Search Documents

By W. Kint

More than 10 years ago, one of MECS?s current partners KVT developed the so called SULFOX process for cleaning waste gases containing sulfuric compounds. In this Wet Acid Process (WAP) compounds such as SO2 and H2S, CS2, COS are oxidized over catalyst bed(s) to SO3 and finally sulfuric acid is formed. The individual plants are designed according the feed gas concentrations and customers requirements to keep the investment and operating costs as low as possible. MECS strongly believes the technology we propose will meet all your expectations. Thanks to our vast experience in the construction of sulfuric acid plants (MECS built over 800 sulfuric acid plants worldwide) we were able to design you a very reliable installation. MECS is offering the metallurgical industry, besides our conventional acid plant technology (for strong SO2) and our DynaWave? scrubbing technology (for very low SO2), a SULFOX wet acid plant (for the mid range SO2 concentrations) including an optional upstream DynaWave gas cleaning plant if required. See the figure below. Besides providing advanced technology, MECS is the only company who designs and manufactures its own key critical equipment. We manufacture our own catalyst, mist eliminators, acid distributors and coolers. Because of our in-depth technology knowledge, we understand the critical aspects necessary for making optimum equipment designs. With this combined supply of technology and key critical equipment, we can make a single overall guarantee second to none other in the world.

Jan 1, 2009

By James M. Barker

Sulfur is a nonmetallic element of great physical and economic importance to the world. It is widely but sparingly distributed throughout the hydrosphere, lithosphere, and biosphere. Sulfur is the tenth most abundant element in the universe and eighth most abundant in the sun. In the earth's crust, which is mainly igneous, it ranks 14th, but is eighth or ninth in sediments (Kaplan, 1972; Stanton, 1972). It apparently is very abundant in the core of the earth, because it is a strong chalcophile, and it is fifth in abundance in stony and iron meteorites (Field, 1972) where it occurs as trolite (FeS). In ancient times sulfur was called brimstone, literally "burning stone." Today the term brimstone is used interchangeably with the term elemental sulfur. Shelton (1979) summarized most of the common definitions of terms, grades, and specifications for the sulfur industry as follows (with minor additions): Sources of Sulfur: Combined sulfur-Sulfur that occurs in nature combined with other elements. Cupriferous pyrites-Pyrite containing relatively minor amounts of copper sulfide minerals. Hydrogen sulfide-A toxic gas (H2S) occurring in natural gas and petroleum. Involuntary sulfur-Sulfur produced primarily as a result of legislative or process mandates. Native sulfur-Sulfur that occurs in nature in the elemental (uncombined) form. Nonferrous metal sulfides-Copper, lead, zinc, nickel, and molybdenum sulfides that are processed for their metal content. Organic sulfurs-Complex organic sulfur compounds occurring in petroleum, coal, oil shale, and tar sands. Pyrites-Iron sulfide minerals that include pyrite, marcasite, and pyrrhotite. Sulfate sulfurs-Sulfur in anhydrite and gypsum. Voluntary sulfur-Sulfur produced in response to market forces. Basic Sulfur Products Produced and Marketed: Acid sludge-Contaminated sulfuric acid usually returned to acid plants for reconstitution. Brimstone-Synonymous with crude sulfur. Bright sulfur-Crude sulfur free of discoloring impurities and bright yellow in color. Broken sulfur-Solid crude sulfur crushed to -8 in. Byproduct sulfuric acid--Sulfuric acid produced as a byproduct of a metallurgical or industrial process, generally relating to combined sulfur sources. Crude sulfur-Commercial nomenclature for elemental sulfur. Dark sulfur-Crude sulfur discolored by minor quantities of hydrocarbons ranging up to 0.3 % carbon content. Elemental sulfur-Processed sulfur in the elemental form produced from native sulfur or combined sulfur sources, generally with a minimum sulfur content of 99.5%. Formed sulfur-Elemental sulfur cast or pressed into particular shapes to enhance handling and to suppress dust generation and moisture retention. Frasch sulfur-Elemental sulfur produced from native sulfur sources by the Frasch mining process. Hydrogen sulfide-Associated with natural gas or petroleum and produced at refineries and coke oven plants; used to make sulfuric acid or recovered sulfur. Liquid sulfur-Synonymous with molten sulfur. Liquid sulfur dioxide-Purified sulfur dioxide compressed to the liquid phase. Molten sulfur-Crude sulfur in the molten phase.

