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By Lawson F

Narrowly sized samples of synthetic chalcocite (Cu2S) and covellite (CuS) were leached in oxygenated acidic sulphate-chloride solutions. Chalcocite leaches via a two-stage process, the first stage being much more rapid than the second. The apparent activation energies are 42.7 kJ/mol and 68.2 kJ/mol respectively, indicating that both stages are controlled by surface chemical reactions. The leaching of covellite is also chemically rate limited with an apparent activation energy of 77.0 kJ/mol. The shrinking core model is able to be used to describe the leaching processes of both copper sulphides. Over 97% of copper present in chalcocite dissolved in 0.5 M H2SO4i0.5 M NaCl solution under one atmosphere pressure of oxygen at 85¦C in three hours from particles 36 pm in diameter while only 85% of the contained copper in covellite particles 13 pm in diameter dissolved in the same solution under the same pressure at 90¦C in six hours. About 99% of the sulphide sulphur in chalcocite was oxidised to elemental sulphur while only 90% of sulphide sulphur was converted to elemental sulphur during covellite leaching. The mechanism proposed for the two-stage leaching of chalcocite particles is as follows: in the first stage, cuprous ions rapidly diffuse to the external reaction surface where they lose electrons and go into solution as a complex cupric chloride ion CuCl'. The second leaching stage begins when covellite is formed at the external surface. Copper again goes into solution as the CuCl* ion. The mechanism for leaching synthetic covellite is similar to the second leaching stage for chalcocite except that the leaching rate of synthetic covellite is substantially lower than that of the newly formed 'covellite'. Elemental sulphur formed on the particle surface retards the dissolution processes during both chalcocite and covellite leaching. The presence of chloride ions is necessary if essentially all of the copper from chalcocite is to go into solution. When no chloride ions were present, the leaching rate of both newly formed and synthetic covellite was almost zero. The main role of chloride ions in both chalcocite and covellite leaching appears to be to disrupt the passivation film of sulphur on the particle surface.

Jan 1, 1989

By B. Singh

The use of wire ropes has already been tried in a few countries for roof support In mines. But the use of scrap wire ropes, as a method of support on extensive scale has not been reported from anywhere except India. Extensive trials using freshly discarded wire ropes for roof support were undertaken both in the laboratory and field. In laboratory, model beams supported with different reinforcing techniques were tested to evaluate their comparative load bearing capacity vis-a-vis reinforcing factor. Among all the tests, the model supported with wire rope system at 60° angle in combination with two supplementary vertical bolts offered the best result 1.e. about 95% reinforcement. It also accepted post fracture loading of the beam. In statical analysis too, the best result could be obtained with the rope installed across the gallery at 60° angle. All these findings are in conformity with the field observations obtained during roof stitching practices in coal mines. Of late, roof stitching, an effective and economical method of roof support developed at CMRS, India in 1972, found wide application in over 200 coal mines. In this method, a freshly discarded wire rope is grouted across a gallery in two inclined drill holes supplemented with two middle vertical roof bolts at every 1.0 to 1.2 m interval along the gallery. It is tensioned against the roof using wooden sleepers and thus, the whole system functions like a roof truss.

Jan 1, 1990

THE. extraordinary volume of work done in this period, and the multiplicity of subject matter, make a year-by-year historical account undesirable, if the account is not to be an assembly of unrelated fragments. We shall, instead, undertake to narrate the development in this period of each of the branches of the subject separately, hoping that their interrelations will be self-evident. There is a certain arbitrariness in the selection of subject matter in the following sections. The development of important engineering alloys-for example, high-speed steel-is disregarded, for it is the primary purpose of this account to relate the advances in ideas, the growth of the science of metals; other historical accounts relate these parallel advances. Nor are advances in techniques stressed, though occasionally the most important are noted; nor is the progress described in allied fields such as welding, cutting, etc.; for though these developments have very frequently made possible the advances herein related, they are far too numerous to recount in anything short of a ponderous volume. There is a more serious arbitrariness, however; it is not an easy matter to draw the boundaries of physical metallurgy, and some contiguous subjects have been omitted that perhaps should have been included, such as, for example, corrosion, gases in metals, the magnetic behavior of metals and alloys, and certain other fields in the physics of metals. REACTIONS IN ALLOYS--DIFFUSION Many of the reactions occurring in alloys proceed by the operation of the process of diffusion in the solid state: the annealing of mixed powders to form alloys, the homogenization of castings or forgings, the freezing of alloys, the treatment of clad metals, the loss

