fluid immiscibility at shallow levels caused concentration of salts and metals into the aqueous phase. Gold precipitation was caused by reduction by pelitic country rock and/nr dluILion by other aqueous fluids.

Jan 1, 1987

By H Zhang, S Li, J Song, Z Lv

In this paper, a method for extracting and refining metallic molybdenum using low-temperature ZnCl2- NaCl-KCl molten salt was proposed. The electrochemical behaviour of molybdenum ions in ZnCl2- NaCl-KCl molten salt was investigated in detail, and pure metallic molybdenum was collected on the cathode. The reduction and diffusion processes of Mo(V) ions in ZnCl2-NaCl-KCl molten salt were determined through a series of electrochemical methods. The diffusion coefficients and nucleation modes of Mo(V) ions were also studied, and electrolysis was conducted for a prolonged period at a constant current density. The results indicated that the electrode reduction of Mo(V) ions in ZnCl2- NaCl-KCl molten salt proceeds through a three-step reaction: Mo(V) → Mo(IV) → Mo(III) → Mo at 250°C. The Mo(V) → Mo(IV) reaction was reversible and diffusion-controlled, with a Mo(V) diffusion coefficient of 6.02 × 10-6 cm2 s-1. Additionally, the nucleation mode of Mo(V) ions was instantaneous nucleation. The products electro-deposited were confirmed of metallic molybdenum with a particle size of less than 1 μm.

Aug 21, 2024

Full aerodynamic design development of the proposed fans for the enlarged primary ventilation system at Mount Isa Mines Limited was initiated before tender specifications were prepared. Theoretical and analytical design studies were made of many possibilities to determine the optimum proposal. Major considerations were efficiency, simplicity, standardization, and mechanical feasibility. Model testing and experimental work covered blading design, inlet shape, diffuser and tail fairing dimensions, instrumentation requirements, ancl noise studies.Theoretical and predicted performance estimates were prepared for the three 20 ft diameter vertically mounted axial flow fans.

Jan 1, 1967

By H Zhang, Y Wang, S Sukenaga, H W. Ni, H Shibata, W Z. Mu

The crystallisation behaviour of low melting point CaO-SiO2-Al2O3-MgO inclusions greatly affect the deformability of inclusions during the rolling process. The crystallisation characteristics of CaO-SiO2- Al2O3-MgO melts representing the oxide inclusions in Si-Mn killed steel were systematically investigated. The effect of Al2O3 and MgO contents on the crystallisation change were analysed under a fixed CaO/SiO2 in the complex inclusions. The continuous-cooling-transformation (CCT) and time-temperature-transformation (TTT) experiments were conducted. The results showed that the increase of MgO content increases the crystallisation ability of CaO-SiO2-Al2O3-MgO inclusions, while the increase of Al2O3 content has the opposite effect. The viscosity, liquidus temperature of oxide melt and also the initial crystallisation potential might be the reasons for the change in crystallisation behaviour. Also, the crystallisation activation energy could semi-quantitatively characterise the crystal growth during the crystallisation of inclusions. To obtain low melting point plasticized CaO-SiO2-Al2O3-MgO (CaO/SiO2=1) system inclusions, the Al2O3 content of the system needs to be controlled larger than 15 wt per cent and the MgO content should be kept at a small amount.

Aug 21, 2024

By D E. Ralph, D-J Kim, G-J Ahn, Y-H Rhee

The amount of discarded dry batteries are presently found to be increasing globally and waste cathode active materials of the lithium ion battery industry are among them. Hydrometallurgical operations are being applied to recover the valuable metals from these waste batteries. To find an economic and environmentally friendly process, the bioleaching process was applied in the present investigation for recovery of valuable metals. Its principle is the microbial production of sulfuric acid and simultaneous leaching of metals. Bioleaching of spent lithium ion secondary batteries, containing LiCoO2, has been studied in this investigation. A new method for recovery of cobalt, potentially the basis of an economic and environmentally friendly process was examined. The present study has been carried out using chemolithotrophic and acidophilic bacteria Acidithiobacillus ferrooxidans, which utilises elemental sulfur and ferrous ion as the energy source to dissolve metals from spent batteries. Bio-dissolution of cobalt was found to be faster than lithium. The effect of initial Fe(II) concentration, initial pH and solid/liquid (w/v) ratio were studied in detail. Higher Fe(II) concentration showed a decrease in dissolution due to co-precipitation of Fe(III) with the metals in the residues. Similarly, at higher initial pH values and higher solid/liquid ratio (w/v) metal dissolution was found to be inhibited. The optimised conditions for bio-dissolution were solid/liquid (w/v) ratio û 10 g/L, initial Fe(II) concentration û 3 g/L, elemental sulfur û one per cent (w/v) and initial pH û 2.5. In the optimised conditions, cobalt dissolution was observed to be about 60 per cent, whereas that of lithium was ten per cent after 20 days. A first order kinetic model was derived to study the rate of dissolution of both the metals.

Jan 1, 2006

By N LaBranche

The resurgence of Silicosis and Coal Worker’s Pneumoconiosis (CWP) in coalmines has placed the spotlight back on the management of worker exposure to particulate matter across all mining sectors (Coal Workers Pneumoconiosis Select Committee, 2017). There already exists a substantial body of knowledge on particulate matter and its impacts upon human health (National Academies of Sciences, Engineering and Medicine, 2018). The contribution of silica to respiratory disease is well known. However, it is also clear that there are major gaps in our understanding. In part, those gaps relate to the contribution to adverse health effects of mineralogical constituents in the dust (LaBranche et al, 2021a). It is also becoming evident that the size and shape of the particulate matter can affect its potential impact on human health. The University of Queensland has developed a methodology for characterising respirable and inhalable dust samples using scanning electron microscopy. Multiple samples from numerous mining operations have already been analysed using the UQ methodology. The process has been successful in showing the variety of mineralogical components and particle size distributions present in various areas of the mines.

May 5, 2022

The exploration methods used by the British Coal Corporation in 1990 improve the geological reliability of underground coal production. Although some of the techniques in common use have been proved to be effective, their limitations are recognised and concentration has been on the increasing integration of direct and remote sensing techniques. Attention is focussed onto first seam workings in sections of at least 2 metres in the depth range of 400-1200 metres and covers both surface and underground exploration. The case studies of exploration techniques and their effect on mine design at several existing collieries are representative of a wide range of geological environments within the more productive British coalfields. Notwithstanding such improvements in exploration and geological reliability, further new exploration technology is currently being investigated or trialled by British Coal.

Jan 1, 1991