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By Richard F. Lynch, Frank E. Goodwin

"The development of Galfan, a new generation 95% zinc-5% aluminum-mischmetal alloy coating for steel, offers opportunities for greater fabrication flexibility and upgraded corrosion performance in automotive applications. The formability of Galfan is equivalent to that of electrogalvanized steel, based on laboratory tests and automotive component fabrication. Corrosion resistance of Galfan exceeds that of hot dip and electrogalvanized, including performance in automotive industry tests. Automotive production applications for deep drawn and stamped components in France and Germany are based on the ability to meet dual performance requirements for upgraded formability and corrosion resistance. The first U.S. Galfan application was on 1985 model Ford cars and light trucks for transmission oil cooler lines which has now expanded into a number of power steering tubing uses. IntroductionContinuing requirements for improved vehicle performance coupled with the ever present need for reduced cost have spawned the development of a number of new coated steel products. Among this new generation of coated steels is Gaifan™, a 95070 zinc-Solo aluminum-mischmetal hot dip alloy coating. Galfan exhibits particular promise for automotive use based on broad fabrication advantages and upgraded product performance(I ),The unique characteristic of Galfan is the key combination of greatly improved formability with much longer corrosion life. Galfan provides significantly better formability than any other hot dip coating. Testing shows that formability is limited primarily by the steel substrate to which the Galfan coating is applied. Galfan exhibits excellent resistance to flaking and microcracking during commercial forming operations. The result is the elimination of unnoticed damage to the coating which would show up later as premature rusting on the finished product."

Jan 1, 1987

By Mario Aiezza

This paper outlines the results of a relationship developed during the design and construction of the foundations for the Gallery Towers project in Melbourne. Both the builder and the piling contractor were determined to arrive at a satisfactory foundation solution to the problems encountered at the site. The scope of piling work was to provide load-bearing piles under the building columns, some of which were located within a retention system that also required a piling solution. Geological conditions were variable and challenging. The site area was small and located adjacent to the National Arts Centre in the developed Southbank area, a high density office area. This presented logistical problems in limiting construction traffic on site and also demanding minimal noise and vibration emanating from piling activities. The piling contractor, Vibro-Pile, and the builder, Walter Construction Group, faced the challenges presented with a refreshing cooperative attitude that was beneficial to both companies. Commercial issues rising from design and construction problems were first put apart in order to allow the respective technical department of each company to work with minimum constraints to achieve the most cost effective solution. In the process usual adversarial attitudes resulting in loss of time and money was avoided. A number of issues were addressed successfully at minimum cost and time during this contract. Despite the difficulties encountered, the job was completed on time and with negligible claims for extras, resulting in the development of a strong mutual respect between both companies.

Jan 1, 2002

Project Located in northwestern British Columbia 70km West of Cassiar Highway Galore Creek Project and Road Access Corridors Designated For Mineral Development in Stikine-Cassiar Land Resource Management Plan (LRMP)Approved in 2000Strong BC Government, local community and Tahltan First Nation Support for Project

May 1, 2006

By Jan E. Nesset, James A. Finch, Frank Rosenblum, Rebecca Payant

"Under certain conditions of moisture and oxygen, sulphides can spontaneously heat, a phenomenon known as self-heating. In this paper, we test a hypothesis that galvanic interaction between some sulphides can promote self-heating. Galvanic interaction is controlled by restpotential difference between minerals and their surface area of contact (particle size). In order to decrease rest-potential, four sulphides were tested: pyrite, chalcopyrite, sphalerite and galena. Two series of samples consisting of mixtures of two sulphides, each representing a mass fraction of 50 %, were run in standard self-heating tests. The first series comprised five mixtures, two with low rest-potential difference (pyrite-chalcopyrite and chalcopyrite-sphalerite) and three with high rest-potential difference (pyrite-galena, chalcopyrite-galena and pyrite-sphalerite). The second series was performed on a pyrite-sphalerite mixture at four particle sizes (80 % passing 850 µm, 300 µm, 75 µm and 38 µm). The first series showed that the individual sulphides and the mixtures of low rest-potential difference did not self-heat but the mixtures of high rest-potential difference did self-heat. The second series showed that self-heating increased inversely with particle size (increased specific surface area) and revealed that it was the fineness of the pyrite (high rest-potential sulphide) that governed the self-heating effect, indicating the rate-limiting step is the reduction reaction on pyrite (cathodic mineral). The increase in self-heating with high rest-potential difference and increasing particle fineness supports the hypothesis that galvanic interaction contributes to sulphide self-heating. A possible mechanism based on the hydrogen sulphide hypothesis is proposed where the reduction reaction at the cathodic mineral surface is ferric to ferrous. The understanding gained will be of interest to those involved in storage, shipping and disposal of sulphide minerals.INTRODUCTIONSulphide mineral ores are the major source of most base metals such as copper, zinc, nickel and lead. Once the ore is extracted, the sulphide minerals are liberated by size reduction (crushing and grinding), concentrated by flotation, and the concentrates sent for further processing to extract the metal (smelting and refining). At the various stages from mining to concentrate shipment and tailings storage, the sulphides are exposed to a variety of environments, which under certain conditions of air (oxygen), humidity and temperature can cause them to heat. Since no external heat source is involved, this pyrophoric process is known as spontaneous heating or, more commonly, self-heating. The self-heating of sulphides is associated with oxidation reactions under moist conditions. If the heat generated is greater than the heat dissipated, the sulphides will self-heat and the material temperature will rise. This can make working conditions potentially dangerous as oxygen is consumed from the surrounding air and significant quantities of sulphur dioxide (SO2) can be released (Ninteman, 1978)."