Jan 1, 1983

By John M. Dale

Now that the price of sulfur has reached unexpected high levels, it is little wonder that sulfur from surface ores is again receiving attention. In most instances, it is advantageous for an ore to be at or near the surface. However, it is a distinct disadvantage for sulfur ore to be close to the surface because it precludes the use of the Frasch process. The Frasch process depends on the presence of at least 180 m of uniform overburden to allow pressure injection of superheated water into the sulfur-bearing formation to melt the sulfur. In the Frasch process, sulfur separates cleanly from the gangue underground and comes to the surface in a very pure form. Surface sulfur deposits, particularly those in the Western Hemisphere, exist largely due to volcanic activity, and sulfur separation from the gangue is a formidable technical problem. None of the surface deposits are large compared to some of the Frasch deposits, but at the present sulfur price, they are certainly of economic importance. From the turn of the century until 1975, the price of sulfur was for the most part $18-$28/t. However, with the price of sulfur now over $154/t, there are a variety of technical alternatives to consider for sulfur surface ore separation that may not have been economically attractive a few years ago.

Jan 9, 1981

By H. K. Lin

Elemental sulfur is founded to be the predominant sulfur-containing species in a leaching residue resulting from ferric chloride leaching, under given conditions, of a chalcopyrite concentrate. The mineralogical study of the leaching residue which consists of 52% elemental sulfur reveals that the sulfur formed at the end of leaching process is in the form of discrete crystal rather than coating film. Flotation has been applied to recover the sulfur successfully using xanthate as a collector. Dispersants arc needed to prevent the mechanical entrapment of silicate and quartz by sulfur. Very high recovery of sulfur with satisfactory grades can be achieved with a relatively simple notation scheme.

Jan 1, 1991

By Albert W. Deurbrouck

The coal reserves in the United States are estimated to be in excess of 300 billion recoverable tons, and current projections of energy requirements indicate our increased dependence upon these reserves. The Department of Energy's Energy Outlook for 1984 projects that coal consumption in the United States will increase from 737 million tons in 1983 to 958 million tons in 1990, and then to 1,110 million tons in 1995 (Table 1). As shown in this table, the future utilization of coal in the United States is closely tied to the electric utility market, a market that consumes about 85% of the coal produced. Be- cause of this dependence on the utility market, the uncertainties of new environmental regulations, particularly those concerning sulfur emissions, could have a significant adverse impact on future coal demands in the United States. SULFUR IN U.S. COALS Most of the Nation's coal reserves contain too much sulfur to be fired directly and meet existing emission control standards. In Table 2, the sulfur contents of the coals of the eastern United States are summarized by sulfur levels according to regions. While the coals of some of the eastern regions are predominantly high in sulfur content, it is important to recognize that large tonnages of coal with relatively lower sulfur content are available in these regions. Furthermore, an often significant portion of the sulfur occurs in the form of iron sulfide (Fes2 or pyrite). Because pyrite occurs as discrete particles of high specific gravity, it can often be removed by simple, inexpensive physical coal beneficiation techniques after being liberated by stage crushing. The potential for physical removal of pyrite by conventional specific gravity processes combined with stage crushing is summarized in Table 3 on a regional basis.

Jan 1, 1986

By Hengwei Yan, Zhanwei Liu, Wenhui Ma, Ping Xiong

The sulfur in high-sulfur bauxite not only pollutes the environment but also harms alumina production. This study investigated the removal of sulfur from high-sulfur bauxite by adding Zn or ZnO during the Bayer process. The results showed that the different valence sulfur (S2−, S2O3 2−, SO3 2−, and SO4 2−) in sodium aluminate solution can be effectively removed by adding Zn during the digestion process. Adding ZnO removes the S2− in liquor, but the other sulfur compounds (S2O3 2−, SO3 2−, and SO4 2−) are not affected. The mechanism of sulfur removal has been elucidated, where the S2O3 2−, SO3 2−, and SO4 2− are first reduced to S2−, and after adding Zn, the S2− enters into red mud in the form of ZnS. The ZnO then reacts with S2− to generate the ZnS that enters into red mud. Thus, this is a new and effective method of sulfur removal by adding Zn during the digestion process. The results shed light on the removal of sulfur from high-sulfur bauxite during alumina production.

