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By Orr C. W

In previous papers (1, 2), the influence on the creep resistance of elements normally found in commercial lead has been recorded. The results in the present paper refer to the influence of calcium, an element which is not found naturally in lead, but which has been used commercially in the form of alloys. It was realised that calcium would act as a deoxidising agent for lead-and in fact it was with this feature in view that both calcium and magnesium were used as additions. Subsequent work (including the results given in the present paper) has tended to diminish the importance which at first seemed to be associated with the presence of oxygen in lead. The structure of the dilute calcium lead alloys has been worked out in detail (S) and the phase diagram shows the existence of limited solid solubility and a compound CaPbs.

Jan 1, 1938

By Orr C. W

Continuing the systematic investigation of the influence of elements on the properties of lead(1). If the effects of additions of copper (up to 0.3%) on Port Pirie lead have now been determined in so far as creep rate is concerned.The results in the present paper contain also a survey of the influence of copper on the micro-structure of lead, a feature which has not appeared in the previous papers of this series. Further, it has now become known that creep is but little related to the more usually determined properties such as hardness and tensile strength. Since, however, these properties are of considerable importance in connection with the fabrication and use of this metal. Brinell hardness determinations have also been made and are here included.It is becoming more and more realised also that to be useful, creep data should refer to stresses of the order of those used in practice. This is due to the fact that as soon as deformation takes place, the properties of the metal are automatically changed. Lead does, of course, creep during industrial use, and probably (in lead chamber construction for example) extensions of the order of 5%...

Jan 1, 1938

By G. Howell Clevenger

FORMERLY great divergence of opinion existed in regard to the influence of copper in steel, as affecting its various physical properties. More recently the investigations of Stead,1 Breuil,2 Wigham,3 Burgess and Aston,4 Ball and Wingham,5 Miiller,6 Dillner,7 and others have shown fairly good agreement in the major points. Copper steel has been shown by these investigators to possess special properties which make it valuable for certain uses. The general range of composition of the useful alloys of copper and iron, and of copper, iron, and carbon, has been quite definitely established, for the former by Burgess and Aston,8 and for the latter by Breuil 9 and Stead.10 Stead 11 has removed one difficulty in reconciling certain of the earlier data by calling particular attention to the influence of carbon in copper steels. Another point which caused confusion in the earlier investigations, particularly in regard to " red-shortness," was the presence of sulphur. Failure to note the presence of sulphur often led to attributing " red-shortness " to the presence of small amounts of copper. Turner 12 has called attention to the fact that where copper exists in an iron ore it often occurs as the sulphide, so that the presence of copper in steel made from such ores might also, necessarily, mean the presence of sulphur. It is evident that the effect in this case might be quite different than where pure copper was added.

Jan 10, 1913

By Steven D. Knudsen, Dale S. Preece

Computer modeling of the blasting process can aid in gaining an understanding of the physics controlling the process. The sequence of events in a blast occur so rapidly and in such a violent environment that measurements are still difficult to obtain. Computer modeling using a program such as DMC [Taylor and Preece, 1989a, 1989b] can provide insights into the physics of the rapid and violent events associated with a blast. DMC has been used to simulate crater blasting @‘teece, 199Oc] and the blasting of Oil Shale for modified in-situ retorting [Freece, 1990a, 1990b]. This paper will address the influence that damping has on the velocity distribution in the rock mass during the rock motion phase of a blast. Since velocity distribution is a controlling factor of muck pile shape, damping also conbibutes to muck pile shape.

Jan 1, 1992

By A. R. Kiani-Rashid

Controlled graphitization has become known as a practical method for improvement of wear resistance and machining properties in steels. In this paper, the effect of heat treatment on microstructure of CK45 steel has been investigated. Austenitising was carried out at 920°C for 5 hours. Besides, isothermal transformation was conducted at 750°C in the time range of 1-20 hours. The microstructure of the steel considerably changes by this heat treatment process which exhibits the effects of temperature, appropriate austenitising duration and isothermal transformation. Conducted experiments show a suitable distribution of semi-spherical graphite particles especially on the surface of the steel. Also, analyses demonstrate that the amount of formed graphite in the austenitising temperature 920°C is more than graphite in single heat treatment temperature of 750°C.

