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By John P. Hager, Igor A. Wilkomirsky

The thermodynamic properties of the Pb-Ag system have been determined between 775° and 950°C by the cell: Electrotransport measurements on silica-saturated PbO-SiO2 melts established that the conduction was entirely ionic and that lead is present only in the divalent state. The activities of lead and silver exhibit Positive deviations from ideal behavior. In dilute solutions the activities of lead and silver follow Henry's law. The values obtained for yhb and yig at 1200°K are 1.49 and 1.69, respectively. Determination of a portion of the liquidus curve agrees well with the established phase diagram. provides an accurate means for the thermodynamic study of liquid alloy systems. However, Wagner and wernerl have shown that cells of type I are limited to alloy systems for which the reaction at the alloy-electrolyte interface will be extremely small. The traditional electrolyte for cells of type I has been a low melting point mixture of group IA chlorides, to which a small amount of the compound ACIZa has been added. However, the choice of a chloride electrolyte may not always be practical, in that the Gibbs free energies of formation of the compounds ACIZ, and BCIZb may not be sufficiently different to minimize Reaction [I]. On the other hand, the Gibbs free energies of formation of the oxides of metals A and B may be sufficiently different to minimize Reaction [I]. In this case, the use of molten oxide electrolyte would be clearly advantageous. In the present study, the thermodynamic properties of the Pb-Ag system have been investigated using the cell: Previous galvanic cell studies on the Pb-Ag system2'= are not reliable due to the displacement reaction between the alloys and the chloride electrolyte. Wagner and ~erner,' using Laitinen and Liu's' value at 450°C for the standard electrode potential of Reaction 111, have estimated the percent error in the activity of lead bPb) when using a chloride electrolyte. At 1000°C the error for xpb = 0.10 is 12 pct. Taking the Gibbs free energies of formation for PbClz and Ag cI,' and the equations of Wagner and Werner,' the error in apb at 1000°C and Xpb =0.10 was calculated to be 140 pct. However, using the Gibbs free energies of formation for Pb O' and an estimated value for Ag 20, the error in apb when using a molten oxide electrolyte at 1000°C was estimated to be less than 1 pct for The virtual reaction of cell I1 for the passage of n Faradays of positive electricity from left to right in the cell is: where 5 is the Faraday equivalent (23,063 cal per v equivalent), E is the electromotive force of the cell in volts, and n is the number of Faradays of electricity required for the transfer of 1 g-atom of lead through the cell. The value of n should be equal to 2 since lead is generally divalent in oxide melts. However, the presence of either tetravalent lead ions or electronic conductivity through the molten oxide electrolyte will result in a value of n greater than 2. Bockris, Kitchener, and Davies' have determined the amount of ionic conductance in a liquid PbO-SiO2 mixture (xPbO= 0.50) at 920°C by measurement of the volumes of CO and C& evolved at a carbon anode during electrolysis. From their data a value of 2.13 * 0.16 was calculated for n. Although their measurements indicate the possible presence of multivalent lead ions and/or electronic conductivity, their measurements were not at silica saturation and no definite conclusions can be drawn. However, as a result of the electrotransport measurements described in the next section the ;due of n can be taken as equal to 2.

Jan 1, 1969

By E. P. Youngman

The rapidly growing demand for titanium pigments has aroused new interest in actual and potential sources of supply of titanium- bearing ores , which only a comparatively few years ago were almost unmarketable . This paper , which supplements a general circular entitled " Titanium" ( Information Circular 6365 ) , represents a summary of current trade literature and Government reports , together with some hitherto unpublished material that has accumulated in the files of the Bureau of Mines . The purpose of this pamphlet is simply to indicate the commercial possibilities of the deposits , and the discussion is confined almost entirely to the three commercial ores , ilmenite , rutile , and magnetite ( titaniferous iron ore ) .

