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US 4,185,078-In the recovery of rhenium values from an aqueous sodium molybdate solution contained in the hydrometallurgical processing of roasted molybdenite, improved results are realized by using a described extractant consisting of a quaternary ammonium compound and benzene or other highly aromatic solvent which dissolves a quaternary ammonium-rhenium complex Essentially all rhenium is recovered from the solution and the extractant can be regenerated and recycled. This patent is a continuation-in-part of US Patent No. 4,049,771, dated Sept. 20, 1977. L R. Quatrini and M.B MacInnis, assigned to GTE Sylvania Inc. Jan 22, 1980. 6 pp (423-49). Flied. 7-19-78 (926,167).

Jan 1, 1982

By Ali M. Heidarieh Zadeh, Raghu N. Singh

The paper presents a stability investigation of shaft intersections and pit bottom roadways in the vicinity of upcast and downcast shafts at a colliery in the U.K. Aschemeof instrumentation was aimed at monitoring the strata displacement surrounding the pit bottom roadways and shaft intersections with a view to ascertaining the origin of the strata movement and effectiveness of the control measures. The bore- hole instrumentation results together with a theoretical analysis suggested that the cause of instability could be attributed to the drivage of a roadway within the shaft pillar. A semi-empirical technique was used to calculate the amount of support resistance required to reinforce the pillar to take additional abutment load. A rock bolting system was designed to provide a required increase in thrust capacity of the roadway support. The results indicated that roadway closure was effectively controlled after installation of bolts indicating efficacy of the control measures adopted.

Jan 1, 1982

By Stratton-Crawley R., G. E. Agar

"A study has been done of the scale-up of laboratory bench-scale flotation to continuous plant circuit performance. It was found that the impellor speed and the air flow rate influenced the results and in this case extreme values of these operating variables were required in order to reproduce the plant rougher results in the laboratory. Despite the experimental uncertainty introduced by these extreme values, it was demonstrated that the plant performance could be predicted and experimentally reproduced with bench-scale tests.IntroductionThe mineral processing industry relies heavily on batch flotation testwork to design flowsheets, evaluate reagent s and compare various types of ore. The batch tests are generally regarded as being directly comparable within themselves, but quite often they relate poorly or not at all to continuous circuits. Obviously this dilemma generates considerable uncertainty with wide-ranging ramifications. One of the manifestations of this unfortunate situation is the commonly expressed opinion that ""it may work that way in the laboratory, but it will never work that way in the plant"".In a previous publication, a method was described whereby the results of batch bench-scale tests could be used to simulate a locked cycle flotation test series. The work to be described here is a continuation of that investigation with an extension to the simulation of an actual plant circuit. It would have been preferable to progress from laboratory batch data to a continuous pilot plant and then finally to a full-scale plant operation. However, because that possibility did not present itself, an attempt will be made to show that the performance of an existing plant circuit can be successfully simulated from batch data. The success of the procedure can be judged by the agreement among the plant results, a locked cycle test and the predicted results based on batch tests."

Jan 1, 1982

By Matthew N. Rubin

This report summarizes the work performed under USBM Contract No. H0155155. The purpose of this work was to obtain operational data on retrofit noise control treatments suitable for use in coal preparation plants. This data was obtained by evaluating the performance of four categories of noise control treatments which were installed in a commercial coal preparation plant. The four categories of treatments were resilient screen decks, resilient impact pads, chute liners, and curtains. The selection, installation and initial evaluation of the treatments was documented in the Volume I report issued in 1977. This Volume II report summarizes the results of the long-term evaluation of the original treatments, as well as some additional tests which were conducted on elastomer-clad (resilient) screen decks. This project demonstrated the feasibility of a number of retrofit noise control treatments, some of which also proved to be quite durable over the long term.

Jan 1, 1982

By Jalna R. Zatko

Coal-clay waste slurries were dewatered in laboratory-and small-scale continuous tests by the Bureau of Mines using polyethylene oxide (PEO) as a flocculant. Dewatering from a nominal 7-wt-pct solids to over 50-wt-pct solids was accomplished using 0.5 lb of PEO per ton of feed in small-scale continuous tests. Parameters such as pH, initial solids content, and PEO concentrations were investigated. Water recovered from dewatering was reused as dilutant for PEO solutions.

