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By R. S. Dean

The original flotation reagents were certain oils selected for a combination of properties that occurred fortuitously. It was recognized quite early in the study of flotation mechanism that, in order to function, an oil must have an active group-one that differs from the remainder of the molecule in its affinity for water or the mineral particle. Wark4 gives credit for recognition of this elementary chemical principle to the senior author of this report.5 However, it was soon found that simple hydrocarbons could not be used as flotation reagents and that two of the functions, which were combined in the early flotation oils such as pine and eucalyptus, could be obtained in separate compounds and their relative intensity controlled to advantage. These two functions were called collecting and frothing.

Jan 1, 1944

By Henry E. Perlee

In a Bureau of Mines study two-dimensional mathematical equations were solved that describe the transient thermal response of a rock dust particle in a cloud of similar particles in a gas flame's preheat zone subject to a radiant field from the approaching flame. The description includes both radiant energy absorbed and emitted by the particle and thermal conduction inside the particle and into the surrounding gas environment moving relative to the particle. Two situations were studied; in one the radiant energy incident on the particle is converted to thermal energy at the particle surface, and in the other the radiant energy is converted to thermal energy uniformly over the volume of the particle. The result of the study showed that for a 10-µm-radius particle, a 200-mg 1-1 loading density, and a flame approach velocity of 30 m sec-1, the particle temperature rise was twice that previously calculated by Singer and Cook based on the model of Essenhigh and Csaba. It was further established that under the conditions examined a rock dust particle temperature never increases more than about 200 K before crossing the flame front.

Jan 1, 1976

By C. H. Stockwell

"The Precambrian rocks of southeastern Manitoba contain a great variety of mineral deposits, including gold, chromium, copper, nickel, lithium, tin, beryllium, tungsten, and molybdenum. Although considerable interest has been shown from time to time in each of these types of deposit, production to date has been almost entirely in gold. This has had a value of about $26,000,000 and has been derived chiefly from the San Antonio mine, with lesser amounts from the Central Manitoba, Gunnar, Beresford Lake, Ogama-Rockland, Diana, and other properties.Most of the deposits lie within volcanic and sedimentary rocks or within basic intrusions cutting these rocks. These favourable rocks occur in several areas, which have been given local names and are separated from one another by large bodies of granite (Fig. 1).In general, the several areas are characterized by different types of mineralization. Thus, the Rice Lake-Beresford Lake area contains numerous gold deposits and has yielded almost all the gold production to date; the Maskwa River, Euclid Lake, and Oiseau River areas are, on the whole, characterized by deposits of chromium, copper, nickel, lithium, tin, and beryllium; and in the West Hawk Lake area there are deposits of gold, tungsten, molybdenum, and lithium.As might be expected in a district containing such a variety of mineral deposits, the structural conditions controlling their deposition also vary greatly. It is, accordingly, convenient to discuss the structural geology and mineral deposits of each of the more important areas separately."

Jan 1, 1954

By S. J. Laskowski

In potash ore flotation, carried out in NaCI-KCI saturated brine (about 6-7 molar KC1 and NaCI solution), long-chain primary amines are used as flotation collectors. Long-chain primary amines are poorly soluble in water and their solubility further decreases at high electrolyte concentration. For ionic surfactants there is a characteristic temperature (Krafft Point, KP) below which their solubility is too low for micellization. In a previous study, the effect of pH on the KP of dodecylammonium chloride in water was determined [Q. Dai and J.S. Laskowski, Langmuir, 7, 1361-1365 (1991)]. This paper deals with the effect of electrolyte concentration on the KP of dodecylammonium chloride. The derived theoretical relationship between the KP and the critical micelle concentration (CMC) for dodecylamine can be used to calculate the KP for electrolyte concentrations of up to 0.5 mol/L (about 8% NaCI-KCI brine). A simple experimental procedure for the determination of the KP for higher electrolyte concentrations is also described. The results show that the Krafft point of dodecylamine increases from about 17-18°C (in distilled water) to about 80°C at 16% brine saturation.