Oct 1, 1930

By Thomas Novak, Sampurna Arya, Joseph Sottile

Dust generation and its dispersion in a longwall mine pose significant health and safety issues. The concern is prominent at both the working face, where coal excavation exposes workers to high dust concentrations, and also in the return, where float dust accumulates. To address this issue, researchers at theUniversity of Kentucky designed and fabricated a flooded-bed dust scrubber integrated into a full-scale physical model of a longwall shearer. This mock-up was installed in the longwall test gallery at the Pittsburgh Research Laboratory (PRL) of the National Institute for Occupational Safety and Health (NIOSH). A full-factorial experiment was designed to measure the effectiveness of the scrubber on dust capture. Test results indicated dust reduction of up to 57% in the return airways. This paper presents the development of a computational fluid dynamics (CFD) model and its validation by comparing the simulation results against the experimental results. The CFD simulations show good agreement with experimental results with differences between + 6.9 and − 9.7%. The validated CFD model was used further to predict the scrubber performance under additional operating conditions, resulting in a dust reduction of up to 66.5%. With this level of success, the scrubber concept can be a game changer for the mining industry, and it can be utilized to improve health and safety in longwall mines.

May 26, 2020

This publication contains four papers presented at a seminar on mine subsidence control held in Pittsburgh, PA, on September 19, 1985. The seminar was designed to keep the mineral industry informed of new technology developed by the Bureau of Mines that permits reliable and accurate prediction of mine subsidence. The papers describe actual field studies undertaken by the Bureau to monitor surface subsidence over longwall panels. Topics discussed include the efects of subsidence on water table levels, the development of subsidence pre calculation methodology suitable for use with the specific lithological conditions of the Pittsburgh coalbed, an engineering comparison of technologies used in surveying for longwall mine subsidence, and a comparison of the process of subsidence over two different longwall panels.

Jan 1, 1985

By Robert L. Kranz

The U.S. Bureau of Mines (USBM) has been monitoring and studying seismic activity associated with mining in the Coeur d'Alene silver district of northern Idaho. New statistical methods of studying the stope-scale (1-to l00-m) seismicity at one Idaho silver mine are used in this report (part 1) and its companion (part 2). This report deals with methodology and its limitations. The recent concept of fractals and their seismological use is discussed and applied to mining-induced seismicity. Three types of fractal studies are addressed: spatial analyses (including temporal changes of spatial patterns), temporal analyses, and size analyses. Other statistical measures of mine seismicity are also addressed: event mean location, inter-event distance distribution skewness, temporal coefficient of variation, nearest neighbor and next event statistics, and event location planarity patterns. Each of the methodologies discussed (fractal and nonfractal) is presented using sample data from two stopes in the mine. It is shown that stope-scale, mining-associated microseismicity has a fractal nature. The usefulness of demonstrating fractality (scale invariance) for predictive or descriptive purposes depends on recognition of the factors affecting the calculation of fractal dimensions. Several methodological traps are illustrated that can lead to an incorrect conclusion.

Jan 1, 2010

By K. H. Concannon, K. I. Hindle

"The use of simulation modeling in the primary metals industry (including mining, smelting, and metals processing) is expanding as significant cost-benefits can be realized by companies employing capital intensive processes. The economic scale and complexity of operations found in this industry is well-suited to applications using this ""what-if' computer modeling technique, ranging from proof-of-concept projects to testing facility design or configuration, and determining resource requirements. More recently this technique is being used to support on-going planning and scheduling for operations using the simulation as the engine to derive the best schedule. With increased computer processing capability, deterministic models are now being developed to capture the workings of a production system or conversion process, allowing real-time monitoring and scheduling of these operations. This paper presents a sample of some recent discrete-event simulation modeling applications that demonstrate the capability and benefits of this technique in the primary metals industry. These include the use of simulation to support the long-range planning of underground mining operations; the modeling of a metals supply chain network that employs a multi-modal distribution system; the scheduling of a metals coil finishing process using a deterministic simulation model; and a more detailed description of the use of simulation to model furnace and converter aisle activities within a smelter operation in Northern Canada."

