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By Arthur Forsyth

A SEARCH through the available literature shows that the cobalt-nickel-silicon system has not been systematically studied. This seems rather odd because all three elements are fairly abundant and have better than average corrosion resistance; however, they have high melting points, which makes experimental work difficult. Cobalt and nickel form a continuous series of solid solutions and each metal dissolves about 7.5 per cent silicon. Many ternary alloys have been studied and the results have been published in a great many different ways, but to present such data in a short but clear and understandable manner is still a problem. The following pages describe the results of the study of 76 alloys from which the partial ternary diagram (Fig. 1) of the cobalt-nickel-silicon system has been drawn. The alloys were chosen according to the plan in Fig. la by taking definite ratios of cobalt and nickel, such as 70 Ni, 30 Co or 40 Ni, 60 Co, and adding silicon in various percentages. Each section was studied in detail by means of thermal analysis and microscopic examination, but only two of these detailed sections were thought necessary in the point perspective drawing to give a comprehensive picture of the liquidus, solidus and solid transformations that take place over the temperature ranges studied. Complete thermal analyses and microscopic data are given in Table 1.

Jan 1, 1940

The scheme of rehabilitation of surface plant commenced in 1936, included the provision of improved and more hygienic changing and bathing facilities for the employees.At that time the Thompson's Shaft section of the British Mine was being prepared for a resumption of operations, and it was decided to repair and re-equip the existing building. Thus any new scheme adopted could be given a thorough trial, and the proved arrangement used as a basis for the contemplated new main changehouse on the North Section.Investigations were carried out to determine the most suitable arrangement for the Thompson's Shaft changehouse, to provide for a total of 120 men, with particular regard to the internal fittings and fixtures. Also, as the mining conditions were such that a large proportion of clothes worn underground by miners, etc., were wet by the end of the shift, the problem of drying these clothes in the availaole time from a man coming off shift to his commencing again some sixteen hours later was one of the most important to be dealt with.The changehouses in use on the North mine section of the lease were provided with racks around the walls for the men to hang their street clothes on, and a section was partitioned off to house the mine clothes and their drying facilities. The actual drying was carried out by means of hanging the wet clothes over racks between which ran pipe coils heated by means of hot water circulated from the hot water boiler supplying the showers.This method had proved to be far from satisfactory for several reasons, the main objections being:-

Jan 1, 1940

By F. D. DeVaney

Manganese-bearing deposits f the Leadville, Colo., district are of two distinct types. Manganosiderite, a combined or intimately mixed ferrous and manganous carbonate, occurs in unaltered zones as the predominant mineral. From 50 feet below the surface to as deep as 900 feet, psilomelane and wad, both black manganese oxide minerals, are found in intimate contact with hematite and limonite. A typical analysis of the black oxide ore shows 20.08 percent Fe, 18.64 percent Mn, 15.91 percent insoluble, 14.91 percent moisture, 0.94 percent Zn, and 2.13 percent Pb. A considerable tonnage of the oxide ore has been mined for production of spiegeleisen and for other purposes.

Jan 1, 1940

The smelting of the Broken Hill lead concentrates at the Broken Hill Asso,ciated Smelters produced, among other products, approximately 4,900 ounces of gold and 8,800,000 ounces of silver during the year ending June 30th, 1938. The following table shows the actual amounts of gold per ton of lead concentrate produced during this period at the important mines. The total gold in the period is calculated from the number of tons of lead concentrates produced, and by comparison with the production' of silver, shows thatthere is no constant relation between the amounts of gold and silver.The fact that no gold is seen during milling, even when gravity concentrating tables are employed, signifies that the gold does not occur as occasional coarse particles.Further, as the values increase considerably in the flotation slime, it can be inferred that the gold occurs as minute inclusions in one or more of the minerals in the lead concentrates.The four most abundant minerals in the lead concentrate are galena, zinc blende, chalcopyrite, and...

