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By Julie Shang, Tim Evans, Michael McDonald, Yu Guo, Bingfeng Xue

Effective chemical grouting represents a technical and economic solution to many challenges related to soil stabilization and blocking the flow of water. Chemical grouts are facing increasing demands in durability, environmental impact and value. To better meet these challenges, a novel and cost effective process was developed to produce a sodium silicate that increases the ratio (i.e. silica to alkali) beyond what has been used in traditional silicate-based grouts. The move to a lower sodium form of silicate was anticipated to have two desirable performance enhancements; a reduction in leachable sodium and improvement in the durability of the silicate grout. An in-depth study was performed at the University of Western Ontario Geotechnical Research Centre to quantify improvement in durability as well as other performance properties such as compressive strength. The study began by first modelling the gelation time and reaction kinetics of the high ratio sodium silicate over a range of silicate concentrations using two different setting agents as well as with/without a hardener. As expected, reducing the level of sodium produced a much more water resistant grout. These same formulations also showed a four order magnitude reduction in permeability. Somewhat surprising, test results showed the higher ratio silicate having much higher compressive strength. At the time of this abstract, the high ratio silicate was moving to the trial stage for geotechnical applications while the petroleum industry was further along with several successful field trials for water blocking as well as cement remediation. This paper will review the chemistry, testing and features of this next generation form of sodium silicate. Introduction Sodium silicate based grouts have been used for decades for soil stabilization and water control. Over the years, several silicate-based systems have been tailored for specific application conditions to maximize performance and reduce cost. Past research has also focused on the selection of setting agents and hardeners for silicate grouts. A constant in the development effort has been the grade of sodium silicate. The vast majority of chemical grouts have been formulated using a ~3.2 ratio sodium silicate. As a very brief overview on the meaning of “ratio” and why it is so important to performance properties. The ratio describes the proportion of sand to alkali or SiO2:Na2O used to make different grades of sodium silicate. Comparing a 2.2 ratio to a 3.2 ratio, it is easier to polymerize and set the 3.2 ratio. Upon setting and forming a silica gel, the system has higher compressive strength values and improved durability with a reduced level of syneresis (i.e. shrinkage). This leads to the question if 3.2 is better than 2.2 why not go to 4.2 or higher?

Jan 1, 2018

By J. R. Nettle

The purpose of these studies by the Federal Bureau of Mines was to determine the feasibility of refining low-grade hafnium by an inert-gas-shielded molten-salt electrorefining technique to produce a hafnium metal meeting reactor specifications. The techniques were adapted from those used success-fully for titanium electrorefining. Three electrolytes containing hafnium chlorides were developed from which deposits having a Brinell hardness of 170 or below were recovered. A KC1 + NaC1 + HfC14 electrolyte produced deposits in the hardness range of 140 to 165 Brinell. Deposits with a hardness range of from 132 to 152 Brinell were pro-duced from an electrolyte composed of KC1 + LiC1 + HfC14. A third electrolyte composed of NaC1 + K3HfC17 produced deposits with a hardness as low as 139 Brinell. In a fourth electrolyte, composed of NaC1 + K2HfF6, a measure of refining was accomplished, but under the test conditions no metal meeting specifications was recovered; none was softer than 174 Brinell. A number of metallic impurities were reduced in quantity by the electro-refining process, notably iron, which normally was reduced from 250 p.p.m. to less than 50 p.p.m. Magnesium generally was reduced from 680 p.p.m. to less than 80 p.p.m. Manganese content was also reduced by the electrorefining process. Sponge containing 90 p.p.m. Mn yielded deposits containing a maximum of 50 p.p.m.; some deposits contained only 10 p.p.m.

Jan 1, 1961

By Gloyd M. Wiles

The property of the Park City Consolidated Mines Co. is situated in the northeast part of the Park City dining district 1 mile east of the town of Park City. The elevation at the collar of No. 1 shaft is 7,250 feet. Park City is a town of approximately 4,500 population lying about 30 miles east of Salt Lake City. The two are connected by an oiled State Highway, which is cleared of snow in winter and maintained in first-class con¬dition by the State throughout the year. The district is served by branches of the Denver & Rio Grande Western and Union Pacific Railroads, each operating on a daily' schedule, except Sunday. These two railroads have constructed 1 ½ miles of joint track from the town to the Park City Consolidated Mines Co. loading tipple, located 200 feet from the portal of the adit that leads to No. 1 shaft.