Jan 1, 2007

By D. A. Reynolds

THIS REPORT gives results of an investigation of the carbonizing properties of two Tennessee coals, one from the Jellico bed in Campbell County and the other from the Sewanee bed in Marion County. Jellico coal and blends with 20 and 30 percent Pocahontas No. 3 coal were carbonized at 800° and 900° C. by the BM-AGA method. Sewanee coal was carbonized by the same method at 800°, 900°, and 1,000° C.; blends with coals of similar and different ranks were carbonized at 800° and 900° C. The coals were subjected to various physical and chemical tests, including complete chemical analyses, low-temperature assays, and agglutinating, free-swelling, friability, plasticity, and expansion tests. The Tennessee coal field is a part of the Appalachian field, which extends from northern Pennsylvania to central Alabama. The Jelico bed, one of the most important in the State, is part of the Jellico formation, which is above the Lee formation of the Lower Pottsville. Sewanee coal bed belongs to the Sewanee conglomerate and is stratigraphically lower than the Jellico bed.

Jan 1, 1953

By L. E. Djingheuzian

"IntroductionDURING the past two decades an enormous amount of empirical data has been accumulating on grinding. These data have been obtained by mill operators on grinding ores with a diversity of characteristics, and generally they have been published. However, whenever an operator, who has started milling on a new ore, has tried to find a case in literature which would exactly fit his particular grinding problem, he has failed. Evidently, something fundamental has been lacking in all these empirical data, and, as a consequence, each new operator has had to undertake his own experimenting, get the best results he can, maybe publish these results, and let it go at that. This, in the writer's opinion, has been• due to the fact that even the ablest and most inquisitive millman has been forced to look on grinding as an art, and so, except very rarely, has not been able to find the time to stop and think; if he did so, it was rather in a philosophic way, that grinding is a fundamental process, a process that takes place in river beds, on the sea shore, etc.Nevertheless, when all the data so far published are correlated and examined as a whole, one is struck with the advances that have been made in grinding. The writer (7) had made such a study in 1949, and, when the correlation was completed, it showed that there was nothing heterogeneous about the accumulated data and that when brought together they were in harmony with each other. The writer's conclusion was that, if grinding criteria were defined and were expressed in such a way as to make integration of any data into basic formulae possible, grinding would be established as a mathematically exact science, and grinding worries of the harassed mill operator would be at an end!The first attempts to rationalize comminution were made by Rittinger and Kick. However, their theories led to endless disputes which did not accomplish much, except possibly clearing the path for subsequent investigators."

Jan 1, 1952

By Noan Tonini SImonassi

Fibras de rami (Boehmeria nivea) estão entre as lignocelulósicas naturais com potencial para utilização em compósitos poliméricos. O presente trabalho avalia a resistência ao impacto deste tipo de compósito. Corpos de prova normalizados foram confeccionados com percentuais de até 30% em volume de tecido de rami alinhadas ao longo de todo o comprimento. As fibras foram embutidas sob pressão em matriz de resina poliéster do tipo ortoftálica curada à temperatura ambiente por 24 horas. Os corpos de prova foram ensaiados em pêndulo de impacto Izod e as superfícies de fratura analisadas por microscopia eletrônica de varredura, MEV. A resistência ao impacto aumentou exponencialmente com a quantidade relativa de tecido de rami reforçando o compósito. Este desempenho foi associado à dificuldade de ruptura imposta pelas fibras bem como ao tipo de trincas resultantes da interação tecido de rami/matriz de poliéster que ajuda a absorver a energia do impacto.

Aug 17, 2017

By Thiago de Souza Amaral

Os aços de alta resistência microligados ao nióbio tem se demonstrado uma solução ótima na fabricação de aços para utilização em perfis estruturais utilizando os conceitos já desenvolvidos para a indústria de gás e óleo. O nióbio com seu efeito refinador de grãos, com redução da temperatura de transformação entre austenitaferrita, endurecimento por precipitação e retardamento da recristalização da austenita, usado em equilíbrio com titânio, manganês e silício e os novos processos de produção com resfriamento controlado torna possível a obtenção de aços com microestrutura bainítica, baixo carbono e alta resistência mecânica. Este trabalho demonstra os pontos de destaque referentes ao projeto de estruturas utilizando estes aços, bem como uma avaliação quanto ao processo de soldagem durante a fabricação das mesmas. É possível evidenciar que a estrutura final se torna ideal para aplicação em diversos ambientes devido a sua baixa temperatura de transição dúctil-frágil, produção de uma estrutura com cerca de 10% a menos em peso, 5% a menos em custo e com excelente soldabilidade.

