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Jan 1, 1967

Jan 1, 1969

Jan 1, 1969

By L. E. Mannion

Sodium carbonate (soda ash) is one of two principal commercial alkalis. Its principal competitor is sodium hydroxide. The use of sodium carbonate is recorded in ancient Egypt, where naturally occurring brines and solid salts provided impure soda for early glassmaking. Until the 19th century, soda ash (as well as potash) was recovered mainly by leaching wood or other plant ashes. In 18th-century Europe, for example, leaching seaweed ash with hot water produced a brown laundry lye. One of the better grades of this material was a Spanish product, barilla, which analyzed 24 to 30% Na2CO3 (Hou, 1942). The modern chemical industry was born in 1691 with the LeBlanc process for making sodium carbonate from salt, sulfuric acid, and lime. English industry used this process extensively in the 17th and 18th centuries. The next major advance was in 1863, when Ernst Solvay devised the ammonia-soda, or Solvay process. The first of many Solvay plants was built in 1874. These supplanted the LeBlanc method and dominated worldwide soda ash production until 1974, when mined sodium carbonate became predominant. Although considerably less important until recently, natural sodium carbonate deposits historically have supported small soda ash operations throughout the world. Shortages during World War II stimulated production of "natural" soda ash from such deposits, particularly at Searles Lake, CA and Lake Magadi, Kenya. More spectacularly, increased production from the vast trona deposits in Wyoming has virtually supplanted the Solvay process in the US. Principal producers of natural soda ash as well as the character of the source deposits are listed in Table 1. [ ]

Jan 1, 1983

By Charles W. Tandy, Wm. I. Weisman

Sodium sulfate is an important industrial chemical, being one of perhaps a dozen or so chemical commodities that are produced and consumed in the United States in quantities exceeding one million short tons per year. In recent years over half of the country's production of sodium sulfate has come from natural sources, whereas 20 years ago only 25% was derived from these sources. Production of natural sodium sulfate from various types of deposits is the main source of this chemical in Canada and Mexico, and probably in Argentina, Chile, and the USSR. [Table 1] illustrates the growth in production of natural sodium sulfate in the United States. Mineralogy and Physical Properties Sodium sulfate is widespread in occurrence and is a common constituent of many mineral waters, as well as seawater. Many of the saline or alkali lakes throughout the world contain varying amounts of sodium sulfate. In its natural form it is found as the hydrous salt, mirabilite, commonly called Glauber's salt, and as thenardite, the anhydrous variety. The largest quantities occur in the form of mirabilite. Sodium sulfate is found in varying degrees of purity, from theoretically pure efflorescent crystals of mirabilite to combinations and admixtures of other salts and impurities. It is a common constituent of some brines, and it is from this source that much is extracted commercially. Sodium sulfate is also found combined with other compounds, such as the mineral glauberite, the double salt of anhydrous sodium and calcium sulfate, and blödite, the double salt of sodium sulfate and magnesium sulfate. While these and other minerals containing sodium sulfate are not economically important, they are of interest because of their frequent occurrence. The reader is referred to other publications (Cole, 1926; Dana, 1932; Grabau, 1920) for descriptions of these minerals. Only the two economically important minerals, mirabilite and thenardite, will be described herein. Mirabilite, Na2SO4 • 10H2O, contains 55.9% water of crystallization. It is noted for its efflorescence or spontaneous loss of water. On

Jan 1, 1975

By Donald E. Garrett

Sodium sulfate is one of the larger tonnage industrial minerals. A little more than half of this tonnage — 3 Mt/a (3.3 million stpy) of natural product— is recovered from ore deposits. Most of the rest is produced as a byproduct from other manufacturing operations. Sodium sulfate is mined in a variety of ways. These include conventional room-and-pillar mining, strip mining, in situ leaching of thick ore beds, solar evaporation and cooling-crystallization of lake brine, and the pumping of brine from complex salt deposits. There is also a variety of commercial sodium sulfate ore sources. They include thenardite (the mineral form of sodium sulfate, or Na2SO4), mirabilite (glauber salt,Na2SO4•10H2O), glauberite (Na2SO4•CaSO4), astra-kanite (bloedite; Na2SO4•MgSO4•4H2O), burkeite(2Na2SO4•Na2CO3), sodium sulfate-containing caliche and various brines.

Jan 1, 2002

By Mohammad Irshad, Larry H. Heflin

INTRODUCTION The planned 166 kilometer (103 mile) Metro rapid rail transit system in Washington, D.C. is being designed and constructed by the Washington Metropolitan Area Transit Authority. At the present time, 112.6 kilometers (70 miles) of this system is in operation and contains 21 route-kilometers (13 miles) of rock tunneling, and 14.5 route-kilometers (9 miles) of soft ground tunneling. An additional 2.4 kilometers (1.5 miles) of single track tunnels in rock are planned and 6 additional contracts will consist of some 8 kilometers (5 miles) of twin tunnel, resulting in 16 additional linear kilometers (10 miles) of single track tunnel in soft ground. The Authority plans, upon its evaluation and the recommendation of the General Engineering Consultant, to include an alternative design incorporating the convergence confinement method of construction known as the New Austrian Tunneling Method (NATM), for Sections E-5, E-6e and E-8a of the E-Route. The Metro system is constructed in a variety of geological conditions and crosses the boundary of two major geographic provinces. Rock tunneling is to the west of this "fall-line" boundary, soft ground tunneling to the east. The soft ground tunneling portions of Metro construction lie in the coastal plain which consist of a

