Search Documents

By C. Machio

This paper reports the results of a study to determine the effect of process control agent (PCA) on the characteristics of Ti-Mg powders during milling. It has been shown that a 2% increase in PCA content leads to up to a 40% increase in yield of the milled powder but reduces the kinetics of the mechanical alloying process. The introduction of 4% PCA decreases the mean powder particle size by up to 30%, whereas 6% PCA increases the mean particle size by up to 230%. The characteristics of the milled powders will be discussed in relation to the role of PCA in the milling process. Keywords Titanium?magnesium, mechanical alloying, PCA.

Jan 1, 2011

By S. G. Shabestari, S. Saeidinia, P. Mokarian

"The experiments were conducted to investigate the influence of various process parameters in rotary degassing of aluminum alloy AS5U3G. Degassing was carried out by use of argon inert gas. The flow rate of the gas was investigated in the range of 12 to 21 L/min., 350 to 500 rpm rotor speed, 6 to 12 minutes degassing time, and 755°C to 780°C melt temperature. Degassing efficiency was evaluated through measuring the density of RPT samples. By optimizing the process parameters, RPT sample density was increased up to 2.73 g/cm3, which guaranties the production of high-quality aluminum castings. Tensile strength and elongation were increased considerably by degassing process. Scanning electron microscopy (SEM) shows small size and well-distributed microporosity. IntroductionOne of the major problems associated with the casting of aluminum alloys is the formation of gas porosity. Aluminum and its alloys are very susceptible to hydrogen absorption. Because solubility is much lower in solid state than liquid state, hydrogen atoms leave their position during solidification and combine together to form hydrogen molecules. These micrometer- scale cavities, called microporosity, cause the reduction of mechanical properties, particularly strength, ductility, fracture toughness, fatigue resistance, pressure tightness, and corrosion resistance (Laslaz, 1991; Jorstad and Rasmussen, 1993; Sigworth and Wang, 1994; Korasani, 1996; Anson and Gruzleski, 1999; Zhang et al., 2000). To avoid these problems and produce good quality castings, it is necessary to remove hydrogen from the melt. Several methods are available for degassing aluminum melt. One of them is a rotary degassing system using inert gas, e.g. Ar or N2. Various thermodynamic and kinetic factors govern the removal of hydrogen from molten aluminum (Anderson, 1987; Sigworth, 1987; Pignault, 1993; King and Reynolds, 1995). These are some parameters that affect degassing efficiency. Some of them are discussed here and some are examined in this project."

Jan 1, 2004

By M. Suzuki, T. Shiomi, M. Nakada, K. Tsutsumi

Mold powder plays an important role in the continuous casting process for high quality steel production. It is well known that mold powder entrapment causes surface defects in steel sheet and the high viscosity of mold powder prevents the entrapment of mold powder in molten steel in ultra low carbon steel. This paper deals with the entrapment of mold powder caused by suction by Karman?s vortex in a laboratory experiment. At first the effect of the viscosity of oil and interfacial tension between water and oil was investigated in a water model experiment. Then hot model experiments were carried out by mold powder and molten steel. The amount of mold powder entrapment was affected by the viscosity and the interfacial tension between molten steel and mold powder. As a result, the following equation of the mold powder entrapment was obtained. m=1.06*107?-0.255?m-s-2.18 The amount of mold powder entrapment decreased when the viscosity and interfacial tension increased. But the effect of viscosity was larger than that of interfacial tension in the case of the industrial mold powder when the viscosity was under 0.5 Pa.s, interfacial tension was from 1200to 1300 mN/m.

