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By J. R. Mihalisin

THE application of electron-microscopic techniques to the study of high-temperature alloys has met with considerable success.' This is due, in part, to the submicroscopic nature of the phases present in this type of alloy making high resolution methods necessary. Among the newer electron-microscopic techniques, the extraction replica technique' has proven to be of great value. This method allows phases to be examined in situ in the microstructure and permits their identification by means of electron diffracticn. This technique eliminates the main disadvantage in using electrolytic extraction of residues as a means of phase identification; that is, the uncertainty of relating constituents identified in the residue to what is observed microscopically. In the course of work relating microstructure to physical properties in high-temperature alloys, it was found that the formation of grain-boundary carbide phases and intragranular precipitation of an age-hardening phase greatly influence strength and ductility at high temperature. In particular, it was found that the formation of a unique type of precipitate in Nimonic "80" (a nickel-chromium-aluminum-titanium type superalloy), termed cellular or discontinuous precipitate, at grain boundaries generally results in poor ductility at high temperature. However, this mode of precipitation can be avoided by proper heat-treatment. It was assumed that this precipitate was either a carbide or age-hardening type of phase. Using various etching procedures with the extraction-replica technique, it was found to be possible to extract the carbide and age-hardening phases preferentially in this type of alloy. Previous work has shown that the age-hardening phase can be extracted from superalloys merely by

Jan 1, 1959

By Leon Dominian

I. INTRODUCTION APART from local needs in the country's development, the interest attached to Turkish fuels grows chiefly out of the importance of the railway industry in Asiatic Turkey. Geographical conditions make of the tracks in this region the most essential link in a chain of world-girdling lines. By its position Asia Minor can be likened to a bridge in the through routes destined to connect European factories with Asiatic and African markets. An uninterrupted right-of-way from points in central Europe to populous Indian cities must necessarily pass through the valleys A Anatolia. Crossing thence the Taurus Mountains its natural passage is indicated as the Mesopotamian lowland and the shores of the Indian Ocean. Similarly land connection between Europe and Africa can be obtained only by passage through Asia Minor, Syria and Palestine. The occurrence of fuel within an area of such significance from the

Jan 6, 1916

Jan 1, 1898

By William E. Ford, Edward Salisbury Dana

447. Minerals, as regards their chemical constitution, are either the uncombined elements in %native state, or definite compounds of these elements formed in accordance with chemical laws. It is the object of Chemical Mineralogy to determine the chemical composition of each species; to show the chemical relations of different species to each other where such exist; and also to explain the methods of distinguishing different minerals by chemical means. It thus embraces the most important part of Determinative Mineralogy. In order to understand the chemical constitution of minerals, some knowledge of the fundamental principles of Chemical Philosophy is required; and these are here briefly recapitulated. 448. Chemical Elements. - Chemistry recognizes about eighty sub- stances which cannot at will be decomposed, or divided into others, by any process of analysis at present known; these substances are called the chemical elements. A list of them is given in a later article (452) ; common examples are: Oxygen, nitrogen, hydrogen, chlorine, gold, silver, sodium, etc.

Jan 1, 1922

By Milton H. Ward

This paper contains a review and discussion of the major design parameters of a block caving mine, with special attention given to access, development, and operational methods. Information will be provided on the economics and costs of various design alternatives, and how they can influence financial results of a particular project. Technical and economic factors that pertain to an actual operation, Freeport Indonesia, Incorporated's block caving mine in Indonesia, will be provided, and highlights of the planning, development and operation of this mine will be presented. The major thrust of the paper will be to emphasize the importance of good planning and to encourage economic analysis of various methods of layout and design.

