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By D. A. Stanley

The Bureau of Mines conducted laboratory-scale experiments to determine whether or not surface waters with a high organic content could be purified sufficiently to be used to replace the natural high-quality deep well water currently being used in the silica flotation step of phosphate rock beneficiation. Waters abundant in organic matter were collected from two central Florida streams, flocculated with a cationic polyethylenimine polymer, and processed in a sand filter. This treatment removed most of the organic materials from the water. Untreated surface water, treated surface water, and distilled water were used to compare the flotation response of the acid insolubles in an amine flotation circuit. Surface water treated with PEI-1000 was shown to be as effective as distilled water for the acid-insoluble-flotation step. Flocculation and filtration can therefore produce water suitable for amine flotation of quartz, which would permit substitution of surface water for deep well water.

Jan 1, 1981

By N. I. Jayaraman

High-pressure shrouded sprays were first tested on a bench to determine air-moving capability and dust collection efficiency. The bench-scale tests indicated that at 500 psi and above, the dust collection efficiency, when sampled downstream of a water eliminator, was about 99 pet for two types of nozzles. However, for the same water flow, the induced airflow was about three times greater in one type than in another. Since the only difference in the nozzles was the spray angle, this factor was important in air movement through a shrouded spray. Full-scale model mine tests were then conducted to determine the reduction in dust concentration behind the line curtain and at the operator position produced by high-pressure sprays in a shroud. The shroud was mounted on top of the boom of a model continuous miner, and high-pressure (greater than 500 psi) sprays were installed inside the shroud. The inlet of dusty air to the shroud was open toward the face and the outlet toward the exhaust line curtain. The high-pressure sprays were compared with conventional sprays mounted at the head of the continuous miner and directing water toward the face. The difference at the operator position (opposite side of brattice) was significant in that, under certain conditions, with conventional sprays an increase in respirable dust concentration of 471 pet was noticed compared with dry operation due to rollback from face. High-pressure shrouded sprays, on the other hand, decreased the dust concentrations at the operator position (opposite side of brattice) by 28.2 pct.

Jan 1, 1981

By D. R. Flinn

A newly developed chemical conditioning technique, which greatly simplifies the preparation of plating baths for the electrodeposition of titanium diboride (TiB2) coatings, is described in this report. The new plating technique was used to prepare samples of titanium diboride (TiB2) coatings on three types of substrate materials. These samples were then evaluated in both low- and high-speed wear-test programs to determine the wear resistance, microhardness, and adhesion of the coatings. In general, it was found that the wear resistance of the coatings is independent of substrate. Scanning electron micrographs have shown that the coating wear surfaces are very smooth, suggesting slow and continuous removal of the coating during the wear test (that is, adhesive wear). Adhesion between the coating and all substrates was excellent. Microhardness results show that the TiB2 coating is harder than alumina, with a hardness value exceeding 5,000 kg/mm2 measured in one test. The results of the wear tests show that TiB2 coatings have relatively poor wear resistance compared with alumina in low-speed unlubricated sliding environments, but exhibit wear properties comparable with alumina in high-speed unlubricated sliding environments.

Jan 1, 1981

By I. Liebman

The Bureau of Mines conducted experiments on coal dust explosion suppression. The investigation took place on a beltway in the double-entry of the Bureau's Experimental Mine. Using conditions that simulate those in a working mine, the investigation showed that a coal dust explosion can be readily initiated in a conveyor belt entry. Also, the explosion can spread into adjacent entries through opened crosscuts (stopping destroyed by explosion) to propagate for long distances even though the adjacent entries are rock dusted in compliance with regulations. Passive water barriers (water-filled tubs) were found to be effective in suppressing explosions on a beltway; however, barrier efficiency was reduced by opened crosscuts. The study indicated that the beltway barrier should be the distributed type consisting of continuous rows of water-filled tubs covering long distances along the entry. A plan is outlined for the installation of a water barrier system in a working coal mine for the protection of a beltway.

Jan 1, 1981

By S. R. Crane

One Bureau of Mines goal is to minimize the undesirable environmental impacts associated with industrial plants emitting waste gases containing S02. To help meet this goal, a regenerable flue gas desulfurization process was developed. This process, known as the citrate process, uses a buffered weak acid solution to absorb S02 from the waste gas. The absorbed S02 is reacted with H2S to precipitate elemental sulfur and regenerate the solution for recycle. The H2S feedstock for the process, if not otherwise available, may be produced by reacting two-thirds of the recovered elemental sulfur with natural gas and steam. Laboratory investigations and pilot plant operations were conducted by the Bureau to determine if H2S from the natural gas, sulfur, and steam reaction was suitable for the citrate process. The laboratory investigations, in which an H2S generator was integrated with other citrate process operations, provided a basis for design and operation of the pilot plant. The objective of the pilot plant was primarily to provide H2S for the citrate pro-cess pilot plant at the Bunker Hill Co. lead smelter in Kellogg, Idaho. The design capacity of the pilot plant was 0.4 to 1.25 tons of H2S per day. The operation demonstrated that (1) a 77-to 79-dry-volume-percent H2S product could be produced from pilot-plant product sulfur, natural gas, and steam; (2) the product R2S regenerated the SO2-loaded citrate solution; and (3) under certain conditions over 95 percent of the natural gas could be converted to H2S.

