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Stripping of Fe (III) from D2EHPA Using Different Reagents The common way to extract Fe(III) from an organic solvent is by using concentrated acidic solutions. The stripping of Fe(III) from organic solvent Di-2-ethylhexyl phosphoric acid (D2EHPA) by hydrochloric acid (HCl) solutions has been found to increase with increasing the acid concentration. However, the use of a concentrated acidic solution such as 6 M HCl can degrade the organic molecules. In this research, to increase the efficiency of Fe(III) stripping from D2EHPA, effect of some acids, salts and buffer solutions was studied. Influence of Tri-butyl phosphate (TBP) as modifier on the Fe(III) stripping operation was also investigated. According to the results, the best Fe stripping recovery was achieved in the presence of low acid concentration and the salts which was 72.4 per cent oxalic acid, 70 per cent ammonium oxalate and 75 per cent buffer of oxalic acid and ammonium oxalate. The results also showed a better recovery in the presence of the buffer rather than the salt. Finally, increasing the concentration of TBP, HCl and H2SO4 resulted in a higher stripping efficiency of Fe(III). However, in the presence of oxalic acid and its salts increasing the reagent concentration did not increase the stripping efficiency and at this condition, the recovery of iron remained constant.

Sep 13, 2010

In the latter half of 1973 a contract was given to Roberts-Holland Joint Venture for the stripping of the southern exhaust airway.The contract was carried out efficiently and relatively cheaply. It was completed 2 months ahead of schedule.The sinking stage and in particular the drilling jumbo proved to be a success and helped produce an above schedule stripping rate.No major problems were encountered with ground conditions or ventilation. A survey of the shaft showed the diameter to be within the set limits of 5·49 m ± 0·15 m.

Jan 1, 1974

By J. D. Morgan

Demand for nonfuel minerals depends on the overall state of the economy, which steadily improved each quarter in 1984. New housing starts rose to 1.8 million units. Automakers turned out about 15% more cars (7.8 million) and 30% more trucks (3.1 million) than in 1983. Nevertheless, many domestic mineral operations experienced difficulties in 1984. This resulted from import competition greater use of newer engineered materials, emphasis on multi-unit housing and downsizing of motor vehicles. About 15% of our energy was imported. This in cluded $36 billion worth of crude oil and $22 billion in refined products This added significantly to the overall merchandise trade deficit of $12; billion. On the bright side for mining, coal production rose 14% to 810 Mt (890 mil lion st). Three-fourths o: the coal was burned to generate electricity and more than half of our electricity was derived from coal-burning plants. With the exception of a few large-bulk, low-value raw minerals, most minerals move relatively freely in world trade. The strong dollar encouraged imports and made exporting more difficult. Consequently, our nonfuel minerals trade deficit rose 60% to $19 billion, reflecting imports of $39 billion and exports of $20 billion. There were increased pressures from some major segments of the minerals industry for some form of import protection. But President Reagan said, "Our goal is a system of free and fair trade in goods, services, and capital. We will work toward this goal through both bilateral and multilateral trading agreements." The US minerals industry consists of domestic mines, concentrators, smelters, refineries, mineral manufacturing plants, and recyclers. It also includes many wholly- or partially-owned operations in many parts of the world, providing employment and income for US citizens and others as well. Compared with 1983, the value of US raw nonfuel mineral output rose 8%, to $23 billion. The $253 billion worth of goods processed from this crude mineral output was a 14% increase. Major Metals Raw steel production - a major indicator of both material use and mineral production-rose 10%, to 84 Mt (93 million st). This stimulated a 36% rise in domestic iron ore production, to 52 Mt (57 million st), about 98% pelletized. Iron ore imports rose 44%, to 14 Mt (15 million st). Despite the increase of steel production, output remained well below levels of just a few years ago. For example, 1984 production was still 23% less than in 1981. Raw steelmaking capacity remained steady at 122 Mt (135 million st). The industry continued to cite steel imports as a major reason for low domestic capacity. In December, pacts with seven leading steel exporting nations were announced. This is an effort to reduce import penetration to about 18.5% of the domestic market. Domestic producers of bulk ferroalloys of chromium, manganese, and silicon operated at about 50% capacity. The US mined no manganese or chromium. Only a small quantity of ferronickel was produced from domestic laterite mining in Oregon. Molybdenum production, at 45 kt (49,500 st), rose threefold. Mine shipments of tungsten, another mineral tied to steel