Jan 1, 1948

A simple production technique has been initiated and implemented at Oaky Creek open cut coal mine to optimise recovery of coal from the relatively thin geological seams. The production technique is based upon minimising coal dilution through careful dragline operation and the selective use of mine mobile equipment to clean the top of coal. In addition, recovery of coal from the pits has been increased by refining blasting and dragline methods.The implementation of the recovery optimisation programme at Oaky Creek has provided significant economic benefits from increased yield through the preparation plant by the reduction in dilution, and from increased raw coal tonnage through improved pit recovery methods.

Jan 1, 1990

By Galen G. Waddell

Several years of rock-burst research conducted by the U.S. Bureau of Mines in cooperation with the mining companies of the Coeur d'Alene mining district, Idaho, in addition to progress made by others throughout the world, have led to a good understanding of the rock-burst problem. This paper describes conditions which have caused specific bursts, present capabilities of detecting stress buildup and bursts, control methods, and a suggested approach to analyzing any individual mine-burst problem. A rock burst is the sudden, violent release of stored strain energy in rock by some mechanism of rock failure, generally accompanied by expulsion of rock with consequent damage to the mine. A burst may be audible for only a few hundred feet, or on the surface it may sound like a sonic boom miles away. A Dictionary of Mining, Mineral, and Related Terms, U.S. Bureau of Mines (USBM)* 1968yand defines a burst as Bureau "That phenomenon which occurs when a volume of rock is strained beyond the elastic limit and the accompanying failure is of such a nature that accumulated energy

Jan 1, 1971

By Ryan Brogden

On the 5 September 2014 a road train (tractor-trailer) with two trailers carrying ammonium nitrate was involved in a single vehicle accident on the Mitchell Highway, 30 kilometers (18 miles) south of Charleville in Central Queensland, Australia. The ammonium nitrate was being transported to a mine site for use as a blasting explosive. The truck came to rest in the creek bed adjacent to a road bridge and caught fire. The vehicle burnt for over one hour before the load of ammonium nitrate exploded. Miraculously there were no fatalities; however eight people nearby sustained injuries, some seriously. The road and rail bridge over Angellala Creek were destroyed and vehicles in the nearby vicinity were seriously damaged. The truck carrying the ammonium nitrate was completely destroyed with over 2500 pieces of debris scattered up to one thousand yards (one kilometer) from the blast site.

Jan 1, 2018

By Bloom M. S

Epithermal vein and breccia hosted Au mineralisation at the Kerimenge prospect, in the Wau district, Papua New Guinea, occurs within a block of multiply fractured dacite porphyry of Pliocene age, and is localised on intersecting regional fault structures, marginal to the eroded vent of a Late Pliocene-Pleistocene maar volcano (diatreme).Au mineralisation is primarily controlled by the steeply dipping Kerimenge Fault zone, which hosts a basal zone of silicified breccias,transitional laterally and vertically to networks of fracture controlled veins.Early quartz+pyrite veins, deposited from CO2 rich, NaCl saturated, boiling fluids pre-date the main phase of Au mineralisation. Four stages of Au bearing vein mineralisation have beenrecognised. Quartz+sulphide veins (stage 1) and partially coeval quartz+sulphide+carbonate+ adularia veins (stage 2) occur marginal to silicified breccias, and are associated with quartz+sericite+pyrite wallrock alteration. Similar depositional conditions prevailed for stage 1 and stage 2 mineralisation. Mineralising fluids underwent two stage boiling at temperatures of 145 to 2300 C. Boiling resulted in the loss of approximately 3 wt.% CO to the vapour phase. 2 Fluid salinity was probably I wt.% NaCl or less.

