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By J. H. Jacobs

In late 1946, research was begun at the Bureau of Mines Electrometallurgical Laboratory at Boulder City, Nev., to determine the possibility of electrowinning manganese from chloride electrolytes on a continuous basis. All phases of electrodeposition were investigated on a small scale it the laboratory, and the results were reported by Jacobs and Churchward. These results indicated that a chloride process had certain possible advantages over the sulfate process that made it worthwhile to continue the investigation on a semi-pilot-plant basis, and this paper reports the results of this work. Research and development work on a process for electrowinning manganese from low-grade ores has been carried on intermittently by the Bureau of Mines since 1936. A process was developed, using sulfate electrolyte, that has been extensively described in the literature.

Jan 1, 1951

By William L. Crentz

In the past, Westmoreland County together with Fayette County produced about one-third of the bituminous coal mined in Pennsylvania. The Pittsburgh bed in Westmoreland County has furnished enormous quantities of coal to the by-product and beehive ovens, gas-manufacturing plants, and general industrial manufacturers over a wide area until about 20 years ago. Little attention was paid to the thinner beds because of the superior quality of the Pittsburgh. The approaching exhaustion of Pittsburgh coal will require accelerated-exploitation of these coals if Westmoreland County is to continue as an important source of bituminous coal, Much of the Pittsburgh coal in Westmoreland County is low-sulfur and requires no mechanical cleaning for the preparation of a metallurgical fuel. Even those areas where the sulfur percentage increased to a maximum of about 2 percent, a relatively easy washing operation usually produced a cleaned coal, which found ready acceptance by the coke industry. Davis reported the remaining recoverable reserves of the .Pittsburgh bed in Westmoreland County to be 255,439,000 tons as of January 1, 1937. Since that date, more than 100,000,000 tons of Pittsburgh coal has been extracted so that the time is not too distant when this important coal bed will be depleted. A study of the Pittsburgh bed in Westmoreland -County has not been made a part of this report as the remaining reserves of the coal can be used in coke making with a, minimum of preparation. The production from the Upper 'Freeport bed will increase as the supply of coal from the Pittsburgh bed diminishes, and as of the present time it supplies a substantial proportion of the county's coal output.

Jan 1, 1951

By Earl T. Hayes

For several years the Northwest Electrodevelopment Laboratory of the Bureau of Mines, in cooperation with the Air Materiel Command, U. S. Air Force, has been studying zirconium alloys. A preliminary survey of these alloys has been completed and reported as a Bureau of Mines Report of Investigations. 4/ Originally the purpose was to determine the suitability of zirconium alloys in medium-temperature applications. However, data also were obtained on other properties of these alloys, and later the scope was broadened to include amore detailed investigation of a selected group. The zirconium-titanium system was one of those chosen. The Bureau of Mines has been instrumental in the commercial development of both of these metals and has constructed pilot plants for the production of titanium at Boulder City, Nev., and for zirconium at Albany, Oreg. Both elements are in subgroup A, fourth series of the periodic table, and therefore have many properties in common. Since both have similar atomic structures and lattice dimensions the possibility of extended mutual solubility seemed likely. Inc transition-point diagram of Fast indicated that the two metals are completely miscible in all proportions in both the alpha and beta forms.

Jan 1, 1951

By Donald F. Reed

In the Coastal Plain sedimentaries of northeastern Mississippi, high-alumina clays and kaolins, which are bauxitized locally to varying degrees, are found in many places along the contact between the Midway (Paleocene) and the Wilcox (Eocene) series. The trace of the contact extends from Tippah County, on the Tennessee border, south to Winston County, thence southeast to Lauderdale County, and into Alabama. Its length within Mississippi, disregarding sinuosities, is 185 miles (fig. 1). Commercial production of bauxite from the region has amounted to about 400 tons, shipped from one outcrop in Komper County. In December 1941 and January 1942, the Bureau of Mines and the Federal Geological Survey made a reconnaissance survey of the contact zone and selected the most promising areas for further study. In 1942, four areas in Benton, Union, and Pontotoc Counties were investigated by auger and rotary core drilling, and in 194, core drilling was done on five areas in Kemper, Noxubee, and Winston Counties. The present report records the work done by the. Bureau of Mines and the factual data obtained from the investigations of the nine areas in the two projects.