Aug 17, 2017

During fiscal year 1966 the Bureau of Mines published 99 scientific and technical papers and engaged in 67 research projects on petroleum, natural gas, and oil shale. A basic appropriation of $3.4 million was supplemented by $1 million in cooperative funds from other Governmental agencies and industry groups. Petroleum conservation was advanced by development of scientific knowledge and improvement of technologic methods in both the extraction and utilization of petroleum, natural gas, and oil shale. Experimental work was carried out at research centers in Bartlesville, Okla., and Laramie, Wo., and in laboratories in Morgantown, W. Va., and San Francisco, Calif. ACHIEVEMENTS IN FISCAL YEAR 1966 Bureau of Mines--Petroleum Research in fiscal year 1966 (July 1, 1965- June 30, 1966) was involved in many public issues--air pollution, peaceful uses of nuclear explosives, utilization of oil-shale resources, computerization of recovery-stimulation techniques, and fuels for supersonic airplanes. Scientific contributions included compositional studies of petroleum and oil shale, determination of thermodynamic properties of petroleum compounds, development of analytical techniques, and correlations of petroleum properties with geologic occurrence. Technologic advances included rock-fracturing research, in situ combustion studies, waterflood techniques, use of radio-tracers to study stability of petroleum fuels, and hydrogenation as a tool to prepare shale-oil products.

Jan 1, 1968

By B. M. Bird

For several years the U.S. Bureau of Mines and the University of Washington have been cooperating, in a study of coal tabling. The first pert of the work consisted of experiments using, one of the commercial-sized coal washing tables in the laboratories of the College of Mine. As an outgrowth of this work, hindered-settling classification has been successfully applied in the tabling of coal4, and several important improvements, mainly in the riffling, have been made in the table itself. Both of these developments have resulted in increasing the rapacity and efficiency of the coal-washing table. In order to facilitate further progress in this work an investigation has been undertaken to throw more light on the mechanism of table separation. The final separation of a table is obviously the resultant of several operations; namely, stratification, removal of the top strata or parts of them as washed coal by the cross-flowing water, and removal of the bottom strata or parts of

Jan 1, 1929

By J. E. Dooley

A mass spectral scheme of analysis was devised which can be used to identify individually a single compound from a larger group of similar compounds. Mass spectra for 32 alkyl aryl sulfides are provided for future reference work, and analytical correlations used in producing the analytical scheme are discussed. Some of the correlations show that base peaks are either the same mass as the parent peaks or may be derived from cleavage alpha to the sulfur atom with migration of one hydrogen to the sulfur atom. Other spectral consistencies provide means of separating ortho-, meta-, and paratolyl arrangements in an overall analytical scheme. Determinations of chain lengths and separation of isomeric species are also discussed.

Jan 1, 1972

By NIOSH Publications

In 2004, 14,478 mining operations reported employment statistics to the Mine Safety and Health Administration (MSHA). Almost half (48.9%) were sand and gravel mines, followed by stone mines (30.4%), coal mines (13.9%), nonmetal mines (5.1%), and metal mines (1.7%).

Sep 1, 2007

By Leonard Obert

Between 1927 and 1957, sodium borate minerals were mined by underground methods in the Kramer District, Kern County, Calif. In 1957, surface mining methods were initiated, and during the next two or more decades it is probable that most of the production from the district will be obtained from open pits. However, part of this borate deposit is sufficiently deep that surface mining may not be economical and, hence, at some future date underground methods may again be employed. This report was prepared to document the underground mining methods employed in the district before 1957. The general geology of the district and the detailed geology of each of four mine sites are presented, together with a mineral and mechanical description of the ore and enveloping rock. The report also describes the stoping, extraction, pillar support, methods of artificial support, and other factors that affect the structural characteristics of these mines.

