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By B. D. Sartwell

The formation of alloyed regions near the surface of metals using ion implantation is being investigated by the Bureau of Mines as a means of providing corrosion resistance using much smaller amounts of the strategic alloying metals. Two ion implantation systems that can implant low-energy chromium, nickel, or aluminum ions into low-cost substrate materials such as iron or carbon steel have been designed and constructed. The development of the ion source, ion beam acceleration stage, mass analysis system, and target chamber are described in detail. The ion-implanted alloys have been characterized using proton-induced x-ray emission to give the total number of atoms implanted and to determine the extent of any surface contamination introduced by the ion implantation process. Research conducted at other laboratories on metallurgical applications of ion implantation is given.

Jan 1, 1980

By R. V. Ramani, G. W. Luxbacher

Computer simulation of mine ventilation system is rapidly becoming an essential tool in mine planning and design. This Paper examines the utilization of ventilation simulation techniques to evaluate the number, shape, size and layout of mine entries in a typical coal mining system. Since the mains and sub-mains serve primarily for transportation and ventilation and the ventilation system is critically important to the health and safety of the workers, there exists a great need for optimal designs in this area. Evaluation criteria could include, among others, minimization of power costs, shaft requirements and leakage. Constraints of this optimization problem include health and safety regulations and production and mine infrastructure requirements.

Jan 1, 1980

By Rudolf E. Greuer

It is undisputed that an interaction between mine fires and mine ventilation systems exists. The ventilation carries the poisonous and sometimes explosive combustion products, which constitute the greatest danger of mine fires, through the mine and it provides the oxygen on which the intensity of the fire depends. The fire, on the other hand, can produce considerable ventilation disturbances which make it difficult to predict the path along which the combustion products travel. The opinions, how serious a threat such fire generated ventilation disturbances are, vary. Where shallow deposits are mined and brisk ventilation currents are used, it is frequently felt that these disturbances are of no serious concern. Where mine workings extend over larger elevation differences and where such disturbances have been encountered and been the cause of some larger disasters, their assessment is an integral part of all fire emergency plans. The author felt that the potential of digital computers for the design of ventilation emergency plans, contrary to their acceptance for conventional ventilation planning for more than two decades, is not yet fully utilized. He designed a program for the simulation of ventilation systems under emergency conditions in particular fires. This was part of work completed for a contract with the U.S. Bureau of Mines ( Open File Report OFR 115(1)-78)

Jan 1, 1980

By Robinson B, Ham B

Outbursts have occurred irregularly in the Collinsville Coal field since 1954 when an incident claimed seven lives. Further significant outbursts occurred in 1960, 1961, 1972 and more recently in the No. 2 mine in 1978. From the information collected over 25 years a comprehensive program to minimize the hazard of outbursts has evolved. Further developments of techniques to combat outbursts are being developed.

Jan 1, 1980

By W. N. Marchant

[The citrate process for flue gas desulfurization (FGD) is a product of continuing research by the U.S. Bureau of Mines to meet the goal of minimizing the objectionable effects of minerals industry operations upon the environment. The reduction of SO2, in solution by H2S to produce elemental sulfur by the citrate process is extremely complex and results in solutions that contain at least nine different sulfur species. Process solution analysis is essential to a clear understanding of process chemistry and its safe, efficient operation. The various, chemical species, the approximate ranges of their concentrations in citrate process solutions, and the analytical methods evolved to determine them are hydrogen sulfide (~0M to 0.06M) by specific ion electrode, polysulfides (unknown) by ultraviolet (UV) spectrophotometry, elemental sulfur (~0M to -0.001M dissolved, ~0M to ~0.1M suspended) by W spectrophotometry, thiosulfatc (~0M to ~0.25M) by iodometry or high performance liquid chromatography (HPLC), polythionates (~0M to ~0.01M) by thin layer chrornatogrphy (TLC), dithionite (searched for but~ not detected in process solutions) by polarography or TLC, bisulfite (~0M to 0.2M) by iodometry, sulfate (~0M to 1M) by a Bureau-developed gravimetric procedure, citric acid (-GM to 0.5M) by titration or visible colorimetry, glycolic acid (~0M to 1N) by HPLC, sodium (~1.5M) by flame photo¬metry, and chloride by argentometric titration.]

Jan 1, 1980

By Burgess JM

Research on gas distribution in the iron- making blast furnace has been conducted in three separate areas. Firstly, experimental work has been conducted to determine the important parameters which dictate the pressure losses in homogeneous and heterogen- eous packed beds. Secondly, a theoretical analysis of gas flow through the furnace softening-melting zone has been undertaken to determine the effect of the shape of the zone on the distribution of gas flow towards the furnace walls. Thirdly, a theoretical programme has been undertaken to develop methods for the prediction of furnace soften- ing-melting zone shape from furnace tempera- ture and gas composition measurements.

