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By R Bose, M Bovell, G Cheong

Grinding media is a major consumable in mineral processing and therefore decreasing costs associated with its consumption is regularly considered a key goal for the minerals processing industry. Grinding media manufacturers have historically developed steels with improved wear life for their products as a way of delivering incremental media quality improvement. This has included increasing carbon levels from low-to-medium carbon steels up to the eutectoid carbon composition of 0.77% where the relationship between higher carbon and better wear performance is well understood. Producers today will regularly use grades in excess of 0.8% to further improve wear performance particularly for rolled grinding media.This paper first introduces the demonstrated relationship between this increased carbon content and improved wear resistance along with metallurgical rationale behind the high carbon production process and limitations. To test the performance improvement associated with the higher carbon steel grade, a series of Marked Ball Wear Tests (MBWT) were carried out. This paper also explores the relationship between ball properties, test methodology and wear performance and concludes by correlating increased carbon grade with a reduced consumption rate of between 3.1% and 6.1% in the tests conducted.CITATION:Bovell, M, Bose, R and Cheong, G, 2018. Improved forged grinding media performance with carbon content greater than 1.0%, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 559–570 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

In dense medium processes for the beneficiation of minerals the consumption of medium (generally ferrosilicon) represents a major component of the operating cost. This provides a strong incentive for improvements in heavy medium recovery circuit design and operation. A major thrust in heavy medium plant design over the past decade has therefore been towards circuits which reduce medium losses. In this paper recent trends in plant design are examined in relation to the factors infl uencing circuit performance and medium losses. Operational details ' which have a significant effect on losses are discussed and illustrated by means of plant and pilot plant test data, with particular emphasis on the performance of wet drum magnetic separators. While the emphasis is on reducing the consumption of the high-cost ferrosilicon medium used in minerals beneficiation, most of the principles described in this paper are equally relevant to the design and operation of magnetite recovery circuits for coal preparation plants.

Jan 1, 1987

By M Zengerer

The Basil Cu/Co deposit comprises a 26.5 Mt Inferred Resource of copper and cobalt, grading 0.57?per cent Cu and 0.05 per cent Co. It lies in the Harts Range, Central Australia, within the Riddock Amphibolite of the Irindina Province. Analysis of drilling within the mineralised zone of the deposit determined a spatial association between pyrrhotite with high magnetic susceptibility and chalcopyrite, following a strong magnetic trend as determined from airborne geophysics. A study was commissioned to examine if geophysical inversion could predict the distribution of sulfide mineralisation based on pyrrhotite from drill hole intersections, as well as predicting further mineralisation at depth or in the vicinity of the deposit. Petrophysical and geostatistical analysis of drilling susceptibility and mineralisation provided a basis of property distribution inside the model. This was followed by 3D geological modelling of mineralisation based on domain kriging of drill hole susceptibility sensitivity testing of signal to source depth, and distribution was performed using 3D forward modelling. Stochastic inversion generated alternative 3D geological models, which were tested for behaviour and adherence to observed drilling data and geostatistical limitations using GeoModeller software. Predicted mineralisation distribution was compared with conventional geostatistical modelling and found to be in agreement in planar behaviour but exhibiting possibly isoclinally folded trends, with reliability increasing closer to the surface. Predictions of mineralisation at greater depth and beneath weaker anomalies were more diffuse due to small model cell size having limited influence on the signal at depth.The Blackbush uranium deposit comprises a 64.5 Mt Inferred Resource, grading 230 ppm U in the Pirie Basin south of Whyalla, South Australia. It directly overlies the radiogenic Samphire Granite and is considered a tertiary unconformity deposit. Sensitivity modelling was performed using high-resolution ground gravity to see if a deposit signature could be detected using gravity. This required 3D implicit modelling of the geology and mineralisation from drill hole data and characterisation of an associated physical property model using domain kriging in GeoModeller. Density models relied on exploiting an observed relationship between logged density and measured uranium oxide percentage. The residual gravity response of the background geology model identified the location of the uranium deposit. Stochastic inversion of the litho/property 3D model has refined the known distribution of uranium from drilling and provided structural insights into the deposit.These projects have become excellent case studies for exploiting the relationship between mineralisation and potential fields and for testing the applicability of using domain kriging of properties determined from drilling to build robust 3D geological models for stochastic geophysical inversion, leading to robust methods for exploration targeting and mineral deposit prediction.CITATION:Zengerer, M, 2014. Use of geostatistically-constrained potential field inversion and downhole drilling to predict distribution of sulfide and uranium mineralisation, in Proceedings Ninth International Mining Geology Conference 2014 , pp 281–290 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 18, 2014