Jan 1, 1962

By W. W. Adams

Two important facts stand out as features of the metal- and nonmetal-mining4 industry of the United States in 1941 as compared with 1940: First, the number of employees and man-days of employment increased; second, accident-frequency rates, both fatal and nonfatal, decreased. Reports from mining companies to the Bureau of Mines covering underground, open-pit, and surface operations for 1941 re¬vealed the largest number of men employed since 1926 and the largest number of man-days worked since 1929. The combined fatal and non¬fatal accident-frequency rate for 1941, calculated on a basis of one mil¬lion man-hours of exposure to hazard, was (except for 1931 and 1932) the lowest since 1911, the earliest year for which figures are available. During this 31-year period, only 1938 and 1939 showed lower fatality rates, and only 1931 and 1932 had lower nonfatal-injury rates. Operating companies reported that 9,620 mines were active during all or some part of the year. These employed 125,290 men, an increase of more than 4 percent over 1940. The total volume of work performed at all mines, measured in terms of man-shifts, increased to nearly 32 million, a gain of 10 percent; man-hours of employment rose to almost 254 million, an increase of 10 percent over the 231 million man-hours worked in the previous year. The year's operations resulted in an average work-year of 255 days per man, an increase of 13 days per employee over the average working time in 1940. Although the 8-hour day prevails generally at most mines, the industry as a whole averaged 7.94 hours per shift, as in 1940.

Jan 1, 1944

By C. Feng, W. Song, B. Moudgil, P. Zhang, W. Xiao

Separation of dolomite from phosphate is the most challenging problem in phosphate mineral processing. Over 50% of the future phosphate reserves in Florida contains too much dolomite to process using the current industry practice. The FIPR Institute has collaborated with worldwide experts in the field to address this issue. As a result, the industry is now offered with three feasible options. Optional 1 involves crushing and grinding of high-dolomite phosphate pebbles followed by dolomite flotation at slightly acidic pH using a new collector that does not require phosphoric acid as a phosphate depressant, achieving a final concentrate analyzing less than 0.9% MgO at about 87% P2O5 recovery. Option 2 offers three methods for reducing MgO content in the concentrate from the Crago process, including adding a dolomite depressant in the rougher flotation step, dolomite flotation of the cleaner concentrate, and scrubbing the cleaner concentrate in quartz sand. These methods could reduce MgO content in the final concentrate by 20-40%. Option 3 is a gravity separation technique using an innovative separation jig, and may well be the ultimate solution to the problem. INTRODUCTION Magnitude of the Dolomite Problem With the depletion of the higher grade, easy-to-process Bone Valley deposits, the central Florida phosphate industry has moved into the lower grade, more contaminated ore bodies from the Southern Extension. The phosphate deposits in the Southern Extension may be divided into two zones: an upper zone and a lower zone. The upper zone is readily processable using the current technology, but the lower zone is highly contaminated by dolomite. Geological and mineralogical statistics (Hassan and Bogan, 1994) show (Table 1) that more than 50% of the phosphate resource would be wasted if the lower zone is bypassed in mining, and about 13% of the resource would be wasted if the dolomitic pebbles in the lower zone were discarded.