Jan 1, 1936

By Robert R. Perron

The U.S. Bureau of Mines is engaged in many diverse programs fur improving mine safety. One area of interest to the Bureau is new and improved means for minimizing the hazards of accidental gas ignition or electrical shock should the frame of an off-track machine assume potential above ground. Various means presently used to prevent such occurences are the use of ground fault detectors for phase to ground faults in ac machines, and grounding conductors and diodes in dc machines. In a three phase ac power center, a phase to ground fault may be detected by monitoring the current in the grounding resistor which is required between the power center neutral on the load side of the power center transformer and ground. Another method for detecting a ground fault is to pass the three load conductors through a toroidal core transformer. The phase currents vectorially add up to zero if none of the phases are faulted, and hence the voltage of the transformer secondary is either zero or not zero if one of the phases is unbalanced or faulted.

Jan 1, 1976

By G. W. Jones

Fires in anthracite refuse banks are troublesome and may become exceedingly costly to combat. Instances are known in which refuse-bank fires have grown to such magnitude that entire mining properties have been endangered. In one instance4/ a refuse-bank fire cost the mine management several hundred thousand dollars to extinguish. The exact number of fires formerly existing or now active in the anthracite region of Pennsylvania is not known, There are hundreds of anthracite refuse banks in this region, some very high and large in area, that have never caught fire, although a few are over 50 years old. This would indicate that spontaneous ignition of the material in these banks is improbable, a conclusion confirmed by recent laboratory research.

Jan 1, 1939

By K. E. Tame

Pollution from radioactive nuclides, principally Ra226, in liquid waste from uranium mills can be minimized by reusing the waste solution within the mill. Such reuse of waste solution in the Vitro Chemical Co.-type process was investigated in the laboratory. Vitro employs an acid leaching process for dissolution of the uranium, countercurrent decantation for liquid-solid separation and washing, and amine solvent extraction for recovery of the uranium from solution. The simulated reuse of barren raffinate in the mill circuit was carried through two separate laboratory campaigns of 29 and 31 cycles. Conventional chloride stripping of the amine was employed in the first campaign, whereas nitrate stripping was used in the second campaign. Dissolution of uranium from the are in the acid leaching circuit averaged 96 percent. Washing efficiencies of 98 to 99 percent were attained by using 4 volume tons of combined raffinate and makeup water per ton of ore. Uranium recovery from the pregnant solution using a 5-percent solution of amine LA-1 in kerosine ranged from 99.3 to 99.9 percent.

Jan 1, 1962

By Ted J. Williams

Underhand cut and fill mining methods are used at the Lucky Friday, Stillwater, and Galena mines in the western US in an effort to safely mine in difficult ground conditions and as a primary mining method where access below the ore is limited. The method has evolved at each mine to meet the unique situations associated with their milling procedure and mine layout. Details of the operational aspects of the backfilling and mining cycles at each mine are presented in this paper, accompanied by a summary of the mechanical properties of the backfill and its in-situ geomechanical behavior.

May 1, 2007

By S. J. Broderick

[Xuge d-mp heap co:lt:.ini9: tilcu?:na3s of tons of cad ~eP~se 2r3 a failiar sight in coal-mininc regior@:. T5ey reprecei~t considergole economic 1083, are very l.u.,si~hC,ly, ?:ld t?ke un m-lch vaL-x3le qace. Cor.sequentl;r thelr remcval i~ geatlyr dezir36, ax2 my ret-sn t?-at c,m be obtained would be er;pecic.llj .a~elconre&apos; t.7 the cod ir.S..r; kry. T?.e vaste rk.t~ri..tl conpl-ises large pieces of slr.t.e, hi~h-2s&apos;. bore c~al., luqs cf cle:., ,ad finer refuse conin,= fro3 the vrtskery, Tilt 1:zshcr:r refilsn contnins sone yood coal. Rig coal and the &apos;better p~lcs of bore ere the zat~rla2.s ~15:;~itiered in this in- vest ig:?.tion. 7% Il~avter frnctions of the w~~sherjr ref;lw aizd tts large 2ieces of slcte ?,".:I rgck contilin 1it:lei ccai-i-bcna.c~o~s caterial ad are vir- tu<dly worthiess nc, rz:. ::atcrin!. for .*=irin,= zct,iv?*teb cCvb~n. 13 the 3irniingh.m district, i13br.12, a-c.ju",P p?rcccn",f the c3sl r?.ir?ed is washed, ,md in tkis c?i.;trict nlz:~c rcfilce ecc;:?:lletcs ~t the r%tg of 1 to 2 million .! tons 2 yew.]