Jan 1, 1940

By Phil N

A large number of experiments have been carried out by many workers on the recrystallization of deformed and subsequently annealed metals and alloys. Although observations on single crystals are of great importance in the study of the recrystallization textures of deformed and annealed metals, very little of this work deals with material in this form.Since, in deformed metals, the stress concentration is greatest at the grain boundaries and along the planes of slipping, it is to be expected that recrystallization will start in these regions. For example, in polycrystalline aluminium (1),:1: (2), copper (3), a-iron (4) and brass (5), (6), which had been deformed by cold-rolling, drawing, pressing or stretching and then annealed, the new grains first appeared in the boundaries of the original crystals, whilst in the case of cupronickel (7) and iron (8), recrystallization commenced along the slip planes of the deformed material. Deformed and annealed single crystals of aluminium (9) and cadmium (10) first start to recrystallize along slip planes and in deformation twins.The present work deals with the process of recrystallization of single crystals of lead after deformatjon by creep.Two factors enter into these experiments that were not met with in other work on this subject. Firstly, lead...

Jan 1, 1940

By H. S. Auvil

[The shrinkage of coke after formation is one of the variables that effects the net expansion of the change in both industrial and test ovens. Various test results5/ have been interpreted as indicating that cokes from certain coals shrink to a marked extent and that other cokes show very little shrinkage; but no comprehensive experimental study of the shrinkage of coke after its formation and of the factors influencing this shrinkage has come to the attention of the authors.]

Jan 1, 1940

By Arno C. Fieldner

This is the fifth of a series of annual reports4/ of technologic investigations conducted by the Bureau of Mines on the occurrence, properties, mining, preparation, and uses of coal. The research of the Bureau is carefully coordinated with the requirements of the producing and consuming industries, with a view to conservation of resources of coal in mining and use, and conservation of the health and lives of workmen employed in these industries. Such coordination is facilitated by the wide range of specialization of the several groups on engaged in studies concerning coal. Here are reported correlated studies ranging from paleobotanic analysis of the formation of coal as it occurred some millions of years ago to the effect of mechanical methods of mining on present-day employment in mines. As this is a summary of the current work of the Bureau of Mines, so the Bureau likewise has provided a condensed review of the outstanding current work of others on research and technology of coal 5/.

Jan 1, 1940

By D. A. Reynolds

A few studies on the relationship of the fusion temperature of the ash on coke to that of the corresponding coal have been made on commercial high-temperature cokes. H. J. Rose3/ in 1921 compared the fusion temperatures of the ashes of 10 coals and the cokes produced from them and concluded that they were in such hose agreement that either figure could be used. More recently, Quarfort4/ found that the ash of coke fused at a somewhat lower temperature than that of the original coal. As the ash of a coal and that off tie coke produced therefrom have the same origin their chemical composition should be identical, provided that carbonization has not altered the inorganic, or ash-forming, constituents of the coal, and such alteration seems highly improbable. However, it has been shown5/ that coke is liable to contamination by iron during crushing and grinding preparatory to sampling. Pieters6/ found that coke ash was contaminated in this manner up to 0.4 percent. Extraneous iron would lower the ash-fusion temperature because such iron may form ferrous silicate, which is readily fusible.7/ These results provide a basis for the prediction that the ash of coke will fuse at a lower temperature than that of the corresponding coal, especially if the fine grinding of the coke was done by rubbing -surfaces of iron, as in a disk pulverizer or bucking plate.

Jan 1, 1940

By M. F. Trice

PYROPHYLLITE is a hydrous aluminum silicate (A12Si4010(OH)2)1 that occurs in both the foliated and the massive forms. The foliated variety resembles talc in that it has a greasy feel, a pearly luster, perfect basal cleavage, and usually is white, although in some deposits apple green, gray, brown, russet, and nearly black specimens may be found. The massive deposits of pyrophyllite yield pearl gray to light tan aggregates, some of which are so friable that they may be crushed with the hands into a fine gritty powder. Frequently specimens of the massive variety are studded with crystals of radial structure. The mineral has a specific gravity of about 2.7 and a hardness of 1 on Mobs' scale.1 The chemical composition of commercial pyrophyllite reflects the mineralogy of the deposits, which, according to Stuckey,2 contain pyro-phyllite and quartz, together with chloritoid, sericite, and a few other minerals of negligible importance. The latter, he says, "are noticed in but small quantities to the extent they might occur as accessory constitu-ents of an igneous rock or as products of regional metamorphism or weathering. . . . Quartz is abundant everywhere except in the very best grades of pyrophyllite." Analyses of specimens from several deposits are listed in Table 1, showing that the silica content varies from 57 to 73 percent and the alumina from 22 to 33 percent. Oxides of iron and the alkaline metals are collectively present, with one exception, to an extent of about 1 to 1.5 per cent.