Jan 1, 1982

By Cyrus W. Field

Metalliferous sediments constitute an important component of the sedimentary veneer that overlies basaltic oceanic crust of the Nazca Plate and elsewhere. Although first collected more than one century ago near the East Pacific Rise during the Challenger Expedition and recognized for their anomalously high content of Fe and Mn, occurring as very fine-grained, yellow-orange, oxides, hydroxides, and oxyhydroxides, it was not until the more detailed studies of Bostrom and Peterson (1966) that their geologic significance and concentrations of other transition metals were fully appreciated. The Nazca Plate is a dynamic lithospheric unit bordered by the Peru-Chile trench and the East Pacific Rise to the east and west, and by the Galapagos Rift and the Chile Rise to the north and south (Fig. 1). Samples employed in this study were taken from piston core recovered from the Nazca Plate (Fig. 2), D. S. D. P. drill core from the northeast Pacific (Dymond and others, 1973), ferromanganese nodules from dredge-haul s at several locations, and from hydrothermal mineral deposits of the Andes. Our efforts have been largely sponsored by the National Science Foundation through its International Decade of Ocean Exploration Pro- gram. The metalliferous fraction of these sediments is widespread, but generally small. Sedimentation is dominated by biogenic silica in the equatorial latitudes, terrigenous debris adjacent to the South American Continent, and by biogenic carbonate elsewhere, except at depths below 3500 m in the central and northwest parts of the Nazca Plate near the East Pacific Rise. Contributions of these distinctive sediment types are shown by the distributions of Si02, A1203, and CaC03 given in Figure 3.

Jan 1, 1982

By James M. Spear

Sample results suggest the only mineral resources in the study areas are placer gold deposits along the South Fork Kern River in the Woodpecker RARE II unit (fig. 1). These deposits, in Rockhouse Basin, total 4.5 Figure 1.--NEAR HERE. million cu yds (3.4 million cu m) of indicated subeconomic gold resources in four deposits of "older" gravel. Gold value in samples averages $0.36 per cu yd ($0.47 par cu m) and is as much as $4.44 per cu yd 1/. Cost of mining the gravel and recovering the placer gold is estimated to be more than $2 per cu yd ($2.62 per cu m) for a deposit of this size and type. Additional inferred subeconomic placer gold resources with similar grade probably occur in four other deposits of "older" gravel on which no mining claims were located. Placer gold occurrences on upper Trout Creek contain gold worth as much as $4.50 per cu yd ($5.88 per cu m) 1/. Average grade is much lower, and only about 1,000 cu yds remain (760 cu m). These occurrences do not constitute a resource, but may attract hobbyists not dependent upon making a profit.

Jan 1, 1982

By Firth B. A

The flotation of fine coal (minus 0.5 mm) often requires the addition of an insoluble hydrocarbon collector to apparently promote the adhesion of coal particles to air bubbles. A series of experiments was conducted using a radiotracer and narrow size fractions of clean coal to determine the effect of particle size distribution, collector addition rate, desliming of feed and emuIisification of collector on the distribution of collector between the different size fractions. The concentration of collector per gram of each size fraction was found to be approximately proportional to (average particle size)-2 except if the collector was emulsified prior to addition, the dependence altered to approximately (average particle size)-1. Mechanistic consequences are discussed.

Jan 1, 1982

By M. A. Mahtab, T. M. Yegulalp

This paper presents the development and application of an approach for clustering fracture orientation data. Data are projected on the surface of the unit upper hemisphere and the clustering approach is applied in three steps: (1) randomness test and identification of dense clusters, (2) estimation of cluster statistics, using Bingham distribution, and (3) rejection of extremal data based on Chauvenet's criterion.

Jan 1, 1982

By D. E. Kirby

In line with the Bureau of Mines' goal of providing technology to maintain a supply of minerals adequate to meet national economic and strategic needs, a method for recovering chromite from lateritic materials was investigated. Laterites are a large resource of Ni, Co, and Cr, critical metals of which the United States has insufficient domestic sources. A roast-leach method was developed by the Bureau to extract nickel and cobalt from domestic laterites. A concurrent effort was made to recover chromium from either unprocessed laterites or the leach residues. This report characterizes laterites and laterite leach residues. It describes a chromite recovery procedure using conventional industrial beneficiation equipment for sizing, low-intensity magnetic separation, and gravity concentration. Concentrates containing 20.0 to 22.4 pct Cr (29.0 to 32.7 pct Cr203) and with a 1.6:1 to 1.9:1 Cr-Fe ratio were recovered from laterites and residues containing 1.3 to 2.5 pct Cr with recoveries exceeding 50 pct. Because of their low grade and fine size, these concentrates would be suitable for preparing chromium chemicals. The direct beneficiation of laterites for chromite recovery resulted in the minerals containing nickel and cobalt concentrating in slime products. No iron oxide coproducts of acceptable grade were recovered from either laterites or residues.