Jan 1, 1990

THE problem of reaction rates in the open-hearth process is essentially that of trying to form a fairly clear picture of the "chemical mechanisms" in the bath. Quantitative data on reaction rates would perhaps not be of much practical importance even if they were available; however, what few approximate data there are can be used in combination with data given in Chapters 16 and 17 to sketch a picture of the "chemical mechanics" of the open-hearth process that is consistent with essentially all the present available evidence. The result may later be found incorrect in many details but even so it will illustrate certain useful methods for obtaining a clearer understanding of the process. Consistent with the treatment in Chapter 15, but in simpler terms, we may say that chemical reactions in general involve the following elements or steps : 1. The reacting molecules are mixed together in space in such fashion as to favor collisions among them. 2. Units of what is usually an intermediate molecular arrangement called an activated complex are formed at a certain rate, depending on temperature and concentrations. 3. .These activated complex units decompose into the reaction products (this step usually assumed to be so rapid as never to limit the over-all process). 4. In any of these steps, heat energy may have to flow into, or away from, the reaction zone to permit the reaction to proceed. 5. The products of reaction will usually have to move out of the way to permit further reaction. The temperature factor enters mainly through step 2, and its effect is very marked. (What is called temperature is really the mean energy content of all the molecules of the substance involved; at any one temperature a certain proportion of the molecules will have much higher energy content than the mean value.) Various reaction rates measured at around room tem-

Jan 1, 1964

By A. Goldberg, T. E. Tietz, J. E. Dorn

INTRODUCTION THE concept that the flow stress for plastic deformation of metals in the work hardening range is a function of the instantaneous values of the strain, strain rate and test temperature was promulgated by Ludwick1 many years ago. This thought has been more or less a guiding principle throughout the immediate period of development and growth of mechanical metallurgy. It has been tacitly assumed or knowingly applied to many investigations on the plastic behavior of metals. Spurred by the theoretical interest and practical importance of the plastic behavior of metals, many investigators have attempted to determine empirical, semi-empirical, and theoretical equations2-18 relating the flow stress with the strain, strain rate, and temperature. Although the applications of such equations have been extensive, the experimental verification of the existence of a mechanical equation of state is weak. Furthermore, some of the available evidence on plastic flow appears to suggest that no simple functional relation between stress, strain-rate, strain and temperature can exist. The mechanical equation of state demands that [a = a(e, E, T)[I]] Where o = true stress = load/instantaneous area e = true strain = In Instantaneous gauge lengths initial gauge length e = true strain rate T = temperature] This formulation implies that [da] is an exact differential. Therefore the flow stress (o) is a function of the instantaneous values of the strain (e) the strain rate (e) and the temperature (T), independent of the previous mechanical or thermal history. Having reached a certain strain, strain rate, and temperature, by any path whatsoever, a definite and fixed value of the flow stress should be obtained. One check on the validity of the mechanical equation of state is easily obtained. Consider the following three tests on the stress-strain curve at constant temperature: [A. Strain at rate [ei] B. Strain at rate i2 C. Strain at rate [Ei] to [ei] and continue test at i2] A graphical representation of possible results of such tests are shown in Fig I. If, for strains greater than [el], test (C) data coincide exactly with the data from test (B), as shown in Fig Ia, a limited verification of the mechanical equation of state is obtained for the range of strain rates from [ii] to [e2]. But if the data from test (C) differ from those of (B) beyond strain [el] where the strain rate is changed from [e,] to [€2i] the mechanical equation of state is not