Jan 1, 1952

By Wiliam L. Crentz

The importance of Somerset County, Pa., as a coal producer is due in large measure to the presence reserves of low-volatile bituminous coals. Although many coal beds of minable thickness are present, the important reserves are to be found in those beds underlying the Pittsburgh bed. The Kittenning beds and Freeport beds, which are responsible for the bulk of the present coal production in Somerset County and contain the largest reserves to meet future coal requirements, are usually thin and entirely free from impurities. The Pittsburgh bed, which has been such an important coal deposit in the coal areas immediately west and south of Somerset County, is of secondary importance in this county. Although generally rather friable, Somerset County coals have enjoyed wide receptability as excellent coals and to some extent have been utilized in the metallurgical market.

Jan 1, 1951

By M. A. Cook

Crude titanium metal, produced by the reduction of titanium tetrachloride with magnesium, is contaminated with some excess magnesium end adhering magnesium chloride when it is removed from the reaction pot. The method of vacuum 'purification is described in which the crude mixture is heated in a vacuum at a temperature of about 1,700° F. and the magnesium metal and chloride are volatilized away from the titanium, leaving it practically magnesium-free in a sponge-metal form. The pilot-plant equipment is described in detail, together with the technique of operation and methods of sponge recovery. Operating data is given, which compares ten 24- to 30-hour heats with ton 48-hour heats, and finally, power and labor requirements are discussed. Vacuum purification of raw titanium produced by the Kroll process has boon employed for treating of several tons of raw titanium with results for superior to those achieved by the method of leaching and grinding. The operations described, while on but little more than pilot-plant scale, indicate commercial feasibility of the process, even though it is a batch-typo operation. All equipment is either of standard manufacture or can be readily fabricated from standard materials, and operation of the units can be satisfactorily maintained by semiskilled labor.

Jan 1, 1952

By Theodore R. Jolley

The estimated recoverable reserves in the area in the vicinity of Eska 2 mine are, 699,300 tons in the Chapin and Emery bas of the Maitland group. Those recoverable reserves are in the area between the Eska fault zone and Jonesville fault and extend down dip from the outcrops. No reserves were developed by the Eska 2 entry or by drill hole 14-16 in the Eska fault zone. The small quantity of reserves in the vicinity of the Eska 2 mine is insufficient to justify development of a now, modern .nine in this area. The estimated recoverable reserves in the area east of aka Creek are 974,500 tons in the Eska, Shaw, and Martin beds of the Eska group. Most of those reserves occur in the south limb of the syncline. It will be necessary to practice subjacent mining methods to recover these reserves in the Eska group. The Eska bed developed by the diamond drilling in this area comprises coal end few thin partings. The Shaw and Martin beds comprise two bunches of coal separated by partings, and the product from full-bed mining will require thorough preparation.

Jan 1, 1952

By G. S. Scott

Safety problems in the mining and allied industries have led the Bureau of Mines to investigate over a period of years; the flammability (explosibility) of many types of combustible atmospheres principally at ordinary pressure; the results of these investigations have been made available as a bulletin. However, more recently, the demand for information on the flammability of gaseous mixtures at high and low pressures has increased greatly. In particular, the rapid development of high-altitude aviation has brought demands for information on the flammable (or explosive) characteristics of certain gases and liquids at low pressures. The present report gives the results of about 900 tests made to determine the flammability of the lighter paraffin hydrocarbons mixed with air and nitrogen at pressures of 400 200, 100 and 70 ram. Hg. The gases tested include natural gas, methane, ethane, propane normal butane and isobutane. The minimum pressures at which these gases are capable of propagating flame whorl individually mixed with air also were investigated.

