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By Lawrence K. Nordell

The selection of belt conveyor drive systems (*) is the subject of ongoing investigation. Frequently this choice has been governed by an incomplete perspective on the major considerations. A more comprehensive and objective approach is desirable. This paper presents additional factors which hopefully will broaden this perspective. BACKGROUND Conventional belt conveyors are powered by electric or electro-mechanical drives(*) mounted at the conveyor's head, tail, intermediate return span, or a combination of these (Fig. 1). A list of the drives reviewed is given in Table I. The following are main elements influencing the selection of the drive system: 1) dynamic characteristics, 2) economic factors such as capital cost, plant spares compatibility, reliability, availability, maintainability, and 3) environmental constraints. The principal dynamic characteristics of concern are the reactions of belt forces generated by the drive system during starting of the conveyor. Another attribute for consideration is the application of multiple driven pulleys used to 1) lower the conveyor's belt tension requirements, 2) increase the expected tonnage throughput, allowing for possible drive component failures, and 3) increase the plant spares flexibility related to the drive assembly.

Jan 1, 1977

By Ernesto de la Torre, Karla Velín, Alicia Guevara

"The following study shows the improvement and simulation of a gold recovery plant of 24 t/day of capacity by gravity concentration, flotation and leaching. The ore processed had grades of 6 g/t Au, 15 g/t Ag, and 0.69 %Cu with the mineralogy consisting of 2 %chalcopyrite, 12 %pyrrhotite, 7 %plagioclase and 50 %quartz. The recovery process starts with crushing the ore followed by grinding it further in a ball mill. The ground ore is then concentrated in a Falcon centrifugal concentrator with concentrate being processed by amalgamation process. Gravity tails are sent to a flotation circuit where the copper minerals and some gold are concentrated. Lastly, the flotation tailings undergo cyanidation for gold recovery. Currently, the overall recoveries are 82.8 %Au, 49.6 %Ag and 99.1 % Cu. The optimization was developed in the laboratory using a Wilfley table by gravity concentration. Flotation tests in the laboratory were performed using potassium amyl xanthate and pine oil. Lastly, cyanidation was then performed on the flotation tailings. The results showed the optimum concentration of sodium cyanide in cyanidation is 2 g/L, which produced an increase in gold recovery from 30% to 44%. The reduction of diameter particle from 132 to 80 µm also produces an incremental recovery of gold and silver from 11% to 21% Au and 0.4 to 3% Ag in gravity concentration. Likewise in the cyanidation the recovery of gold and silver has shown a rise from 44 to 62% and 8 to 32% for Au and Ag respectively. However, the flotation method the gold recovery is reduced from 68 to 30% Au by reducing the particle size. Computer simulations using the programs, Moly-Cop and ModSim were performed to determine optimum parameters for the recovery of precious metals at the gold recovery plant."

Jan 1, 2014

By Frank E. Williams

Nuclear detonation data were accumulated, studied, and evaluated by the Bureau of Mines to visualize how nuclear explosives might be used in a shale?-oil industry, The evaluation shows that the Green River Formation at the semi-isolated locale of Piceance Creek Basin, in northwestern Colorado; is thick and widespread enough to warrant consideration of nuclear mining in lieu of conventional methods, Because cost data for nuclear explosions are limited; cost comparisons are made largely by assumptions. Also described are the history of the shale-oil industry, the geology and size of oil-shale resources; and conventional mining methods and processing technology.