By M English, M Yumlu

At times of high metal prices, mining projects that have previously been put into the ætoo hard basketÆ are now being more closely examined. Typically these projects include the potential recovery of small mineable tonnes with high contained metal values and often with poor ground conditions. For many underground mining projects, the drift and fill method is viewed as a high-cost method and a æmethod of last resortÆ. As a result the method is not well known in Australia and it is the authorsÆ view that the method is under utilised. The drift and fill method can be applied to a variety of underground mining situations and is a preferred method for some orebody geometries and where ore recovery is viewed as a key to project success. This paper examines some of the critical mine planning and backfill issues involved with the drift and fill mining method.

Jan 1, 2008

By Kapoor M. L

EMF measurements were performed in the temperature range of 933-1095 K to determine the thermodynamic properties of oxygen dissolution in liquid lead and lead-tin alloys with tin in the dilute concentration range of 0 to 6 atom per cent. The oxygen in the Pb-O system was varied by equilibrating with (PbO) slag, and that in the Pb-O-Sn system was varied with the addition of lead oxide. Wagner's interaction parameter approach was used to evaluate the self interaction parameter and ternary interaction parameters at different temperatures, to yield: E8(pb) = 97.35 - 113.27 x 103/t Eo(pb) = 139 - 20.616 x104/1' Quasichemical formulation was employed to yield Inf to reveal the effect of tin on oxygen in lead. Results have been predicted on the basis of classical models and those obtained using the QCT approach of Alcock and Richardson at Z=2 have been found to agree with the experimental Data.

Jan 1, 1992

Conventional narrow vein mining, utilising hand held methods, is expensive and requires specialised miners who are becoming a rarity. Hand held mining techniques (shrinkage stoping, leading stoping and cut and fill) have the advantage that they can be selective. The methods allow continued sampling of the face, control of hanging wall conditions and are adaptable to changes in strike and dip. On the other hand, more productive longhole stoping methods can allow excessive dilution due to drill hole deviations and changes in orebody dip and can be subject to unexpected hanging wall or footwall failures. Development of small scale equipment (as narrow as 0.8m wide) used for drilling or bogging very smallaccess drives has been ongoing over the past decade. In this paper, types of equipment are examined and compared, particularly with respect to their produc- tivity, size, and working environment. The introduction of electric hydraulic equipment has provided a better working environment with reduced noise, exhaust fumes and heat. The concept of the "hydraulic cherry picker" may have application in mining steeply dipping orebodies. The system requires orebodies to be reasonably consistent in dip over 15 metre sub-level intervals. The system involves the basic concept and skills of machine and airleg mining, combined with the safety and productivity of a mechanized work platform. The platform or basket is stabilized between the hanging wall and foot- wall by hydraulic rams and is extended by a tilting hydraulic boom mounted to a small prime mover or trailer. Design concepts (including remote controlled charging of explosives, adaptation to the boom for rock cutting and the overall electric hydraulic mining concept) are put forward in the paper as a view as to how narrow vein mines will be mined in the future.

Jan 1, 1987

The Imperial Smelting Process (ISP) for the simultaneous smelting of zinc and lead was developed at Avonmouth from the 1930's with activity intensifying in the late 1940's/early 1950's. Present operations are based around the No.4 furnace which was built in 1967. Development during the 1980's has been driven by the need to sustain operations at low metals prices and has been aimed at reducing manning whilst increasing output. Although hit by several major plant disruptions, progress has been steady, culminating in a ú10 million capital programme in 1988?89 to upgrade the operation. The most important technical developments, reflecting the needs of the 1990's have, in the sintering area, included improvements to feed conditioning and sinter quality, a 20% uprate in production capacity by debottlenecking, and pilot work leading to the installation of a Boliden-Norzink mercury removal plant. In the smelting area the ISP furnace has been rebuilt, with a redesigned bottom section to eliminate earlier operating sensitivities, and to achieve higher blowing capability, and at the zinc refinery the columns have been rearranged for more flexible operation and higher capacity.