Jan 1, 1948

By John Wulff, H. H. Uhlig

Since its first mention in the literature in the eighteenth century12 the phenomenon of passivity in metals has stimulated much speculation and attendant controversy as to its nature and cause. No one of the numerous theories so far proposed has been generally accepted. ‡ Faraday,' in 1836, associated the passivity of iron with a protective film over the surface of the metal, which materially prevents or slows down reaction with corrosive environments. His theory was that oxidizing acids like nitric acid form an unstable oxygen or oxide layer over the iron surface, which protects the underlying metal from further attack. This concept was simple yet plausible, and without alteration has frequently been assigned in present-day discussions as explanation of the passivity of many metals. With the advent in recent times of stainless steels, it is not surprising that this oxide film theory of passivity proposed by Faraday has been used to explain the phenomenal corrosion resistance of stainless steels and other passive alloys. The passive alloys, such as the chrome-iron alloys, are supposedly covered with a protective oxide film, which forms on exposure of the alloy to air, is extremely stable and self-healing, and accounts for the remarkable resistance of these alloys to corrosion. Within the past few years, several investigators, following the theory of film protection, have attempted to gauge the resistance of the supposed film on steels. Brennert8 and Donker and Dengg9 determined the potential at which a negative ion (e.g., C1-) moving in an electric field reacted with the metal anode, as detected by increased current flow or change in potential of the steel electrode in an electrolytic cell. The potential corresponding to reaction Brennert called the film break-through potential.

Jan 1, 1939

By Bowling K. McG, Hamilton J. D G

The influence of three important para- meters which affect the induration of iron-ore pellets, viz temperature, time, and lime content, have been assessed in terms of internal pellet structure and commonly-used pellet quality criteria. The pellets studied were produced from a typical hematite ore from the Pilbara area of Western Australia, using a 25 cm dia. pot-grate test rig. Isothermal laboratory induration tests were conducted in accordance with a statistically-planned programme. The internal structures were studied by optical microscopic examination of polished sections of the test pellets. The effects of SFCA (silico- ferrite of calcium and aluminium) and slag formation, matrix consolidation and grain modi- fications were studied, and have been related to pellet properties and to the time/temperature histories produced by the firing conditions chosen. The implications of the data for commercial pellet plant operations are discussed.

Jan 1, 1974

By J. B. Morrow

WITH numerous plans under consideration for coal classification, and with the advent of the Bituminous Coal Code, the intelligent sam-pling of coal has become increasingly important. To us it is rather significant that there have been very few fundamental studies of coal sampling in American technical literature since those of E. G. Bailey, which appeared in the Journal of Industrial and Engineering Chemistry in March, 1909. He covered the subject up to that time so thoroughly and in such an excellent manner that perhaps many other later students have felt that they could add very little to his findings. The recent studies of the British Engineering Standards Association have indicated the possibility of a somewhat different interpretation of Bailey's results, permitting the taking of smaller samples, and perhaps it will now be helpful to reopen this question. C. W. H. Holmes, in an informative series of articles on coal sampling recently published in Colliery Engineering, makes two rather interesting statements, as follows: It is scarcely surprising to find a lack of interest and knowledge regarding the sampling of coal not only in the mining industry itself but also among consumers of industrial fuel: at its best coal sampling is a dirty business, regarded as a nuisance and an expense by the commercial man, and usually as a nuisance and nothing else by the chemist. The writer can conceive only two classes of people who have never experienced any difficulty in obtaining representative samples of coal from wagons; those who have never tried to, and those who have never had the necessity or desire to check the accuracy of their work. The primary purpose of this paper is to present some tabulated data of the more significant results of a sampling investigation undertaken during the last four years to obtain certain fundamental data on the variables connected with coal sampling and to point out that often assumptions have been made that are not in accordance with the facts. One of the standard sampling methods states:

Jan 1, 1935

Access to the Rosebery Orebody, which dips into the western slopes of Mount Black at 45¦, has been achieved in sequence by the following means: - A series of adits down to 8 level - An inclined shaft (No. 1 Shaft) sunk internally from 8 level to 14 level - A vertical circular concrete lined shaft (No. 2 Shaft) sunk internally from 4 level to 19 level. Although the orebody has been fairly well defined to 19 level, deeper ore occurrences have been outlined by a series of drill holes decreasing in frequency with depth to 26 level. No. 2 Shaft (sink) was stopped some 10 m below 19 level in order to make an early start on doubled production at West Coast Mines, with the intention of subsequently extending the shaft or of driving a decline from the lowest operating horizon for deeper access. The decline approach was adopted some six years after production commenced from No. 2 Shaft. The reasons for that decision are outlined, together with an account of the constraints and design requirements imposed by commencing by a vertical shaft in the hanging wall of the orebody.