Jan 1, 1952

By James J. Dowd

The investigation to evaluate the reserves of coking coal in the United States suitable for the manufacture of metallurgical coke is being made by the Bureau of Mines in three parts: (1) To estimate known measured and indicated recoverable reserves of all coking coal; (2) to upgrade marginal coals through effective preparation; and (3) to study the carbonizing properties of coals and coal blends not now widely used for metallurgical coke making. This is the eighth of a series of reports giving the results of studies by counties under part (1) of the investigation. (See appendix.) This report covers Jefferson County, Pa., which comprises parts of Marienville, Hallton, Ridgway, Brookville, DuBois, Penfield, Smicksburg, and Punxsutawney quadrangles. (See fig. 1.) A short resume of the chemical and carbonizing properties of the coals is included. Data on the coal beds in the county were obtained from mining companies, land companies, individual landowners, and other sources of authentic information. A base map for each bed in each quadrangle was made to the scale 1 inch equals 1,200 feet. Maps of mines, locations of drill holes, bed and total coal thicknesses, and the outcrop of the bed were plotted on the maps. With all available data plotted, isopach lines were drawn to limit areas of known unmined reserves in beds 0 to 14 inches thick, 14 to 28 inches thick, 28 to 42 inches thick, and over 42 inches thick, These areas of coal reserves also were divided into "measured" and "indicated" categories. All areas in each thickness range and in each category, mined-out areas, areas excluded from the estimate, and areas outside of the outcrop were measured by planimeter on the base maps. Estimates of total reserves 14 inches and more thick and maps for individual beds were prepared from these data.

Jan 1, 1952

By W. A. Calhoun

A method for treating high-iron Arkansas bauxites for recovering both abrasive and metal-grade bauxite has been developed by the Bureau of Mines. Present practice usually produces a reject containing appreciable quantities of metal-grade bauxite; however, the processing renders the alumina in the reject unsuitable for the Bayer extraction treatment. Thus the Arkansas abrasive bauxite industry has, in the past, produced little or no metal-grade bauxite. The present investigation was made to determine the possibilities of batter utilization of those particular bauxites through recovery of the wasted metal-grade portion. The large expansion of aluminum-production facilities planned for 1951-53 makes recovery of metal-grade bauxite from presently treated abrasive and marginal abrasive ores en especially timely objective and a welcome addition to our aluminum potential. The quality of the Arkansas bauxites and the inherently associated titania content have made this material particularly attractive to the abrasives industry. however, the gradual depletion of natural abrasive-grade bauxite reserves in this area, the comparative scarcity of high-grade ore, and the difficulty of maintaining adequate reserves have necessitated blending different grades of bauxite calculated to meet specifications. Production of abrasive-grade bauxite from tile, high-iron reserves 13 becoming, increasingly necessary. In one commercial operation, producing abrasive-grade from ores averaging slightly less than 10 percent Fe2O3, approximately 2.7 tons of ore are required to produce 1 ton of abrasive-grade bauxite. The reserves of ore of this grade, however, have been considered inadequate for a long-range production, and ultimately ores averaging 12 to 15 percent Fe2O3 will have to be treated to moot the continued demands of the abrasive industry.