Jan 5, 1985

By A. M. Milev

A stand-alone instrument especially designed for recording strong ground motions was used in this study to create a large data base of peak particle velocities measured on stope hangingwalls. A total number of 58 sites located in stopes mining the Carbon Leader Reef, Ventersdorp Contact Reef, Vaal Reef and Basal Reef were monitored. The peak particle velocities were measured at the surface of the excavations to identify the effect of the free surface and the fractures surrounding the underground mining. From the monitoring results obtained, the velocity criterion of 3 m/s will bean adequate value that support systems have to sustain during a rockburst in most cases. However, PPVs in excess of this criterion were recorded, and some PVDs were damaged or irretrieveable, a consequence of which was that possible extreme events were not recorded. The data recorded on the skin of the excavations were compared to the data recorded by the mine seismic networks to determine the site response, defined as the ratio of the measured peak ground velocity to the peak ground velocity inferred from the mine seismic data. The site response measured at all mines studied was found to be 9 ±3 times on average. Values of the site response did not vary significantly with seismological parameters such as peak ground velocity, hypocentral distance and source radius.

Jan 1, 2005

By S. K. Murphy, S. M. Spottiswoode, A. M. Milev, D. Geyser

A portable, stand-alone instrument especially designed for recording strong ground motion was used in this study to create a large database of peak particle velocities measured underground. A total number of 39 sites located in stopes mining Carbon Leader and Ventersdorp Contact Reefs were investigated. Peak particle velocities whith values up to 3 m/s were recorded at some sites. The data recorded on the skin of the excavations were compared to the data recorded by the mine seismic networks to determine the site response. The maximum site response was obtained for source radii of between 5 m and 30 m and events locating within 200 m of the site. The extreme values of peak particle velocities were obtained in cases were the face-area lay within the source radius. Un instrument portable unique spécifiquement conçu pour enregistrer les mouvements dynamiques des terrains, a été utilisé dans cette étude pour créer une base de données importante sur la vélocité maximum des particules, mesurée en souterrain. Un nombre total de 39 sites situés dans les excavations exploitant les récifs appelés ‘Carbon Leader et Ventersdorp Contact Reefs’, a été investigué. Une vélocité maximale avec des valeurs allant jusqu’ à 3 m/s a été enregistrée sur certains sites. Les données enregistrées sur le bord de l’excavation ont été comparées aux données enregistrées par les réseaux séismiques de la mine pour déterminer la réponse du site. La réponse maximum du site a été obtenue pour des sources de rayons entre 5 m et 30 m et des évènements situés dans les 200 m du site. Les valeurs extrêmes de vélocités maximales ont été obtenues pour les cas où la zone de face se trouve à l’intérieur du rayon de la source. Ein mobiles, alleinstehendes Instrument, speziell entworfen um starke Formationsbewegungen aufzuzeichnen, wurde in dieser Studie verwendet um eine große Datenbank von Partikelspitzengeschwindigkeiten, die Untertage gemessen wurden, aufzuzeichnen. Eine Gesamtanzahl von 39 Aufstellungsorten in den Schichtabbauorten vom Carbon Leader und Ventersdorp Contact Reef wurden untersucht. Partikelspitzengeschwindigkeiten mit Werten bis zu 3 m/s wurden an einigen Standorten aufgezeichnet Die an der Oberfläche des Grubenraumes aufgezeichneten Daten wurden mit jenen Daten verglichen, die vom seismischen Netzwerk der Grube notiert wurden, um die örtliche Reaktion des Standortes zu bestimmen. Die maximale Standortreaktion wurde für Ursprungsradien von zwischen 5 m und 30 m erhalten und Ereignissen die sich innerhalb von 200 m vom Standort befanden. Die extremen Werte der Partikelhöchstgeschwindigkeiten wurdenin jenen Fällen erreicht wo sich der Abbaubereich innerhalb des Ursprungsradiuses befand.