Jan 1, 2004

By Karl Hoover, Cassandra Spence, Brent Bachewich, Jaakko Levanaho

"Since year 2000 the gold recovery into copper concentrate at Hudson Bay Mining and Smelting has reduced considerably during the summer months. This initiated a testwork program in the fall 2003 to find reasons and solutions for such change. During the testwork mineralogical factors, water quality effects and different reagents were evaluated. The reason for the lower recovery appeared to be the sensitivity of some collectors to pulp temperature. As a result of the work different collectors are being used in the mill in the summer than in the winter. A modification to the water system was also made to provide cooler water to the mill in the summer months.INTRODUCTIONHudson Bay Mining and Smelting (HBMS) is located in Northern Manitoba, just on the border of Manitoba and Saskatchewan. The complex consist of four different mines, Callinan, Trout Lake, Konuto Lake and 777 mine including copper smelter and zinc hydrometallurgical plants producing metallic copper and zinc. Gold is a very important byproduct providing about 30% of the mine revenue. In early 1990s when the company was facing declining ore reserves and was starting to gradually close down the operations, the 777’th exploration drill hole discovered a new orebody, which initiated a $0.5 billion expansion program. The main projects were a new 777 hoist with underground development and a new zinc cell house. About $30 million was used to increase the mill throughput to the present 2.27 million tonnes or 2.5 million short tons per year. The expansion programs were finished by the end of the year 2003.Historically the gold recovery at HBMS has varied between 60 and 70%. The recovery has been somewhat lower during the summer months. Gold recovery improvement projects were conducted throughout the 1990s, but were not focused on the seasonal gold recovery variance. However, since 2000, when the water system modifications to meet the increased water demand were completed, the gold recovery during the summer has been much lower than in the past. In August 2003 gold recovery fell below 30%, which initiated a metallurgical research program to discover the reasons behind the low gold recovery in the summer."

Jan 1, 2005

By H. W. McQuaid

IT IS usually assumed that chemical specifications are sufficient for steel to be used for case carburizing, and if the steel analyzes within the ordinary limits specified for steel for this purpose, no difficulty traceable to the steel used should be encountered in obtaining satisfactory results in the case carburizing and hardening. Much work has been done to determine the effect of various alloying elements on the rate of carbon penetration, etc. but, to our knowledge, little if anything has been published in regard to the effect of the quality of the steel on the final results in the hardening of case-carburized steel parts. The writers believe that the structure of the case both before and after quenching is greatly affected by the actual condition of the steel itself as made, and that for good results in the case-carburizing and hardening departments, the steel should be of the best possible quality as regards non-metallic impurities. It is the purpose of this paper to prove that the presence of excess dissolved oxides in the steel, as made in the melting furnace, affects permanently the results obtained in carburizing and hardening and that it is possible that the presence of dissolved oxide can result in total unfitness of low-carbon steel for, case hardening purposes. When races and rolls for roller bearings are made from a low-carbon steel, case carburized and hardened, it is of primary importance that the results of this treatment be of the highest quality. It is necessary, therefore, that in the case-carburizing work each detail be rigorously checked to avoid any defects which would cause the loss of much time and material. The case carburizing with which this paper deals was done in under-fired oil furnaces. The temperature of each furnace is controlled by means of a platinum platinum-rhodium thermocouple, in connection with a potentiometer indicator and potentiometer recorder. The temperature of each furnace is registered every 15 min. by an operator, who is continually checked by the automatic recorders.

