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By Walshe JL, Solomon M

The Emperor vein system lies on the eastern margin of the Tavua volcanic structure. This is of Miocene age and occurs in basalts(the Mba Volcanics) probably underlain at about 2 km by calcite-rich sediments (the Vatukoro Formation). The lodes are generally flatmakes, or steep fault fillings, or complex shatter zones, and consist of quartz and altered wall rock. In areas of open cavities it is possible to establish a paragenesis which involves five quartz stages and two ore mineral stages. The first ore stage contains calaverite, krennerite, sylvanite and native tellurium, the second petzite, hessite and native gold. The quartz stages are thought to have formed slowly (102 years) from boiling solutions of low salinity at temperatures varying with time from about 250¦C to 190¦C. The system was sealed, the temperature gradient near vertical and the mass flux small. The ore mineral stages probably formed relatively rapidly (101years) from boiling solutions at 250¦ to 200¦C when the system was mainly open. Gold deposition was probably largely a result of fall in aH2S due to boiling, the calculated solution concentration falling from a maximum of about 8 ppb at 250¦C to about 8.10-3ppb at 200¦C. Boiling is also probably responsible for an increase in a02 (by loss of H2) and fall in aTe2 (by loss of H2Te). The fluids are thought to have had a large component of meteoric water and to have been heated by plutons in the core of the volcanic structure. Stable isotope data indicate that they derived their carbon from the underlying Vatukoro Formation and their sulphur from sediments. Circulation may have been confined to the outside of the volcanic structure because of the relatively low permeability of the flows, pyroclastics and dykes within it.

Jan 1, 1987

By Thomas T. Read

The cost of labor turnover in industry is so large as to justify the adoption of almost any means to bring about its reduction. Intensive study has shown that faulty methods of hiring and discharging men is the most important factor in labor turnover. Complete control over hiring and discharging by the foreman is a relic of outgrown industrial conditions; centralized hiring permits this work to be put on a scientific basis and also does away with many serious evils that cannot, otherwise be reached. Centralized hiring does not impair the authority of the foreman; he hires his men from the employment office and discharges them back to it, instead of from and to the street. The employment manager, being a direct representative of the employer, tends to restore the former relation of direct intercourse between employee and employer that was helpful in avoiding friction between them. Being a specialist,, he is able to bring special knowledge and skill to bear upon the task of selling employment in his concern to desirable workmen; he is also able to give the foreign workman the special attention he requires. Employment managers have been used for the past few years by a number of large organizations, a few of which are engaged in the mining and rnetallurgical industries. They have invariably reduced labor turnover, in some cases to as little as one-tenth of what it had been. So great a reduction is due in part to other changes made in the light of the data made available by scientific study of the labor problem. In my former paper on personnel work' I advocated the more general use of the employment manager in mining and metallurgical enterprises as a means of reducing labor turnover. The form of organization recommended seems not be to understood by all, and I have requested the privilege of explaining it at greater length, since it is perhaps the most important factor of all in personnel work, and has a vital influence on the cost sheet of every industrial enterprise.

Jan 1, 1918

By J. M. Neilson

The occurrence of iron ore deposits in the State of Western Australia has been known at least since the 1930's,3 but the true significance of the deposits has only come to light within the past four years. Although they are widely distributed throughout the State, it is now known that more than 90% of the available iron ore reserves are located in the "Hamersley Iron Province". Western Australia may well contain the world's largest known reserves of iron ore. Recent reports place this reserve at 15 billion tons and an even higher figure may appear in the future. LOCATION, CULTURE AND COMMUNICATIONS It is difficult to comprehend the immense size of Western Australia (Fig. 1). The State occupies almost one million sq miles and it is more than 2000 miles from north to south. More specifically, it stretches from the 14th to the 35th parallel of latitude south. The Ophthalmia Region in the Hamersley Iron Province is barely halfway up the long dimension of the State. Nevertheless, the region is 800 miles north of Perth, a distance comparable to that from New York to Chicago or to that from Chicago to New Orleans. The Hamersley Iron Province (so named in 1963 to distinguish it from the Pilbara mineral district adjacent to it on the north) covers an area of approximately 30,000 sq miles in the northwestern part of the State. It extends in a roughly oval form from the Indian Ocean to the Gibson Desert of the interior, a distance of about 300 miles. With the exception of the small coastal towns of Onslow, Roebourne and Port Hedland and a few other communities such as the asbestos-mining town of Wittenoom, the region is very sparsely populated. Sheep and cattle stations are scattered thfough the region and these and the main towns are connected by truck tracks and a few main highways. Voice communication is almost entirely by the short-wave radio net operated by the Royal Flying Doctor