Jan 1, 1989

By S W. Richards, J Buys

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. Magmatic arcs are prime targets for porphyry- and epithermal-style mineral deposits, although settings within continental arcs and/or tectonically-thickened crust generally tend to be more prospective than intra-oceanic arcs in extensional settings. In this paper, we report new geochemical and geochronological data on igneous rocks of the Western Belt of the Vanuatu intra-oceanic arc. Dating of igneous hornblende (Ar-Ar) and zircon (U-Pb) from the igneous rocks place their formation in the late Eocene to Miocene. In most respects, these are typical arc igneous rocks. However, they contain inherited zircon grains with significant age populations at ca 2.8–2.5 Ga, 2.0–1.8 Ga, 1.75–1.5 Ga, 850–700 Ma, 530–430 Ma and 330–220 Ma. This inheritance signature is unlike anything recognised from the oceanic realm of the south-west Pacific, but, in general, does match the age of the major crustal blocks of the Australian continent. An exception is the significant proportion (~20 per cent) of zircons of Rodinia breakup age (~800 Ma), which previously has not been found in eastern Australia or the south-west Pacific.We propose that part of the Vanuatu arc basement comprises a ribbon of continental material rifted from northern Australia prior to, or during, the Cretaceous. The presence of ancient continental material within the Vanuatu island arc may help reconcile the relatively large thickness and low density of the crust of Vanuatu, and may enhance the prospects for significant porphyry and epithermal ore deposits in the region.CITATION:Spandler, C, Buys, J, Holm, R J and Richards, S W, 2015. Remnants of ancient Australia in Vanuatu – implications for south-west Pacific tectonics and mineralisation potential, in Proceedings PACRIM 2015 Congress, pp 183–188 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By D Semini, B Newcombe

Base-metal sulfide refractory gold ores often contain a portion of ‘free’ gold that is amenable to recovery using gravity concentration methods, whilst the refractory portion of the gold is better recovered using flotation. The decision as to whether a plant treating a refractory gold ore should utilise gravity concentration or a flash flotation circuit (or a combination of both) within the grinding circuit is usually made at the design stage of flow sheet development. Very limited data is available in the published literature which provides an industrial scale comparison on which to base such a decision and conventional laboratory testing methods are often the only way of obtaining such data. The optimum processing route will also be mineralogy dependent.This paper presents the findings of operating a refractory gold plant with either flash flotation (normal operation) or a combination of flash and gravity recovery methods treating the cyclone underflow stream and will demonstrate the regions of the recovery profile that each contributes to. Size-by-assay analysis has been performed on a number of streams around the operating plant to gain an insight into the changes that occur when the gravity circuit is in operation in addition to the flash flotation circuit. A discussion around the implications to overall plant operation in combining the use of a batch process (gravity concentration) with a continuous process (flotation) is presented.CITATION:Newcombe, B and Semini, D, 2014. Interactions between flash flotation and gravity concentration – an industrial case study of a refractory gold concentrator, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 427–436 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