Jan 1, 1987

By Jack Magtoto, Lysa Voight, Tom Martin, John Forero

SUMMARY Commitment by all parties to partnering goals established early in the contract aided Affholder, Inc. in constructing 2,360m (7,700') of soft ground tunnel in Rancho Cordova, CA. Despite two zones of known contamination, encountering a zone of loose cobbles and boulders in a matrix of flowing sand, some perched water tables and a flooded tunnel after 2 upstream safety plugs failed, the Contractor finished the work 33 days early and only 1.91% over his original bid.

Jan 1, 2007

By Priscilla P. Nelson

Many concepts concerning equipment selection, performance prediction, and evaluation of support requirements for tunnel construction in soil or hard rock tunnels cannot be extrapolated directly for application in soft rock (compressive strength between 1.0 and 35.0 MPa). Case histories for small diameter (less than 3.5 m) tunnels in Austin, Texas, are analyzed to gain insight into particular problems encountered during tunnel excavation in weak sedimentary rock, and the performance of different excavation systems are compared.

Jan 1, 1987

By Thierry Bernard, Jean Marc Laboz

This paper explains why and how integration of EIS (Electronic Initiation System) with dedicated software tools can increase benefits to blasters and at the same time simplify the design of blast sequence

Jan 1, 2000

By Peter K. Mathison

The U. S. Department of Interior, Bureau of Mines (Bureau) is developing a hydrologic monitoring system for in situ leaching operations. A working prototype of this system was installed and tested at the Cyprus Casa Grande copper mine. Requirements specific to in situ leaching operations were identified by researchers. The system has been a useful tool for researchers and for mine personnel. Observations of the hydrologic monitoring system, including details of the development process, the design of the system, and the software developed at the Bureau have resulted in new ideas for an enhanced design of the system.

Jan 1, 1992

By Kal V. S. Sastry

Comminution is an important unit operation of mineral processing in terms of large tonnage of materials processed, huge energy consumption, and high capital and operating costs. Substantial research efforts have been directed towards the development of process-engineering tools including mathematical models, process scale-up procedures and computer simulation packages (Austin et al., 1984; Rajamani and Herbst, 1990; Kawatra, 1992). The simulation systems are found to provide significant cost savings by enabling efficient circuit design and development of control systems. Most of these simulators are built from scratch, do not make use of software modules from other sources and are designed with minimal usage of formal software methodologies.

Jan 1, 1995

By Lynn B. Hales

The Supervisory Computer System at Cities Service copper mine and concentrator at Miami, Arizona was installed at Pinto Valley in the spring of 1975. Design and specification [l] of the digital system was initiated jointly by key plant personnel at Pinto Valley and staff of Cities Service Research and Development Company. The Pinto Valley digital system [2] may be classified as a supervisory control system of hierarchical design. There are three fully independent satellite computers which retrieve and reduce the raw plant data from each of the three main operating areas - the primary crushing plant, the fine crushing plant, and the grinding and flotation plant. While the three satellite computers are core resident systems, the master computer is a disc-based operating system which also interfaces with a computer controlled on-stream x-ray analyzer system. Figure 1 illustrates the basic system configuration [3]. The software systems required to support a large system are quite diverse and vary greatly in function. The philosophy followed in dividing the software into three categories was designed to: 1) fully utilize existing process knowledge of technical staff; 2) delegate certain software tasks to outside sources already skilled and trained in software development; and 3) maintain final control over the design and operation of each system.

Jan 1, 1976

Ledcap Pty Ltd has developed two software tools for assisting in the determination of life-of-mine (LOM) trucking requirements. The first tool generates haul paths and the second calculates truck travel time over these paths. The two step approach allows the paths to be viewed and if required edited, to better represent the actual site haul routes.The first tool automatically creates haul paths between the mine bench and the dump. To do this the user supplies a master haul route and a scheduled block model. The master haul path and the block model are interacted to create multiple haul routes, one for each pit/dump bench pair in each scheduling period. Each path carries with it a record of the scheduling period it represents and the dry tonnage hauled over the path in that period.The second tool calculates truck travel time over the path. Data from the manufacturer's rimpull and retarder curves are used to calculate accelerations and speed over each segment of the haul path. As the paths are derived from digitised representations of mine haul routes the path f les often have over a hundred segments. This detailed representation of the haul route allows the software to automatically adjust speed for different radius corners and accurately simulates the changing accelerations over the gradient changes that occur in real life mine ramps. Rolling resistance can be specified at a global level, at a segment level and at a period level. This allows rolling resistance to be changed seasonally as well as spatially.Life-of-mine trucking studies attempt to calculate an accurate answer from extremely variable inputs. This paper will detail the features of the two software tools and how the tools provided in the software can assist the mine planner to have greater confidence in their life-of-mine trucking requirements and the subsequent production capacity inputs to their scheduling calculations.

Dec 6, 2010