Jan 1, 1969

By Y Li

An ilmenite ore from the Murray Basin was initially characterised using combined X-ray Fluorescence Spectroscopy (XRF), X-Ray Diffraction (XRD), Scanning Electron Microscope (SEM) and Electron Probe Microanalysis (EPMA) techniques. XRF analysis showed the ilmenite sample contained 58.7 wt per cent TiO2 and 26.2 wt per cent Fe2O3. Major impurities included: Cr2O3 (4.5 wt per cent), Al2O3 (2.7 wt per cent), SiO2 (1.9 wt per cent), Mn3O4 (1.5 wt per cent) and MgO (1.1 wt per cent). Manganese and magnesium were present as solid solution components within the ilmenite lattice while the elevated Al2O3 and SiO2 levels were due to separate aluminosilicate gangue minerals. Chromium was associated with discrete chrome spinel gangue phases of variable composition, (Fe,Mg)(Cr,Al)2O4. Quantitative XRD analysis of the sample identified rutile (12 per cent), ilmenite (11 per cent), and pseudorutile (67 per cent) as the main titanium-containing phases and chrome-rich spinels (seven per cent) as the major impurity phase. Minor quartz, aluminosilicates, zircon and monazite were also present. The ilmenite was mixed with synthetic graphite, pressed into pellets and reduced carbothermally in nitrogen at 1200 and 1400°C with C/O molar ratio of 1.2. Titanium oxide in the ilmenite was converted to titanium oxycarbonitride. Iron oxides were reduced to metallic iron. The Changes of impurities as a result of reduction was examined by SEM and EPMA analyses. Iron and chromium oxides within Fe-rich chromite were reduced to form a Fe-Cr-C alloy. Mg-rich chrome spinels were partly reduced at 1200°C. Zircon particles were not reduced at 1200°C, but were significantly reduced at 1400°C, with the particles becoming porous and the silicon being removed.

Oct 5, 2011

By Fernando JAS Barriga

The world-class Neves-Corvo deposits were intersected by drilling in 1977. They occur in the (Carboniferous) Iberian Pyrite Belt (IPB), Western Europe&apos;s largest stock of base metals (see Bamga, 1990, in Dallmeyer RD, & Martinez E, eds, Pre-Mesozoic Geology of Iberia, Springer-Verlag). Massive and stringer sulfides in the area sum up to about 200 Mt (109 kg), in five main orebodies (Neves, Corvo, Graca, Zambujal and Lombador). They include unique, extremely high grade copper and tin ores ( - 33 Mt Cu ores, -7.5% Cu, and -4 Mt Sn ores, -2.6% Sn, - 12.5% Cu). Also present are -50 Mt polimetallic ores (-6% Zn, 1.2% Pb, 64 ppm Ag). The remaining are relatively low grade pyritic massive and stringer sulfides (Cu < 2%. Sn < 1%, Zn equivalent < 4%). The geological setting is one of bymodal submarine volcanism, with predominant felsic, explosive volcanism and associated sedimentation (detrital and chemical), which took place on a shelf-facies, quartzite-phyllite basement (of Upper Devonian age). The plate tectonic setting has been the object of much debate. Current interpretations favour that the IPB volcanism took place in a tensional fore-arc region, associated with oblique subduction and collision (Silva et al., 1990, same volume as above). At Neves-Corvo there are many different ores, that may be grouped in four main types: fissural (at the base), breccia, massive (intermediate) and "ruban6 " (at the top). Fissural ores seem to correspond to stockworks in contrasting types of host rocks (gray to black shale, sericitic, chloritic and graphitic, and light gray volcanic rock). Massive ore may contain significant shaly gangue, at the base of individual orebodies, and silica-rich (cherty) varieties towards the top. The more sulfide-rich varieties predominate, and are usually well banded.

Jan 1, 1993

By James E. Bell

Quartz crystals occur on a farm in the vicinity of Laurel Fork, Carroll County, Va., in abundance over a large area, This has been known for several years, but no work had been clone, up to the Bureau of Mines examination in 1943, to determine the amount of crystalline quartz of usable quality. Field exploration was undertaken throughout the month of June 1943.