Jan 1, 1981

By T. B. Crowe

MucH has been written upon the precipitation of metals from cyanide Solution by zinc. We often read of the many factors that influence precipitation, such as zinc surface, purity of zinc, percentage of lead, temperature of solutions, strength of solutions in cyanide or alkali, etc. -Little do, we hear, however, of the part that oxygen plays in precipitation. Caldecottl says: "As the dissolving of gold is essentially an oxidation process, so its precipitation is one of reduction." All who have studied or worked with cyanide solutions will agree that Caldecott's statement is true.' . In the cyanide work in the mills of the Portland Gold Mining Co., we have always found oxygen to be the greatest enemy to precipitation. Oxygen Antagonistic to Good Precipitation A few years ago, while making some experiments on the effect of pressure upon the dissolving rate of gold from our ores, to prove a point, I made some bottle tests under vacuum. The results were surprising, and showed that under vacuum practically no gold dissolved, which confirmed my belief that Elsner's equation was true and also led me to investigate the amount of dissolved air carried by solutions at atmospheric pressure. The experiment consisted in partly filling an acid-bottle with mill-solution and connecting it by a rubber hose to a vacuum pump. When the vacuum was suddenly applied, a cloud composed of thousands of small air bubbles rose out of the solution, showing qualitatvcily' the amount of dissolved air that was contained in the solution, and also proving that the relief of atmospheric pressure on the solution permitted this dissolved air to escape. In studying literature on the subject, we find Henry's law—"The amount of gas dissolved by a liquid is proportional to the pressure to which the gas is subjected."

Jan 1, 1919

National Society of Professional Engineers has thrown its full sup- port behind pending legislation to appropriate $500 million for national conversion efforts that would provide employment opportunities for engineers, scientists, and technicians who are currently unemployed because of the decline in defense and aerospace programs. Known as the Davis-Giaimo bill, the proposed legislation would raise total Federal investment in science and technology to an adequate annual spending level and keep it proportionally equal to the growth in the GNP. If passed, the bill would increase and maintain Federal obligations for civilian-oriented research and development activities to a parity level with similar obligations for defense research development. U. S. Bureau of Mines has cataloged and placed on open file an inventory of U.S. coal deposits which can be economically strip mined at today's production costs. The costs include charges for reclaiming the mined land as required by 21 states. The report claims that some 46 billion tons of bituminous coal and lignite can be strip mined under present economic conditions, and that 32 billion tons of the total is classified as having less than 1% S. The report reviews strippable coal deposits by state, by county, by coal seam, by coal-seam thickness and by sulfur content. The report also gives an up-to-date summary of state laws on surface mine reclamation. Open-file copies of "Strippable Reserves of Bituminous Coal and Lignite in the U.S." may be consulted in Washington, D.C., at the Department of the Interior library and at U.S. Bureau of Mines offices in Pittsburgh, Denver, San Francisco. Dallas. Spokane, and Douglas Island, Juneau. Alaska.

Jan 1, 1971

By Albert Hahn

ABOUT three years ago John Hays Hammond took over the control of the Eureka Metallurgical Co., at Salt Lake City, Utah. Funds were advanced for investigating the process invented by R. V. Smith, for concentrating oxidized lead ores. A great deal of laboratory work was done and a reagent was developed by C. M. Nokes of Salt Lake, which was found to be particularly suitable for oxidized copper ores, refractory manganese silver ores, and oxidized gold ores. After sufficient laboratory work had been performed to demonstrate the fundamental principles of these inventions, a test mill, having a capacity, of 20 tons of ore daily, was erected at Murray, Utah. In this test mill approximately 1200 tons of various types of ores have been concentrated by means of the above-mentioned process and reagents, and this large-scale work as well as laboratory work is being continued at present. Details of these mill tests are given in Table 1, and a representative group of laboratory tests are shown in Table 2. The process requires no special machinery or appara-tus. Its success depends entirely, on the method of preparing the pulp and its subsequent flotation in clean water, as outlined in the Smith patent. The reasons for the success of the Nokes special reagent are not definitely known. The outstanding feature, which seems to be of extreme importance, is that when the concentrates are examined under the microscope, each particle of mineral appears to have a particle of paraffin, attached to it. This paraffin-mineral combination seems to be particularly suitable for flotation and it follows that any coating oils readily attach themselves to the paraffin-mineral combination.