Jan 2, 1922

By Hidenori Hatta, Takero Watanabe, Hideo Yoshida

"The effect of the quenching rate on age hardening in an Al-6.0mass%Zn-0.75mass%Mg alloy sheet was investigated. The quenching rates and aging conditions were as follows: water quenching (WQ) or furnace cooling (FC) followed by pre-aging at 20°C,then artificial aging at 120, 160 or 200°Cwere performed. The peak strength of the FC and the WQ are very similarat120°C aging. It is important high strength was obtained even at the extremely slow quenching rate. On the other hand, the strength of the WQ significantly decreased compared to the FCat200°C aging. GP(I) zones were formed during the pre-aging at 20°C even if the cooling rate was very slow like the FC, and were transformed into the GP(II) ones at 70°C or higher and then into the ?’ phase. However, these zones were dissolved by reversion during heating to 200°C. Thus the strength of the WQ decreased. On the other hand, it is considered that an unknown cluster or GP zone with a thermal stability formed during the FC was not dissolved up to 200°C and was transformed into the ?’ phase. Therefore, a higher strength was obtained in the FC for the200°Caging.INTRODUCTIONAl-Zn-Mg alloys are widely available in commercial production because these alloy have lower quench sensitivity and can be produced by air cooling (AC). Heat treatable aluminum alloys are usually produced by water quenching (WQ) to increase their strength because a high cooling rate inhibits the precipitation of the stable phase during cooling and increases supersaturated solute atoms. However, Baba(1967)reported the strength of an Al-6%Zn-1.8%Mg(mass%) alloy without additional elements quenched by very slow cooling (15°C/min) was 96% of that quenched by WQ. Furthermore,the age hardening at room temperature (RT) occurs after annealing at 410°C followed by furnace cooling (FC, 0.5ºC/min or less)in these alloys. Therefore, the process of annealing at 410 to 430°C for 120 min followed by AC, and reheating at 230°C for 240 min, then cooling is recommended in the specifications (Japan Aluminum Association, 2011). Matsuda and Yoshida(1996)also recommended annealing at 300°C for Al-Zn-Mg alloy extruded products to inhibit age hardening at RT by precipitating the solute atoms and decreasing them in the matrix. It has been considered that the higher the content of excess quenched-in vacancy becomes by WQ, the higher aging rate at RT is obtained. Therefore,it is theoretically and commercially important to clarify the reason why the age hardening occurs relatively quickly in almost no excess quenched-in vacancies such as the FC, and why the same strength as the WQ can be obtained in the FC"

Jan 1, 2018

By E. Matinde, S. L. Msibi

"The robust nature of alumina refractory materials presents opportunities for their in-process reclaiming and re-use in non-critical applications. Virgin refractories can be substituted with different quantities of reclaimed materials without compromising the quality of the refractory products. In this study, the effect of reclaimed bauxite on andalusite-containing refractory castables for tundish applications was investigated. The recycled bauxite was formulated in different proportions to replace virgin andalusite in the castables. Standard tests were conducted to evaluate the physical, physicochemical, and thermochemical properties of the formulated products. Static corrosion tests were conducted using tundish slag in order to simulate the actual operating conditions. The results show that the standard flow behaviour, open porosity, and bulk density of samples containing up to 22 mass% reclaimed bauxite were comparable to those of the reference castable. However, high-temperature properties such as static corrosion at 1400°C and hot modulus of rupture at 1500°C indicated that there is an upper constraint to the amount of substitution. The study demonstrated direct potential savings of up to 10% when the reclaimed alumina replacement ratio was increased to 22 mass%. IntroductionAlumina-based refractories can be classified into low-alumina, containing less than 50% Al2O3, and high-alumina or bauxite, containing between 50 and 90% Al2O3. High-alumina refractories have widespread applications in high-temperature metal extraction processes due to their outstanding thermochemical and thermomechanical properties and stability (Rebouillat and Rigaud, 2002; Frulli, 2016). The typical chemical composition of refractory-grade bauxite consists of 85–90 wt.% Al2O3, 5–10 wt.% SiO2, 1–2wt.% Fe2O3, 3–4 wt.% TiO2, 0.4–0.8 wt.% CaO + MgO, and 0.20–0.8 wt.% K2O + Na2O (Nyoka et al., 2013). The thermochemical and thermomechanical properties of bauxite-based refractories rely principally on the conversion of the contained silica and alumina to the highly stable corundum (?-Al2O3) and mullite (3Al2O3· 2SiO2) phases (Rebouillat and Rigaud, 2002; Hill and Sehnke, 2006; Garbers-Craig, 2008; Frulli, 2016)."

Jun 1, 2019

By Zhiyun Li

Room temperature infrared reflection spectra of 2 n-type homo-epitaxial epifilms have been measured in the work. The effect of the refractive index on the determination of layer thickness using traditional calculation measurement is studied and some improvements have been added to the measurement to improve the accuracy and stability of the measured results. Results of the improved method have great agreement with the results from SEM and both variance and mean relative error decrease an order of magnitude.