Jan 1, 1965

By d&apos, Kathleen J. Amico

THIS summary appears in Minerals Yearbook volumes I and III, which cover mineral production in the United States, its island possessions, the Canal Zone, and the Commonwealth of Puerto Rico, as well as the principal minerals imported into and exported from the United States. The several commodity and area chapters contain further details on production. A summary table comparing world and U.S mineral production also is included.

Jan 1, 1964

By M. van Swaay, C. E. Birchenall

Palladium has a large capacity for the dissolution or occlusion of hydrogen; the gas also diffuses very rapidly through the metal. Palladium thimbles are widely used in the laboratory for purification of hydrogen by diffusion. The use of palladium filters could be extended to several large-scale applications if greater stability of the permeation process could be attained. In this paper a number of aspects contributing toward this goal are discussed, and new data on solubility and diffusivity are given. Palladium sheets of 0.005, 0.010, or 0.020 in. thickness were prepared by three procedures: casting and rolling, sintering palladium powder, and sintering palladium powder to which 0.1 pct thorium oxide had been added. Half-inch diam circular specimens were cut and clamped in a stainless steel holder provided with knife edges to seal the palladium sheet with soft copper gaskets. The seals were tested for leaks at l0-5 mm Hg. No difficulties from this source were encountered even after many temperature cycles in the system. The holder was silver-soldered to Kovar-glass seals and attached to the system through glass ball joints. Each joint was sealed with Apiezon wax and was adjacent to a cold trap. In several experiments the holders were fused directly into the system, eliminating the ball joints, to show that the wax did not affect the filter. Three filter holders were supported in holes in a stainless steel cylinder, which also acted as a temperature equalizing block inside the resistance wound furnace. The measuring thermocouple was inserted in one of the holders. A potentiometric controller with control thermocouple on the furnace heater winding maintained ± 0.2oC. Electrolytic hydrogen was purified and stored as shown in the flow diagram, Fig. 1. It could be admitted to either or both sides of the palladium specimens. Only a mechanical pump was used, for even high pumping speeds would not bring the pressure on the off-gas side of the filter below 10 to 50p Hg owing to the rapid hydrogen flow through the filters. A series of steady-state permeability studies allowed identification of several conditions of permeability loss. A constant fore pressure was maintained while the low-pressure face was pumped. After enough time had elapsed for a steady flow to be established the pump was cut off, and the rate of pressure increase in a thermostated bulb was measured to determine the flow rate. The time delay method of Daynes1,9 was adopted since it offered the possibility of determining solubilities and diffusivities. For each measurement both sides of the filter were evacuated for 15 min, which gave about 10-4mm Hg residual pressure. Hydrogen was admitted to one side or the other of the filter at a fixed pressure. The pressure on the off-gas side was observed as a function of time. A

Jan 1, 1961

By David W. Houseknecht

Probabilities of encountering coalbed discontinuities during vertical or horizontal drilling in a specific coalbed can be estimated based on analysis of mined-out areas of the coalbed where the size, shape, orientation, and distribution of discontinuities are known. The result-ant probability estimates can be applied to cost-risk evaluations of drilling programs proposed for exploratory, developmental, or methane drainage purposes in undeveloped areas of that coalbed. Data compiled from mine maps of the Beckley Coalbed in southern West Virginia were used to estimate the probabilities that discontinuities would be encountered in two illustrative hypothetical drilling programs--one for drilling vertical boreholes and the other for drilling horizontal boreholes. Analysis based on a mined-out area of the Beckley Coal bed indicated that vertical methane drainage boreholes spaced 1,000 feet apart in a square grid pattern would each have a 29 percent probability of encountering a discontinuity in a geologically unexplored area of the coalbed. It was also determined that exploratory vertical drilling could locate most of the discontinuities if a borehole spacing of 2,500 feet were used. For horizontal drainage boreholes in the Beckley Coalbed, the analysis indicated a linear relationship between hole length and the probability of encountering a discontinuity.