Jun 24, 2020

By A. R. Byers

"This paper describes the distribution, occurrence, and paragenesis of known sulphide deposits within an area bounded by longitudes 102°00' to 106°00' west and latitudes 54 ° 301 to 57 °00 1 north. The Precambrian bed-rock which outcrops over all but the southern fringe of the area con- . sists of regional metamorphic assemblages ranging from low grade or green schist facies to high grade or amphibolite-granulite facies. The areas . of low-grade metamorphism correspond to 'islands' of volcanic rocks which are surrounded by highgrade paragneisses and migmatites. Intrusive rocks range in composition from ultrabasic to granitic and may be divided into syntectonic and posttectonic sequences. The average composition of the former is granodiorite and of the latter quartz diorite.The massive sulphide deposits fall naturally on basis of mineral content into the following divisions: ( 1) pyrrhotite and / or pyrite, (2) sphalerite and/ or chalcopyrite plus iron sulphides, (3) sphalerite and galena, ( 4) sulphide-bearing pegmatite, and (5) nickeliferous pyrrhotite and / or chalcopyrite. The deposits of iron sulphides are ubiquitous. Ratio of pyrrhotite to pyrite is fairly constant for individual deposits, but their areal distribution appears to be independent of the nature of the enclosing rock and grade of regional metamorphism. All deposits containing ore-grade quantities of base metals have been concentrated at favourable structural locations. Copper-zinc and lead-zinc deposits appear to be associated with syntectonic granodiorite with the lead-zinc concentrations confined to calc-silicate gneisses. Copper-nickel deposits show a close relationship to post-tectonic gabbros and pyroxenites. The paragenesis is more or less the same for the majority of deposits, with iron sulphides and sphalerite being introduced early and followed by chalcopyrite and galena. Some vertical and / or horizontal zoning is apparent in a few deposits. Temperatures of formation and origin of the deposits are briefly discussed."

Jan 1, 1960

With the recent increase in the number of underground secondary sulphide dust explosions in Canada, Australia and elsewhere in massive sulphide ore mining industry, establishment of quantitative and realistic methods of analyzing the mine dust is of paramount importance. This paper examines and analyses dust samples from a mine area that has very recently experienced sulphide dust explosions. Also, it attempts to evaluate the physical and chemical characteristics of the dust. Explosibility of the dust samples was determined by quantifying the oxidation reaction of the sulphide dust particles in a 1.2 L, Lindenberg open horizontal tube furnace. Percentage sulphur', % S oxidised during ignition of a dust sample of known assay, % S and dust concentration (g/m3) were determined by the quantitative chemical analysis of SO2 gas produced during the oxidation reaction. A dust sample with high sulphur content, 22.3% S (assayed) and mean particle size 9.82 pm, was found to exhibit a low degree of oxidation compared with a sample of low sulphur content, 15.44% S and mean particle size 21.7 tcm, at the same Temperature.

Jan 1, 1988

By Selby DW, Hamill J, Cauley ID, Thomas I, Thornton AJ

The main objective of sulphide flotation in a cassiterite concentrator is to remove sulphide minerals (pyrite, pyrrhotite and sometimes chalcopyrite) from the ore prior to gravity concentration. Tin losses in the sulphide flotation stage account for a significant proportion of the total tin loss. separate studies of the sulphide flotation circuits of Renison Ltd and Cleveland Tin Ltd were conducted to investigate reasons for the tin losses. Sampling surveys were conducted in the rougher-scavenger and also the regrind-cleaner sections of both plants. In both plants, the rougher circuits recover excessive quantities of liberated cassiterite, while recovery of the desired composite cassiterite-sulphide fraction is low. The regrind mills are successful in liberating the composite cassiterite in the rougher concentrate, but at the expense of increasing the proportion of very fine tin mineral. The cleaner circuits recover between 40 and 60% of the cassiterite received, and this is all lost.