Jan 1, 2010

By B. Unver

Effective strata control is a prerequisite for maintaining an efficient mining operation. If the strata in the vicinity of an opening are not controlled effectively, it is impossible to perform a safe, efficient and economical operation. In this paper, the reasons and outcome of instability problems observed in roadways opened in clay and marl at the Bolu Colliery of Yeni Çeltek Establishment are investigated. Roadways under examination were located in a syncline causing high residual tectonic stresses. Factors affecting the instability have been studied thoroughly by examining geology and tectonics of the area, establishing convergence measuring stations to understand in situ behaviour of supports and laboratory tests to determine engineering properties of samples taken from nearby convergence measurement stations. As a conclusion, a new production strategy and a new support system are recommended to maintain stability.

Jan 1, 1999

By Murat Baydogan

Effect of retrogression and reaging treatment on hardness and stress corrosion cracking resistance of 7075 aluminum alloy was investigated. As received 7075 alloys in T6 temper condition were retrogressed at 170, 220, 240 and 380°C for different durations between 15 s and 60 min. Subsequent reaging was made at the T6 aging condition. Treated materials exhibited higher hardness and better stress corrosion cracking resistance than T6 temper in a wide range of retrogression temperature and time. The highest hardness was obtained after retrogression at 170°C for 210 s followed by reaging, corresponding to 20% hardness improvement. Improvement in stress corrosion cracking resistance of the alloy by as much as 85% was also observed. In this paper, improvements in hardness and stress corrosion cracking resistance are discussed on the basis of the microstructural changes during retrogression and reaging treatment.

Jan 1, 2006

By Rajagopala Reddy Kallu

After the Sago and Darby No. 1 mine incidents, the new regulatory standards for the design of mine seals in underground coal mines of the United States require the mine seals to withstand higher explosion standards. This necessitated for the development of new design approaches and standards. For development of any new design standards or approaches a detailed understanding of effect of key influencing parameters on the stability of mine seal is a must. This paper attempts to address one of the factors, i.e. roof convergence, that play an important role in the stability of mine seal under explosion loading. Initially a couple of three dimensional numerical models were built and tested for different levels of roof convergence. These models confirmed that roof convergence has great influence on seal stability. A detailed study is undertaken, with some simple assumptions, to establish typical influence of roof convergence on the stability of mine seal under different levels of static explosion pressures. Three dimensional distinct element code 3DEC is used for this purpose.

Jan 1, 2007

By J. E. Chilton

The National Institute for Occupational Safety and Health (NIOSH) has conducted research to determine the influence of mining machine-mounted scrubbers on airflows and methane concentrations at the face when blowing ventilation systems are used. Tests were conducted in a full-scale ventilation gallery with a model mining machine that simulated airflow created by a dust scrubber. During the tests, ultrasonic anemometers were used to measure airflow speed and direction at several locations near the face. For the same test conditions, methane was released from the face and gas concentrations were measured at 21 locations above the machine using fixed point methanometers. Changes in airflow speed and direction are correlated with scrubber airflow and the measured methane distribution above the mining machine. The research results showed that operation of machine-mounted scrubbers improved face ventilation when blowing ventilation is used by increasing both the intake flow and the quantity of air reaching the face.