Jan 1, 1980

By A C. Carter

The increasing need for alternative energy sources as well as the less clearly perceived but equally increasing demand for non-fuel minerals has resulted in extensive exploitation of near surface deposits. Many such deposits have depleted reserves and mining corporations are increasingly turning their attention to deposits, with thicker overburden, less competent materials, steeper dips and more complex structure. These deposits pose mine layout, geotechnical and equipment problems as well as the need for large outputs to achieve economies of scale. The paper describes the major problems and operational solutions for such deposits using continuous excavation and transport equipment.

Jan 1, 1980

By William H. Holley

Thirteen additional preservative/fire retardant systems were applied to Ponderosa pine and evaluated for flammability both before and after water leaching. The more promising four systems were given a thorough evaluation for flame spread, toxic gas and smoke density levels, resistance to decay, and compressive strength. The most promising system on the basis of history of usage in the mine, ease of application and low cost as well as overall performance is the Fyreprufe/ACC Albi 107A/ 144 combination. A survey of inspection tools and instruments, identified equipment which could be assembled into an inspection kit for use in determining the extent of decay and/ or impregnant retention levels in mine timber. A literature search identified those high fire hazard areas found in a typical mine. Timber and other wooden structures used in such areas should be treated with an acceptable fire retardant system. A survey of insurance companies revealed that the use of such treated timber in the mines would probably have little or no impact on the rate structure.

Jan 1, 1980

As a result of the rapid economic growth in Japan, environmental problems have become a national concern in the latter half of the In 1967, the Basic Lair for Environmental Pollution Control was enacted as a fundamental ::olicy in this field. This lair provided compre- hensive guidelines for the action to be taken pollution prevention. The biggest problem n air pollution of those days was that of the sulphur dioxide content of the atmosphere. Based upon the law, the smelters in Japan have struggled hard to solve this difficult problem. Consequently, the ambient SO2 level has been lowered gradually year by year. At present, the ambient SO2 level is nearly equal to that in the atmospheric background. Furthermore, the fixation ratio of sulphur in Japanese copper smelters has attained up to 99.5 per cent.

Jan 1, 1980

By R Hoskings

Conceptual studies of the run of mine stockpiling and reclaiming requirements commenced in 1975. Final selection of equipment was made in 1978 and the equipment was commissioned in June, 1979. Equipment selection was made after extensive investigation and visits to existing facilities throughout the world. The equipment selected is described and compared with the alternatives. Foundations were designed to minimise cleanup effort and to ensure stability of equipment under design wind loading without storm bays. Programmable logic control enables the stacking and reclaiming facility to provide a blended feed to the coal preparation plant.

Jan 1, 1980

By Pollard DM, Willis GM

The removal of bismuth from liquid copper in a vacuum furnace was studied over a range of pressures. The rate determining step changes from diffusion in the gas at pressures above 0.2 Torr to approach the Langmuir evaporation rate at pressures of 10-2 Torr. Oxygen and sulphur were found to have a negligible effect on the rate. Bismuth removal from copper sulphide was found to be considerably slower than from copper. This is consistent with the known thermodynamic properties of ternary sulphide melts.

Jan 1, 1980

By K. Ananthanarayanan, R. I. L. Guthrie, S. A. Argyropoulos

"The low cost and availability of micro-computers and their peripherals provides the metallurgical engineer with the opportunity to use such computers in a wide variety of applications. In this paper, the authors describe the development of a low cost data acquisition system capable of measuring up to 8 analogue channels at a sampling rate of up to 5000 measure mentsper second. This system is equipped with proper hardware and software so that the micro-computer can be linked to a central computer facility such as the McGill System for Interactive Computing (MUSIC). This central computer facility is supported by an AMDAHL V7 computer. Using the present interface, communication rates between the microcomputer and the central computing facility can be as high as 9600 (baud).The above mentioned data acquisition system is currently used for monitoring dissolution kinetics of ferro-alloy additions in liquid steel. In addition to this, special software has been developed which enables the user of this system to monitor solidification rates of ingots, etc. As economic considerations are always important, comparisons have been made with existing recorders which show that the cost Of the present system is only 30 per cent more than a two-pen strip chart recorder.RESUMELa disponibilité et le bas prix des micro-ordinateurs et de leurs périphériques permet à l'ingénieur métallurgiste d'utiliser de tels ordinateurs pour diverses applications. Dans ce rapport, les auteurs décrivent le développement d'un système d bas prix pour l'acquisition des données, capable de mesurer jusqu'à huit canaux analogues jusqu’à une vitesse de 5000 mesures par seconde. Ce système est équipe avec son propre ""hardware"" et ""Software"" qui relient le micro-ordinateur d’un ordinateur central, comme le système de McGill pour computations réciproques (MUSIC). Ce central d'ordinateurs est soutenu par l'ordinateur AMDAHL V7. Utilisant cet "" interface"", la vitesse de communication entre Ie micro-ordinateur et l'ordinateur central peut atteindre jusqu'd 9600 (baud)."