Jan 1, 1982

By H. H. Dewing

The Bureau of Mines constructed a process research unit (PRU) to demonstrate new technology for extracting zinc from sphalerite concentrates. Up to 9 kg/hr of sphalerite (ZnS) concentrate was reacted at ambient pressure in the PRU with 80 pct sulfuric acid at 160° to 180° C to produce zinc sulfate and elemental sulfur. The PRU consisted of a three-stage glass reactor system: a 4-liter premix stage in which feed was slurried with 78 to 82 pct H2S04, a 40-liter stirred reactor, and a ISO-liter settling stage in which high reaction conversions were effected and excess H2S04 for recycle was separated from insoluble ZnS04 and sulfur. Evolution of sulfur-containing gases was minimized by sub-surface addition of acid feed slurry to the stirred reactor and by exclusion of air from the reactor to prevent the oxidation of elemental sulfur. Conversion of zinc to zinc sulfate averaged over 99 pct at the optimum acid concentration of 80 pct. Total sulfur losses (primarily S02) were less than 2 pct of the sulfur in the sphalerite. Elemental sulfur remained in the insoluble portion of the settled reactor product after leaching with simulated spent zinc electrolyte containing sulfuric acid. The sulfur residue contained 75 to 89 pct sulfur. Neutral zinc sulfate, required for zinc electrowinning processes, was separated from the sulfuric acid leach solution by crystallization at -15° C as zinc sulfate heptahydrate (ZnS04?7H20). The crystallization operation simultaneously effected a partial concentration of the recycled electrolyte solution by removing water.

Jan 1, 1982

By Douglas F. Scott

In 1981 the U.S. Bureau of Mines and U.S. Geological Survey conducted a mineral survey of the Pyramid RARE II area (No. 5023) covering 23,500 acres (9,500 ha) of E1 Dorado National Forest and 7,900 acres (3,200 ha) of the Lake Tahoe Basin Management Unit (fig. 1). The Bureau of Mines investigation did not reveal mineral deposits in the area. Samples taken from silicified and limonite-stained metasedimentary rocks and aplite dikes were void of precious or base metals or uranium. Placer samples from stream gravels contained no gold values. Molybdenite occurs in quartz stringers within quartz monzonite near Grass Lake, adjacent to the area; no extension; were found in the area.

Jan 1, 1982

By E. LaRocque

"Long term contracts requiring delivery of 6,000,000 pounds of U308 per year to its customers have made it necessary for Denison Mines to expand its milling capacity from 7,100 tons per day to 15,000 tons per day.Previous papers (1) and (2) described the old leaching and product recovery practice. The flowsheet briefly includes a crushing and grinding circuit, sulphuric acid leaching in a Pachuca plant, liquid-solid separation with wash thickeners and two-stage drum filtration, concentration and purification by moving bed ion exchange followed by two-stage precipitation to produce an ammonia yellowcake.No. 1 Shaft ore, about 4,000 tons per day, will be processed through the truck dump into the old crushing and grinding plant and through the old leaching plant. Ore from Stanrock (No. 3 shaft) will be hauled by truck and also processed through the truck dump as No. 1 shaft ore. Beginning in 1982, ore production from Stanrock will gradually increase until 1985 when some 3,000 tons per day will be milled from the source.A new 8,000 ton per day circuit was designed and constructed to increase the milling capacity to 15,000 tons per day. The new circuit is separate from the old one except that it coins together for the precipitation and tailings neutralization sections of the plant. The feed to the new plant will be from No. 2 shaft.The flowsheet is much the same as the old plant with the exception of the grinding circuit and the ion exchange plant. A semi-autogenous grinding (SAG) plant, unique in the Elliot Lake area, has been installed rather than the conventional crushing and grinding plant; the ion exchange plant is the stationery bed type.This paper describes the major equipment installed for the expanded grinding and hydrometallurgical plant."

Jan 1, 1982

By E. Morrice

As part of its efforts to maximize process efficiency and decrease energy requirements in mineral processes, the Federal Bureau of Mines has investigated methods for beneficiating bastnäsite ores from Mountain Pass, Calif. The results of a bench-scale study on the flotation of bastnäsite ore are presented. Flotation at a pulp temperature of 40° to 45°C yielded a cleaner concentrate containing 58.7 pct RE203 at a rare-earth recovery of 67 pct. These results are comparable to those reported for the commercial beneficiation method in which the pulp is heated to boiling before flotation. An attempt was also made to recover a barite flotation concentrate from the bastnäsite rougher tailing. Concentrates containing only 70 pct barite were obtained.

Jan 1, 1982

By Ned Baker

Details are given of a fuel-induction system for a hydrogen, fueled engine. The induction system was designed to preclude backfire otherwise common in hydrogen fueled engines. System features and test data are presented and discussed in the context of the requirements peculiar to use in an underground mine environment. The fuel induction-system when tested in conjunction with a modified Caterpillar 3304 engine provided backfire free engine operation and satisfactory engine performance.