Jan 1, 2010

By Met M, Orr C. W, Met B. E

As was mentioned in the last paper of this series(l), magnesium was added to lead with the idea that it would act as a de-oxidiser. The magnesium lead alloys give rise to an inter-metallic compound of the composition Mg2Pb(2) and it has some remarkable properties. It is known to disintegrate on standing in the atmosphere and it confers this property also on lead alloys in which it occurs. Magnesium forms a solid'solution with lead, and according to Kurnakow, Pogodin' and Vidusova(S) the limits of solubility are as follow...In conformity with the practice used in preceding series, the limit of concentration used in the present investigation was 0.1 %. Accordingly, it would be expected that all the alloys used would consist of the solid solution and the detrimental Mg2Pb would be absent. Whilst this was the case, it...

Jan 1, 1939

Viscosity measurement was carried out over a narrow range of silica content around the fayalite composition. A wide range of temperature and oxygen potential was covered where the slag was completely liquid. In order to keep the slag composition and the Fe3+/Fe2+ratio constant, theCO2/CO ratio was kept constant as the temperature was varied. Increasing the Fe3+content has little effect on viscosity for slags with a silica mole fraction of 0.31. At higher silica contents, increasing the Fe3+content brings about a small decrease in the viscosity.

Jan 1, 2004

By Nicol S. K, Swanson A. R

The poor flotation response of many coals has in the past been attributed to such factors as differences in rank, differences in degree of oxidation, differences in petrographic composition, or slime coatings. The present work shows that while all these factors undoubtedly influence flotation, the size distribution of the feed may override these. Evidence is presented which shows how this factor can lead to substantial losses of coarse coal (>250 µm)from a coal which would normally be considered amenable to flotation. Reasons for this loss of flotation response are suggested together with means of overcoming the problem.

Jan 1, 1978

The introduction and subsequent ascendancy of autogenous and semi-autogenous milling for comminution circuits has undoubtedly lead to many economic advantages. From a process viewpoint, however, at least one downside has been the sensitivity of these machines to process input variations. Foremost among these is ore competence, though feed size comes a close second. This sensitivity is due to the reliance of ag/sag mills on the feed ore for their grinding media competence and size. Autogenous (ag) mills are the most sensitive in this respect with semi-autogenous (sag) mills being increasingly less so as the ball charge is increased. Increasingly designers and operators are recognising the importance of feed size and the benefits of manipulating it to improve performance. This has been achieved by installing additional crushing/screening capacity ahead of the ag/sag, better operation of the primary crusher, better control of segregation cased by stockpiles and bins and by changing blast design/practices to modify the ROM size distribution. This paper describes the influence of feed size distribution on ag/sag mill performance with reference to a range of plant data. It particularly concentrates on how changing blasting practice to modify ag/sag feed size can have a considerable overall benefit.

Jan 1, 2003

By Davy A. T, Hansen J. O

The causes of ferrosilicon loss from Dense Media Separation (DMS) plants, and the related properties of ferrosilicon, are identified. Two characteristics, corrosion resistance and saturation magnetisation, are examined in detail. The chemistry of the corrosion mechanism is described and its relationship to plant parameters discussed. Methods of reducing corrosion losses are proposed. Lack of particle homogeneity, and its influence on corrosion and abrasion is noted. The relationship between low magnetic susceptibility-and increased magnetic separator losses is demonstrated experimentally.

Jan 1, 1986

By N. Reddy

The influence of local geology and rock mass characteristics on deformations during a rockburst caused by a controlled blast was studied. This was done by means of visual examination, mapping and photography both before and after the blast. We found that the ejected material was bounded mostly by fractures associated with the bow-wave fracturing and bedding surfaces and that existed prior to the blast. Most of the damage was caused by shake-out. This information is important input for the design of rockburst resistant support systems under conditions of moderate stress.