Jan 1, 1980

By Charlie Wyche

The British Solomon Islands Protectorate continued developmental work on bauxite deposits on the Islands of Rennell and Vaghena. A feasibility study was completed by Mitsui Mining & Smelting Co., Ltd., and Pacific Aluminum Ltd. (a subsidiary of Conzinc Riotinto of Australia Ltd,), and negotiations with the Government were in progress. The Government will receive a 25% share if the project is realized. It was estimated that the Islands contain 60 million tons of bauxite with an alumina content of 45% to 50%.

Jan 1, 1980

By G. M. Ritcey, K. E. Haque, S. H. Lucas

"Laboratory-scale hydrochloric acid leach tests were conducted on an Elliot Lake uranium ore. Hydrochloric acid leaches without an oxidant or with molecular oxygen (i.e., air or pure oxygen gas) as an oxidant favoured uranium and radium extractions. Conditions for maximum uranium, thorium and radium extractions with hydrochloric acid in the presence of sodium chlorate were determined. The highest extractions of uranium (96%), thorium (81%) and radium (91%) were obtained using a mixture of 44.0 kg HCI and 2.5 kg NaCIOJ per tonne of ore at 75°C with 18 hours ' retention.Flowsheets for two-stage leaching are proposed. The residues obtained from the second-stage leach contain uranium (0.002%), thorium (0.006%) and radium (15 to 20 pCi/g). Tailings of this nature are considered suitable for mine backfill, and, if pyrite is removed, suitable for surface disposal.IntroductionThe nuclear energy industry forecasts an increasing demand for uranium. This increasing demand requires not only largescale mining and processing of conventional and complex uranium ores, but also leads to the consideration of new and nonconventional sources of uranium, e.g., black shales, phosphate rocks, granite, sea water and fossil-fuel ash."

Jan 1, 1980

This publication summarizes the in-house and contract research and development projects programed for fiscal pear 1980 by the Bureau of Mines under its Minerals Environmental Research activity. The document provides a mechanism for interested parties, including potential contractors, to gain insight into ongoing and projected work of the Bureau's environmental research efforts. Research to identify and correct environmental problems associated with mining and metallurgical operations has long been an integral part of the Bureau's mission. Through the years, efforts of various Bureau programs have yielded valuable information on the origin and control of many of these problems. With the reorganization of the Bureau of Mines in 1979, the Minerals Environmental Technology program was structured to consolidate these efforts into a single program that will systematically investigate al aspects of mining- and processing-related environmental pollution and damage-from initial discovery of the mineral resource to ultimate return of the land to productive use. In fiscal year 1980, the Bureau received an appropriation of about $21 million to conduct research and development work on these problems.

Jan 1, 1980

By L. J. Heaslip, J. M. Toguri, T. R. Meadowcroft, R. L. Addinall

"""Pilot Plant Operations"" is a final-year core course given to the Metallurgy and Materials Science students at the University of Toronto. This course involves a laboratory study of an industrial project at an industrial site. Details of this program are discussed and reviewed after eight years of experience. IntroductionEducators in the field of Metallurgy and Materials Science have long agreed that ""hands-on"" experience is an important component in the education of metallurgical engineers. This philosophy is reflected in the undergraduate curricula of most metallurgical schools. The major problems encountered with laboratory-associated courses are the requirements for equipment, space and funds for both purchase and maintenance of equipment. For example, consider an exercise in crushing and grinding treatment in a mineral processing laboratory. Such operations require the handling of tons of material and often equipment of large size. The problems of storage of ore, methods of handling and maintenance of equipment are a few of the concerns facing the department. Considering that metallurgical departments at universities are, in general, relatively small, the support to purchase and maintain largescale equipment becomes an annual budgetary concern. In reality, universities today are not geared to operate mini-pilot plant equipment, either in terms of space or personnel.For the above reasons, in 1972an undergraduate core course called ""Pilot Plant Operations"" was introduced to the fourth year curriculum in Metallurgy and Materials Science at the University of Toronto. This course consists of I to 2 full weeks (8 hrs per day) of pilot plant laboratory study at an industrial site on a project of mutual interest with the industrial organization whose facility is being used. The first 5 years of the program were carried out at the pilot plant facility at the Ontario Research Foundation; Stelco's Research Centre in Burlington, Ontario, was used for the last 3 years. The nature of the projects undertaken during the 8-year period is shown in Table 1."