Jan 1, 1950

NEW- MEMBERS The following list comprises the names of those persons who became members during the period Feb. 10, 1917 to Mar. 10, 1917. ANDERSON, .LAWRENCE W., Min. Engr., Boston Mine, Utah Copper Co. Bingham, Utah. AUSTIN, JOHN W., Assayer, Magma Copper Co., P. 0. Box 101, Superior, Ariz. BARNARD, C. W., Treas. and Resident Mgr., Arizona Asbestos Assn., Globe, Ariz. BIERMAN, A. C : Geol., Producers Oil Co., Box 75, Houston, Tex. BOCHERT, W. C., Prof. of Mining, South Dakota State School of Mines, Rapid City, So. Dak. BROOKS, FLOYD R., Shift Boss, Mond Nickel Co., Ltd., Worthington, Ont., Can. BROWN, CECIL J., Draftsman &,Surveyor, Wallaroo SC Moonta Min. & Smelt. Co., Wallaroo, South Australia. BURRAGE, ALBERT C., Vice-Pres., Chile Copper Co., 85 Amos Bldg.; Boston, Mass. BURGESS, JOHN ALBERT Genl. Supt., United Eastern Min. Co., Oatman, Ariz. CARLOCK, JOHN BRUCE, Supt., O&apos;Neall Oil Process Co., - 608 Haas Bldg., Los Angeles, Cal. CARPENTER, BYRON H., Min. Engr., . . Willoughby, Ohio.

Jan 4, 1917

By A. Karzhau, B. Aldamzharov, Y. Tussupbekov

"This case study produced for the metal mine operating in Kazakhstan, which has ventilation controlled manually and working continuously at maximum speed to keep air flowing through each part of the mine 24 hours a day. The mine auxiliary ventilation has been designed with the maximum length of ducting systems with extra air volumes to compensate for potential leakage. The mine provided auxiliary ventilation to all production stopes even to those, which for various operating reasons become temporarily inactive. However, mine safety has to consider risks associated with the deficit of fresh air for mine gases dilution and removal. The mine needs additional investments for re-designing ventilation network and therefore needs to estimate financial risks associated with it. The aim of this study is to conduct risk analysis for ventilation network optimisation processes at the operational metal mine in Kazakhstan. Mine ventilation surveys were undertaken for validation of the computerised ventilation model. The mine ventilation network modelling has been undertaken to be compliant with Kazakhstan mining regulations. Results of the mine ventilation optimisation processes were analysed in terms of financial risks for investments into reconstruction of the ventilation shafts, extension of the ventilation network, variable speed fans and automated regulators. Savings were resulted from improving ventilation system efficiency by reduce airflow in areas without mining activity and redistributing existing ventilation capacity. Based on savings derived from the optimised ventilation network an additional NPV has been received. Stochastic modelling use Monte Carlo simulation producing representation of possible outcomes for the additional NPV considering electricity pricing as a major variability. As result probability distribution for the optimised ventilation network demonstrates the additional NPV in a range of 1.6 - 2.2 million US$ in the corresponding defined value of 90%. Moreover, there is only 5% chance that the additional NPV to be less than 1.5 million US$. Conducted risk analysis for ventilation network optimisation processes gives considerations on volume of investments into the mine ventilation system.INTRODUCTIONCosts for mine ventilation are typically increasing when mines expand to deep levels. Some underground mines in Kazakhstan still use continuously operating fans at its maximum capacity. This is not helping to save energy and costs that are in many cases very significant. This case study produced for the metal mine operating in Kazakhstan, which has ventilation controlled manually and working continuously at maximum speed to keep air flowing through each part of a mine 24 hours a day. The mine auxiliary ventilation has been designed with maximum length of ducting systems and extra air volumes to compensate for potential leakage. The mine provided auxiliary ventilation to all production stopes even to those, which for various operating reasons become temporarily inactive. However, mine safety has to consider risks associated with the deficit of fresh air for mine gases dilution and removal from the mine workings (Sabanov, 2019). The mine needs additional investments for re-designing ventilation networks and therefore need to estimate financial risks associated with it. The aim of this study is to conduct risk analysis for ventilation networks optimisation processes at the operational mine in Kazakhstan. Mine ventilation surveys for validation of the computerised ventilation model have been undertaken"