Jan 9, 1923

By Alan U. Seybolt

UNLIKE its sister elements, columbium (niobium) and tantalum, vanadium has not been available until recently in fabricated form. While Vanadium Corporation of America has offered the metal in fairly pure form for sale for many years in small lots for research purposes, this grade of vanadium has been brittle, probably because of a high oxygen content. Hence, when in 1950 the announcement1 was made that wrought vanadium was available as a commercial material, this represented a large step forward in the metallurgy of vanadium. While vanadium is generally regarded as a rare metal, data on its occurrence in the earth's crust show it to be as abundant as copper, zinc, and lead combined. Vanadium is widely distributed, but it does not seem to occur in massive deposits except in a few localities, principally in Colorado, Utah, and Arizona, where it is found in sandstone formations, and in Mina Ragra, Peru. Only in Colorado or Peru are ores mined solely for the vanadium content. Ores in the United States are principally carnotite and roscoelite; the former is of particular interest because of its uranium content. It is a uranium-potassium vanadate containing approximately 52 pct of UO2 and 18 pct of V2O5. Production in the United States during the war years averaged around 2000 tons a year, but dropped to 636 tons in 1946. In recent years, ferrovanadium has been selling for about $2.80 per pound of contained vanadium. This suggests that the price of the pure metal will never be as low as $2.80 per pound, but it could

Jan 1, 1953

By Alan Stanley

R. T. Hukki (Finland Institute of Technology, Helsinki, Finland)—In the analysis of mill products containing minerals of appreciable difference in specific gravity the well-known principle of the method described by Stanley is applied in a number of ways for a variety of problems. The use of Le Chatelier bottle as explained in the paper may be a dependable and sufficiently accurate way, although no information is given as to the reproducibility of the specific gravity determinations. In the case of MacIntyre ore the method is applied for three separate products produced apparently without reagents and relatively free of fine slimes. Should it be applied for flotation products carrying a substantial amount of slimes, difficulties should be anticipated in the process of eliminating air inclusions from the sample. The difficulties mentioned above may be overcome by the use of a volumeter, an instrument designed for specific gravity determinations of finely divided solids in dry state. This instrument, see Fig. 4, is manufactured by F. Süffert-Bürner A. G. in Basel, Switzerland. Its operation is based on the law of Boyle and Mariotte. With the use of the volumeter, the specific gravities of test samples having a total volume of about 30 cm are easily reproducible within ±2 units in the second decimal of the specific gravity figure, and even better than that with utmost care. This accuracy is sufficient for ordinary operational control. How closely the specific gravity determinations follow the respective chemical assays depends primarily on the nature of the sample itself. In this respect no specific gravity instrument can give better results than those justified by the consistency of mineral distribution in samples analyzed.

Jan 1, 1954

By Frederic Benard

THE treatment of Balbach-Thum slimes at Copper Cliff by the Ontario Refining. Co. is of interest because it differs considerably from methods usually employed for the recovery of fine gold from parting-plant slimes. Owing to the comparatively high percentages of pal-ladium and platinum, wet methods are used to remove the greater proportion f these metals before electrolytic refining in the Wohlwill cells. THE PLANT The platinum-metals department, Wohlwill room, and gold-melting room extend along the north side f the silver refinery and are separated from the parting plant by a glass partition (Figs. 1 and 2). The platinum-metals department resembles a laboratory built on a large scale, with the various pieces of equipment laid out on terraces to facilitate handling. Because of the corrosive nature of the solutions, chemical stoneware is used throughout. Elevation of acids is accom-plished by means of Mariotte bottles. On the top level are three steam-jacketed stoneware kettles of 50-gal. capacity, also a packed tower. One kettle is used for digesting the slimes while the remaining kettles are used for precipitating the gold. The dissolver is equipped with a treated concrete hood, which is connected to the flue system. Gases are drawn off through the packed tower by means of a 6-in. stoneware exhaust fan. A 15 per cent solution of sodium carbonate is continually circulated through the tower. On the intermediate level are two suction filters, one for removing silver chloride and the other for the gold sand. The filter medium consists of an asbestos pad covered with a filter paper on which is a layer of twill.