By D J. Alchin

Most of South AfricaÆs high-grade iron ore resources are hosted within a fault-controlled structural basin in rocks of the Palaeoproterozoic Transvaal Supergroup in the Northern Cape Province of South Africa. Iron mineralisation occurs as individual orebodies in fault-bounded basins or as fold-controlled concordant lenses around an unconformity plane above the Kuruman Banded Iron Formation. The Sishen mine near Kathu and the beeshoek mine and Sishen South deposit near Postmasburg lie on the northern and southern border of a major domal structure known as the Maremane dome, respectively. The effects and structural constraints of at least three orogenic compressive episodes and several intermittent extensional episodes on the formation, erosion and preservation of iron mineralisation on the Maremane dome and surrounding environs were investigated. Ventersdorp impactogenal rift basin development at ~2.78 - 2.64 Ga, finalised with the deposition of the volcano-sedimentary Vryburg Formation during the thermal subsidence stage at ~2.64 - 2.6 Ga, and was followed by tectonic quiescence/stability and an extensive marine transgression across the entire Kaapvaal craton. The drowning event led to the formation of a carbonate platform with the deposition of the Schmidtsdrif and Campbellrand subgroups conformably above the Vryburg Formation at ~2.6 - 2.52 Ga. The initiation of distal (to the west of the Kaapvaal craton) off-craton oceanic rifting, causing submarine volcanism and associated hydrothermal activity, led to the deposition of initially manganiferous chert (Wolhaarkop Formation) followed by banded ironstone formations (Manganore Iron/Kuruman Formation) of the Asbestos Hill Subgroup at ~2.52 - 2.46 Ga. Initial passive margin rifting along the N-S oriented western edge of the Kaapvaal craton, initiated at the end of Ghaap Group time (during Koegas Subgroup deposition) at ~2.46 - 2.35 Ga, formed a prominent system of N-S striking, westerly dipping normal faults. Easterly directed crustal compression in post-Ghaap Group time in response to the Kalahari Orogeny (accretion of Rehoboth craton along western edge (Kalahari suture zone) of the Kaapvaal craton at ~2.35 - 2.24 Ma led to the formation of large-scale regional, N-trending F1-folds. Partial to complete inversion of the Koegas passive margin rift system (ie reverse dip-slip reactivation of the N-S striking normal fault system to high-angle reverse faults and dextral strike-slip reactivation of the Ventersdorp rift system developed in the Archaean basement), was followed by uplift, erosion and formation of a regional angular unconformity (Postmasburg unconformity). Uplift was accompanied by deposition of fluvio-glacial sediments of the Makganyene Formation (Lower Postmasburg Group) within an intracratonic peripheral foreland basin setting unconformable above Ghaap Group strata at ~2.35 - 2.24 Ga. Post-orogenic crustal relaxation and rifting caused extensional reactivation of the N-trending Palaeoproterozoic passive margin rift system and NE-trending Neoarchaean Ventersdorp impactogenal rift system, forming a fault-controlled depository for the volcano-sedimentary Upper Postmasburg Group at ~2.24 - 2.1 Ga. Deceleration in rifting was succeeded by thermal subsidence of the Upper Postmasburg Group rift, erosion, formation of a regional angular unconformity and deposition of clastic sediments of the Lower Olifantshoek Supergroup unconformable above Postmasburg Group strata at ~2.1 - 1.93 Ga. Renewed rifting led to the deposition of volcano-sedimentary units of the Upper Olifantshoek Supergroup within a rift system superimposed on the Postmasburg Group rift depository at ~1.93 - 1.83 Ga. Easterly directed crustal compression during the Kheis Orogeny at ~1.83 - 1.73 Ga led to renewed inversion of rift structures of the Postmasburg Group and Olifantshoek Supergroup depository, N-trending F2 folding and thin-skinned thrusting of older rock units eastwards over the cratonic cover, thereby utilising planes of weakness in the strata such as prominent unconformities and lithological contrast boundaries as principal dTcollements. NNW-directed crustal compression in response to Lomanian (Namaqua-Natal) Orogeny at ~1.15 - 1.0 G along the southern margin of the Kaapvaal craton, resulted in minor sinistral strike-slip reactivation of the N-S striking fault system, the formation of extensional NNW-SSE striking fracture/fault zones and the development of ENE-trending F3 folds forming a F2/F3 fold interference pattern. Post-Lomanian tectonic events (eg the Pan-African Orogeny at ~650 - 500 Ma, the Cape Orogeny at ~310 - 240 Ma, and the Gondwana breakup at 205 - 120 Ma), caused only comparatively minor extensional reactivation of the pre-existing fault systems. Iron mineralisation was ultimately preserved from erosion by Kheis Orogeny-related N-trending F2 synclines and Lomanian Orogeny-related ENE-trending F3 synclines, in particular areas of interference between F2 and F3 synclines representing comparatively deep semi-circular trough- like depressions, as well as in half grabens formed adjacent to reactivated westerly dipping N-S normal faults. Support for relating the iron and manganese mineralisation to structurally controlled hydrothermal fluid flow during the Kheis orogenic event has also been found, and ongoing research is aimed at confirming and refining the hydrothermal model for iron ore mineralisation in the Northern Cape.

Jan 1, 2007

By J Boland

Polycrystalline diamond compacts (PDC) have been widely used as cutting elements in the drilling tools for the oil, gas, civil and mining industries because of their faster penetration rates and longer bit life. US Department of Energy reports that PDC bits account for more than one-third of the total footage drilled worldwide (US Department of Energy, 2004). However, non-thermally-stable diamond composites (NTSDC) have seldom been applied to geothermal drilling, since premature failures of such PDC cutters have been observed in hard rock formations. Several factors need to be considered to prevent premature failure of cutters and improve cutting performance when using PDC-based bits and other rock cutting tools. The first set of factors consists of the strength, density, stiffness, toughness and thermal resistance of the PDC and the rock. A second set relates to the complex behaviour of the bonding between the PDC cutter and the bit matrix, or the pick and the pick holder, which is vital in maintaining stable, reliable and durable adhesion of the cutters to their hubs. Finally, based on a better understanding of the cutting processes, the formulation of a predictive model would assist in further development of cutter design.