Jan 1, 2019

By Filippo Maria Leoni, Wesley Schmutzler, Matteo Bertoni

"Deep Mixing Method (DMM) for the Rio Puerto Nuevo Project (Project) in San Juan was chosen by the Corps of Engineers to improve the soils adjacent to a 92 inch ID forced sewer main relocation and to improve the soils for the base of a new drainage channel. The soils to be improved consisted of sandy fill, soft clays, organics and stiff, plastic clays. A pre-construction soil investigation campaign, followed by a Bench Scale Mixing Programme and a Full Scale Field Test were performed during the pre-construction stage to assess soil properties, select binder type and dosage, and disclose the most suitable combination of injection parameters to improve the different soil layers. Production started at the end of August 2012 and was completed in October 2013; over 3,000 DMM elements were installed to a maximum depth of 57 ft below ground for a total gross volume of approximately 125,000 cubic yard. Each element consisted of two 5.5 ft diameter overlapping columns installed simultaneously, and their layout was such to meet the 100% Area Replacement Ratio required by the design. The ground improvement was successfully completed despite some difficulties due to a considerable amount of obstructions. Wet grab sampling and UCS testing of the retrieved specimens were designed as the main QC/QA method for the verification of the quality of the ground improvement. Upon completion of production, approximately 3,000 specimens were cast. The contract also required continuous coring of at least 12 randomly selected DMM elements and the testing of 8 cored specimens per bore for strength assessment. This paper will illustrate means and methods used in the field to construct the designed ground improvement and the results of the QC/QA program, with a focus on the differences between wet grab and coring sampling methods.INTRODUCTIONThe Rio Puerto Nuevo project involved the stabilization of a major drainage channel using the Deep Mixing Method (DMM), and the relocation of a 92 inch ID forced main sanitary sewer outfall. Previously, in 2004, a 40 x 16 x 2,000 ft. box culvert was installed under a different contract to convey runoff waters to the ocean.However, the connection between this culvert and the upstream network of channels was not constructed due to the presence of the forced main sewer pipe. In order for the drainage system to be completed and function properly, the 92 inch ID forced main needed to be lowered about 20 ft to allow for proper drainage.DMM was chosen by the US Army Corps of Engineers to stabilize the drainage channel as well as improve the soil under the relocated sewer main. The DMM was arranged in different zones (A through E) with variable top and bottom design elevations as can be seen in the typical cross section for Zone A (deeper and with a higher strength requirement) and Zone B as an example (Figure 1)."

Jan 1, 2015

By R. B. Hyde

"Severe drilling conditions and difficult mud problems are briefly out-lined as the major cost items in all production operations. The chief problems discussed are abnormal pressures, high temperature, trouble-some shales, and low rates of penetration. These problems have been eliminated or greatly reduced in many areas by• the proper application of recently developed drilling mud products and techniques. These severe problems and their solutions are discussed generally: the application of high-density weighting materials to overcome abnormal pressures; surfactant muds with sodium polyacrylate as a solution for deep and high-temperature drilling; shale control muds and new dispersants for severe shale problems; and low-solids emulsions and •extreme-pressure lubricants for greatly improved rates of penetration."

Jan 1, 1959

By J. Shahabpour

"Many porphyry copper deposits of the Kerman copper province in central Iran are associated with a consistent structurally con-trolled main drainage pattern, which is shown in this paper to be a useful regional prospecting tool in the search for new deposits. The main drainage trends also generally allow the distiction of high-grade (>0.2% Cu) from low-grade (<0.2% Cu) deposits. Topographic maps1:50 000 or geologic maps 1:100 000 have been found suitable for identification of promising drainages.IntroductionTrends of the main drainage systems transecting the high-grade porphyry copper deposits of the Kerman Region in Iran coincide with Quaternary age regional faults and fractures. Observation of such drainage trends can expedite regional evaluation prior to field examination. Thirty deposits located in the Kerman Region (Fig. 1) have been studied to identify common features that can be used for exploration purposes, especially for the first stage of regional exploration. A variety of field criteria are available for subsequent rapid field checking prior to trenching and more costly methods such as drilling, etc.Characteristic geomorphic features have been considered as aids in mineral exploration by many authors (e.g., Faniran, 1971; Piotrovski and Lubkashov, 1976; Verstappen, 1983). Clark et al. (1967) indicated the relationship between geomorphology and the supergene enrichment of copper in Atacama Desert, Chile, and correlated three periods of supergene enrichment with three periods of pediment disection. Seeland (1978) used fluvial drainage patterns for uranium and hydrocarbon exploration in the Wind River basin, Wyoming. Postolenko and Konopleva (1973) used the reconstruction of ancient valley systems for exploration of gold placers"

Jan 1, 1996