Jan 1, 1982

Tailings embankments can develop a high phreatic surface if the original design for the embankment does not include drainage facilities or if existing drainage facilities become ineffective. Subsequent raises can develop a seepage surface due to a high phreatic surface that can lead to stability problems. The U. S. Bureau of Mines amended contract J0100013 to initiate this study of horizontal drains in tailings embankments. This study developed a technique for determining the length of and spacing between parallel drains through the use of the finite element model UNSAT2. The analysis is based on the combined output of a vertical planar mesh and a horizontal planar mesh. The slot opening in the drain pipe and the length of the perforated section are determined from an analogy to water well design. The pipe diameter and gradient can be determined from Manning's equation. To the authors' knowledge, this is the first attempt at horizontal drain design using a finite element model. Additional research is recommended in this area.

Jan 1, 1982

By Fookes R. A, Gardner K. J, Gravitis V. L, Watt J. S, Steffner E. J

Two radioisotope techniques suitable for the rapid laboratory determination of the ash content of coal have been tested ou unwashed coal samples from four Australian coal seams. In one techniqne, measurements of backscattered 238Pu L X-rays and iron K X-rays from finely ground coal samples have been combined to determine ash content in uuwashed coals to ±0.5 weight per ce111 ash (ls) for three seams and 0.9 weight per cent ash for the fourth.The second technique, which involves measurements of the transmission by the coal of narrow beams of 241Am 60 keV and 123Ba 356 keV ? rays, requires less sample preparat ion. The ash was determined to within the range of 0.8 to 2.6 weight per cent for the four seams (unwashed coal). For washed coals, errors are expected to be < ±0.5 weight per cent ash.

Jan 1, 1982

By Doug Halbe

A number of CIP plants have been built in Western Australia in the past two years. The authors have surveyed several of these new plants and present drawings, data and discussion of operating and design innovations and areas of interest.

Jan 1, 1982

By Frank Mucciardi, Louca Gourtsoyannis

"Low and inconsistent recoveries of aluminum in the production of aluminum-killed steels triggered an extensive research program on the aluminum dissolution kinetics at McGill University. This research program led to the understanding of the melting kinetics and the hydrodynamics of making additions to liquid steel. It showed the necessity of gradually releasing liquid aluminum at the bottom of the ladle to increase aluminum recoveries.This knowledge was verified in practice at Sidbec-Dosco, where a prototype aluminum wire injector was developed and installed for the first time in Canada. The industrial application showed the validity of the theoretical and experimental results and provided further data for the mathematical modelling of the process.The development of the theoretical understanding, the industrial results, and the interaction between university and industry are presented.IntroductionAluminum is an extremely effective deoxidizer of molten steel; nevertheless, an efficient method of adding it to steel has eluded steelmakers for many years. It is well known that the recovery of aluminum used in the production of aluminum killed steel is both low and eratic, especially when the aluminum is added in the form of bars or lumps from chutes into filling ladles, a practice still common in many of today's steelmaking operations.As the density of aluminum is only about 40010 that of molten steel, it is conceivable that loose bars of aluminum simply ""thrown"" into a filling ladle will resurface before any appreciable dissolution of the aluminum has occurred, particularly if the depth of penetration of the additions is small. Before one can conclude that this is indeed the case, it is necessary to know the melting kinetics of an aluminum addition. Back in 1972, this information was not available; hence an extensive research program which focused on melting kinetics was initiated at McGill University."

Jan 1, 1982

By K. H. Singh, J. N. Szuck, J. A. Riddell

"Hydraulic rock drilling equipment has been in use at Falconbridge over the past two years in both production and development situations. This paper deals with the experience gained in the application of hydraulic drilling in the company's mines and discusses the benefits and problems encountered during their use. The paper primarily focuses on technical, operating, maintenance and economic aspects of the machines, and does not attempt to compare the performances of different machines from the various manufacturers.IntroductionThe Sudbury Operations of Falconbridge Nickel Mines Limited are comprised of five operating mines and two mines under development. All the production comes from underground mines, mostly at depths below 1000 metres. The company, faced with increases in operating costs and difficult mining conditions, has continued to seek solutions with the help of new mining technology.The development of electric-hydraulic drilling machines in Europe had been pursued with great interest and, in 1979, a decision was made to test these machines to prove their technical and economic viability under operating conditions. Since then, a number of electric-hydraulic machines have been evaluated in different situations and currently nine hydraulic machines are being used in the company's various mines. These machines are comprised of two-boom drilling jumbos for development, one-boom machines for longhole drilling and a large-hole-diameter drilling rig for blasthole drilling. One hydraulic jumbo has also been used in a cut-and-fill stope."

Jan 1, 1982