Jan 1, 2019

The October General Meeting of the Institute was held in Kelvin House, Johannesburg, on 15th October, 1969, at 4.30 p.m. Mr J. K. E. Douglas (President) was in the Chair. There were also present 17 Members, Messrs: M. Barcza, R. C. J. Goode, J. A. Nixon and V. C. Robinson (Council Members), M. L. Fitzgerald, D. F. H. Graves, C. G. Hinds, S. D. Hill, J. S. Hall, D. F. Malan, T. Meyer, W. pyne-Mercier, K. S. Rae, S. G. Taussig, L. W. P. van den Bosch, Dr A. Whillier, C. H. Wyndham. Four Associate Members: Messrs O. Davel, M. J. Martinson, M. P. J. Sandys, T. G. Harington. One Student: R. P. W. Henrard. Three Visitors: Messrs A. V. Pike, B. Schmitz, A. P. Raats. Secretaries: D. C. Visser and S. de. Gersigny. Total present: Twenty-eight. OBITUARY The President: "It is my said duty to announce the death of Pieter Ulrich Fischer, Member, who joined the Institute in 1961 and passed away on 24th June, 1969. As a mark of respect to the memory of the deceased and in sympathy with the bereaved I would ask you all to rise and observe a few moments&apos; silence." MINUTES The President: "The minutes of the last meeting will only appear in next month&apos;s Journal and I would request that the confirmation of these minutes be held over." MEMBERSHIP The President: "I have much pleasure in announcing that the names of the undermentioned candidates, having been published in accordance with By-Law 5.2.2, Council has elected them to membership of the Institute in the following grades:" Members: Alexander Edward O&apos;Meara, Anton Leopold Melvill, WilIiam Harold Wise, Eric John Dunstan, Frank Nel, Lubertus Hendrikus Jakob Poortier. Associate Members: Michael Irvine Britten, Selwyn Wilson Lange. James McCormack, Christiaan Lodewyk de Jongh, WilIiam Andrew Hustrulid, Reinhold Johannes Ortlepp, Felix Henry Lancaster. Graduates: Willem Adriaan Gericke, Hamish David Sneddon Miller, David lan Ossin, Robert Antony Layboume, Ewart John Shillaber, Colin Hewitt Wiggett. Affiliates: Bernard Andre Thomas, Waiter Arthur Wood, Andrew John George Paschalides, David John Perry, Alex Richardson, Gert Blekker Kotze. Student: Matthys Jacobus de Beer. MEMBERS TRANSFERRED TO A HIGHER GRADE From Associate Member to Member: David Alphonso Viljoen. From Student to Associate Member: Michael Charles Carruthers. "I welcome the newly elected members to the Institute and congratulate the members who have been transferred to a higher grade." PAPERS FOR PRESENTATION The President: "Professor Wyndham, may I call on you to deliver the paper entitled &apos;Factors affecting the mechanical efficiency of men shovelling rock in stopes&apos;, written jointly with J. F. Morrison, J. H. Viljoen, N. B. Strydom and A. Heyns." After the presentation of the paper the President said: "Gentlemen, I would like to thank Dr Wyndham and his colleagues for once again reporting through the medium of this Institute the results of the very important work they are carrying out at the Human Science Laboratories. It is most appropriate that this work which is leading to a better understanding of the capabilities and efficiency of the human body under the arduous conditions encountered underground should be reported to this forum. In this way our members, who are actively engaged in the job of mining, can firstly learn something of this research and secondly, can, with their practical knowledge of conditions underground, contribute to what has been learnt and possibly pose new problems for our scientists in the laboratories. The scientist should always have the opportunity of subjecting his research to the scrutiny of people engaged in practical operations. By the very nature of our gold mines we are unfortunately heavily dependent on a large labour force and while mechanization has been introduced wherever feasible, we are likely to continue to be heavily dependent on this labour. In accepting this fact we can be proud in this country of what has been achieved, not only in obtaining the best efficiency from labour but in ensuring that their working conditions are reasonable and that their health and well-being are adequately cared for. When one visits our gold mines, one cannot help being impressed with what is being done to ensure that we have a satisfied, happy and healthy labour force. The Human Sciences Laboratory with its scientific approach has assisted greatly in promoting a better understanding of the problems associated with labour under the conditions experienced on our mines. Thank you." Mr M. Martinson then contributed to the discussion. (This contribution will appear in a later issue of the Journal.) "Professor Wyndham, may I call on you to deliver the paper entitled &apos;Acclimatizing men to heat in climatic rooms on mines,&apos; written jointly with Prof Strydom." After Dr Wyndham had presented the paper the President said: "Thank you Dr Wyndham for so ably describing the work associated with the acclimatization procedures on our gold mines. It has certainly been an eye-opener to those of us not familiar with this work and I believe it is very important that everyone and not only people in the gold mines should know about it. It is fortunate that all industries do not have the same arduous heat conditions experienced on our mines but other industries such as our chemical and metallurgical industries do have other problems relating to the adjustment of labour to the work situation. The scientific approach employed by the gold mines in tackling this problem is an example to these industries of what can be achieved by logical