Jan 1, 1981

By E. D. Calvert

The Bureau of Mines, in its effort to promote greater utilization of domestically abundant materials, conducted reasearch on an alternate mold material that has commercial potential for titanium investment casting. Using variations of the conventional lost wax molding process, investment shell molds were formed entirely of fused, calcia-stabilized Zr02 and a Zr02-forming binder. Optimization of binder/slurry properties', stucco grain size and dis¬tribution, and curing practices resulted in a structurally sound investment shell that was distortion free and thermally stable. Small titanium castings, weighing up to 10 pounds, were prepared in unheated molds by both static and centrifugal casting techniques. Microstruc¬tural examination of the castings revealed that mold fill and surface quality were enhanced by centrifugal casting, although good results also were obtained from the statically poured molds. Microstructural and electron microprobe examinations showed that excessive, brittle case formation could be avoided by curing the dried shell molds in air for at least 2 hours at 1,400° C. Increasing curing temperature and time above these levels yielded added bene¬fits. Molds fired in vacuum at 1,500° C for 4 hours yielded castings essen¬tially free of case formation. The tensile properties of as-cast test specimens (no surface conditioning performed) id the chemical composition of representative metal samples showed that castings produced were comparable to Grades C-1 and C-2 unalloyed titanium This indicated that no sifnificant degradation of metal properties resulted from mold/metal interaction.

Jan 1, 1981

By B. W. Madsen

To help maintain an adequate supply of minerals to meet national economic and strategic needs, the Bureau of Mines developed a mathematical model that describes acidic ferric sulfate leaching of copper from sulfide ores. The leaching model can aid in maximizing minerals and metals recovery from primary sources by giving operators and management a better understanding of the copper leaching process. This will aid in improving dump leaching operations. The model is based on a steady-state approximation of the continuity equation for diffusion of ferric ions in the rock pores and the intrinsic leaching kinetics of the various sulfide mineral particles. Ore characteristics included in the model were ore particle-size distribution, particle shape, grade, mineral content, mineral particle size, porosity, and tortuosity. The continuity equation was used with ferric ion concentration gradients and a fixed value for the diffusion coefficient. Except for effective diffusivity, each of these factors was either measured experimentally or estimated from theoretical considerations. The effective diffusivities were determined by fitting calculated leaching curves with experimental leaching data. Vertical variations in leach solution composition and temperature within a dump are not considered in this model. The model accurately predicted copper extractions for several large-scale tests during nearly 500 days of leaching.

Jan 1, 1981

By Noel N. Moebs

The coal wants at the Westland Mine in southwestern Pennsylvania consist chiefly of elongated, sandstone-filled channels with slickensided basal contacts. Tentatively identified as washouts, these channels are about 1,000 feet long and 300 feet wide, are erratic in occurrence and trend, and are difficult to delineate from the customary core drilling pattern. Roof conditions are hazardous adjacent to the washout contact, but roof stability is generally unaffected greater than 30 feet away.

Jan 1, 1981

By Roy T. Sorensen

As part of its mission to maintain an adequate supply of minerals to meet national needs and maximize mineral production from domestic sources, the Bureau of Mines is investigating the recovery of alumina by hydrochloric acid leaching of kaolinitic clay. Most iron impurities are leached from the clay along with the alumina and must be removed before or during crystallization to aluminum chloride hexahydrate. The thermal decomposition step then provides an alumina product of acceptable iron analysis. Miniplant studies of a Bureau-developed solvent extraction technique, using a tertiary amine in kerosene diluent, have demonstrated that the iron content in aluminum chloride leach liquors can be reduced to levels of less than 0.007 wt-pct (7 ppm), expressed as Fe203. Entrained and dissolved organic matter in the purified pregnant leach liquor from the solvent extraction circuit can be reduced to less than 2 ppm by using a fabric-packed coalescer and subsequent activated carbon treatment. Investigators discovered that a steady buildup of zinc accumulated in the solvent phase within the extraction circuit, proportional to the amount of leach liquor treated. The solvent phase zinc analysis increased by 0.01 wt-pct ZnO for each 1,000 gal of pregnant leach liquor purified.