Jan 1, 2001

"Blasthole deviation is a frequent, well documented and undesirable occurrence in mining operations. It is caused by the drill string mechanics, operating variables and the 'interactionbetween the drill bit and the rock mass characteristics. It is composed of three distinct components: collaring or marking error, alignment error and trajectory deviation. This study has focussedon the dependence of trajectory or natural deviation on the geological features of the rock mass being drilled."

Jan 1, 1996

Blasthole deviation is a frequent, well documented and undesirable occurrence in mining operations. It is caused by the drill string mechanics, operating variables and the interaction between the drill bit and the rock mass characteristics. It is composed of three distinct components: collaring or marking error, alignment error and trajectory deviation. This study has focussed on the dependence of trajectory or natural deviation on the geological features of the rock mass being drilled.

Jan 1, 1996

From time to time failures occur in structures made of lead, and the failure may be due to corrosion involving a definite thinning of the lead sheet, or it may be of such a nature that cracks develop and the lead appears to disintegrate. The idea of lead cracking will at once suggest something abnormal, for common experience shows that this metal is very ductile and will withstand considerable bending without showing any sign of fracture. Cracking, on the other hand, is usually associated with brittleness.Fig. 1 is a natural-size photograph of a cracked sheet of lead. Prior to photographing, the sheet was etched byimmersion in a solution of ammonium molybdate. Several characteristics of this crack will be evident. First of all it is distinctly a zigzag crack, and secondly it passes between, rather than through, certain well-defined areas which appear bright in the photograph. This is particularly noticeable at the lower end where the crack appears to terminate.

Jan 1, 1932

This paper forms the second of a series, in which it is proposed to communicate the results of an extensive research into the influence of alloying elements on the physical properties of lead, now being carried out in the Metallurgy School of the University of Melbourne.Some general comments on this research were made by the present writer as an introduction to the first contribution by R. S. Russell*: It was there pointed out that it was the intention to prepare lead as pure as possible, to determine its properties and then to make alloys with the various elements added singly, and in various combinations, in order to determine the effect of each. This line of action is still being pursued.It occurred to the writer, however, that this fundamental attack might, with advantage, be accompanied by a parallel investigation in which lead of commercial purity would form the basis material. In this way, using a standard *Professor of Metallurgy, University of Melbourne.

Jan 1, 1934

The work to be described is part of a comprehensive research on the influence of impurities on the properties of lead. The author had previously compared an electrolytic lead containing less than 0.002% total impurities with a commercial lead containing 0.008% impurities (excluding oxygen) and had shown that the former recrystallised more readily than the latter under the same conditions of cold work and annealing. This difference in properties was attributed to the difference in purity. Electrolytic lead containing only 0.0005% total impurities has been prepared and cast in vacuo. Some interesting effects have been obtained by working and annealing this lead, and by adding silver to it. The preparation of this lead, and the effects obtained thereon, are described in this paper. Thepaper is divided into the following sections:(I) Preparation of electrolytic lead.(II) Vacuum Casting.(III) Effect of Cold, Work and Annealing on two Electrolytic Leads, having 0.002% and 0.0005% Total Impurities respectively.1 Research Fellow, Dept. of Metallurgy, University of Melbourne.2 Proc. Aust. lnst. Min. Met., 1932, 87, 145.