The 2012 North American Tunneling (NAT) conference is expected to attract more than 800 tunneling and underground construction professionals. But don?t let the North American part of the meeting?s title fool you. Many of the attendees will come from all over the world. The meeting is scheduled for June 24-27 at the JW Marriott Indianapolis Hotel in Indianapolis, IN. In addition to two and a half days of technical programming, the accompanying exhibit has attracted 116 exhibitors in 140 booths. And the conference will include short courses, a field trip and plenty of social activities that will give attendees the opportunity to catch up with each other.

Jan 1, 2012

By Elham Kordzadeh

As the world’s reserves of coarse and high-grade iron ores continue to shrink, beneficiation is becoming increasingly important. The resulting concentrates cannot be used directly as feedstock for iron making, but require an additional agglomeration step. Pelletizing is preferred, because the uniform chemical, physical, and metallurgical characteristics of pellets make them a more desirable feed for the iron making processes. The heat hardening or induration of pellets is typically done in shaft furnaces, grate-kiln systems or on straight grates. Rotary kilns were originally developed in the late 19th century for Portland cement production [1]. The main development work for the successful adaptation of the process to the thermal treatment (induration) of green balls from iron ore was performed by Allis Chalmers in Milwaukee, Wisconsin, USA in the 1960’s [2].The straight grate process, which was first used in 1955 at Silver Bay, Minnesota, was a dedicated development with the aim to pelletize and indurate magnetite (taconite) concentrate [2]. There are various important technical and economical distinctions between the two pelletizing technologies. The most important differences include that a grate-kiln has three distinct pieces of equipment, a preheat grate, a rotary kiln and an annular cooler, whereas in the case of a straight grate, the entire indurating process is done on one piece of equipment only. In addition, both technological solutions have differences in their recuperation systems, direction of air flow in drying, number of burners, form of pellet movement, etc., which cause differences in raw material suitability, process control, economical aspects, plant operation and product pellet quality.

Oct 30, 2017

By T. E. Gray

This report describes the preparation characteristics of the more significant coalbeds in Monongalia County, W. Va. It is one of a Bureau of Mines series planned to determine coals suitable for producing metallurgical coke, either as mined or after beneficiation. Over 9.5 million tons of coal was produced in Monongalia County in 1957, of which more than 7 million tons was cleaned mechanically in 8 cleaning plants. On January I, 1954 the Bureau of Mines estimated that 1,576 million tons of recoverable coal remained in the county in beds 28 inches or more thick.