Jan 1, 1940

By M. W. Von Bernewitz

Because the cutting and polishing of stones are parts of the work of the Bureau of Mines in its study of rocks and minerals and in the determination of specimens sent in for identification, it was decided that a circular covering the subject in a general way would be of practical interest. As several books and periodicals give details of the problems in cutting and polishing, this report will not duplicate their information more than necessary. ACKNOWLEDGMENT The manuscript for this circular was read by Oliver Bowles and Forrest Moyer, Building Materials unit, Bureau of Mines, who supplied some of the illustrations; several photographs were taken by Howard Carl, Optical Section, Bureau of Mines. Equipment firms that y contributed information and publishing houses whose books have been abstracted are mentioned in the text.

Jan 1, 1940

By J. Koster

[Boron is an element whose metallurgical possibilities never have been investigated thoroughly, probably because of the difficulties experienced in the preparation of elemental boron and its intermetallic compounds. The southwestern United States contain the world's s largest deposits of boron minerals. In general, the mineral is readily available, and mining costs are not excessive. The most important boron mineral of commerce is borax (sodium tetraborate) however, there are large deposits of colemanite (a mineral having the composition represented by 2CaO 3B2O3 5H2O) in Clark County, Nov. This material was worked in times past by converting it to sodium tetraborate. In recent years the deposits have laid idle because of a mire readily available source of borax in the old lake beds of California.]

Jan 1, 1940

In spite of the many contributions that have been made to our knowledge of the creep properties of polycrystalline lead, the precise influence of various factors on these properties is not yet fully understood. Indeed, the position is such that several important points in connection with the creep of lead are a matter of controversy. This has been brought about largely by the fact that, in the case of lead, the changes that are produced in the creep behaviour by slight variations of such factors as the purity, grain sizeand previous treatment are out of all proportion to the magnitude of these variations.In order to study the fundamental properties of lead as related to creep, and so gain a more enlightened perspective with which to consider the creep of lead in general, the work that is described in a series of papers, of which the present paper is the third part, has been carried out. It deals with lead in the form of single crystals.It has been shown (1) - (3) that the grain boundaries as well as the actual grains play a part in the creep of polycrystalline lead. The present work, by eliminating grain boundaries, enables the. contribution of the grains themselves to the process of creep, in other words, crystalline creep, to be studied effectively.This object was, possibly, the major one in this work.

Jan 1, 1940

By Thomas L. Kesler

THE Cartersville mining district, 35 miles northwest of Atlanta, Ga., has been of varying but continuous importance in the southern mineral industry during the past century. Noted chiefly for its production of brown iron ore, manganese oxide ores, barite, sienna, and magnesian limestone, the district and its environs have produced brick and tile clays, slate, gold, bauxite, and graphitic schist. Minor deposits of serpentine, sericite schist, copper ore, and red iron oxide have been prospected. The obvious deposits of brown iron ore, together with some associated specular hematite, were mined out years ago, although a little ore was left in the workings. Moderately steady production of sienna reached a peak about 1930, then declined rapidly. Manganese mining passed through a relatively active period from the World War to 1931, but has subsided to a small but rather constant output for the Birmingham market. However, the White Manganese Corporation has prepared for possible increased production by constructing a new washer capable of handling about 300 tons of ore per day. Principal activity in the district proper has centered for some years in the production of barite and magnesian limestone. GENERAL GEOLOGY Geologic relations of the ore deposits of this district are more or less similar to those of many Appalachian districts. The lowermost Cambrian formation, heretofore called Weisner1 in this region, supposedly partly or wholly equivalent to the Erwin and Hesse quartzites as recognized to the northeast, is overlain conformably by the Shady [+] formation, also of Lower Cambrian age. In the Cartersville district, the sedimentary rocks of these formations were folded with increasing intensity eastward, and were recrystallized.