Jan 1, 1982

By Irving R. C

THE objective of the iron smelter is naturally the production of high quality iron at the lowest practicable cost. To enable this, large tonnages are put through the blast furnace, and, at the same time, the quality of the iron must be under definite control.The modern blast furnace enables these objectives to be attained. The description whieh follows sets out the general details of construction of such furnaces, and the operation at thc Broken Hill Proprietary Company's blast furnaces at Newcastle, New South Wales.The occurence of iron in many forms is so well known as to need no description. Modern civilisation may be said to be built on a foundation of iron, and, today, the production of iron and steel has beeome one of the world's industries.A short historical introduction will serve to show the evolution of the processes and apparatus since iron production assumed importance.There is no definite date fixed as to when iron was first made, or by what means it was first discovered. Perhaps prehistoric man threw iron bearing stone on to his fire, and these became reduced, Ieaving a soft metal behind, or more probably the first iron was of meteoric origin.There is evidence, however, to prove that it has been known for a period of 6000 years. Iron has been found in the Pyramids and its use was known to the early Eqyptians and later to the Hebrews, Assyrians, Greeks and Chinese. Following the Greeks, the Romans excelled in its extraction and uses in the manufacture of their instruments of war, and to this fact can largely be attributed the success of their many wars of conquest. As the Romans overran the rest of the then known world they carried the art with...

Jan 1, 1930

By Herryal Z. Anwar

In recent years, many both mining and civil engineering projects are developed in the area which may be categorized unstable, such as fractured and jointed rocks or "water sensitive rocks". For example, in underground coal mining, in which the floor strata normally consist of weak shale, the problem that may arise in roadway is floor heaving. In this case cement injection in borehole appears to be an economically effective method in order to make roadway more stable. This method may be also applied in the projects in which the constructions are laid on fractured and jointed rock. Nevertheless, the successful cement injection is much dependent on the water-cement ratio and the injection technique. This paper discusses the application of cement grouting to improve the ground stability in longwall mining, the laboratory experimentation of cement grouting and the method of floor injection.