Jan 1, 2006

By M. Clair Smith

The Bureau of Mines investigated the Rip Van Winkle mine, which is about 25 miles northwest of Elko, Nev., from October 1942 to February 1943 to determine possible resources of lead-zinc-silver ore. The property is owned by the Rip Van Winkle Consolidated Mining Co., which maintains its offices in Salt Lake City, Utah. Ore was discovered in the 1860's, and active mining was carried out intermittently until 1939, when the Rip Van Winkle Consolidate Mining Co. acquired the property. This company equipped and developed the mine, erected a flotation mill, and operated on a 65-ton daily basis. The ore is mined from veins, mineralized faults, and replacement deposits of wall rock. The country rock comprises cherty shale, granite, porphyry, intrusive breccia, and breccia, and brecciated shale. Mining operations were carried down to the 700-foot level. The Bureau of Mines drilled 5 diamond-drill holes, totaling 1,084 feet, from the 600- and 700-foot levels, excavated a 250-foot surface trench, and took 26 underground samples. The ensuing sections note the location and physical features of the district, mention the equipment, and specify the property and ownership. The history of the mine is briefed, and the geology, mine workings, and plant are described. The work performed by the Bureau of Mines is summarized and supplemented in detail by assay maps, logs of diamond-drill holes in appendix A, and by tables of sample analysis in appendix B.

Jan 1, 1949

Council Members 1988/1989, left to right: Row 1 (seated): H.E. James, P.W.J. van Rensburg, Dr H. Wagner, B.C. Alberts, C.E. Flvaz (President), H.G. Mosenthal, R.D. Beck, Professor A.N. Brown, Dr P.R. Jochens Row 2 (standing): P.C. van Aswegen, J.P. Hoftman, D. Wllson, P.M.T. White, K.A. van Gessel, Dr LA. Cramer, J.S. Freer, V.J. Moore, G.A. Brown, R.A. Snodgrass, J.D. Austin Row 3 (standing): Dr G.A. Fourle, Dr J. Lurle, A.M.P. Henderson, R.P. Mohring, J.A. Cruise, J.L. Nel, H. Scott Russell, J.P. Deetlefs, D.A.J. Ross-Watt Inserts, top row: K.R. Beard, N.J. De~ine, R.J. Dlppenaar, G.T.G. Emere, Dr J-P. Franzidls, Professor R.P. King, J.G. McCallum. Bottom row: G.Y. Nisblt, Professor R.P. Plewman, Dr R.E. Roblnson, Dr O.K.H. Steften, P.A. van Wlelllgh

Jan 1, 1989

By Valenta R. K

A technique is presented for the integrated forward modelling of the three-dimensional structure and the geophysical response of multiply deformed terrains. This technique allows information collected by field geologists and geophysicist to be reconciled by the development of a simplified kinematic structural history of the area. The structural modelling simulates the deformation history of the area in terms of a succession of structural events, such as folds, shear zones and intrusions. The interaction of these events with a starting stratigraphy results in the prediction of the geometry of the structures. By specifying geophysical rock properties for the units in the initial stratigraphy predictions are possible for the potential field anomalies for gravity and magnetics. This approach is suited to a range of applications, and its uses in the modelling of regional structures, testing of geophysical data processing, volume balancing, multiply constrained inversion and training are discussed.

Jan 1, 1995

By R. D. Currie

Haulage accidents in the anthracite region cause fewer fatal and lost-time accidents per million man-hours than similar accidents in bituminous mines, a fact that may be accounted for in several ways, but primarily because haulage, in a large part of the region, is restricted to haulage crews operating only on the gangways where most of the miners seldom come in contact with movement or handling of cars and locomotives. Generally in underground mines the number of men injured compared with the number killed is greater for haulage than for roof-fall accidents, while the number of men killed by haulage is second only to the number killed by roof falls.

Jan 1, 1939

By E. Allain

Extraction of basic metals from sulfides by conventional pyrometallurgical processing leads to the emission of SO2. To avoid this inconvenient, low temperature selective chlorination of sulfide concentrates could be an alternative. However, such process generates hazardous chlorides SxCly. A part of sulfur chlorides such as SCI2 can be recycled as a chlorinating agent of metal sulfides. Hydrolysis of sulfur chlorides, using a solution containing Na2S.9H2O, led to the recovery of more than 90 pct of elemental sulfur. Reduction of SxCly by hydrogen was investigated between 300 °C and 800 °C. About 70 and 90 pct of elemental sulfur were recovered from SC12 and S2C12, respectively. A flow sheet for the chlorination of metal sulfides and the treatment of sulfur chlorides was suggested.