Jan 1, 2011

By C. J. Allen, L. Battiston

"Introduction It has long been recognized by the hot-dip galvanizing industry that the characteristics of the galvanized coating can be influenced significantly by steel and pro cessing variables. Probably the variable of most concern to galvan izers today is steel chemistry. More specifically, the problem is the excessive reactivity of continuously-cast, silicon-bearing steels. In the past, structural steels processed by general galvanizers were in the low-to-medium ca rbon category and contained silicon at either low impurity levels (as with rimmed steels), or less than approximately 0.10% (as with semi-killed steels). The structures of the coatings produced on such steels are characterized by dense, compact layers of delta and zeta iron-zinc alloy phases and a distinct outer layer of eta zinc, which usually imparts a bright shiny appearance to the coating. The presence of silicon in steel, above the so-called semi-killed levels, is known to cause marked stru ctural changes in galvanized coatings. Such coatings are characterized by a relatively thin delta layer, a thick , coarse zeta layer and frequently an absence of the eta layer. The eta phase, comprising zinc which is carried out of the bath during withdrawal of the work, can be consumed by the continuation of the coating reactions until its temperature drops to the solidification point. This results in a dull grey and often mottled surface instead of the usually bright metallic appearance. These galvanized coatings are usually much thicker than coating specifications requ ire and they are usually more brittle and have poor adhesion to the steel. In service, these coatings tend to develop a rust-like discolouration. With the wider use of continuous casting by the steel producers and the associated additions of silicon in this process, the problem is becoming more important and receiving greater attention from the galvanizing industry ."

Jan 1, 1987

By K. L. Ford, D. R. Lentz, J. H. Rickard, R. P. Taylor

Abstract - Coupled gamma-ray spectrometric and lithogeochemical studies throughout the Heath Steele Mines area, Bathurst Camp, New Brunswick, indicate that primary and secondary geochemical differences exist between the stratigraphic footwall and hangingwall crystal tuff units which host the massive sulfide deposits. Of particular interest is Th, and to a lesser extent, Zr and Y, which are more concentrated in the hangingwall than the footwall crystal tuffs, whereas the opposite is true for TiO2. This expands on earlier lithogeochemical-chemostratigraphic results concentrated in the eastern part of the Heath Steele belt that led to revision of the local stratigraphy, and necessitated a structural re-interpretation of the area with implications for exploration. Although K depletion (decreased K and K/Th) is typical of chloritized footwall zones of chloritization, these features were not fully apparent here due to the recessive nature of these altered zones. In situ radiometric analysis using a portable gamma-ray spectrometer is a rapid, inexpensive analytical technique for chemostratigraphic characterization of rock units within volcanogenic massive sulfide deposit settings, provided there is a contrast in the distribution of natural radioelements, particularly Th and K.

Jan 1, 1998

By Enrique Albarrán, Julian Hernández

"In 1942 The “Presa Mixcoac” dam was built, along with 15 other dams, to control the rain fall waterin the mountains west of Mexico City. Mexico City’s population at that time was around 1.5 millionpeople, and the dam was way out of the city."