Jan 1, 1940

By R. A. Cattell

A technologic group such as the Petroleum and Natural Gas Division of the Bureau f Mines, which conducts research on many of the complicated and frequently interrelated problems f extracting crude oil and natural gas from the ground, transporting them to market or to daces for subsequent treatment, and manufacturing products, should report progress from time to time. Engineers and others who apply the results obtained by this division are closely associated with its personnel, because many of the problems are attached cooperatively with groups in industry. Some of this cooperation is formal, as exemplified by work now in progress under cooperative agreements with the States of Oklahoma, Kansas, and others, but much of it is informal, prompted by the desire to be mutually helpful in the public interest. Furthermore, the published reports of the Bureau on subjects pertaining to petroleum and natural-gas technology come to the direct attention of a relatively large number of persons, whose interest in results and appreciation of the value of this type of work have caused them to be kept currently informed regarding available data.

Jan 1, 1940

By G. W. Jones

As part of its program for the promotion of safety, the Bureau of Mines has investigated various means of mitigating or eliminating the explosion hazards of combustible gases and vapors found in the mining and other industries. Knowledge as to the explosive characteristics of cyclopropane in air, oxygen, and other gaseous mixtures is of both theoretical and practical importance because cyclopropane is now used extensively in anesthesia. As such an agent it has many desirable characteristics, and increased consumption of this gas may be expected if the explosion hazards now attending its use can be minimized or eliminated. The present practice of using mixtures of approximately 20 percent cyclopropane and SO percent oxygen should be discouraged because such mixtures are violently explosive and have led to fatal accidents.

Jan 1, 1940

By John C. Holtz

Interest in the possibility of using Diesel6/ engines for haulage power in mining and tunneling is increasing in the United States, owing largely to the reported successful use of Diesel locomotives in European coal mines and to the comparatively recent development of automotive Diesel engines in this country. The extent of this interest has been evidenced to the Bureau of Mines by numerous requsts for information as to the factors that must be considered if Diesel engines are to be used safely underground.

Jan 1, 1940

By Charles B. Carpenter

For many years, studies of ground movement and subsidence accompanying subsurface mining operations have been part of the research program of the Bureau of Mines. Periodic observations by engineers of the Mining Division of the Bureau of man-built structures beneath which mining operations are conducted offer indisputable evidence of subsidence in the form of creeks in masonry structures and fractures and depressions in tie surface of the earth. As the removal of subsurface rock and earth material by mining, especially by the room-and-pillar method, is equivalent to withdrawing some of the foundation of a building, subsidence of the formations above, the mining levels in certain air-as is easily understood as a gravitational adjustment of the overlying earth formations.

Jan 1, 1940

By John C. Holtz

Interest in the possibility of using Diesel6/ engines for haulage power in mining and tunneling is increasing in the United States, owning largely to the reported successful use of Diesel locomotives in European coal mines and to the comparatively recent development of automotive Diesel engines in this country. The extent of this interest has been evidenced to the Bureau of Mines by numerous requests for information as to the factors that must be considered if Diesel engines are to be used safely underground.

Jan 1, 1940

By J. R. Thoenen

[For several years the Bureau of Mines conducted tests on ground vibration t emanating from quarry blasting in an effort to determine an index of destruction for different types of structures. Results of these studies have been published in four Bureau of Mines Reports of Invitations as well as in several articles in the trade and technical press.5/ The first paper (3)6/ discussed the subject in general and gave results s of a few blasting records. Some tentative theories also were advanced. The second paper (4) discussed results s of records made from blasting in a number of quarries.]

Jan 1, 1940

By F. D. DeVaney

Metallurgists and coal-washing engineers have used heavy liquids for years in studying the characteristics of ores and coal. By such means true separations can be made between the various specific-gravity increments in the materials examined. To use of heavy liquids has permitted determination of the possible grades of tailings and concentrates by specific-gravity methods on any particular size, and therefore the size to which the ore must be crushed to free the valuable material. The simplicity of float-and-sink separation and the high degree of efficiency attained in the laboratory are factors that commend the method for commercial concentrations.

Jan 1, 1940