Jan 1, 1952

By Jr. Sayre

Results of studies of reservoir and wax-precipitation temperatures relating to wax deposition in the reservoir of the Bradford oil field are presented in this report. During 1949 and 1950 Bureau of Mines engineers made temperature measurements in 42 wells, which indicate that the Bradford Third-sand temperatures range from 59.7° F., at 1,150 feet, to 71.9° F., at 2,040 feet. Reservoir temperatures measured at the same depths in newly drilled wells and oil-producing wells differed as much as 4.5u F. Injection-well temperatures measured during water injection showed that the temperature of the water entering the sand was 11.5° F. lower than reservoir temperatures before injection. The cooling in the formation resulting froth the injection of low-temperature water was 11.5° F. in the vicinity of the injection-well bore, and a maximum of 2.1° F. 200 feet from the injection well. Sand temperature, after 5 months of water injection, was reduced 1.5° F. 90 feet from water-injection wells. The temperature at which wax begins to precipitate from solution in crude oil was determined at atmospheric pressure for 26 samples and ranged from 51° to 67° F. Oil samples from wells producing no water had wax-precipitation temperatures ranging from 51° to 58° F. and wax contents from 2.20 to 2.97 weight percent, whereas the samples from wells producing water and oil had wax precipitation temperatures ranging from 580 to 67° F. and wax contents from 2.57 to 3.42 weight percent .

Jan 1, 1952

By J. B. Zadra

The use of activated carbon for extracting gold and silver from pregnant cyanide solution and pulp has been investigated many times. The primary advantage of this use of activated carbon is that .the dissolved values can be recovered from slimy ore pulps or from slime portions of ore without settling and thickening or filtering. The loaded carbon is removed from the barren pulp, and the pulp can then be discarded. Activated carbon has been used recently in treating gold ores containing very little soluble silver. When the carbon was loaded with a suitable amount of gold, the silver load was negligible. The remaining problems concerned the removal of the gold from the carbon, the recovery of the gold as bullion, and the reuse of the unloaded carbon. As described in a recent report, a method that solved these problems was developed. The gold-laden carbon was leached with caustic sodium sulfide solution and the gold simultaneously recovered by electrolysis. Both the carbon and the spent solution can be reused. That process was applicable to gold-laden carbon only. It was not applicable to carbon carrying silver, because sodium sulfide does not leach silver from carbon but "fixes" it. It has been necessary, therefore, to develop a modified process for the removal or desorption of both gold and silver from loaded carbon. This modi¬fied process permits the use of activated carbon for extracting both gold and silver from gold ores carrying enough silver to have economical interest or in which silver may be the predominating value.

Jan 1, 1952

By F. A. Rutledge

The Batesville district in north central Arkansas is one of the important sources of manganese ore and ferruginous manganese ore in the United States, with a history of production dating back to 1849. From studies by the Federal Geological Survey, it was recognized that the district probably still contains substantial reserves of low-grade ore. It was natural, therefore, that the deposits in this area should be among the first investigated by the Bureau of Mines under the Strategic Materials Act of June 1939, by which the Bureau was authorized to explore domestic deposits of strategic minerals, at that time designated as those of antimony, chromium, manganese, mercury, nickel, tin, and tungsten. The field work of the Bureau of Mines in the Batesville district was done in two distinct phases. Under project 308, active from August 1940 to June 1941, carbonate-oxide ores were investigated at five separate areas in which 100 trenches, test pits, shafts, and edits aggregating 4,364 linear feet were excavated and 839 samples were taken and assayed. Under project 323, in progress from February 1941 to January 1942, wad deposits were explored at 10 separate areas by 408 prospect shafts, churn-drill holes, and bucket-drill holes aggregating 23,680 linear feet from which 285 samples were taken and assayed. Processes for beneficiating the wad ores were investigated at ore-testing laboratories of the Bureau of Mines.

Jan 1, 1952

By John H. Soule

The Torpedo Copper mine in the Organ Mining District, Dona Ana County, N. Mex., was discovered In 1899. Production was begun immediately and continued until 1907. Since 1907 very little ore has been produced, although Many individuals and companies have been interested in the property at one time or another. Approximately 6,621 feet of diamond-core had been completed on the property before 1949. The results from some of this drilling were unsatisfactory because of the poor core recovery. In addition to its investigation of the Torpedo ore deposits, attention was given by the Bureau of Mines to obtaining better core recovery through the use of special equipment and techniques. This project was begun October 3, 1949, and was completed April 30, 1950. Four diamond-drill holes totaling 2,140.5 feet, which includes 18.2 feet of overlap in a deflected hole, were drilled. All drilling was done with a Government-owned hydraulic-feed drill with some special rods and core barrels, in addition to the usual equipment. The over-all core recovery was 89.5 percent. Omitting the drilling in overburden where little or no core was desired, the recovery was 94.6 percent. Core recovery in the ore zones averaged 95.2 percent. This paper describes the location, the general features of the area, the geology, the Bureau of Mines procedures, and the results attained by these procedures.