Jan 1, 1978

Traditionally, the Lead Lode at Broken Hill has been represented on presentation plans, cross sections and diagrams in scientific papers as a solid black mass, around which the more 'interesting' and 'structurally useful', wall rocks appear to wrap. Structural analysis of the Broken Hill orebodies has usually turned to these wall rocks to determine the structural history of the mineralisation.This tendency to represent the orebody as a massive single entity is incorrect and the aim of this paper is to illustrate that sulphide orebodies (in this case Lead Lode), are a dynamic part of the mine stratigraphy. They can preserve a great deal of useful structural information that can be recorded with detailed internal mapping.Three main categories of ore type are recognised in Lead Lode; Stratiform ores, Mobilised ores and Metasomatically altered ore. The ore types in these categories occupy or have formed in distinct structural and stratigraphic positions and have clearly recognisable inter-relationships.

Jan 1, 1993

By Ralph B. J, Sadler W. R

Thiobacillus ferrooxidans was shown to catalyse biodegradation of chalcopyrite concentrates. The process was growth associated at normal temperatures (30°C) in dilute acid solution (pH2, H2SO4) in submerged cultures. Approximately 20% of the copper dissolved in 22 days in the presence of T ferrooxidans while less than 0.6% was released when bacteria were absent. In ore column leachates, the iron and sulphur oxidizing species T ferrooxidans, ranged from I04 to I06 cells/ml while exdusively sulphur oxidizing species ranged from I02 to 104 cells/ml. T ferrooxidans predominated below pH 3 while other sulphur oxidizing bacteria favoured higher pH. Organisms were distributed vertically in ore columns according to pH differences, resulting from gradual acid consumption by gangue, during trickle irrigation.There was a sequential development of bacteria in leachates from fresh ore irrigated with water only. High pH sulphur oxidizers were always present, low pH sulphur oxidizers appeared within a week while T ferrooxidans took 50 days to show up. Routine monitoring of bacteria in dump leachates provided a qualitative indication of events in otherwise inaccessible ore bodies.

Jan 1, 1981

Two structurally and mineralogically distinct sulphiderich veins cross-cutting the disseminated sulphides of the Nairne Pyrite Member appear to be products of local remobilization of sulphides under fracture-induced free energy gradients during regional metamorphism and tectonic deformation.The contrasting mineralogy of the two vein types may have arisen as a result of differences in the structural orientation of the veins and!or the relative ages of the veins.

Jan 1, 1969

The mineralogy of the rocks now observed in the Nairne pyrite deposit developed under conditions of internally-controlled sulphur activity during amphibolite facies metamorphism. In the sulphide-deficient metasediments the activity of sulphur was low, and pyrrhotite developed with iron-bearing silicate minerals. At higher sulphur activity, in the sulphide-rich meta-sediments, pyrite formed in addition to pyrrhotite, and the associated silicate minerals are iron-deficient.

Jan 1, 1969

By William E. Ford, Edward Salisbury Dana

This section includes one distinct group, the Stibnite Group, to which orpiment is related; the other species included stand alone. Pyr., etc. - In the closed tube melts and gives a dark red liquid when hot and a red- dish yellow solid when cold; in the open tube (if heated ver slow? ) sulphurous fumes, and a white crystalline sublimate of arsenic trioxide. B.B. on ciarcoaTburm with a blue Hame, emitting arsenical and sulphurous odors. Soluble in caustic alkalies. Artif. - Realgar is frequently noted as a sublimation product from furnaces roasting ores of arsenic. Crystals are produced when arsenic sulphide is heated in a sealed tube with a solution of sodium bicarbonate. Obs. - Realgar occurs usually in veins associated with silver and lead ores. It has been found in volcanic regions as a sublimation~duct. It has also been noted as a deposit from hot spring waters. It is often rtasociate wlth orplment. It occurs at Felsi5bBnya, Kapnik and NagyAg, Hungary; Allchar, Macedonia. Binnental, Switzerland, in dolomite. In the United States, at Mercur, Utah; in the Norris Geyser Basin, Yellowstone Park, as a deposition from the hot waters. Found at the Monte Cristo millin district, Snohomish Co., Washington: the namerealga7 is from the Arabic, Rahj af gh&r,powder of the mine. Use. - Was used in fireworks to give a brilliant white light when mixed with saltpeter and ignited. The artificial material is now used for this purpose.