Jan 1, 1998

By H. J. Struth

The benefits of proration of oil production were perhaps more concretely realized in 1932 than at any time since the oil industry adopted nation-wide production control. Reduced output of crude petroleum, which brought the daily average of the United States down to approximately 2,000,000 bbl. from a peak in 1931 of more than 2,600,000, had a telling effect on the trend of oil prices. Mid-Continent crude was advanced in price from 776, for 36-gravity oil, to $1.04 a barrel. California crude, of 26-gravity at Signal Hill, moved forward from 736 to 976 a barrel. Pennsylvania crude, the only exception to the upward trend, rose in price from $1.82 per barrel to $2.02, only to react to $1.72. This was due to local conditions which necessitated an adjustment to overcome competition from other areas of the United States. East Texas continued to exert a far-reaching influence on the crude and gasoline market during 1932. Despite the fact that oil prices were advanced in most fields, large quantities of oil were produced in East Texas in violation of state proration orders, and sold in the market at prices considerably below official postings. This created competitive conditions in the gasoline market that were felt by all refining centers of the United States. The quantity of gasoline produced from cheap East Texas crude was not large, but the volume was sufficient to influence prices in practically all sections of the country. Thus, while the industry's' economic situation showed visible improvement statistically, the unreported and unseen statistics originating in East Texas proved to be an insurmountable obstacle to the economic betterment that was otherwise apparently justified. Somewhat surprising to many was the fact that gasoline consumption was maintained within 10 per cent of the preceding year. Domestic consumption showed only a net decline under 1931 of about 8.5 per cent; exports dropped in volume to the extent of about 23 per cent. As a matter of fact, domestic gasoline consumption was only about 1.4 per cent less than it was in the predepression year of 1929. Exports, however,

Jan 1, 1933

By Hayward B. Oblad

The effects of eight independent variables on froth flotation product yield, ash content, and coal recovery were studied using laboratory batch flotation of 0.6 am x 0 coal. The eight flotation variables investigated were air feed rate, pre-dispersion of collector oil, impeller speed, product collection time, initial solids concentration, collector conditioning time, frother (methyl isobutyl carbinol) concentration, and collector (No. 2 fuel oil) dosage. The two-level Plackett-Burman screening design and the three-level Box-Behnken design were used. Within the ranges studied, air feed rate had no effect on product yield. Pre-dispersion of collector oil, impeller speed, product collection time, initial solids concentration, and collector conditioning time showed only minor effects on the product yield and quality. Frother concentration (mg/L) in the process water and collector oil dosage (g/kg) were shown to be the dominant independent variables in coal froth flotation. Flotation experiments that vary initial solids concentration at constant frother dosage (g/kg) confound the effects of frother concentration (mg/L) and solids concentration. The dominating effects of frother concentration and oil dosage on coal recovery and froth product ash content are illustrated with three-dimensional plots. The relationship between froth product ash and coal recovery is also clearly illustrated by the flotation data.

Jan 1, 1985

By Jörg Holzhäuser, Matthew Crow

An 18.5 km (12 mile) long tunnel is being driven by four Earth Pressure Balance Tunnel Boring Machines (EPB-TBMs) of 4.7 m (15.5 ft.) diameter through alluvial sand, gravel, silt and clay above and below the groundwater table in Los Angeles beneath buildings, railroads, freeways and the L.A. River. Continuous automatic data recording of TBM operation and field inspectors' records, accompanied by monitoring of 5,000 surface reference points and 268 borehole extensometers were used to obtain information. The paper explains the reason for selecting the method of EPB-tunneling to ensure stability of the tunnel and meeting of environmental requirements, and presents data collected to monitor and demonstrate the performance of the TBM sin the different ground conditions encountered.

Jan 1, 2003

By Isaac A. Zlochower, Michael J. Sapko, Ronald S. Conti

The Bureau of Mines has developed a system using a high-speed electropneumatic mechanism for the rapid (grab) sampling of dusts and gases during an explosion. The sampling system consists of an aluminum housing that incorporates two 30-cm3 preevacuated glass vials with rubber septums. Upon actuation, the sampling probe needle is driven through the septum with a pressurized air pulse, filling the tube with gas and dust from the mine explosion. After a predetermined time, the sampling probe needle is retracted by a second high-pressure air pulse to its normal (quiescent) state, allowing the sampling tube to reseal. The onset and the duration of sampling are independently variable and controlled by a time-delay relay package. This technique enables the monitoring of pyrolysis-charring in coal particles and the generation and combustion of the pyrolysis vapors in both large- and small- scale explosions. The following results were obtained from full-scale dust explosion tests at the Bureau of Mines Lake Lynn Laboratory: (1) Gas sampling of the leading edge of the flame front shows the large concentration changes, characteristic of the flame front; (2) gas samples taken entirely in the flame zone consist of pyrolysis and combustion products with very low residual oxygen; and (3) the particles collected in the flame zone show signs of extensive pyrolysis and charring.