Jan 1, 2016

By Wiley C. Buford

Gary Works No. 1 BOP Shop is a three furnace shop which went into operation December, 1965. The heat size is over 200 tons, with a substantial percentage of the production used to feed a Continuous Slab Caster. Vessels are driven by a shaft mounted bull gear and main housing utilizing eight 35 HP flange mounted motors and primary gear reducers. Torque absorption is controlled by two spring actuated torque arms. At 1:00 p.m. on Thursday, August 6, 1970, as "E" furnace was being turned down for a preliminary test, the drive side trunnion bearing failed. The furnace dropped slightly and shifted several inches north in the direction of the drive unit. The decision was made to tap the heat which was done without incident and the vessel uprighted. No attempt was made to completely drain the slag from the vessel, so as to avoid any further damage to the trunnion shaft bearing surface. The bearing failure occurred approximately four years and eight months after start up of the shop. Unfortunately ?M? furnace had gone down for a normal reline two days prior to the bearing failure, leaving the shop with only one operating furnace.

Jan 1, 1972

By B. Woyski

MANY writers, in discussing defects caused by oxidation and gassing of bronzes and red brasses advocate substantially the same cure for both. But from its nature, oxidation cannot take place if there is an excess of fuel in the furnace, while the gases absorbed by some alloys are products of incomplete combustion of the fuel. Hence the metal can be either oxidized or gassed, but it is doubtful whether these actions can take place simultaneously. Oxidation can be easily overcome by the use of deoxidizers or it may be avoided by protecting the molten metal with suitable fluxes. Absorption of gases is more difficult to overcome. The regulation of the air and fuel, so as to produce complete combustion, and the protection of the bath by mineral fluxes are the most important factors. Gas expulsion, resulting in gas holes, porosity, unsoundness, and swollen or cauliflower-headed risers, is said to have several causes. One writer' lists the most common causes in the order of their importance, as follows: Superheated metal, dirty or slaggy furnace conditions, using metals low in quality or those previously subjected to bad melting practice, poor grade of fuel, use of newly lined or damp ladles, indiscriminate mixing of scrap or illogical combinations of metal. Superheating the metal usually occurs when the heat is ready to be poured but for some reason must be held in the furnace. In this case, a careful furnace tender tries to avoid overheating the metal by keeping a mild fire; that is, a reducing fire which, unfortunately, results in gassing the metal. A dirty, slaggy furnace may result in gassing the metal by retarding the heating and prolonging the time necessary to bring the metal to the proper temperature, thereby increasing the chances of gassing in uncertain furnace atmosphere.

Jan 5, 1922

By C. A. C. Sequeira, G. N. Anastassakis

Electrochemical processes occur on nano-, micro- and macro- scale in numerous applications such as fuel cells, batteries, hydrogen production, mineral extraction, water treatment, electrotherapy, sensors and many others. In most of these applications, gases evolve either at one or both electrodes due to electrolysis. These gases form bubbles play a crucial role in electrochemical systems. For example, in electrowinning (EW) that is used to extract and refine metals such as Cu, Zn, Ni, Mn, and Cd from their solutions, in most cases the solution is acidic and oxidation of water molecules at the anode is the common counter reaction, which results in the liberation of oxygen bubbles. This generally requires a high overpotential and accounts for a considerable percentage of the energy consumed in metal EW electrolytic cells, apart from producing acid mist that is very corrosive for other cell equipment and building structures. The behaviour of bubbles in electrochemical systems is still a complex challenging topic which requires a better understanding of gas bubbles hydrodynamics and their interactions with electrode surface and bulk liquid, as well as between the bubbles themselves. The objective of the current paper is to briefly review the fundamental hydrodynamics of both gas bubbles on the electrode surface and gas bubbles interaction with the liquid bulk solution. The current work also investigates the impact of gas bubbling and some operating parameters in copper EW, such as current density (100-500 A/m2), temperature (25-75ºC), acidity (50-300 g/L) and a typical chemical mist suppressant (<50 ppm). The results clearly show that both suppressant and temperature reduced the overall surface tension of the solution. Also, chloride concentration and applied current improved electrolyte flow and copper quality at higher current densities. The current paper contributes to the development of mineral processing (specifically to copper hydrometallurgy), as it deals with fundamental hydrodynamics and interactions of gas bubbles that formed during copper EW and play a crucial role in copper electrochemical systems.