Jan 1, 1981

By G. M. Martinez

The Bureau of Mines has investigated methods for the recovery of byproduct heavy minerals from sand and gravel operations in Oregon and Washington. These heavy minerals are not currently recovered except for gold in a few areas. The recovery of byproduct heavy minerals would provide a domestic source of minerals presently imported, and a more efficient use of domestic resources would be accomplished. Samples from more than 40 locations were treated by gravity separation to yield heavy mineral concentrates (black sands). Magnetite, ilmenite, zircon, rutile, chromite, platinum-group minerals, radioactive minerals and gold were identified in the concentrates. Individual zircon, ilmenite, chromite; magnetite, and gold products were recovered from selected concentrates by low-and high-intensity magnetic, high-tension, and heavy-medium separation techniques. The recovery for the individual mineral products ranged from 67 to 95 pct.

Jan 1, 1981

By John Durkin, Roy J. Greenfield

This report discusses the configuration and system deployment for the postdisaster surface seismic system for detecting and locating trapped miners. It analyzes the results of 15 field tests to define a signal model, background noise levels, and subarray performance. A waveform modeling procedure is described and compared with observed waveforms. The resulting similarity indicates that the major factors affecting the signal amplitude, waveform, and spectral character are understood. A model is presented which gives the signal amplitude as a function of source type, source depth, and horizontal off- set between source and receiver. Using this model a curve is presented which gives the range at which a signal will be detected for different signal and noise levels. Finally, and most important relative to the mission of the sys- tem, the ability of the system to detect signals on one or more subarrays is put into a probabilistic framework. For a strong source it is almost certain that a subarray directly over the source will detect the signal. After signal processing, it is highly likely that signals will he detected on sufficient subarrays to locate the trapped miner. Location errors have been found to be less than 100 ft in the majority of cases. Techniques have been used that can reduce the location errors to this level even when soil layer variation between subarrays is severe.

Jan 1, 1981

By Joseph A. Perry

One goal of the Bureau of Mines is to develop technology tp insure a dependable supply of minerals to the United States. To support this goal, the Bureau's Albany Research Center has modified a commercial atomic absorption spectrophotometer to rapidly determine trace levels of mercury by cold-vapor atomic absorption spectrophotometry. Such diverse materials as ores, mill products, stream water, sediments, and flue dust have been analyzed. A very high dynamic range of 0.2 ng/ml to 1 µg/ml of mercury in solutions is routinely analyzed by this instrument.

Jan 1, 1981

By A. T. Iannacchione

Roof-rock instability in advancing sections of underground coal mines is a major contributing factor to accidents resulting in fatalities and injuries. Such roof-rock conditions can also result in loss of production due to additional cleanup time and increased amounts of reject material. The Bureau of Mines is investigating fundamental geologic factors affecting coal mine roof-rock instability in order to develop techniques to predict zones of potential unstable roof-rock. Two distinct directional trends of unstable shale roof-rock in a mine working the Upper Kittanning Coalbed are delineated: one trend is associated with the sandstone-shale transition zone, the other with a fault system. The unstable shale roof-rock associated with the transition zone, a consequence of differential compaction, is comprised of slickensided roof-rock. Whereas, the unstable shale roof-rock associated with the fault system, a consequence of structural deformation of the strata, is comprised of fault planes. These faults, small in comparison to the sandstone-shale transition zone, are difficult to delineate with a standard drilling program. Trends of the transition zone associated with the sedimentary facies change are projected into unmined portions of the coalbed with the aid of exploration core data.

Jan 1, 1981

By G. L. Finfinger, J. Cervik, L. J. Prosser

The Bureau of Mines has completed an underground degasification project in which an underground piping system was used to transport methane from the coalbed to the surface. In a 10-month period four horizontal holes were drilled to an average depth of 1,450 feet. All four holes were surveyed vertically and azimuthally. In 991 days of degasification, 255 MMcf of gas was drained from the coalbed. The underground piping system proved to be a safe and effective means of transporting methane from the coalbed to the surface.

Jan 1, 1981

By L. J. Prosser

The Bureau of Mines has completed an underground degasification project in which an underground piping system was used to transport methane from the coalbed to the surface. In a la-month period four horizontal holes were drilled to an average depth of 1,450 feet. All four holes were surveyed vertically and azimuthally. In 991 days of degasification, 255 MMcf of gas was drained from the coalbed. The underground piping system proved to be a safe and effective means of transporting methane from the coalbed to the surface.

Jan 1, 1981

By T. L. Hebble

The Bureau of Mines investigated a hydrometallurgical procedure to recover Co, Ni, and Cu from an electrolytic zinc industrial copper filter cake. The copper filter cake is presently unmarketable or of low value because economic and environmentally acceptable processing technology is lacking. Research by the Bureau of Mines has developed a multistage process for recovering or recycling over 93 pct of the Zn, Cd, Cu, Co, and Ni from this material. The stages involved are (1) wet sizing, (2) H2S04 leaching of undersized material, (3) H2S04-Mn02 leaching of H2S04 leach residue, (4) selective precipitation of As, Cu, and Co-Ni products, and (5) precipitation of manganese for recycling to the leach circuit. The final process residue is only 1.6 wt-pct of the initial cake and consists of lead sulfate.