Jan 1, 1952

By Jr. Sillers

To prove to .the satisfaction of all concerned that electrolytic manganese from our low-grade domestic ores could be substituted satisfactorily for ferro-manganese made from high-grade foreign fires, an extensive series of tests was conducted in cooperation with industry, in which electrolytic manganese pro-duced by, the Bureau of Mines at its Boulder City, Nev., Station was substituted for the ordinary ferro grades in the production of ferrous and nonferrous metals and alloys and welding-rod coatings. Over 1,200,000 pounds of manganese was given out for this purpose. The objectives of the tests were accomplished, and for some purposes electrolytic manganese was shown to be superior to other grades because of its high purity. The only serious objection that can be raised against electrolytic manganese is its price, which puts it out of reach for most purposes. Even if the price were to be lowered to a point where it would be in line with ferro grades, it is questionable whether electrolytic manganese from domestic ores could supply more than a small part of the needs of American industry because of the large volume of domestic ore that would have to be processed to supply a satisfactory feed for the electrolytic process. Thus, although electrolytic manganese is highly desirable from a metallurgical standpoint, it could not be expected to substitute for more than a fraction of our domestic manganese requirements.

Jan 1, 1952

By L. H. Kalenowski

The metal lithium, its alloys, and its salts are becoming Increasingly important as industrial materials. Lithium metal, because of its great affinity for elements, such as nitrogen, hydrogen, oxygen, sulfur, phosphorus, carbon, and silicon, has become important for a wide variety of uses, ranging from purifying helium gas by removing the nitrogen to scavenging molten metals of undesirable impurities. The excellent fluxing properties of lithium salts have found increasing use in such applications as fluxes for welding aluminum and in lower melting ceramic glazes and coatings. Lithium chloride is one of the most hygroscopic salts known and is widely used as a dehumidifying agent. .About 17 lithium minerals are known. Four of these have commercial importance: Amblygonite, lepidolite, zinnwaldite, and spodumene. Spodumene is the most important source of lithium and lithium salts at present, but sizable deposits of amblygonite occur in the pegmatite area of the Black Hills of South Dakota. The size and nature of these deposits preclude the, possibility of, any assurance of an adequate supply of amblygonite for an operation processing only this mineral. Frequently spodumene and amblygonite occur associated in pegmatite minerals. Preliminary investigations indicate that a simultaneous recovery of spodumene and amblygonite can be made by froth flotation. A single process for treating spodumene and amblygonite or mixtures of thorn, would make possible more use of amblygonite as a source of lithium and obviate the separation of spodumene and amblygonite when they occur together.

Jan 1, 1952

By A. L. Engel

This report is a compilation of results of preliminary tests on scheelite (tungsten) ores and tailings. These investigations were made to assist in establishing satisfactory treatment methods for small-scale concentrator operations, or to indicate a. method for conserving previously lost mineral values in old tailings, if possible. A discussion of test procedures is included, as it was felt that this would add to understanding the results reported under the several projects. The treatment of scheelite ores has become more or less standardized. Important differences occur in textures of ores from various mining districts. However, and this must be considered when planning ore-dressing operations. In most of the present investigations, only a limited amount of work was done, usually just enough to answer a specific question in regard to a particular ore or concerning local conditions. Two methods of treatment included gravity concentration, magnetic separation, and flotation.