Jan 1, 1938

By J. R. CAIN

SAMUEL L. HOYT, ? Nela Park, Cleveland, Ohio (written discussion?). The work that Dr. Cain is doing on gases in steel should have a highly important bearing on investigational work in connection with steel-making practice. We found, for example, in our work in connection with the use of manganese in open-hearth practice that we needed expressions for the manganese efficiency and the "condition" of the steel. To get these figures we assumed that we would need to know the amount of FeO at different stages of the heat and the amounts of the gases present. This required simultaneous analyses of our samples for FeO and the gases and Dr. Cain seems to be the only investigator who has considered the analytical work from this point of view. That he has done so is very encouraging and it is to be hoped that his work will solve the mys-teries now surrounding this neglected phase of steel metallurgy. Those interested in the Ledebur method for use in connection with the efficiency of manganese as a "deoxidizing " agent will he disappointed to learn that more recent work at the Bureau indicates that Ledebur determinations are not reliable. The principal source of error seems to be due to the partial reduction of the ferrous oxide by the carbon present in the steel. However, it seems like an unnecessary criticism of the Ledebur method to state (p. 1319) that it proved of little value because it showed little differences in oxygen for a series of steels treated with ,various reagents and showing variations in physical properties and free-

Jan 12, 1919

By C. L. Meyers, J. L. Lytton, T. E. Tietz

The recovery of tensile flow stress of 99.995 pct A1 under conditions of elastic strain and plastic creep straining was investigated using a fractional recovery parameter. Tensile straining was conducted at room temperature to a true strain of 0.10, and recovery treatments were made under stress in the temperature range from 80° to 198°C. Whereas elastic strains had no appreciable influence on flow-stress recovery, plastic creep straining was found to accelerate the recovery process. Although higher creep stresses gave greater recovery for a given time and temperature, it was found that lower stresses produced greater recovevy at equal ALTHOUGH many studies have been made to date on the recovery of metals from the cold-worked creep strains above about 0.005. This effect was attributed to the coarser, and therefore weaker, substructure developed during creep at the lower stresses. The activation energy for recovery during creep straining at 2075 psi between 160" and 198°C was found to be 25,000 cal per mole. This value was not significantly greater than the value previously obtained for no-load recovery. The activation energy for creep at 2075 psi between 160" and 198°C was 34,000 cal per mole, a value significantly greater than that for recovery under the same conditions. state, little is known concerning some important aspects of recovery behavior. One such area is the effect concurrent strain has on the recovery process. Since metals in structural applications at high temperatures are under stress, the possible effects of the resulting elastic and plastic strain on recovery may be of significant importance.

Jan 1, 1962

By C. B. Foraker

THE Magma mine, of the Magma Copper Co., at Superior, Pinal County, Arizona, is 68 miles east of Phoenix and 21 miles west of Miami, Arizona, on highway U. S. 180. Temperatures and Underground Waters Surface Temperatures.—The average surface dry-bulb temperature at Superior is 72.4°; wet-bulb, 57.4°; with an indicated relative humidity of 38 per cent. The average yearly rainfall from 1921 to 1936, inclusive, was 18.74 in. The maximum condition of the atmosphere is in June, July and August, and the minimum is in January and February. The surface temperatures, of course, influence the temperatures of the downcast shafts; however, the variation between winter and summer causes a difference of only 2" to 3" in the stopes and working places that are not close to the intake shafts. Average atmospheric conditions are shown in Fig. 1. Rock Temperatures.—Rock temperatures on the deeper levels of the mine are as follows:

Jan 1, 1940

By Robert Mehl

THE mechanical behavior of metals and alloys is presumably conditioned by two factors; namely, the crystalline symmetry and the interatomic forces. Considerable attention has been given to the first of these factors through the recent advances in X-ray .technique. It is the purpose of the present paper to call attention to the importance of the second of these factors, to point out promising methods of investigation, and to present some pertinent data. Plastic deformation takes place by-slip along atomic planes.1 This slip may be inhibited in a number of ways: by the interatomic forces of cohesion which bind the atoms rigidly in a lattice structure, which in pure metals is usually of high symmetry; by lattice distortion caused by solid ,solution formation or by mechanical strain; by the intercrystalline boundaries where slip is restrained by the non-registration of the atom planes in adjacent crystallites;2 and by the presence of small hard particles which serve to "key" the slip along the atom planes.3 In pure metals, and perhaps also in solid solutions, the atom planes, of easiest slip are those exhibiting the greatest density of atomic population and the greatest interplanar distance4 and apparently can now be predicted from the analysis of the lattices. Concerning the interatornic forces, which resist this slip by holding the atoms firmly together, little is known. Most textbooks on physical metallurgy, following the work of Bot-tone,5 correlate the hardness of the pure metals with the atomic volume;.