Jan 1, 1922

By H. Saridikmen, C. S. Kucukkaragoz

In the present study, the measurement of sulphur distribution ratios between the slag and metal phases encountered in the ferromanganese smelting has been carried out at 0.83 atm of partial pressure of CO at 1773 K by using classical gas-slag-metal equilibrium quenching technique as a function of composition. The distribution results were employed in calculating the sulphide capacities of SiO2-Al2O3-CaO-MgO-MnO slags in equilibrium with the Mn-Fe-Si-Csatd.-S metal phase. It is shown that the sulphur transfer from metal to slag phase increases with increasing the basicity of the slag. As expected, the sulphur distribution ratio decreases by increasing the silica content of the slag system. The effect of metal composition on the sulphide capacities of the slag as well as on the sulphur distribution ratios between the slag and metal phases have been discussed. Emprical relationships were developed to express the sulphur distribution ratios and sulphide capacities of the above slag system.

Jan 1, 2007

By H. Preßlinger, H. Hiebler, K. Klepp, W. Posch, M. Mayr

It was investigated in which form sulphur is bonded in ladle slags. For this purpose, the mineralogical phases of the ladle slags were qualitatively and quantitatively evaluated by means of a microprobe. This slag characterization allowed reconstructing the bonding of sulphur into the phases of the ladle slag. Moreover, the reaction process with regard to the ionic theory as well as the structural formula for the mechanism of sulphur bonding were discussed. The bonding of sulphur into calcium aluminate slags is determined by the sulphide ion content in the slag as well as by the ratio of (CaO)/(Al2O3). Calcium sulphide separates only if the slag contains a large number of sulphide ions. When Ca12Al14O33is separated, the sulphide ion is successively integrated into the lattice. The crystal lattice of Ca12Al14O33is characterized by an open, three-dimensional anionic network composed of aluminium-oxygen tetrahedrons linking the edges. In this network, large interstitial spaces are formed, which may be filled with calcium ions on the one hand and statistically with a free oxygen or sulphide ion on the other hand. Key Words: ladle slag, structure, phases, calcium sulphide, calcium aluminate, desulphurization

Jan 1, 2004

By Andre L. De Vegt, Cees J. N. Buisman

"For the past eight years Paques has been engaged in the development and installation of treatment systems based on biotechnological processes to remove sulfur compounds from water, air and gaseous streams. Metal and sulfate can be removed from mine waters using two biological steps:1. Sulfate reducing bacteria convert sulfate to hydrogen sulfide (H2S). The H2S reacts with the dissolved metals to form insoluble metal sulfide precipitates.2. Sulfide oxidizing bacteria convert excess H2S to elemental sulfur.Paques has designed and installed a groundwater treatment system for the Budelco zinc refinery in the Netherlands to remove metals and sulfate as described above. The system has been operating since May 1992 treating a flow of 5000 m3/d. A test program, utilizing a large scale pilot plant, will commence in November 1995 at a copper mine in the U.S.A. to remediate groundwater contaminated with sulfate and heavy metals. Biological reactor performance and selective metal recovery will be studied. Sulfur dioxide (S02) can be removed from fluegas using a combination of scrubber technology and the two biological steps. The end product is elemental sulfur. A commercial size biological desulfurization plant has been in operation since July 1994 treating 50,000 Nm3/h of fluegas. Sulfide can be removed from mining waters or anaerobic wetlands using a THIOPAQ® Sulfide Oxidizing reactor.lntroductionSulfur can be present in various water and gaseous streams in a mining operation. In many cases the sulfur compounds have to be removed because of toxicity, corrosive properties and contribution to acid rain. Mine waters can contain dissolved heavy metals. An efficient way to remove dissolved metals removal is the precipitation as metal sulfides. Paques has developed and installed treatment systems based on biotechnological processes to remove sulfur compounds from water, air and gaseous streams. These treatment systems biologically convert sulfate to hydrogen sulfide (H2S) which can be used in heavy metal precipitation. Excess H2S is biologically converted to elemental sulfur. This paper provides an overview of these newly developed biotechnological treatment systems."