Jan 1, 1952

By G. W. Jones

From evidence made available during the investigation, it was concluded that the first of a series of explosions occurred at 1:15 to 1:20 p.m. September 21, 1951, in an underground vault that housed pressure regulators on the gas-distribution lines that served Brighten. This explosion damaged the pressure regulators and permitted high-pressure gas to enter the distributing mains and individual-service lines. As a part of the gas-distribution system was not provided with means for protection against such excessive pressures, gas gained access to the interiors of many residences in this area and caused a series of disastrous explosions and fires, which took place during a period of approximately 2 hours after the initial explosion in the pressure-regulator vault. Two persons were killed in the first explosion in a residence, and a third person died of a heart attack attributed to the excitement that prevailed during the explosions and fires, Twenty-three persons were listed as injured. Forty-one residences were either destroyed or damaged - 11 by explosion and the remainder by fires, which developed as a result of gas leakage into residences. Fifteen residences were listed as "completely down" or "gutted." Unofficial estimates of property damage ranged from $1,000,000 to $1,500,000. In view of observations made and information obtained during the investigation, recommendations are presented in this report relative to the natural-gas distribution system in Brighton, which may be helpful in the prevention of similar accidents in this and other communities.

Jan 1, 1952

By H. C. Fuller

This paper discusses 105 production runs at Boulder City, Nev., in which titanium metal was made in 200-pound batches. It describes the equipment and techniques used in preparing raw material, the reduction process, and the removal of the reaction mass from the reaction vessel. Also, some data on man-hour requirements are presented. The main emphasis was on producing ductile-grade titanium and developing a standard procedure for obtaining a consistently pure product. Some departures from techniques used before were found to be desirable. The most important of these was the use of a sealed room with a controlled dry atmosphere in which the reaction vessel was opened and the reaction mass removed. This minimized the moisture taken up by the magnesium chloride in the reaction mass, and it could be purified successfully by vacuum distillation. Using the dry room also made it possible to leave al-inch shell of the reaction material on the walls of the vessel, which lowered the iron contamination and eliminated the labor and time-consuming job of cleaning the vessel after each reduction. Another change was lowering of the temperature during reduction to 750° C. instead of 850° C. This was found to give good results more consistently. The first poke to break the crust during reduction was eliminated, as it was found to be unnecessary and only added more work and was another possible way of introducing air. A rotating feed arm was installed in the reaction vessel to distribute the titanium tetrachloride over a larger area and, thus, prevent local overheating. The process, conducted in a batchwise manner as described and followed by good purification and fusion, produces a metal adequate in quality for nearly all purposes.

Jan 1, 1952

By Claude W. Sill

In the usual volumetric determination of uranium, the solution containing uranium is reduced in a Jones reductor, yielding a mixture of trivalent and tetravalent uranium; the trivalent uranium is oxidized to the tetravalent state by bubbling a stream of air through the solution. The resulting solution of. Tetravalent uranium is titrated with a standard oxidant, generally sulfatoceric acid, dichromate, or permanganate; It seemed likely that the, same general procedure could be used in determining semimicro quantities of uranium if the conditions affecting the variables involved were understood more clearly than at present. In the method described below, the use of ferric sulfate to oxidize tetravalent uranium allows the titration to be made at room temperature in an essentially colorless solution with sulfatoceric acid. The latter oxidant its turn permits the use of the very stable indicator, ferroin, with its sharp color.., change and exactly reproducible blanks. Solutions of uranyl sulfate were prepared by diluting a stock solution that had been standardized gravimetrically according to the method of Lundell and Knowles (8).3/ Solutions of sulfatoceric acid were prepared according to the directions of G. F. Smith (12) and were standardized against arsenic trioxide in the presence of osmic acid according to the directions of Gleu. The cerium solutions were stored in 18-liter carboys fitted with siphon arrangements so that the bottles did not need to be opened and protected from light in a dark cupboard. Under these conditions, even the 0.01 N solution changed by less than 1 part per thousand over a period of about 6 months.

Jan 1, 1952