Jan 1, 2004

The key to the successful debt funding of a new mining project, whether in economically established or developing nations, is the submission of a comprehensive feasibility study. The feasibility study forms the basis from which the resource banker can construct financial models which govern the amount of available funds, the conditions which control the supply of such funds and the time period over which the loan may be repaid. The bank will wish to ensure that the feasibility study is the best representation and confirmation of reality possible because this model is the basis of the loan security package. Thus the study will be vigorously interrogated by independent experts in all its elements including the ore reserve, mineability, metallurgy, operating and capital cost profile, environmental factors and management.

Jan 1, 1995

By C Lutherborrow

The Sangdong Tungsten/Molybdenum Deposit is located in the Republic of Korea and was discovered in 1916. At this time Korea was a colony of Japan. It was mined for two years after discovery closing in 1918. Full production recommenced in 1933, and from that point until 1945, it was the major source of tungsten for armour plate for the Japanese military. After World War 2 the US government ran the mine until late 1946. The mine operation then passed to Korean ownership but production ceased during the Korean War and did not recommence until late 1953. The mine ceased operation in 1992 due to low metal prices. From the late 1960s to the time of closure, Sangdong was the largest tungsten mine in the world (Kim, 2002). An understanding of changing mining methods over time has been critical in assessing the potential of redeveloping the Sangdong Deposit.

Aug 22, 2011

By Taylor G. H

The proposed classification scheme is based on two primary parameters, one for petrographic composition and the other for rank, both being determined with microscopical techniques. The scheme has been applied to a wide range of Australian coals and found to provide a useful means of relat- ing their inherent properties to properties such as volatile- matter yield, crucible swelling number, and calorific value, which will determine how these coals might be used coimierciallyti,

Jan 1, 1969

A critical appraisal of the wide variety of processes used in the pyrometallurgical production of metals and non-metals shows that there is a strong physico-chemical and, in particular thermodynamic, basis for the variety. Based on this, a simple classif- ication scheme has been developed which makes it possible to understand the methods for extracting individual metals and non-metals pyrometallurgically and to assess which are the more attractive routes. The analysis presented shows why there are essentially two broad routes for pyrometallurgical production of metals and non-metals; viz., the reduce- refine and the refine-reduce routes. Halides have the role in pyrometall- urgical processing of producing pure compounds for subsequent reduction. The criteria which determine the selection of reduction method for oxide raw materials and intermediate halides (e.g., use of carbon, hydrogen, a more reactive metal or electrowinning) are examined critically in the paper. The treatment of sulfide raw materials is considered also, particularly the criterion for smelting sulfides directly to the metal.

Jan 1, 1987

While sampling techniques used by the mineral industry continue to improve, sampling is still an area which is often neglected. It is often left to personnel who do not fully appreciate the significance and importance of sampling. Yet sampling and sample processing are of vital importance. There is little point in making major capital investments in the latest analytical equipment and spending considerable time obtaining the best analytical precision, if the sample provided for analysis is seriously biased in the first place.