Jan 1, 2018

By T P. Fischer, S N. Williams, N C. Sturchio

Chemical and isotopic analyses of fumarole gases from Galeras Volcano, Colombia provide significant insights into the origin of volatile components in the magma. Water comprises a mixture of magmatic (rock-equilibrated at high temperature) and meteoric, with the relative proportions varying through time. Carbon isotopes are most consistent with a mantle source, although other contributions to the system cannot be ruled out. Nitrogen most likely originated from organic matter in subducted oceanic sediments. All of these &apos;primary&apos; components have been modified somewhat by interaction or exchange with other reservoirs during ascent to the surface. In addition to information on the origin of the gases, these data show significant temporal variations precursory to eruptive events. Chemical ratios change and water becomes more meteoric in character prior to eruptions.

Jan 1, 1995

By Sturchio NC, Williams SN, Fischer TP

Chemical and isotopic analyses of fumarole gases from Galeras Volcano, Colombia provide significant insights into the origin of volatile components in the magma.. Water comprises a mixture of magmatic (rock-equilibrated at high temperature) and meteoric, with the relative proportions varying through time. Carbon isotopes are most consistent with a mantle source, although other contributions to the system cannot be ruled out. Nitrogen most likely originated from organic matter in subducted oceanic sediments. All of these "primary" components have been modified somewhat by interaction or exchange with other reservoirs during ascent to the surface. In addition to information on the origin of the gases, these data show significant temporal variations precursory to eruptive events. Chemical ratios change and water becomes more meteoric in character prior to eruptions.

Jan 1, 1995

Mixers are commonly used for the transfer of oxygen in gas-liquid-solid reactions in minerals processing. The process rate is usually controlled by two steps: gas-liquid mass transfer and reaction kinetics. Some examples are described along with the factors used for analysis of the mass transfer design problem. Typical oxygen rates and appropriate types of aeration systems or mixers are reviewed. The commonly used Rushton turbine has limitations in a number of mineral processes. The development and characteristics of the LIGHTNIN A315 axial flow gas dispersion impeller are described. Some practical examples which highlight its advantages are briefly described.

Jan 1, 1992

By J. A. Finch

"Gas dispersion in flotation defines the efficiency of the process once the chemistry has been established. There are three measurements, superficial gas velocity, gas holdup, and bubble size, which along with the derived quantity bubble surface area flux, are used to define “gas dispersion.” Sensors for measuring gas dispersion in industrial machines have been developed. This communication describes the working principle of the techniques and illustrates their potential to detect problems and to improve the operation of individual cells, banks and circuits. IntroductionFlotation is the most widely used process to separate minerals and is finding increasing application in other chemical and environmental fields. The process exploits natural and induced hydrophobicity to collect selected particles on the surface of a bubble. Once the process chemistry to control hydrophobicity has been established, the efficiency depends on dispersion of air to generate the necessary bubble surface area. Bubble surface area flux, Sb, the interfacial area generated per unit time and unit area of the machine, is emerging as one of the most useful variables to quantify gas dispersion (Gorain et al., 1997, 1998) although not without its critics (Heiskenan et al., 2001).For a bubble population of mean size db at a superficial gas velocity (or rate) Jg, the bubble surface area flux can be derived from geometric considerations (Finch et al., 1999):"

Jan 1, 2002

By Y. F. Bulgakov, Y. V. Melnikova, V. S. Zakharov

A new technology of atmosphere in inertization of fire section with the help of gazeous nitrogen is presented in the report. This technology is based on membrane air subdivision into two streams, concentrated with nitrogen (up to 99%) and with oxygen correspondently with subsequent giving them into the place of fire. This technology belongs to environmentally friendly ones and it has a great number of technical, mobile and economic advantages comparing with the rest of well-known methods of fire extinguishing. This technology application in Ukrainian coal mines allowed to reduce the member of isolated places of fire at the expense of their extinguishing efficiency.

Jan 1, 2003

By Burgess JM

Research on gas distribution in the iron- making blast furnace has been conducted in three separate areas. Firstly, experimental work has been conducted to determine the important parameters which dictate the pressure losses in homogeneous and heterogen- eous packed beds. Secondly, a theoretical analysis of gas flow through the furnace softening-melting zone has been undertaken to determine the effect of the shape of the zone on the distribution of gas flow towards the furnace walls. Thirdly, a theoretical programme has been undertaken to develop methods for the prediction of furnace soften- ing-melting zone shape from furnace tempera- ture and gas composition measurements.