Jan 1, 1982

By J. E. Zeilinger

This Bureau of Mines report describes the preparation characteristics of the significant coalbeds of Clarion County, Pa. Of the 15 samples collected, 1 was of metallurgical quality as received, 4 could be sufficiently upgraded to provide acceptable products, and the remaining 10 samples could not be upgraded to metallurgical quality because their sulfur contents could not be lowered to meet the standard. For steam or power generation, 1 sample was of low sulfur content as received, 1 sample could be upgraded to low sulfur content, and 10 samples could be upgraded to medium sulfur content. The original sulfur content of the remaining three samples can be appreciably reduced by removal of the sink 1.58 specific gravity material; however, these coals would be classified as medium sulfur coals both before and after removal of the sink material.

Jan 1, 1968

By Baron Miya, Keith Hanks, William Edgerton, Francis Fong

The City of Los Angeles capital improvement program includes the construction of a new 35-km interceptor sewer. This sewer will be built as a deep tunnel with finished diameters ranging from 2- to- 4 meters. The project will be constructed concurrently in two phases; an 18-km East-West and a 17-km North-South segment. The new sewer provides additional conveyance capacity for an existing deteriorating sewer that is scheduled for rehabilitation. Large sewage spills during the El Niño storms of 1998 resulted in a Cease and Desist Order that established an aggressive schedule for the completion of the project.

Jan 1, 1999

Recent mineral exploration successes in the Proterozoic rocks of the Mount Isa Inlier are unprecedented in the regionÆs history. This new era of discovery, particularly for æblindÆ deposits, owes its origin to perseverance and advances in geoscience and exploration techniques, notably geophysics. Prospective host rocks outcrop over more than 50 000 km2 of the Mount Isa Inlier and extend a further 100 000 km2 below cover. They contain major deposits of copper, lead, zinc, silver and phosphate (Georgina Basin) and significant deposits of gold, uranium and cobalt. The discovery in 1923 of silver, lead and zinc at Mount Isa established the regionÆs world-class mineral potential. Since 1990, major orebodies have been discovered at Cannington (silver-lead-zinc), Century (zinclead-silver), Ernest Henry and Osborne (copper-gold) and extensions to known deposits at Dugald River and George Fisher (zinc-lead-silver), and Esperanza (copper). This success is of global significance and reflects a prospectivity upgrade since widespread copper mineralisation was discovered and mined in the Cloncurry district a century ago.

Jan 1, 1998

By G. K. Lee, Whaley. H., F. D. Friedrich, I. C. G. Ogle

"IntroductionCurrent coal combustion activities at the Canadian Combustion Research Laboratory (CCRL) reflect the increasingly important contribution that coal is expected to make in meeting our future energy requirements and in reducing our dependence on foreign oil. Widespread use of coal will, however, be heavily dependent on the ability of conventional and emerging combustion systems to cope with the disruptive conflicts caused by variations in fuel quality, on requirements for better equipment availability .and on the implementation of progressively more stringent environmental constraints.To minimize these conflicts, Energy, Mines and Resources Canada has embarked on a systematic sequence of research, development and demonstration- scale (R, D and D) initiatives to stimulate the utilization and competitiveness of thermal coal in both domestic and export markets through a number of complementary in-house projects and external contracts, considered to have short- to intermediate-term benefits to industry and society.Many of the in-house projects are funded in part by industry, whereas the external contracts are either fully funded (100070 government funding) or jointly funded (50% government - 50% project proposer).External contracts and shared-cost projects are an important adjunct to the CCRL in-house effort on coal combustion, because research data can be more effectively transferred to industry and because the commercialization of novel combustion systems can be accelerated significantly."