Jan 1, 1934

In a previous paper the author showed that silver considerably delayed the recrystallisation of lead after cold work. The effect of antimony on the rate of recrystallisation of distorted lead was studied next, and the experiments performed, and the results obtained, are described in this paper. Electrolytic lead was used as a standard of comparison.It was also used to make the lead antimony alloys.This electrolytic lead contained 0.0005% total impurities.It was prepared from commercial lead by fire refining, followed by electrolysis and finally by vacuum casting. The process was described in the previous paper and the description need not be repeated here. PREPARATION OF LEAD - ANTIMONY ALLOYS.The steps taken to procure pure antimony are outlined in the appendix. To make the lead antimony alloys a mother alloy was prepared thus:-A quantity of the antimony (it was received in the powdered form) was placed in a pyrex glass tube, which was closed at one end. The antimony was washed with hot hydrochloric acid (1: 1), then with more dilute acid, then with distilled water, and finally with absolute alcohol; it was dried by warming and evacu,ating the tube. This should leave the antimony more nearly free from surface oxides.The amount of antimony was determined by weighing quickly; the appropriate amount of vacuum-cast electrolytic *Research Fellow, Dept. of Metallurgy, University of Melbourne.

Jan 1, 1936

This paper contains an account of some creep tests on electrolytic lead and some of its alloys. The stresses used in determining creep were 500, 350, and 200 lb. per sq.' in. The alloys contained silver, bismuth, tellurium, antimony and zinc respectively. All were castin vacuo, and tested "as rolled." Tests were done also on electrolytic lead which had been cast in air.The electrolytic lead contained 0.0005% total impurities.The preparation and vacuum casting of this lead have been described in a previous paper in this series. The preparation of the alloys, and the air casting of the electrolytic lead, are described in the next section.EXPERIMENTAL PROCEDURE.Every effort was made to keep the vacuum-cast specimens from contact with the atmosphere throughout their history.The ingots were stored eIther in a vacuum desiccator or immersed in heavy oil. The creep specimens were coated with vaseline except during rolling, etching and photography, which involved exposure to the atmosphere for about 45 minutes all told.It is not claimed that vaseline is a perfect shield against the intrusion of atmospheric gases. Possibly during the months that some tests were in progress the gases diffused through the vaseline and gained a limited access to the lead.Nevertheless, the use of vaseline gave protection that brought the tests nearer the ideal at which the author aimed, *Research Fellow, Dept. of Metallurgy, University of Melbourne.

Jan 1, 1936

By Met M, Worner H. K

In pursuance of the investigation into the influence of various elements on the properties of lead during the past year, the effect of several elements on the creep rate of commercially pure lead has been investigated; a standard initial stress of 500 lb. per sq. in. having been adopted for comparison purposes. Other work which has been carried out indicates that the relative results of creep tests may be altered by varying the applied stress, but this aspect of the problem will need to await further investigations for itscomplete elucidation. The results obtained with dilute tellurium alloys are considered sufficiently interesting, and in some respects are so extraordinary, as to warrant publicatiorr at this stage.n must be realised however that, since the results obtained appear to be at variance with those said to have been obtained in practice and those previously published, the present investigation can only be considered as a contribution to our knowledge of the general problem.Consequently it is not considered advisable or necessary to offer detailed explanation of the results given. In fact, some features of the tests about to be described will need further investigation before an adequate explanation is possible.

Jan 1, 1936

The aim of this investigation was to study the influence that varying production rates have on iron sinter quality. This was done by performing sinter pot tests at different pressure drops over the sinter bed, namely 11 kPa and 15 kPa (for 500 mm total bed depths). During each of the sintering processes temperature-time profiles were recorded of the top, middle and bottom layers of the sinter bed. On completion of the sinter process the sinter cakes were divided into top, middle and bottom layers. The physical properties of each layer were subsequently characterized by performing a tumbler test and a sieve analysis. A comprehensive mineralogical study was also conducted on each layer. This study revealed that sinters of similar cold strength could be produced under the examined production rates. However, a higher production rate was accompanied by an increased amount of fines. The cold strengths of both sinters significantly increased from the top layer to the bottom layer of the sinter bed. This strength variation is not related in any simple way to the phase composition. Keywords: Sinter, sinter bed, production rate, phase composition, cold strength, tumbler index, sieve analysis, temperature-time profile

Jan 1, 2003