By F. Chiesa, Jeremy Carignan, B. Duchesne, D. Levasseur

"Aluminium A206 (AlCu4) is one of the strongest aluminium casting alloys with tensile properties approaching those of ferritic ductile iron. If the specification on the silicon content (< 0.05%) is easy to achieve during alloy ingot production, it is not the case in a foundry, where returns are used which are not perfectly cleaned from the silicate containing molding sand (Olivine). In alloy A206, the Si content is controlled in order to avoid the formation of a low melting point intermetallic phase (such as phase Q Al5Cu2Si6Mg2); these phases will melt during the solutionizing heat treatment to which alloy A206 must be subjected to develop its outstanding mechanical properties. This incipient melting may deteriorate the mechanical properties of Alloy A206 if the solutionizing treatment is applied at the standard temperature of 530°C.In the present study, a lower temperature solutionizing (520°C) was applied to a high Si content 206 alloy in order to reduce or eliminate the possible incipient melting. This was carried out on a complex shape industrial casting weighing 14 kg (31 lb) and 560x410x250 mm (22x16x10”) in size poured in aluminum 206 with a high silicon content (0.22% vs 0.05% max for alloy A206). Twenty ASTM E8 subsize tensile specimens were excised from two locations in the casting in order to compare the tensile properties for the two solutionizing temperature used (530 and 520°C). Optical and SEM microscopy allowed to investigate the causes of the differences in the properties observed between the 2 zones of the casting studied for 3 different heat treatments. INTRODUCTIONIn spite of their “textbook” outstanding mechanical properties (Up to twice the strength and elongation of the widely used A356 alloy), aluminum-copper alloys of the 2xx series are seldom used because of their propensity for hot tearing [Li, 2011], the segregation of copper [Cho, 2003], and their sensitivity to stress corrosion cracking [Jean, 2009, p. 113)]. Also, because of their wide freezing range and high thermal conductivity, a wide mushy zone makes feeding difficult, unless strong temperature gradients are created by liberal use of chills and risers in the critical zones of the part. Because they are prone to hot tearing, grain refining of Al-Cu alloys is particularly important, titanium playing a major role in the process [Sigworth, 2003]; grain refining has also been shown to be beneficial to fatigue strength [Jean, 2009, p. 103]. The practical basis of foundry practices pertaining to these alloys is outlined in an AFS webinar [Weiss, 2014]."

Jan 1, 2016

By Robert H. Hafner, Irvin R. Kramer, Stewart L. Toleman

IN his paper on the calculation of hardenability from chemical composition, Grossmann1 discussed the effect of most of the alloying elements used commercially. The purpose of the work reported in this paper was to determine the effect of several other elements on hardenability-arsenic, antimony, beryllium, cobalt, columbium, germanium, tellurium, tin, aluminum, and titanium-and to extend the range of composition of some of the elements studied by , Grossmann-chromium, copper, manganese, molybdenum, nickel and silicon. EXPERIMENTAL METHODS To determine the effect on hardenability, suitable amounts of the alloying elements were added to experimental heats and the hardenability determined by means of end-quenched hardenability specimens. The steels were melted in a high-frequency induction furnace with a basic crucible, using ingot iron as a base for some of the heats and S.A.E. 1015 for others. The alloying additions were made as ferroalloys or as metal, depending on the &apos; alloying element. Hundred-pound heats were split and poured into square, tapered, cast-iron ingot molds with hot tops. Aluminum was not used as a deoxidizer in most of the heats. The ingots were homogenized for 12 hr. at 1260°C. (2300°F.) , and forged into rounds of 1 ½ in. diameter. These bars were normalized twice from 840°C. (1550°F.) before machining into Jominy bars. The composition of the steels was deter- [ ] mined in most cases by samples taken from the end-quench hardenability specimen. As suggested by crafts,2acid-soluble

Jan 1, 1943

By K. [Muthukkumaran

An extensive program of laboratory model tests was undertaken to study the effect of slope on p-y curves under passive loading in dry sand. The paper concerns the method developed in a series of laboratory model tests to experimentally determine p-y curves. Bending moment curves are differentiated by using curve fitting method of cubic polynomial function. The study includes effect of slope angle and relative density on bending moment and non-dimensional p-y curves. The non-dimensional p-y curves for piles on sloping ground under passive load are developed modifying API method by including a Reduction Factor (R) using the experimental results.

Jan 1, 2006

By Larry M. Southwick

Extraction of gold and other metals from ores suspended in liquid slurries often involves gases (such as oxygen) as a participant in the reaction. An important factor then in setting the rate of extraction can be mass transfer of the gas into the liquid and/or solids. A number of recent studies have indicated that as solids loadings increase, mass transfer rates of gas into solid-liquid mixtures decreases. This would seem to imply that lower solids loadings would be beneficial to increased reaction rates. However, since it is the solids which are being reacted, a most intriguing paradox is created. More solids should lead to more surface area to react, but it seemingly also provides less gas to react. So is the reaction faster or slower as solids loadings increases? The creation of this paradox is imbedded in how mass transfer and reaction data is collected and measured, how it is analyzed and correlated, and finally on the rate controlling steps in the reaction. An alternative analysis of these studies is presented which clarifies and eliminates the paradox. The analysis applies to water slurries as used in gold or other metal leaching processes or in bio-hydrometallurgy, as well as to molten metal/solid/gas mixtures such as might be encountered in submerged gas injection.