Jan 1, 2000

By M. C. Chang, J. Dasher

The Crucible mine in Pennsylvania, operating on Pittsburgh seam coal, is rated at 5000 tpd. The washing plant, built in 1943, is rated at about 400 tph, using hydroseparator boxes to wash the coarse coal (4 x 5/16 in.) and hydrotator units for the fine coal (5/16 x 0). It is generally acknowledged that gravity concentration equipment cannot be used efficiently to bene-ficiate coal finer than about 65 mesh. Before the present flotation circuit was installed, Crucible recovered its fine coal slurry, predominantly —24 mesh material, by passing it through a battery of five 14-in. and one hundred and ten 3-in. Hey1 & Patterson cyclones in parallel with a 75-ft Dorr thickener. About two thirds went to the cyclones and one third to the thickener. Underflows from cyclones and thickener were filtered, respectively, in one 12-disk Eimco and two 4-disk Oliver filters fitted with stainless steel cloth. The resulting cakes were added to the coarse metallurgical coal. The filtrates, overflow from the 3-in. cyclones, and thickener overflow were recycled to the coarse coal plant. The three major problems encountered in this system became acute when the mine switched from track-mounted machinery to the more economical off-track equipment. The quality and uniformity of product declined, too much slime accumulated in the circuit, and waste pond disposal became highly impracticable. Lowering of Quality and Uniformity: Since the filter cake was not beneficiated in any way, addition of this material, which contained about 18 pct ash. would certainly lower the quality of metallurgical coal. Difficulties of handling the high-ash, high-moisture cake were compounded by the lack of adequate blending facilities at the mine, making it impossible to maintain uniform feed for the coke ovens. For a two-month test period, to verify the source of trouble, all filter cake was excluded from the metallurgical coal. The excluded filter cake was stocked in the yard. Slime Buildup: The moisture retained in the coarse coal products and the filter cake provided daily the only means of slime bleed from the circuit. As this bleed was not enough to offset the incoming fines in the raw coal feed, there was excessive buildup of slimes. To operate at all, it was necessary to purge the system each weekend by pumping all the solids from the thickener to a waste pond. The slimes built up during the week progressively increased the apparent viscosity and density of the circulating plant water, so that hydroseparators and hydrotator units had to be constantly adjusted. Uniformity, yield, and quality of the metallurgical coal suffered in consequence, and the filter cake ash and moisture contents increased from Monday to Friday. Limited Waste Disposal: Location of the plant does not permit unlimited waste pond area. Maintenance of a waste pond for the purpose of emptying the thickener during weekends became a costly burden that could not be tolerated. HOW THE PROBLEMS WERE SOLVED The flowsheet (Fig. 1) chosen to overcome these difficulties is considered the one most economical to install and operate. In a preliminary change made before the flotation circuit was installed, the cyclones and thickener were first operated in series, the overflow from the 3-in. cyclones, after flocculation, being discharged into the thickener and the thick-

Jan 1, 1960

By Trois P

A fully instrumented and bench-mounted diamond drilling machine, purpose designed and built, has been used for investigating the effect of aqueous solutions of various chemical compounds when used as drilling fluids. The rocks investigated were andesite, basalt and granite, the chemical compounds were alkylamines, with various hydrocarbon chain lengths, aluminium chloride and dioxane. Rotation speed seems to be one of the major factors affecting the emergence of mechanochemical effects as the results obtained with aluminium chloride clearly indicate. Penetration rate is either unaf- fected or enhanced by the presence of certain compounds, such as aluminium chloride. On the other hand, penetration rate diminishes when the drilling fluid contains dioxane and exhibits an apparently unpredictable behaviour with alkylamine solutions, although it appears that an increase in hydrocarbon chain length usually equates to an increase in penetration 1. Full Professor, Mining and Mineral Dressing Department University of Cagliari - Italy 2. Associate Professor, Mining and Mineral Ikea- sing Department University of Cagliari û Italy rate. Rock texture seems to have a pronounced effect on test repeatability. With hexadecy- lamine acetate solutions in concentrations ranging from 10-5 to 5 .10-4 molò dm 3 and 41.88 radòs-1 rotation speed, 46 % increments in penetration rate of andesite were observed, with respect to water, whereas penetration rate decreased in basalt by as much as 60¦%o when a dioxane solution was used as drilling fluid. An interpretation of the observed effects is proposed in the light of current knowledge of solid state physics and physical Chemistry.

Jan 1, 1992

On Monday, October 25th, 1971 at approximately 12.15 a.m. the night shift proceeding underground discovered smoke at No.1 and No-3 cut throughs on the eastern side of the belt heading and in close proximity to the upcast shaft. Attempts to control the fire continued throughout the morning; as the position underground altered various procedures were adopted in an effort to contain and control the fire. Despite these efforts at approx. 12.40 p.m. a sudden change occurred which made it necessary to withdraw all workmen from underground, the vicinity of the Tunnel entrances and upcast shaft. Sealing of the mine at the entrances was the only remaining alternative. Several boreholes were put down to enable sampling of the atmosphere and air temperatures to be taken. This was essential as a guide to determining when conditions were suitable to allow exploration of the area using mine rescue self contained breathing apparatus.