Jan 1, 1960

By P J. Marsh, P J. Bartsch, N J. Semler

Iron Road Limited is currently studying the feasibility of producing 20 Mt/a of high-grade (67 per cent Fe) magnetite concentrate from a 2.6 Bt resource (JORC) located at Warramboo on the central Eyre Peninsula in South Australia. Bulk concentrate has been tested at a relatively coarse grind size of -106 ¦m. The preliminary flow sheet has been confirmed based on initial mine plans and comprehensive metallurgical testing across the range of mineralisation. Extensive Davis tube testing to predict magnetite recoveries has been conducted over the resource, however this was completed at settings different to the optimised settings developed in the metallurgical test work program.This paper outlines the development of an ore treatment simulation in SysCAD which utilises the mine production plan, the Davis tube test data from the resource, data from metallurgical test work and process design criteria to predict magnetite concentrate deliveries. Mineralogical data, including QEMScan results and metallurgical assessments, were a fundamental basis of the process models which enable predictions of concentrate yield and quality. Power and water requirements are also calculated within the model. SysCAD dynamic simulation has been used to assist with the design of the process plant and downstream infrastructure. The simulation has been set-up to allow iterative integration and optimisation of the mine plan when it becomes available.CITATION:Semler, N J, Marsh, P J and Bartsch, P J, 2013. Iron RoadÆs prediction of magnetite concentrate production from the Central Eyre Iron Project, in Proceedings Iron Ore 2013 , pp 539-546 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By M. Wu, A. Kharicha, A. Ludwig

"The droplet formation during melting of a 400 mm diameter electrode is simulated with a multiphase-MHD approach. The computational model includes a layer of slag and a layer of liquid steel. A VOF approach is used for the interface tracking and a potential formulation is used for the electric and the magnetic field. The Lorentz force and the Joule heating are recalculated at each time step in function of the phase distribution. The first results provided by this model are presented.IntroductionThe Electro-Slag-Remelting (ESR) process is an advanced technology for the production of components of e.g. high quality steels [ 1-9]. An alternating current (Figure 1) is passed from a conventionally melted and cast solid electrode through a layer of molten slag to the baseplate. Because of the electrical resistivity of the slag, Joule heating is generated and the slag transfers this energy to ingot and mould surfaces and to the melting electrode tip. The molten metal produced in the form of droplets passes through the slag and feeds a liquid pool from where directional solidification takes place. The slag and the ingot are contained in a water cooled copper mould. As also the baseplate is water cooled, a heat flow regime is imposed that gives controlled solidification, and this results in improved structure characteristics of ESR ingots.This process involves two liquids, a liquid metal and a liquid slag. Each liquid is subject to a phase change due to melting and/or solidification. From a fluid dynamic point of view, the ESR process is clearly a multiphase process, with free interfaces (slag/pool, gas/slag), and with a mixed area (slag and falling steel droplets) [ 10-15].Physically, the development of the heat and mass transfer at the slag/droplet interface is important for the final ingot quality, composition and cleanliness. Visual observations of the droplet formation just under the electrode being melted is almost impossible. Due to the presence of high temperatures, opacity of the materials, and the presence of the mould it is not possible to directly observe the behaviour the slag/pool interface. Although usually assumed flat [1-9], a previous work [10] using a Volume of fluid (VOF) model has shown that the interface shape between a layer of slag and steel layer in a cylindrical cavity is highly coupled with the distribution of the electric current. A full scale simulation of the ESR process using a VOF model has shown that the shape of the pool interface is likely to be non flat."

Jan 1, 2011

By Evgenii Pavlov, Ivan Tronin, Viktor Timofeev, Vladimir Kislov, Sergei Bogovalov

"Modeling of the magnetohydrodynamical (MHD) and thermodynamical processes during the industrial scale Direct Chill (DC) casting of aluminum slabs is performed using a combination of ANSYS/CFX and ANSYS/EMAG software. The electromagnetic field is modeled through ANSYS/EMAG, while hydrodynamic and thermodynamic processes are modeled through ANSYS/CFX. Both packages were modified in order to calculate MHD flows in the liquid pool that forms during aluminum DC casting, and they were unified into a software combination that provides simultaneous simulation of all the above processes. The simulation shows that the electromagnetic stirring of the molten aluminum changes the shape of the solidification front (solid-liquid interface) very dramatically, namely it becomes significantly flatter. This effect should improve the internal structure of aluminum DC slabs and allows us to increase the casting velocity.IntroductionProduction of Aluminum alloys with high mechanical properties and structural uniformity is one of the main goals of industry. The preferred production method of aluminum alloys in most modern plants is Direct Chill (hereafter DC) casting because it offers high productivity and commercial success. One important limitation of this technology is the development of centerline shrinkage in slabs larger than about 1 meter. The improvement of the internal structure of long DC cast slabs can be achieved by electromagnetic stirring (hereafter ES) of the liquid metal above the solidification front. This intensifies heat transport in the zone close to the solidification front and suppresses shrinkage formation."