Jan 1, 2003

By Z. Sun

Imposing a strong magnetic field is considered to be an attractive method to prepare materials with aligned or textured structures due to its intrinsic properties, e.g. non-contact and easily controllable. However, the nature of the strong magnetic field effect still remains unclear and further research is needed. In the present paper, the effect of a strong magnetic field on the solidification of a hypereutectic Al-Cu alloy was investigated. After magnetic field treatment, the primary phase was aligned parallel to the magnetic field direction. Meanwhile, the eutectic micro-structural constituent became elongated and thinner. A theoretical analysis was conducted to have a better understanding of the phenomena. During solidification, the magnetic Faraday and dipole-dipole interaction forces are considered to decrease the solute pile-up in front of the solid-liquid interface and modify the eutectic cell formation. The alignment of the phase is due to the shape magnetic anisotropy and crystal magnetic anisotropy.

Jan 1, 2010

By Tim O’Neil

Upbeat, surprisingly so, might describe the mood at the2002 SME Annual Meeting and Exhibit in Phoenix, AZ. More than 4,000 mineral professionals gathered for three days of education, networking and product perusal. The Annual Meeting featured the theme, “Minerals for the Future@ SME” at the Feb. 25-27 gathering. Meeting attendance reached 4,039along with 479 exhibit booths show-casing 325 companies. Exhibitors found a good mix of industry types:37% from mining, 19% from processing, 20% from manufacturing and 28% from environment, education and government.

Jan 1, 2002

By Wilfred P. Schmoe

Introduction An integrated oil company has two options in approaching strategic planning. It has to decide whether it is in business for the long-term. I state this in all seriousness. Those who help manage public companies have the responsibility of good stewardship of other people's money. We must decide whether continued investment in our basic business will generate a reasonable rate of return. With a world surplus of petroleum production capacity, and continuing downward pressure on prices, this question should be addressed by all oil companies. And a positive answer is not necessarily a foregone conclusion in all cases. The decision should be made based on proven competence in finding and developing petroleum reserves on a cost-competitive basis with other producers, and on a frank analysis of future prospects. This should include a realistic assessment of the projected rate of return on specific investment projects. If a company did not pass these tests, its strategy could take one of four paths. Diversification First, it could diversify. But recent history suggests that oil companies are not good at managing other businesses. Second, it could seek a buyer for its business at the optimum return for its owners. Third, it could sell its assets on a piecemeal basis. And, fourth, it could adopt a longer-range plan of self-liquidation by living off current recoverable reserves. In other words, by not investing in exploration and development, it could maximize short-term profit and pass the money back to shareholders in the form of dividends. The Conoco component of DuPont has a below-average cost of finding petroleum, a good track record of efficient production, and a full plate of projects that pass the test of return-on-investment. In short, Conoco is in business for the long-term. That fact, in itself, determines at least one key element in strategy. This is to extend the life of the petroleum reserve base while at the same time maintaining maximum efficient rates of production to provide a strong cash flow. A company that is able to maintain a strong reserve base will ultimately see the value of those reserves escalate as world oil supplies tighten. Our planners expect this tightening to occur within the next decade as demand grows and production in non-OPEC areas of the world begins to decline. An exploration program tailored to meet the requirements of reserve replacement and current production should have two basic parts. The first is relatively low-risk exploration in proven oil provinces. This is augmented by

Jan 6, 1985

By M. A. H. Shuva, M. A. Rhamdhani, G. A. Brooks, S. H. Masood, M. A. Reuter

Ferrous-calcium-silicate (FCS) based slag has been used in the copper industry over the last two decades. The FCS slag has also been used in a secondary copper processing such as in black copper smelting which has different operation conditions compared to that of typical primary copper processing. In the process, a variety of copper bearing scraps from sources such as industrial waste, consumer waste and electronic waste (e-waste) are used. The valuable metals in these sec- ondary resources are distributed in different phases during the process. Understanding the behaviour of the valuable elements at the relevant conditions is vital for optimizing the process and to maximize the recovery of the elements. In this study, we investigated the structure of Ge-containing FCS-based slag at different conditions (oxygen partial pressure and temperature) using Fourier-Transform Infrared (FTIR) spectroscopy to explore the effect of the polymerization on the behaviour of the valuable element Ge in the slag. It was found that experimental parameters significantly in fluence the slag structure, and therefore, the partitioning of Ge in the slag. A correlation between the distribution ratio of Ge and the slag structure has developed in the current study.