Jan 1, 1997

Owing to the increased consumption of sulphuric acid; Australian manufacturers have, from time to time, been seeking for a satisfactory source of sulphur that would make them independent of foreign supplies.Some years ago a considerable amount of acid was obtained from the roasting of Spanish pyrites. This ore, in 1913 or thereabouts, cost 16s. per ton f.o.b. Huelva, and freight to the eastern seaboard of Australia was about 20s. per ton. As the ore contained 48% to 50% of available sulphur, it was costing roughly 9d. or 10d. per unit, and, in addition, the cinder, after roasting, was a product of considerable value to smelters, containing as it did a high percentage of iron suitable for fluxing, and appreciable values in silver and gold.

Jan 1, 1925

By Nicholas J. Grant, John Chipman

A FULL understanding of the behavior of sulphur in the basic open-hearth process has been delayed by lack of dependable data covering a wide range of slag conditions in the absence of other complicating factors that are likely to be present under operating conditions. It has been generally accepted that strongly basic slags will dissolve more sulphur than will those in which the acidic and basic constituents are more nearly balanced. It has been known that both slag and metal would absorb sulphur from the flame when the sulphur content of the fuel is high. It has been generally believed that manganese assists in the transfer of sulphur from metal to slag. Almost nothing has been known of the effect of temperature upon desulphurization; the data have been conflicting and there has been a tendency to depend rather heavily upon analogy with the better understood desulphurizing reaction of the blast furnace. Many attempts have been made to build up from open-hearth data a satisfactory theory of the chemical reactions involved in the process. That this has been an extremely difficult task is owing to two reasons that have been very generally recognized. The first is the parallel and simultaneous reaction of sulphur transfer between flame and bath. The second is the difficulty of distinguishing between the factors that ultimately limit the transfer from metal to slag-i.e., equilibrium conditions-and those whose influence is only upon the rate of transfer. It has been the object of the work here recounted to study the equilibrium distribution of sulphur between slag and metal in the absence of these complicating factors, with the hope that a better understanding of the equilibria involved would lead to a better control of the over-all process in the open-hearth furnace. A review of the literature on steelmaking reveals almost complete agreement with respect to the paramount importance of lime in promoting desulphurization. In expressing this effect in quantitative terms, however, and in formulating the relationships between the concentrations of other slag components and the desulphurizing power, there is little agreement. For instance, the "basicity" or basic strength of the slag is commonly measured by some kind of ratio of concentration of basic to acidic oxides. Of these, the following have been reviewed by Schenck :20 [ ] Among others there appear the following:

Jan 1, 1946

By Jannie Maree, Dieks Theron, Ryneth Nengovhela, Patrick Hlabela

In extracting base metals from ore bodies, sulphide as well as oxide, the main environmental concern is sulphur, whether in the form of sulphurous gases or sulphate in liquid form. Generally sulphur is in over supply in developed countries mainly because of strict legislation to capture it. In developing countries on the other hand there is usually a shortage of sulphur because of less strict environmental legislation. Africa falls in this second category and the African continent imports substantial amounts of sulphur despite the fact that large quantities of sulphur is emitted by smelters, thermal power stations, coal mines, fertilizer manufacturers and others. Other than making acid from gaseous emissions, existing methods to capture sulphur from gaseous and liquid effluents are uneconomical and it ends up in the environment either as ammonium sulphate (from gaseous effluents) or as gypsum (from liquid effluents). The CSIR?s Environmentek and Pyroserv has developed a process whereby gaseous sulphur emissions and sulphates in liquid effluents can be economically captured and converted into elemental sulphur and metal carbonates. The elemental sulphur is of high purity as it is precipitated from a gas stream and is readily marketable. The metal carbonates (barium or calcium) can be recycled back to the process or marketed. The only harmful byproduct of the process is carbon dioxide. Should natural gas or methane be available the carbon dioxide could be reduced by about one third. Should solar, wind or hydro energy be available to generate hydrogen the carbon dioxide emissions would be zero. Employing this technology could make Africa independent of sulphur imports and furthermore reduce the impact of acid rain and seepage of sulfate from gypsum and other waste dumps into the environment.

Jan 1, 2005