Jan 1, 1980

By E. A. Gulbransen, J. W. Hickman

In a previous paper' the authors have investigated the structure of the oxide films formed on most of the metals that make up the alloys of this study. The metals were studied in order to provide basic information on the structures, both physical and chemical, of the oxide films and to determine how these structures are effected by the temperature, time of oxidation, and surface preparation. It was felt that an understanding of the physical and chemical structure as well as the stability of the oxide film might furnish clues as to the nature of the reaction process and the protective quality of the film. The oxidation of the metals was studied over the temperature range 300' to 7o0°C. except for copper, wherc the range selected was 100' to 500°C. The results of these studies were presented in graphical form as existence diagrams of the oxides on a time-temperature scale. For some of the metals the existence diagrams were simple and showed few chemical transitions, but there were numerous cases where the physical state of the oxide surface was a function of time and temperature. In general the physical state of the oxide surface changed with increasing temperature so as to increase the sharpness of the diffraction patterns and to cause orientation effects to be more pronounced. Deviatiois in lattice Darameters from X-ray values were noted. In general these deviations were of positive nature and may be due to solid solution of the metal in the oxide lattice. This effect might be expected in thin oxide films. In a study of the oxidation of alloys containing two or more metals, there may arise the complicating factor of identification of the oxides formed. A thorough understanding of the oxides formed on the pure metals, therefore, was, essential before investigation of the oxidation of alloys. In this paper it is our purpose to present a study of the following problems: 1. The existence diagrams of various alloys. 2. The effect of the structure of the alloying metal on the existence diagram of iron. 3. The effect of the percentage of chromium on the oxides formed on Fe-Cr alloys. 4. The relationships, if any, between the oxides formed and the protective quality of the oxides. The following alloys are included in this study: alloys of iron with body-centered cubic, face-centered cubic and other metals, 13 Cr-Fe, 18-8 stainless steel, K4²B, Nichrome V, Hipernik, Inconel, Stellite "²I," Refractaloy, Kovar, mild steel, a series of Cr-Fe alloys and a series of Co-Fe alloys. Since many of the commercial alloys in this list contain more than two metals, various complicating factors in the identification of the oxides formed may arise.

Jan 1, 1947

By Luiz Felipe Mendonça de Amorim, Adimir Fernando Rezende, Gustavo Sampaio Lopes, Claudio Cesar Gajardo Arraño, Eltton de Sousa Veras, Manuel Villalobos Calderon

Many technical challenges were encountered while conducting near-field construction blasting between the critical intersection of Interstate 10 and multiple active railroad tracks in El Paso, Texas, for the Loop 375 Border West Expressway Project. Blasting was utilized for the removal of an andesite bedrock ridge in preparation for the construction of a new elevated super structure to be suspended over the existing railroad tracks. There was concern that the excessive vibrations and/or permanent rock deformation produced from the blasting within near proximity (20 feet, or 6.09 meters) of the railroad tracks would induce excessive stress and foul the tracks by shifting the alignment. This could result in a major loss of scheduling control between the two major railroad companies that operate in this area. There was also concern that the blasting may cause rock fragments to land on and interfere with critical interstate transportation. Blasts

Jan 1, 2019

By Fernando Linares Quiroa

El diseño y operación de la mina es un proceso importante para la construcción de un modelo de cuerpo mineralizado. En este sentido, el presente texto describe la trascendencia del modelo geológico, construcción y uso de este para la extracción del mineral, donde este es una representación de la realidad que se genera a partir de la información predecible y proporciona a los geólogos e ingenieros de planeamiento los recursos más adecuados para una efectiva selección y extracción del mineral tanto física como económicamente. Asimismo estos bloques permiten la manipulación de la información contenida en estos a una escala local y describen contenido sobre las características tales como: leyes, dureza, peso específico, RQD, litología, mineralización, alteración, metalurgia, etc. Finalmente, los usos que se dan a los modelos de bloques se aplican al control del mineral, planeamiento a corto, mediano y largo plazo, el cáculo de los recursos geológicos y las reservas minerales, constituyéndose en la base para la optimización y del diseño del tajo.

Jul 31, 2003