Jan 1, 1972

By Yoon T. Auck, Milton E. Wadsworth

Column leach studies of two low grade prophyry copper ores were made with variables of size, flow rate, pH, drainage rate and tempature. Evidence is presented to show that, in some types of ores, sulfide minerals block leaching channels and regulate the rate of dissolution of gangue constituents. Basic iron sulfates, dissolved by introducing acid, provide oxidizing agent in the form of ferric ion in the absence of oxygen. Ferric ion then acts to release copper from the ore. Oxygen up-take was found to increase with the lowering of the pH and to follow parabolic kinetics attributable to the precipitation of basic iron salts within the pore channels. Slow drainage of residual gravitational water can seriously retard oxygen up-take during oxidation for particles in the coarse sand range. A model is presented for dump leaching in which a reaction zone connected by channels to the surface of the ore particle moves topo-chemically during the course of the reaction.

Jan 1, 1973

By Rowlands N. J, Zimmermann D. O

The Engel Model search simulator is described with particular emphasis on preparation of input parameters. The computer has a "black box" role in the same way a telephone or radio is a "black box" in communications. A search technique (sensor) is selected and applied in two stages of'search, namely, reconnaissance and detailed. The model relies on knowing and quantifying the parameters of the target sought and the search technique; this is usually done by analogy studies from available literature and experience. The parameters are then balanced by feasibility studies on the search area. Case histories show that the study makes the user aware of what he is likely to find rather than what he wants or needs to find to be viable. Two case histories are presented: one for Mississippi Valley type lead- zinc deposits and another for stratiform copper. The first study showed particular benefits in the input stage and highlighted the fact that one could expect a lot of encouragement by way of interesting results but with little chance of finding the high-grade,

Jan 1, 1974

MERLIN, the Queensland Department of Minerals and Energy's corporate geographic information system, provides ready access to all georeferenced data held by the department. Its aim is to provide a consistent, current, statewide coverage of timely information to assist in tenures management, exploration targeting and competing land use decision-making. Initially developed in 1988 and under continual enhancement since then, its functionality is the result of on-going close consultation with a wide range of departmental clients and potential users. A true geographic information system, MERLIN maintains both graphical data with linked textual information on a wide range of features of interest. The proprietary software products Arclnfo and Oracle are used to hold the graphics and attribute information respectively. Access to information is provided by a specially designed graphical user interface programed in-house. Hardcopy output of graphics displays including related attribute data as well as detailed reports of textual information can be retrieved at any departmental office. MERLIN is a network of computer systems which link each of the Department's regional offices and head office in Brisbane. The current state of exploration and mining is maintained by departmental officers processing tenure applications, transactions and dealings directly into the system. Data entered at regional offices are transferred overnight to head office to up-date central records and maintain a currency of data statewide as at the close of business the previous day. Through MERLIN the Department of Minerals and Energy now offers a much streamlined tenures management service as well as access to information about past exploration and mining, Queensland's mineral and energy occurrences and resources, and up-to-date information on the state's geology including maps, boreholes, geophysical surveys and field observations. In the future, this Geographic Information system will be invaluable to the mining industry in the development of mining projects.

Jan 1, 1995

By Falconer A. J

Two magnetic parameters are proposed as a basis for the assessment of ironsands beneficiation. The parameters are deter- mined for raw sand prior to dredging and for magnetic separator head feed over a production period of five months. The relationships between these parameters and the performance of the magnetic separators are examined to establish the value of magnetic assessment compared with the traditional soluble iron assay method. The results illustrate that the first parameter, true magnetic fraction (TMF), has a value superior to that of soluble iron when relating raw sand grade calculated by tri- angulation to magnet performance. In terms of the relationship between magnet head feed grade and magnet performance, TMF and soluble iron perform equally as assessment parameters. For the ironsands mined during the five month period, the second magnetic assessment parameter, composite fraction (CR), is shown to merely reflect TMF and offers no additional information for assess- Ment. Conclusions are that true magnetic fraction has many advantages over soluble iron in terms of time and cost of determination and that it is a meaningful and reliable parameter upon which to base all calculations relating to the mining and beneficiation of ironsands.