Jan 1, 1981

By J. H. Maysilles

The Bureau of Mines is conducting research on various technologies to recover alumina from domestic resources for feedstock to existing aluminum smelting capacity as a means to reduce dependence on imported bauxite, which represents 93 pct of U.S. aluminum requirements. One of the more promising technologies being investigated is the hydrochloric acid leaching of kaolinitic clay. In the hydrochloric acid leaching technology, alumina is recovered from iron-free aluminum chloride leach liquor and separated from impurity elements by sparging the liquor with HC1 gas to crystallize aluminum chloride hexahydrate (ACH). A large-scale crystallizer with a 336-gallon usable volume was constructed and operated to obtain engineering and design data for potential scale up and to demonstrate the ability of the technology to produce specification grade alumina. Test campaigns involving about 1,400 hours of operation were completed. ACH meeting all chemical purity requirements could not be produced by a single crystallization, but was produced by recrystallizing the product from the calcined kaolin clay leach liquor. Product crystals with a size distribution of more than 80 pct plus 100 mesh and 65 pct plus 65 mesh were made at a rate of 10 pounds of ACH/(hr)(ft3). The zirconium tube heat exchanger used to maintain constant process temperature operated with an over-all heat transfer coefficient of 420 to 500 BTU/(hr)(ft2)(°F).

Jan 1, 1981

By Syd S. Peng

The design of retort interchamber pillars is important in determining surface stability over in situ retort mines and to the health and safety of miners, particularly with respect to possible escape of heat and toxic gases from retort chambers. Stress distribution in retort interchamber pillars, roof, and floor was examined with the aid of linear, finite-element analysis using data from experimentally determined mechanical properties. Properties determined included elastic moduli, strength, and creep constants in laboratory tests on core covering a 100-foot depth interval in the oil shale from the Piceance Basin in Colorado. The most critical stress concentration was found in the rib side of the interchamber pillar at a height above the floor line of 1.25 times the width. Guidelines for pillar design that consider pillar strength, creep, and retorting temperature effects are proposed.

Jan 1, 1981

By Martin Hertzberg

The concept of limit burning velocities is being used to formulate a quantitative theory of flammability limits. Competing and complicating processes dissipate power from a combustion wave and quench propagation at some characteristically low limit velocity. Two earlier reports dealt with process (a), natural convection (RI 8127); and with process (b), conductive-convective wall losses (RI 8469). This report considers process (c), radiative losses, and process (d), selective diffusional demixing. The limit burning velocity for radiative losses is [(SU)c ~ e cp] It is normally not a significant process for premixed gas flames; however, for laminar flame propagation in a gravity-free environment, it is the only loss process present. Accordingly, limit velocities at zero gravity should be much lower than on earth, and premixed gases should be flammable over wider composition ranges. For highly emissive dusts, soot, or ash-forming flames, radiative losses are significant even under normal gravity conditions. Selective diffusional demixing is a complication that manifests itself in the form of cellular flame structures and wide gaps in composition between upward and downward propagation limits. It induces a burning velocity shift (?Su)d, causing the flame to behave as though it were richer or leaner than its initial composition, depending on whether the fuel or the oxidizer mole¬cule has the higher diffusivity. A simple pertubation analysis shows that the process generates stable cellular flames whenever [dsu] > 0, where ci is the concentration of the reactant with the higher diffusivity. The same analysis indicates that at the opposite stoichiometry, where [dcu] < 0, laminar structures are stabilized. A simple formula for the diameter of cellular flames is derived, which predicts that dcell should vary inversely with the product of the diffusivity difference Di -DJ, and the burning velocity slope [dc ]. Those predictions are in good agreement with the available data. Buoyancy forces for upward propagation induce flame front curvature, and hence buoyancy and selective diffusion are mutually supportive in upward propagation. Thus large gaps in composition between upward and downward limits are present in those composition domains where cellular flames are stable.

Jan 1, 1981

By Dennis R. Dolinar

Physical property tests were conducted on drill core from three exploratory holes on the Naval Oil Shale Reserve near Anvil Points, Colo. Data and regression analysis curves are presented. Data obtained above the Mahogany zone were used to estimate the potential zone of surface effects from under-ground mining. Single specimen testing was primarily used to obtain Mohr&apos;s envelope and subsequent rock properties. The technique is shown to provide satisfactory results for this rock type with a significant reduction of core preparation and testing time.

Jan 1, 1981