Jan 1, 1980

By L Torckler, R L. Brathwaite

At Neavesville gold-silver (electrum) mineralisation occurs in steeply-dipping zones of intense fracturing, brecciation and quartz veining within rhyolitic pyroclastics, carbohaceous shales and andesites. Hydrothermal alteration extends over an area of greater than 3 by 1.5 km. In rhyolitic tuffs, highly silicified zones containing quartz-adularia-illite assemblages are flanked by less silicified assemblages composed of albite, illite-montmorillonite and chlorite. The mineralogy and sequence of alteration are comparable with the alteration zones which envelop the steam-producing fissures of the active Wairakei and Broadlands geothermal fields. Primary fluid inclusions in quartz from five fissure veins in the Neavesville field show maximum homogenisation temperatures ranging from 220 - 260¦C and salinities of 0.0 - 1.1 wt per cent NaCl equivalent, which cover a similar range to actual measured temperatures and salinities in geothermal fluids at Wairakei and Broadlands. The age of the rhyolitic pyroclastics and related alteration and mineralisation is probably Pliocene and Neavesville therefore represents a fossil geothermal system. The intensely fractured zones containing the gold-silver mineralisation were probably produced by hydraulic fracturing generated by accumulation under pressure of hydrothermal fluid in blind fault zones. Study of fluid inclusions indicates that hydrothermal quartz associated with electrum was deposited under boiling conditions. High grade electrum mineralisation at Graces workings appears to be localised by reaction of hydrothermal fluid with sedimentary marcasite in black shale.

Jan 1, 1980

By J. D. Nye, I. A. Farr, W. J. D. Stone

"A unique deposit of barite exists near Brookfield, Nova Scotia. The crystals are extremely fine and the whole deposit virtually free of heavy metals. The deposit size was not large enough for conventional uses, such as the production of barium carbonate and drilling mud. In an effort to obtain maximum utilization, a program was begun to determine if U.S.P.-grade pharmaceutical barium sulphate for X-ray diagnosis could be produced. Early work was sufficiently encouraging to institute a development program under the federal Program for Advancement of Industrial Technology. This has been very successfully completed. Canadian and U.S. process patents have been issued, clinical trials have been successful, a production plant has been designed and the plant’s production sold. The processing plant will include magnetic separation for the removal of iron minerals, fine grinding by paddle milling to minus one micron and acid leaching. The process is unique in that at no time is the barium taken into solution.Information is given on the deposit, process, markets, use, plant capital and operating costs, and projected profits. The initial production plant will have an annual capacity of 2,000 tons per year of end product. Capital cost is $850,000 and annual turnover more than $1.5 million. As this capacity only represents approximately 15% of the North American market, rapid plant expansion is foreseen."

Jan 1, 1980

By T. A. Raczek

Materials for stronger ventilation tubing for underground use in hardrock mines were developed. The new material composites were evaluated in performance characteristics and compared to currently used materials. The materials were compared on tear, tensile, puncture and flammability properties. Based on cost versus performance data, a polyester film bonded to a polyester fabric was selected as the candidate material for field testing. Ventilation tubing fabricated from the selected material was field tested in two underground uranium mines for four-month periods. The test results indicated that the new composite showed an increase in useful life in the majority of applications, However, the cost performance ratio was not significantly improved to warrant commercialization of the product. When connected directly to some blowers, the material in close proximity to the blower deteriorated. However, material which was punctured or torn by mechanical means did not have further propagation of the tear. The high tear strength of the material prevented further damage. Improved methods of repairing inflated ventilation tubing were investigated and developed. All the repair methods were portable and self-contained. Repair kits based on adhesives, pressure sensitive tapes, and mechanical means were evaluated. Plier staplers and patch systems based on pressure sensitive adhesive proved to be most functional.

Jan 1, 1980

By Tapp B. A

The minerals industry in Australia is currently regarded as the country's economic saviour; the bastion of economic security. As Fitzgerald (1974) stated, 'Australia's natural endowments in minerals are the envy of most countries of the world'. As a result the proposed new mineral developments are on a scale that hitherto in the sixties would have been completely unenvisaged. It is reported that Australia is poised on the verge'of a sixteen billion dollar mining-based investment boom: a boom that will see Australia dominate the energy export field, the mineral processing field, and create the 'coal dollar'. This growth scenario has many inherent dangers, and it is the authors' contention that these should be carefully considered before further development proceeds. Two of the major problems related to the mineral industry growth scenario are the predictability of the future metal market, and the energy cost of mining. The latter problem is the one discussed here. The mining-mineral processing industries in Australia currently use about 36% of Australia's primary energy

Jan 1, 1980