Jan 1, 1999

By B. Kahraman

About 70% of the world?s total boron reserves are located in Turkey. Boron minerals are typically concentrated by attrition scrubbing followed by screening and classification to remove clay minerals and other impurities. These wet concentration methods, however, result in a considerable amount of accumulated tailings in large tailings dams. The tailings are approximately 28% solids and contain 14% B2O3. Problems caused by these tailings can be minimized by employing dry beneficiation techniques involving heat treatment. This method has been successfully tested on laboratory and pilot scales. During heat treatment, borax undergoes expansion in volume. The amount of expansion is dependent on the particle size, temperature and duration of heat treatment. Because the optimum temperature and the duration of the heat treatment are not well defined, the boron ore acts as a calcined clay mineral and is discarded along with the gangue. It is important to predict such parameters using mathematical formulations. Thus, a mathematical model is used to predict the required temperature and duration period prior to heat treatment. In the experimental study presented here, a series of systematic thermal tests was carried out in a muffle furnace. Two variables, temperature and time, were studied in a response surface design. A quadratic regression model was chosen and regression coefficients were calculated. Using a regression equation, the volume expansion of the particles in various circumstances can be predicted. The mathematical test results are then correlated with the experimental results to relate the optimum expansion of borax with heating time and temperature and with borax grades and recoveries.

Jan 1, 2008

By H. A. Bilgin, G. G. U. Aldas

"Ground vibration is the natural result of the blasting process. Many empirical formulae and methodologies including analysis of travel path effects have been developed. The scaled distance, which is the most popular approach for the calculation of the attenuation of particle velocity in the ground, has led to significant advances in the prediction of particle velocity when both explosive charge and distance vary. However, this approach does not consider the effect of ground anisotropy and existence of structural geological features on ground vibration. Therefore, in this study, the effects of these rock mass properties on types, amplitudes, and frequencies of ground vibration waves at four surface mines are examined. The results, which were implemented at Kangal coal mine, Bastas quarry and Kíbrís quarry, provided guidance for the extensive study at Orhaneli surface coal mine.As a result of the study, the authors came to the conclusion that vibration amplitudes change depending on the ground on which sensors were deployed and the conditions depending on whether measurements were done near major structural geological features. It was determined that the vibration amplitudes, measured at equal distances from the source but in different directions, change because of the propagation velocity anisotropy. Besides the change of wave type due to the kind of ground at the measurement location, it was determined that vibration anomolies were due to structural features."

Jan 1, 2004

Effect of Spacer Chain Length on the Flotation of Kaolinite and Quartz by Using Gemini Surfactants as Collector

Sep 13, 2010

By A. W. Khair

Laboratory studies indicate that the specimen size influences the compressive strength of coal significantly. In the past, the diameter/height ratio of coal and rock specimens with different geometry and its influence on failure characteristics was discussed (Khair, 1993; Khair, 1994; Khair and Xu, 1994). In the current attempt, tests are designed and carried out under uniaxial condition in the laboratory to investigate the influence of specimen size. Cubical specimens of coal with edge dimension ranging from 5 cm (2 in.) through 20 cm (8 in.) were prepared according to the standards and tested uniaxially. Results show that compressive strength of coal is dependent on specimen size until certain level and later the change in specimen size would not yield significant change in compressive strength. Cubical specimens were chosen for testing because they are not only in close resemblance to underground pillars, but they are also the most stable shape under loading. The failure characteristics of these specimens were analyzed and their applicability to pillar design aspects in coal mines is studied. A detailed analysis of the physical and mechanical properties of the tested coal seam is also presented.

Jan 1, 1996