Jan 1, 1976

By C Grobler, M Recklies, G Jiang, I Taylor, M Morgan, G MacDonald, L Smith

The resource estimation of lateritic deposits, such as Aurukun, presents specific issues related to the lateral changes in thickness and elevation of the various horizontal layers (or zones) within the deposit where the x and y dimensions are orders of magnitude greater than the z dimension. The objective was to develop a three-dimensional (3D) block model that retained the vertical and lateral variation inherent in deposits of this type to allow full optimisation of the production plan without prior selection of an economic portion (enriched bauxite layers) of the profile at the resource estimation stage. The Aurukun bauxite deposit is held by Chalco Australia Pty Ltd (Chalco) and forms part of the world-class Weipa bauxite province, Cape York Peninsula, Queensland, Australia. The bauxite is predominantly pisolitic with an upper boehmite-rich zone and lower gibbsite-rich zone. The bauxite consists of both in situ and reworked domains, is overlain by a thin soil horizon and has kaolinite clay as a transitional base. A portable infrared mineral analyser (PIMA) was utilised on site, in addition to elemental assay, on each drill sample to determine the mineralogy, in particular levels of boehmite, gibbsite, kaolinite and reactive silica. As part of the scope of work, a field program was undertaken using large diameter Boart Longyear sonic drilling to acquire detailed density measurements across the deposit to allow compliance with Joint Ore Reserves Committee (JORC) reporting requirements. Interpretation of the stratigraphy was conducted on a hole by hole basis with definition of the zone layering based on stratigraphy, geochemistry and mineralogy. The zone boundaries were then modelled as 3D surfaces and used to constrain a block model. The block model estimation used the ordinary kriging method, with the estimation done in unfolded space and then refolded, therefore maintaining the zones irrespective of thickness or orientation. The unfolding process converts the real-world positions for both blocks and informing samples to a scaled position relative to the roof and floor of each zone. Analysis of the data and variography were also undertaken in unfolded space. The x and y dimensions are unchanged, but the z dimension is a relative position. The effect of the unfolding and limits on number of samples per hole is to æpushÆ the informing sample search sideways but within the stratification, rather than vertically. This honours the strong vertical zonation within the bauxite profile. The JORC Code requires that the stated resource must have æreasonable prospects for economic extractionÆ. This is a qualitative rather than quantitative definition. A number of selection criteria to define a resource roof and floor were developed in consultation with the project engineers and owners to meet these criteria. The vertical selection of material to include in the resource highlights the variation in the development (and destruction) of the bauxite profile from area to area within the deposit.

Jan 1, 2009

By Kay JR

In 1984 a new Regional Geological Mapping Program (RGMP) was commenced by the Geological Survey of Queensland (GSQ); the new program was in response to the withdrawal of the Bureau of Mineral Resources from regional mapping. Areas for mapping were selected in northern and south-eastern Queensland on the basis of potential for mineral discoveries, level of company interest, inaccuracies in the first edition mapping and interests of other organisations (government and universities) in joint projects.Geological provinces of particular interest in northern Queensland are the Hodgkinson Basin, parts of the Georgetown Inlier not covered by earlier BMR-GSQ mapping, Broken River Embayment, Burdekin Basin, Lolworth-Ravenswood Block, Campwyn Block and Anakie Inlier. The 1:250,000 sheets covering these areas of interest are shown in Figure 1 including those already completed, those in progress and those planned for future investigation.A flow chart showing the various phases for RGMP projects is shown in Figure 2. Data collection has two facets: (i) field recording and (ii) office work including air photo interpretation, study of company reports, literature research, petrography and various laboratory studies. Two main strands of information collected are represented by a data base and compilation sheets. Compilation sheets are generally at 1:25,000 scale and are available for purchase. The current data base is very fragmentary and can be accessed only by direct contact with the relevant geologist or via written reports. A more accessible field data base is in the process of being introduced this year; this field data base (REGMAP) is based on standardised data recording and computer storage.

Jan 1, 1986

By Azizan A

The paper presents the results of chlorination of beneficiated rutile and struverite (a tantalum-niobium bearing, rutile type mineral in alluvial tin deposits) by carbon tetrachloride in the range 623¦K to 773¦K. The chlorination of rutile could reach near completion at 773¦K in about an hour. The process was found to follow a modified pore-blocking law, with the basic reaction constant K varying inversely with the particle size, so that the basic process may be a reaction under interface control (chemical control) as modified by the pore blocking effect. The pore blocking factors for the various experimental conditions were evaluated and the predicted curves showed good agreement with the experimental data. In the case of Struverite, a similar kinetic behaviour was observed but the chlorination process was relatively slower than that in rutile. It was also observed that in struverite, niobium got chlorinated faster, followed by tantalum and titanium, indicating a good possibility of separation by chlorination using carbon tetrachloride.

Jan 1, 1996

By Matsumura T, Takematsu T

The Brown Coal Liquefaction Process (BCL Process) has been developed by Nippon Brown Coal Liquefaction Co., Ltd. (NBCL), and a 50-ton-per -day Pilot Plant has been partially completed and put into operation by Brown Coal Liquefac- tion (Victoria) Pty., Ltd. (BCLV) at Morwell, Victoria, Australia. This Project has been sponsored by New Energy Development Organization (NEDO), an or- ganization associated with MITI, and has been promoted as a National Project with funding by the Japanese government. This project has also been conducted as a cooperative technology de- velopment project between the Japanese and Aus -tralian governments since 1980 and has been supported by the Victorian state government and

Jan 1, 1987