Jan 1, 1988

By E. Zucker

In this paper, as in the 1960 CIM paper of the same name, s1gmf1cant new developments in electrical-mechanical mining equipment are briefly described. These include static thyristor-supplied D.C. drives for mine hoists, load-haul-dump systems, process controls with small and medium-size computers, and several other new items of equipment and Concepts. All the new hardware descriptions are given in the context of over-all process integration. This means the actual mechanical linking together of two or more processes and the preliminary step in the development of production-line mining.

Jan 1, 1969

By A. W. Hesse

The trend of American construction toward permanence and longevity is noticeable in the more recent coal plant installations; also, the policy of many coal operators has changed from seeking to obtain the desired tonnage from several plants of small capacities to designing a single installation to produce the whole amount. The mine openings and plant of the Nemacolin mine of The Buckeye Coal Co., are located on the Greene County side of the Monongahela River, 73 miles south of Pittsburgh. The map (Fig. 1) shows the general location, also the Lambert syncline. This syncline partly accounts for the selection of the site; the other reasons were the possibilities of rail and river shipments. Two shafts and a slope were sunk to the coal, work starting on all three in the second half of the year 1917. The air shaft was sunk to a depth of 243 ft. and completed in February, 1918; the slope was completed in November, and the skip shaft was stopped at a depth of 21 ft. below the coal, then the concrete lining was stopped 8 ft. above the coal August, 1918. Work on the skip shaft was resumed May, 1923, and sunk to a depth of 60 ft. below the coal by September, but it was not until May, 1924, that the lining was poured. Max. Min. WateR Water during after Sinking, Crouting, Depth or Cu. Yd. Cu. YD. Gal. per GaL. per Opening Size Length Excav. Conc. Min. Min. Air shaft..... 20 ft. diam. 251 ft. 8 in. 4788 1902 475 2 Slope........ 11 it. by 19 it. 1 in. 857 ft. 11500 5200 50 2 Skip shaft.... 32 ft. 8 in. by 12 it. 8 in. 296 ft. 6042 2293 300 3 Fig. 2 shows sections of these openings. The surface plan shows the relative positions of the openings. Coal was first hoisted from the air shaft May 7, 1918, and entry driving was continued; but the coal had to be stored, as the railroad had not been extended from Crucible to Nemacolin. As soon as the slope was driven to the coal and the linings concreted, the entries were driven along projected lines to connect with those advancing from the air shaft, and skip shaft. As soon as the underground connections had been made between the two shafts, the hoisting by buckets was inaugurated at the skip shaft and construction on the fan at the air shaft started.

Jan 1, 1927

By George J. Tamara

The urban environment presents special challenges for the design and construction of earth retention systems. Complications arising from difficult subsurface conditions are compounded by the presence of urban infrastructure and existing and prior construction. The proximity of adjacent structures as well as intense prior use can cause special concerns including the potential for archeological artifacts or contaminated ground or ground water. Utilities and structures may be particularly vulnerable to the effects of ground movement, dewatering and vibrations. Difficulty of access, congestion and limited work areas may severely restrict means and methods of construction. Dewatering may be limited or prohibited because of concerns for disposal of clean or contaminated water, depletion of aquifers, drawing of contaminants to the site or dewatering induced settlements.

Jan 1, 2003

By Robert Vidal

The performance of a laboratory-scale cell for the electrolysis of an aqueous chrome alum solution was studied. Electrode potentials, pH, and Eh were recorded. An optimum catholyte pH of about 2.5, consistent with information from the literature was observed. Values exceeding this range resulted in a precipitate formation and are detected by wavering cathode potentials. The role of anodically produced dichromate ions was investigated by chemical analysis. It was found that the steady state concentration of dichromate ions varies inversely with fluid flow from catholyte to anolyte. This concentration was also reduced with the use of precious metal coated titanium anodes.