Jan 1, 1928

By W. S. Steele

Vermiculite is a nonmetallic mineral of the mica family, probably related to biotite mica. Its occurrence has been noted at numerous places in the United States and in some foreign countries, but it can be said that vermiculite is of only moderately wide distribution. A laboratory and field survey of over 60 deposits in the United States by F. 1;. Schundler & Co., of Joliet, Ill., indicates that the purest deposit represented in this survey is on the property of the Zonolite Company at Libby, Montana The Zonolite Company is commercially active and the vermiculite it produces is sold as Zonolite. Hereafter, in this report, the word "Zonolite " will be used to designate the vermiculite produced by the Zonolite Company. Values given herein to Zonolite are peculiar to the vermiculite produced from the Zonolite Company's deposits. References to " vermicullite," are to he interpreted as covering the broad field covered by the Schundler survey. Composition and Characteristics of Vermiculite Vermiculite is an aluminum-nmgnesium silicate. The following typical analysis is published by the United States Bureau of Standards: silica, 41 per cent; iron oxide, 7; aluminum oxide, 18; magnesium oxide, 21; calcium oxide, 1; alkalis (sodium and potassium), 1; moisture, 11. Vermiculite breaks down into platelike formation in crushing and grinding operations. Its cleavage is basal. Crude, screened, dry Zonolit,e weighs between 80 and 90 Ib. per cubic foot; its specific gravity is 2.8 and its specific heat is approximately 2. The fusion point of Zonolit'e is 2462" F. Crude vermiculite contains between 7 and 9 per cent of chemically combined moisture. The instantaneous introduction of crude Zonolite into an expansion furnace at a temperature of between 1800" and 2000" F. transforms the combined moisture into steam, which in an effort to liberate itself forces all explosive expansion of the platelike crude material

Jan 1, 1934

By R. S. Hutton

Jan 1, 1937

By William E. Ford, Edward Salisbury Dana

The NATIVE ELEMENTS are divided into the two distinct sections of the Metals and the Non-metals, and these are connected by the transition class of the Semi-metals. The distinction between them as regards physical characters and chemical relations has already been given (Art. 453). The only non-metals present among minerals are carbon, sulphur, and selenium; the last, in one of its allotropic forms, is closely related to the semi-metal tellurium. The native semi-metals form a distinct group by themselves, since all crystallize in the rhombohedra1 class of the hexagonal system with a fundamental angle differing only a few degrees from 90°, as shown in the following list :

Jan 1, 1922

By C. B. Foraker

THE Magma mine, of the Magma Copper Co., at Superior, Pinal County, Arizona, is 68 miles east of Phoenix and 21 miles west of Miami, Arizona, on highway U. S. 180. Temperatures and Underground Waters Surface Temperatures.—The average surface dry-bulb temperature at Superior is 72.4°; wet-bulb, 57.4°; with an indicated relative humidity of 38 per cent. The average yearly rainfall from 1921 to 1936, inclusive, was 18.74 in. The maximum condition of the atmosphere is in June, July and August, and the minimum is in January and February. The surface temperatures, of course, influence the temperatures of the downcast shafts; however, the variation between winter and summer causes a difference of only 2" to 3" in the stopes and working places that are not close to the intake shafts. Average atmospheric conditions are shown in Fig. 1. Rock Temperatures.—Rock temperatures on the deeper levels of the mine are as follows:

Jan 1, 1940

[NOTE.-The following discussions of papers contained in this volume are printed without regard to order of succession. It has been impracticable to secure from the various parties, corrected reports of their contributions in time to effect any particular desired arrangement in this respect. The papers of Messrs. Pourcel, Osmond and Sauveur, were considered at Chicago together with others of cognate character ; and the whole discussion will be found in vol. xxiii., under the head, " Physics of Steel."]

Jan 1, 1894