Mar 1, 2018

By H. Urata, K. Ishii

To determine the effect of F ions in the molten alkali silicate systems on their structures, quenched Na2O-SiO2-NaF systems were investigated by Raman spectroscopy and molecular dynamics simulation. The systematic increase of 1100 cm-1band intensity in the Raman spectra of the silicate melts accompanying the replacement of F for O provides the evidence for concomitant polymerization of melts. From the molecular dynamics simulation, it was confirmed that most of substituted F was mainly coordinated to Na+ ions but not Si4+ions. These results were consistent with the mechanism in which F associated with otherwise network-modifying Na rather than with network-forming Si. Since F was associated to Na+ ions, the replace of O ion by two F ions promote the polymerization of silicate melts. Keywords: fluorine; molten flux; slag structure; molecular dynamics simulation; Raman spectroscopy.

Jan 1, 2004

By Mohammad Eslami

The Tabriz-Urmiyeh Highway shortens the distance of north-western cities of Iran by about 130 km, resulting in improved access and efficient transit between Iran and Europe through Turkey. The highway crosses the Urmiyeh Lake, an inland lake surrounded by mountains. Due to the circulation of salt-water in the lake and the necessity to continue shipping between adjacent ports, a waterway should be kept open. Consequently, a bridge was built to provide access of marine traffic. A causeway bridge had a length of 1,260 m, comprising of 19 spans. In construction of the bridge, more than 400 piles having a total length of 32 km have been driven. For design of piles different methods have been used such as static analysis, dynamic testing, and correlations to in situ tests, such as cone penetration test (CPT). This paper presents construction of bridge substructure, full-scale piling tests, and methods of analysis used in the evaluation of the deep foundation capacity. The presentation includes an assessment of four current direct CPT and one CPTu methods to calculate the bearing capacity of the piles. It was found that the CPTu and dynamic testing are two suitable tools for rapid and optimum pile design and verification.

Jan 1, 2010

By Hellsten KJ, Butt CRM

Major Francis Hamilton Buchanan coined the term `laterite' (Latin; brick-rock) in 1807 for the red earths used for building blocks in southern India. Although these earths were actually weathered basalts, the term is now applied to weathering profiles developed upon a wide range of bedrocks. The Ni-laterites are a special class within the broad laterite family.

Jan 1, 1996

By A. L. D. Skury

In the synthesis of diamond, the precursor graphite must present a degree of crystallinity to assure optimum yield and quality for the transformed crystals. X-ray diffraction, SEM and TEM analyses were carried out to investigate the structural and morphologic transformations produced in natural graphite by high pressure-high temperature treatment. The present study had as its objective to characterize the morphological and structural changes suffered by a natural graphite that was subjected to high pressure and high temperature treatments in the region of diamond thermodynamic stability. The results indicate that the material that constitutes the gasket, for the deformable capsule, could act as catalyst in the graphite recrystallization process.

Jan 1, 2006

By Wieslaw Blaschke

The transformation of Polish economy, has contributed to the significant ownership changes and the way of management. Most of non-ferrous metals producers are now joint stock companies or stock companies, which shares are owned mostly by Polish shareholders, the State Treasury, banks or trading companies. However, as compared to the international tendencies, the cost of production of base metals in Poland are still relatively high, and the utilization of secondary sources is still very low. In this sense, the paper point out that some positive results of the current pro-ecological mineral policy in Poland have been already clearly visible in the case of non-ferrous metals smelters, where the emission of dusts and gases was significantly reduced. Therefore, if the current increasing tendency of world production of non-ferrous metals continues, Poland’s role as their primary producer will be reduced.