Jan 1, 2013

By A. Abdollahi

Modification of the silicon in Al-Si alloys can be performed by adding a very small amount of some elements like Na, Sr and Ca to alter the form of silicon from an acicular shape to a fine fibrous one. This modification results in a considerable improvement in mechanical properties especially elongation, Metallographic observations in A356 alloy indicated the degree of the modification with Na, Sr and Ca, They showed that the effect of Ca as a modifier is not as strong as is Na or Sr while Na is the most effective modifier, Although modifiers improve mechanical properties, they also increase porosity in castings, The reduced pressure test (RPT) and Tatur test showed that the increasing porosity with Na is the most and with Sr is the least.

Jan 1, 2004

By N. A. Gokcen

THE data of Chaudron,1 Tonosaki,2 and Collins³ on the thermodynamic properties of MOO, disagree widely. These authors, by using essentially similar methods, studied the following reaction: 1/2MoO2(s) + H2(g) == i/2Mo(s) + Ph,o H2O(g),K = —----- [1] Ph2 Tonosaki used a vacuum system consisting of a furnace containing MOO, and a water saturator whose temperature was kept at 25 °C with a thermostat. After repeated evacuation, hydrogen was admitted slowly into the system. The experiments were based upon the fact that at a constant furnace temperature and constant partial pressure of water, the total pressure of gas mixture over MOO? + Mo is constant. Any attempt to vary the pressure by external forces would vary only the amounts of MoO2, and Mo, after which the pressure should return to the equilibrium value in accordance with the equilibrium constant of reaction 1. The actual value of K was determined from the total equilibrium pressure (sum of Ph2o + Ph2) at each temperature. The total pressure of gas was varied within the range of 80.2 to 125.4 mm Hg, within a temperature range of 645" to 823 °C. The results were summarized as log K = 0.9413 — 1444.6/T for reaction 1. The ratio of H2O/H2 was considered to be uniform in spite of the presence of a thermal gradient across the static gas phase. It was shown by Rosenqvist and Cox,&apos; however, that in somewhat similar circumstances the error resulting from thermal diffusion may be large. Collins³ improved Tonosaki&apos;s method by attempting to avoid thermal diffusion errors. His equilibrium data were obtained at 700°, 800°, and 900° C, and the result for reaction 1 was expressed as log K = 1.258 — 1822/T. The purpose of this investigation was to study reaction 1, avoiding the thermal diffusion errors, and to obtain equilibrium data in a considerably wide temperature range for the reliable extrapolation of the resulting thermodynamic functions. Experimental Procedure The diagram of the apparatus is shown in Fig. 1. Tank hydrogen was passed through a tube containing platinized asbestos at 425 °C in order to convert a trace of oxygen into water vapor. The flow rate was carefully controlled with a capillary-type flow-meter B and a bubbling column D. The gas was then presaturated sufficiently at P and led into a condenser system immersed in a thermostat, controlled to within ±0.002C. The temperature of the thermostat was measured with a thermometer calibrated against a certified standard. The temperature of P was adjusted to avoid the condensation of unduly large amounts of water as judged from the rate of flow out of the capillary tube M. Argon was purified by passing it through magnesium chips kept at 630°C. After passing through the flowmeter B&apos;, it was mixed with moist hydrogen emerging from the thermostat. The resulting gas mixture was then led into the hot zone of the furnace through the heated glass tubing and the silica tube S, thus insuring the same ratio of PII2o/Ph2 from the condenser to the reaction chamber, thus avoiding thermal diffusion. The entire gas system was of all-glass construction, except at the magnesium train. The furnace comprised a glazed alumina tube over which a 15-in. platinum coil was wound. The lower end of the alumina tube was tightly closed with a brass bottom and a silicone rubber gasket, and the upper end with two glass disks, each with a hole of 1/16 in. in diameter, through which the gas mixture escaped into the atmosphere. A back-up coil of kanthal wire facilitated the temperature control of the furnace. A coil of annealed molybdenum strip of 99.99 pct purity, 0.005 in. thick and 0.050 in. wide, and weighing 17 g was hung in the furnace with a 0.010-in. platinum wire attached to one end of a sensitive analytical balance. The temperature of the furnace was measured with a Pt-Pt-10 pct Rh thermocouple checked against a standard. The experimental procedure consisted of heating the gas purification trains, adjusting the gas flow rates, attaining a constant thermostatic temperature, flushing the entire system for 2 hr while heating the furnace to well above the expected equilibrium temperature and then cooling it at a rate of 0.3°C per min during which time the change in the weight of molybdenum was observed on the balance. For a given thermostatic temperature, i.e., a constant Prr,o/Px,, molybdenum oxidized upon cooling slightly below the equilibrium temperature. The procedure was then repeated by heating the furnace and thus reaching a temperature slightly above the equilibrium value. The average of the two temperatures, differing by 2" to 3"C, was considered to be the true equilibrium temperature. In order to determine the stoichiometric composition of the oxide phase present in this investigation,