Jan 1, 1980

By Kilgour I

The installation of a final cleaning column at Ok Tedi Mining Limited was carried out to increase final concentrate grade in order to reduce concentrate handling, shipping and treatment charges and to reduce penalty payments. To fast-track the project a decision was made to install a full-size column on one of the two parallel circuits, designed on information readily available and utilising the experience of mill staff and an engineering consultant, rather than delay installation while a pilot scale program was conducted. A 3.66 m diameter by 12.8 m high column was installed to produce 40 t/h of final concentrate from a combination of rougher concentrate and recleaner concentrate. The column design and sparger system were by Cominco Engineering Services Limited.

Jan 1, 1991

By Isabel F. Barton, J. Brent Hiskey

Chalcopyrite (CuFeS2) is the earth’s most abundant copper ore mineral, but is refractory to leaching with sulfates, chlorides, and other common lixiviants and oxidants. This has led to increasing research into alternative lixiviants for recovering Cu from chalcopyrite. Here, we review the leach kinetics of chalcopyrite in glycine, ionic liquids, and methanesulfonic acid, compared to baseline ferric sulfate and ferric chloride. Glycine (CH2NH2COOH) has long been used in applications such as biocatalysis and electroplating, and has recently been examined as a lixiviant for whole ores and concentrates of both copper and gold. It is nontoxic, biodegradable, and capable of strongly complexing Cu2+. Compatible oxidants are peroxide, dissolved oxygen, and ferric sulfate. Chalcopyrite leaching rate in glycine is chemical reaction-controlled, but the effects of grain size and the reaction orders with respect to lixiviant and oxidant concentrations and mass transfer vary. The use of ionic liquids as a leaching agent for chalcopyrite has been extensively investigated in recent years. This system is based primarily on the use of the imidazolium molecule (C3H5N2), which is a planar 5-member ring structure. This lixiviant has been applied to the leaching of chalcopyrite in the form of pure mineral, concentrates, and ores. Kinetics of ionic liquid leaching of chalcopyrite vary substantially depending on the type and concentration of ionic liquid. Methanesulfonic acid (HCH3SO3) is one of the newest lixiviants available in leaching, having only been examined in the last decade. It has been examined as a substitute for sulfuric acid, since it is less corrosive, is biodegradable, and breaks down to carbon dioxide and sulfate over time. The rate of copper leaching from chalcopyrite by methanesulfonic acid is controlled by diffusion and exhibits a strong dependence on oxidant type and concentration. Despite promising reaction rates and total extraction by some of these novel lixiviants, comparison with baseline ferric sulfate and ferric chloride systems makes it doubtful that any will be commercially viable in the near term. Only at very high reagent concentrations and temperatures, and/or very fine grain size, did any of the systems perform comparably to the much cheaper ferric chloride at extracting Cu from chalcopyrite. Most had similar overall reaction rates and total extraction to ferric sulfate, which is relatively common and cheap. However, the leaching kinetics of these novel lixiviants offer valuable insight into the dissolution behavior of chalcopyrite in various systems.

Jan 1, 2019

By Ralph L. Brown

"IntroductionThe accumulation of gummy and resinous deposits in consumers' gas meters began to assume serious proportions about 1917. As the trouble developed and spread in the years following, it manifested itself in several ways, which ultimately began to the expressible in distinctly economic terms, more specifically in terms of costs; in 1922 an organized and fundamentally based investigation of this trouble was begun. In an earlier paper*** a short statement of the occurrence and costs of the deposition was given and at the same time an analysis of the problem, as well as well as a general plan of attack, was presented. That plan included two general phases, first, a chemical study of typical was 1 quarry or 2 cosinous content , mauformly consituents, rmln and selected subjects; and secondly, a comparative survey of plants affected and sufficient therewith, attention being paid to construction, operation, meter conditions and related data. In reporting progress in the axtual investigation, it was definitely set down that the basis of the gummy deposits was the unsaturated hydro consulting from the carburxtion of the water-gas with oil. That the presence of oily-gas condensate was closely associated with and largely"