Sep 13, 2001

Design of cemented fill in mining is often carried out without any consideration of the structure of the fill. The composition of cemented fills varies in the stopes due to the placement method, and the strength of the fill in the laboratory depends on the density, orient- ation, moisture content and drainage conditions. Within each stope there are definite zones and the structure of both cemented rockfill and cemented hydraulic fill has to be defined for each zone and the field conditions simulated in the laboratory. Structure also affects fill permeability and compressibility. From a study of the cemented fill in place, the effect of changes in the placement methods can be seen and then controlled to improve fill performance and economy. These features of cemented hydraulic fill and cemented rockfill behaviour are discus- sed and illustrated through reference to field and laboratory work undertaken at Mount Isa.

Jan 1, 1973

By Vinícius Resende Domingues, André Pacheco de Assis, Bernardo Cascão Pires e Albuquerque

"The increasing demand for underground works in urban centers, and in particular the need to build undercrossing tunnels, requires constant evolution in building techniques in order to achieve success and safety. In the case of Brasilia, capital of Brazil, in order to preserve an important avenue (Eixo Monumental), where are located many historical monuments, the construction of a tunnel was envisioned as an option to interconnect the National Stadium (on one side of the avenue) to the Convention Center Ulysses Guimarães (on the other side). The excavation design is comprised of a coverage smaller than one diameter, height of 7.5 m, width of 9.0 m and length of 25 m. In order to enable a negligible influence on the avenue’s usage, the structure is designed as a portico system composed of pipe canopy. In this context, this study presents the portico analytical solution computed with the aid of the software Mathematica and a numerical solution using the software ABAQUS. INTRODUCTION Undercrossing tunnels are increasingly common in urban centers as alternative roads or as access to underground works of large dimensions (stations and parking lots). The geomechanical conditions of the soil mass, not always favorable, and the low distance between tunnel’s ceiling and the surface require intense treatment of the soil massif and execution of a rigid support system. The importance of the road just above the undercrossing tunnel emphasizes the need for a highly competent monitoring system because existing structures require minimum allowable displacement and do not allow the interruption of traffic. The soils that are excavated for the construction of undercrossing tunnels are composed, in most cases, of layers of fill and / or soft soil or weak rock, showing stability problems when subjected to tunneling operations. The combination of low coverage and week ground is solved by soil improvement techniques and strengthening of the excavated cross-section with further advance with the so-called New Austrian Tunneling Method (NATM). Another option is to build structural frames that support the surface. In this research, and based on the context of a case study, we propose the study of the construction technique comprising a portico structure composed of pipe canopy. For this paper, the technical standards used are the Brazilian ones as the case study refers to this country."

Jan 1, 2016

By H. E. McKinstry

MOVEMENT on a fracture of irregular shape can cause local widening of the fissure and thereby offer freer channelways for circulation of ore-depositing solutions. This influence, coupled with large areas of wall rock available for reacting with ore solutions in brecciated and shattered ground can account for locally active deposition of metals and the resulting ore shoots. Such irregularities in the fracture system may be caused by local variations in the strength of rocks and by pre-existing lines of weakness, especially if these stand at favorable angles to certain components of the fracturing stress. Therefore correct interpretation of the mechanics of fracturing should permit deductions as to structurally favorable places on unexplored portions of the vein system. INTRODUCTION IT has long been recognized that movement on a curved or irregular fault surface is capable of separating the walls in certain portions of the fault, but until very recent years the importance of this mechanism as a factor in localizing ore shoots has escaped proper recognition. A short time ago W. H. Newhouse' presented a careful analytical study of displacements and their corresponding open spaces. For reasons that will be discussed later, it frequently happens that portions of the vein which are favorably oriented are not merely wider but also richer than the average. In many cases the widening with its accompanying richness coincides with very minor changes in the dip or strike of the vein, irregularities that commonly escape notice unless the vein is mapped in detail and a careful geometrical analysis made. While the relationship between the width of the vein and the changes in dip or strike has been recognized as a matter of observation, the irregularities have been accepted as more or less the result of accident. There has been very little effort except in isolated cases to find out the causes of these changes in dip or strike. Yet it is clear that if the causes can be recognized and expressed in terms of geologic structure the geologist will know where to look for repetitions of these favorable conditions either on extensions of the same vein or on adjoining veins. Any lack of understanding of the causes is due to the limitations of our ability to interpret our observations and not to the sheer capriciousness of