Jan 1, 1994

By C. B. DUTTON, W. F. RITTMAN, E. W. Dean, M. S. HOWARD

NOMENCLATURE USED IN THIS REPORT. In this report the ending ene has been used throughout, except in the bibliography and in quotations from the writings of previous investigators, for all aromatic hydrocarbons, as, for instance, benzene, toluene, xylene. The ending ol, though largely used in technical description, is not correctly applicable to these hydrocarbons, and should be used to designate the impure mixtures of commerce, as distinguished from pure chemical compounds. PRESENT STATUS OF PETROLEUM-REFINING INDUSTRY. Although petroleum is widely distributed, being found in many parts of the world, and although information as to its occurrence and general characteristics seems to have existed from vcry early times, our knowledge of the chemical nature of this substance has been acquired largely within the past 40 years. Within this period a voluminous literature has accumulated, which records work as painstaking as has ever been undertaken in the whole field of chemistry, such as that of C. M. Warren, F. H. Storer, S. P. Sadtler, S. F. Peckham, and C. F. Mabery. Despite this fact, the commercial method of treating crude petroleum for the purpose of procuring marketable products is, in the main, essentially empirical. Much knowledge has been acquired as to methods of separating from crude petroleum such products as are desirable commercially, but little has been done to attain the maximum recovery of such products.

Jan 1, 1916

By A. E. M. Warner, P. J. Mackey

"In 1988, two of the present authors Warner and Vahed [1] were amongst several co-authors on a seminal paper reviewing nickel pyrometallurgical operations of the era. Given that significant changes in the nickel industry have occurred since that time, including the overall political landscape, technology, the overall world energy picture, the countries sourcing nickel and finally the nickel market itself, the present authors considered it timely to provide a 2015 update. In 1988, total world nickel production from sulphide and laterite sources, including production in the former "Centrally Planned Economies"- was about 0.86 million tonnes/a, while in 2014 total world nickel production reached an all-time high of almost 2 million tonnes/a - some 230% higher. On the other hand, while in 1988, about 94% of world nickel was produced pyrometallurgically and of the order of 33% via laterites, today, about 88% of nickel is by pyrometallurgy, with some 41% from laterites, thus showing that more nickel is now sourced from laterites, a trend which is expected to continue.During the period under review, new processing technologies were developed and introduced, along with substantial improvements in both the technologies employed and the scale of operations. Significant productivity gains have been achieved in sulphide pyrometallurgy in part through more efficient mineral processing, particularly in pyrrhotite rejection, and the use of ever larger-scale process equipment. This made it possible to treat lower grade and more complex ores. The significant game-changer from a production perspective was the introduction in the early 2000s of nickel pig iron (NPI) in China via modified iron blast furnace smelting, an old technology long ago cast aside by other nickel producing countries. With the exception of the emergence of this new NPI capacity in China, in the laterite industry modernization and expansion of existing operations has been employed to gain productivity, to cut costs and/or offset the effect of declining ore grades. The NPI technology development has become a game changer in the traditional global supply and demand relationship, opening up a new frontier to supply nickel to low grade utility steel producers. One other key nickel development was the Indonesian ban on nickel ore exports effective in January 2014, thus effectively curtailing NPI production at existing Chinese plants, but on the other hand, potentially prompting new smelting facilities in Indonesia. This paper reviews and updates major pyrometallurgical sulphide and laterite operations worldwide, including changes in nickel extractive metallurgy. It also provides a brief review of new developments in pyrometallurgical operations, with special focus on the NPI process and presents an outlook of the potential future direction of the industry."

Jan 1, 2015

By K. H. J. Clarke

SINCE the beginning of this century the non-ferrous mineral industry has contributed $17,809,-000,000 to the economic growth of Canada. To contemplate the vast amount of investment capital required and the resultant beneficial distribution of these billions of dollars for labour, transportation, supplies, taxes and dividends, challenges the imagination. It is the purpose of this paper, (a) to trace the development of the industry since its formative period to the present; (b) to discuss the current situation and problems; and ( c) to attempt to peer into the hazy future. Although there are 21 metals currently being produced in Canada which are classified as non-ferrous, or as alloying metals, copper, lead, zinc, nickel-the metals which will be discussed in this paper-constitute almost 60 per cent of their total value. ;The story

Jan 1, 1961