Jul 1, 1923

By J. H. Hollomon, L. D. Jaffe

The hardenability concept has become widely used during the last few years for the choice and substitution of steels. Before the work of Grossmann,1 the systems for predicting hardenability from chemical composition could be used only over a narrow range of composition. Grossmann introduced a comprehensive system, which has been effective in calculating the hardenability of most types of moderate or low-alloy steels. However, occasions often arise that require the calculation of the hardenability of high-alloy steels from their chemical compositions. Experimental determinations of the hardenabilities of such steels indicate that the Grossmann system predicts much greater hardenabilities than are realized. The fact that cases do arise in which the Grossmann method does not apply indicates that the fundamental hypothesis of the system may not be generally applicable. It seems advisable to re-examine not only Grossmann's system but also the concept of hardenability itself. Hardenability If steel parts are to possess a martensitic structure after quenching, they must first be austenitized and then cooled through the pearlite and bainite transformation ranges sufficiently rapidly to avoid the formation of pearlite, bainite, and pro-eutectoid products.* If, on cooling, these transformations are avoided, the resulting structure can consist only of martensite (and retained austenite). The hardenability of a steel is measured in terms of the severity of the cooling conditions necessary to avoid the pearlite and bainite transformations. The less rapid is the cooling necessary to prevent the formation of bainite and pearlite, the higher is the hardenability. The pearlite and bainite reactions appear to be differently affected by the alloying elements. Not only is this indicated by the published isothermal transformation data, but recent work by Zener2 affords a rational interpretation of the differing effects of the alloying elements. Manganese,3 for example, appears to decrease the rates of the pearlite and bainite transformations by equal percentages, while molybdenum45 is approximately 10,000 times more effective in retarding the pearlite than in retarding the bainite transformation, on the basis of isothermal measurements. In some steels, the formation of bainite restricts the formation of martensite while

Jan 1, 1947

By Otto H. Henry, Edward L. Badwick

Up to the present time, according to Hansenl and Haughton,² the constitution of the bismuth-indium system has not yet been published. The generally accepted value for the melting point of indium, as listed in most scientific journals and textbooks, is 155°C. Recently, however, H. M. Davis3 has determined a new melting point for indium of 157.3²C O.l°C. Since bismuth has been used in preponderance as an alloying element in the majority of low-melting alloys, and indium has been used with considerable success in lowering the melting points of low-melting alloys, 4,6 an interest has been developed in the application of these two metals, making a complete knowledge of the constitution of its alloys desirable. In this investigation, the melting point of indium reported by H. M. Davis has been found to be substantially correct. A value of 157. ²°C ± O.5°C was determined. The two eutectic compositions have been placed at 34 and 50 pct bismuth with their respective eutectic temperatures as 72.4°C ± 0.5°C and 90°C ± 0.5°C. The bismuth-indium phase diagram has been determined by thermal and microscopic analysis and is shown in Fig I. Thermal Analysis Granulated bismuth and indium shot, having a guaranteed purity of 99.99 and 99.95 pct, respectively, were melted in a carbon crucible by means of a laboratory heater. To minimize oxidation of the alloys, a heavy mineral oil (Nujol) having a high- flash point was used. A platinum-platinum rhodium thermocouple of fine wire encased in a thin-walled Pyrex glass tube, about 1/8 in. in diameter, was connected to a type K potentiometer for temperature measurements. The thermocouple was calibrated against the melting points of tin, bismuth, and the silver-copper eutectic and the boiling point of water. Since the temperature readings could be reproduced to 0.²°Cl and the accuracy of the temperature standards in this range is slightly better than 0.5°C, it scems reasonable to assume that the temperature readings are reliable to approximately 0.5°C. The cooling rate could be controlled by varying the amount of insulation surrounding the crucible. Three or four layers of asbestos paper, 1/16 in. thick, sufficed to give a cooling rate of from I° to ²°C per minute. Undercooling was slightly noticeable. This condition was minimized by vigorous stirring, since the advantage of using slower rates was too small to justify the greater expenditure

Jan 1, 1947