Jan 1, 1954

By X Zhang, Y Zhu, P E. Ngoepe, P P. Mkhonto, W Xiong, L Han, L Lu

The triazine molecules have not been given much attention and they are potential collectors that may positively impact the mineral processing industry. The adsorption of triazine as collectors such as sodium 2,6-dithio-4-butylamino-1,3,5-triazine (SDTBAT) on pyrite form a basis in design of flotation collectors that may be applicable in a wide range of sulfide minerals. The SDTBAT collector was compared with the sodium normal butyl xanthate (SNBX) and sodium normal butyl dithiocarbamate (SNBDTC). All collectors were adsorbed in their neutral form containing sodium on the pyrite (100) surface. The computational calculations found that the adsorption energies followed the order: SDTBAT (-300.35 kJ/mol) > SNBX (-186.10 kJ/mol) > SNBDTC (-163.78 kJ/mol). It was observed that the SNBX and SNBDTC adsorbed through the S atoms, while the SDTBAT adsorbed through the S atoms and N atoms onto Fe atoms. It is clear that the SDTBAT had a strong binding energy which is attributed to the presence of the triazine group that is electron depositing to the active S atoms compared to the SNBX which possessed the oxygen that is electron withdrawing. Moreover, the SDTBAT collector was found to bind stronger than the xanthate. This was complimented by microflotation tests that showed fast floating and higher recoveries of pyrite when using the SDTBAT collector than the xanthate and DTC. This clearly demonstrated that the SDTBAT is a potential collector to replace the xanthate collector due to its high selectivity and flotation power.

Aug 24, 2022

By Walker K, Burton RC

An outline of the ventilation and refrigeration requirements of deep South African gold mines is presented. This is followed by a brief description of the history of controlled recirculation in mines and the practical and economic benefits such schemes can offer. The potential hazard of a fire in a recirculation system is discussed.The major part of the paper describes the first large-scale field trial of controlled recirculation to be conducted in South Africa. Emphasis is placed on the monitoring system that was used for data acquisition during the trial, and also on a safety system designed to shut off the recirculation fans in the event of a fire.The paper concludes with a review of the latest development work taking place on recirc-ulation safety systems.

Jan 1, 1985

By Roger N. Kust

Removal of heavy metals from industrial process streams is becoming increasingly important for _the recovery and reuse of values in process tails. Technology has been available for several years which removes heavy metals, from dilute (0.1-3.0 g/L) streams, as hydroxide or hydrated oxide sludges, allowing discharge of washed cakes with up to 60% solids. This paper reports on improvements to this technology which now allows treatment of streams with metal concentrations in excess of 60 g/L while eliminating the need for thickeners. Streams containing copper, iron, aluminum, chromium, nickel, zinc, cobalt and lead have been successfully treated.

Jan 1, 1992