Jan 1, 1941

By V Morand, W R. H Ramsay

Structural, mineralogical, and textural data from the Tarnagulla Goldfield demonstrate that the area has undergone three significant phases of deformation. The first phase of deformation (D1) predates the intrusion of the Tarnagulla pluton, which has been dated using K/Ar as 391 ¦ 5MY. We regard this pre-granite deformational event as the major regional deformation. Gold-bearing quartz veins have been deposited in dilational sites on west-dipping reverse faults. These sites demonstrate a geometry related both to faulting associated with D1 and the plunge of the F1 fold axes. This evidence, together with chronology of unmineralised ? D2 and D3 faults, the absence of quartz veining associated with D3 events, and the deformation of carbonate-quartz-biotite-sulphide aggregates within Sl by later S2, lead us to conclude that the bulk of the mineralisation was essentially syn- or late D1 . d18O values for fluids in equilibrium with vein quartz from Central Victoria have indicated equivocal support for either a magmatic or metamorphic origin. Our evidence supports a pre-magmatic origin for mineralisation at Tarnagulla and hence tends to favour a metamorphic fluid source.

Jan 1, 1995

The Hyde-Macraes Shear Zone (HMSZ) is low angle, duplex thrust system that has developed in a graphitic pelite schist within the Otago schist belt, New Zealand . At Round Hill lateral ramps have developed parallel to the movement direction between+ the footwall and hangingwall shears. These structures exhibit normal oblique-slip displacement which has been an important mechanism for creating space in an otherwise compressional system. Gold-bearing quartz veins were emplaced along the boundary shears and lateral ramps during thrusting. Gold within the lateral ramps is coarse (up to 300 microns) however hanging wall cataclasite development in the boundary shears after the gold was deposited has reduced the grainzise of most of the gold to less than one micron. This bimodal gold distribution has metallurgical implications with respect to the maximisation of gold recovery at Macraes.

Jan 1, 1993

By D Craw, R Norris

The Golden Bar pit is part of the Macraes mine, the largest gold mine in New Zealand. The Macraes mine is mainly developed in the late metamorphic Hyde-Macraes Shear Zone. However, the Golden Bar pit was developed in a mineralised zone about 200 m structurally above the Hyde-Macraes Shear Zone. The host rocks are dominated by massive quartzofeldspathic schist (5 - 10 m layers) with minor intercalations (1 - 5 m scale) of micaceous schist. All the host schist has disseminated pyrite (micron to mm scale) from pervasive late metamorphic hydrothermal alteration.   In addition, there has been more localised (metre scale) relatively intense hydrothermal alteration controlled by shears subparallel to foliation. Gold occurs in three types of mineralised rock: silicified schist, which dominates, fissile black sheared rock, and cross-cutting quartz veins. There are three principal structural zones in the deposit: 1.   a strongly sheared micaceous and graphitic zone at the base of the structural sequence; 2.   a weakly deformed schist zone cut by relatively flat-lying (= 20¦ dipping) quartz veins; and 3.   a stack of imbricated schist pods and deformed silicified schist confined between two sub-parallel low-angle (ca. 30¦) shears.   These structural zones were juxtaposed during thrust deformation. The lower black shear zone has m-scale folding and over-thrusting packages, kink folding and foliation stacking with associated striations that imply west-directed thrusting. Striations and imbrication geometry between the upper two shears imply oblique thrusting that was directed towards the west. Post-mineralisation normal faults locally disrupt the mineralised zone. The Golden Bar pit mineralised zone has some of the structural and mineralogical characteristics of the main Hyde-Macraes Shear Zone, and may be genetically related.

Jan 1, 2006