Jan 1, 1980

The study of gas emitted from face coal samples at the coal face is part of an investigation of instantaneous outbursts of coal and gas. Normally, seam gas essentially comprises methane of which the origin in the metamorphism of coal is undoubted. The origin of other gases sometimes occurring in high proportion in seam gas, particularly carbon dioxide, is more controversial. A simple meter for rapidly assessing gas in coal was developed. Tests with the meter enabled comparisons of seam gas in face coal at some outbursting and nonoutbursting mines, and under various working conditions. The varying results of widespread testing suggest certain trends, including some prospect of recognising outbursting potential at the coal face.INTRODUCTIONThe aim of this work is identification of differences in gas condition between coals subject to instantaneous outbursts and coals which have not outburst, and between faces of coals which will and which will not subsequently outburst. Any comparative test should be conducted right at the coal face on coal about to be worked and the results of testing should be available after a short period. Moreover, the method and the comparison of results should require no special skill, and be well within the capacity of junior mine officials. Any consistent relation between gas condition and subsequent mining conditions - outbursting or not might be valuable in prediction of outbursts.INSTANTANEOUS OUTBURSTSInstantaneous outbursts (Hargraves, 1958) , are largely unpredictable and unaccountable ejections of coal (up to 5,000 tons) and gas (up to 5,000,000 cu.ft.) from a standing coal face. Usually the gas is essentially methane (CH4 ) but may be essentially carbon dioxide (C02 ), or an intermediatemixture...

Jan 1, 1962

By R. Switalski, M. Schafer, R. Pintabona, M. Kritzer, B. Lukajic, S. Janosko

Methane gas caused an eight-month shutdown of mining operations at the Mill Creek, Phase 3, Tunnel. The gas-related shutdown occurred as the tunnel was advanced to an approximate distance of 2,700 feet, which constitutes approximately18% of the total tunnel length. The construction of an emergency ventilation shaft, a comprehensive program of de-gassing wells and an expanded gas monitoring system were used to mitigate the gas condition. When complete, this tunnel will be utilized to convey and store combined storm and sanitary sewage collected from a portion of Cleveland, Ohio and ten suburbs. This paper will provide an overview of gas related remedial measures and explain how these measures were integrated into the project to ensure safe tunneling conditions.

Jan 1, 2007

By D. W. Alexander

Researchers from the Office of Mine Safety and Health Research (OMSHR) of the National Institute for Occupational Safety and Health (NIOSH) completed field trials during coal mine rescue contests using simulated gas detectors in place of placards. The gas monitor simulator (GMS) devices replaced static, paper placards to deliver gas concentration data. Eleven teams were observed during the field contest, which was approved by the Mine Safety and Health Administration (MSHA). GMS devices were given to three team members, the captain, and both gasmen. Observation of teams revealed that team members changed behavior by acknowledging and sharing information more often while using the GMS. As a result of this research, it has been demonstrated that under the existing contest format, the newly developed GMS device may be used with no adverse impact on team contest performance. Furthermore, when GMS technology advantages are used, contest realism is improved. In the future, competency assessment may be incorporated.

Jan 1, 2011

By Rankin W. J

Increasing concern with the emission of sulphur dioxide from smelters and roasters has caused renewed interest in processes which can use waste sulphur dioxide, such as the sulphation of nickel laterite ores. The process described here proposes to by-pass the production of sulphuric acid and react laterite directly with a sulphur dioxide containing atmosphere. A thermodynamic analysis identified operating windows in which nickel sulphate forms while iron oxide (the major impurity in most laterite ores) remains stable. The initial assumptions included unit activity of all species except nickel oxide. The lowest possible nickel oxide activity (while maintaining selectivity) increased with increasing temperature, indicating that selective sulphation is favoured by low temperatures. The temperature of interest was found to be between 500 and 800¦C. Calculations show that a feed gas containing ten per cent SO2, five per cent 02, balance N2 requires a temperature greater than 650¦C for selective sulphation of nickel. Laboratory experiments showed that the assumption of unit activity of ferric sulphate was unrealistic above about 680¦C due most likely to the formation of solid solutions which decreased the ferric sulphate activity. Results are presented which illustrate the limiting equilibrium sulphur trioxide partial pressures at 700 and 730¦C below which selective sulphation occurs. Cobalt extraction was usually between 80 and 95 per cent under conditions yielding selective sulphation, whilst nickel extraction was about 50 to 75 per cent depending on temperature and choice of upper limit of iron extraction. An operating diagram is presented for a limonite ore and shows that the optimum reaction conditions are 680¦C and an input gas containing 20 per cent SO2. Under these conditions nickel, cobalt and iron extractions are 73, 95 and two per cent respectively.

Jan 1, 1996