Jan 1, 1941

By Harry Dobroski

Communications with moving tracked vehicles in a rail haulage mine pose a difficult problem. These communications take place from dispatcher to vehicles or from vehicle to vehicle via the trolley line, which is a very poor communications line. As a result, deadspots and high-signal areas can occur anywhere along the line, or signal can decrease simply as a function of distance. An analysis is made of the trolley line as a communications line, and methods of improving its characteristics are discussed. Data from inmine experiments are presented, showing actual improvements in communications. Recent Bureau developments in new hardware are also discussed. These include an adaptive speaker control for existing carrier phones and a new generation of improved carrier phones.

By Steve Kral

A near-record crowd of mining history enthusiasts made the trip to Leadville, CO in September to attend the National Mining Hall of Fame and Museum’s 19th induction banquet. Dressed in Victorian garb, black tie tuxedos and formal gowns, the 268 people honored four distinguished men who made a lasting impact on the U.S. mining industry. They joined 188 other inductees. The first induction banquet took place in 1988, with about 500 people attending.

Jan 1, 2007

By Paul J. Cascone

This paper will discuss the science behind the development of a unique gold alloy for dental prosthetic applications. The alloy (GOLDTECH BIO2000) contains 99.7% gold providing unquestioned biocompatibility and unsurpassed esthetics. The topics discussed are: (1) How the alloy meets the functional requirements of a porcelain-fused-to-metal dental alloy. (2) How the alloy color affects the esthetics of the restoration and why the color of gold is best. (3) Overcoming the intrinsic malleability of gold when grinding the alloy surface. (4) Preventing the oxide color from interfering with the alloy esthetics. (5) Attaining excellent porcelain adhesion. (6) How the design of the restoration allows for the production of single and multiple unit restorations. Gold 2003

Oct 1, 2003

horizontal-type classifier prior to charging into a blastfurnace.

Apr 1, 1995

By D. P. Penswick

The Palabora open pit is scheduled to cease operations in 2002. While the ore body continues below the bottom of the final pit shell, the stripping ratio precludes further economic open pit mining. Palabora Mining Company has investigated various means of continuing copper production, and has determined that an underground mine is the best solution. Board approval to commence construction of the mine has been granted and shaft sinking is underway. First production is planned for the year 2000 and full production of 30 000 t/d will be achieved by the end of the year 2002. [ ] Mechanised block caving will be the mining method employed at Palabora. The cave will be initiated by excavating a thin horizontal slice known as the undercut. Removal of the undercut will induce stresses which cause the rockmass overhead to fracture. Fractured rock will gravitate through drawbells to drawpoints on the production level, and be loaded by LHDs for transport to crushers.

Jan 1, 1997

By Louis Schaffer

The purposes of the research were to assess the applicability of new accident investigation methods to mining accidents, and to adapt those found to be applicable in the development of a new methodology for use in mining. The development included field testing, evaluation and modification of the new methodology. The report is in two volumes. Volume one discusses the background research, the design of a methodology for field evaluation, preliminary field tests in Utah mines, and work done to prepare for a formal, complete evaluation by federal government mine safety officials. This, volume 2, discusses the field evaluation done by the contractor and cooperating mines after the program was re-directed by the Bureau of Mines. It relates to research done during a period of approximately eighteen months, ending in April, 1983.

Jan 1, 1986

By S. J. Broderick

[Huge camp heaps coat. in-.n,- ta._ur nd o tons of coal :&apos;efuse are a familiar sight in coa).--:1&apos;_ni`l ; res io The;;&apos; repre£e: t considerable economic loss, are very ~JZ&apos;:Si~i,tly, and tr:_ e u.: mach v lua-ble :price. Consequentl;;* their remcva7. is ,-,reatl:r de sir^~t~ a_." ar return that c,-u? be obtained would. be especially rel.co c to the coal T,-e "a_ste nat(~ria1 commrioes large pieces of bore cca1., lumps rf c12;&apos;, -)nd finer refuc3 coming from the &apos;acxcor~-, Tnc e&apos;-:s: rr;I refuso contains some Food coal. Th1S coal and the better crams of _,)ore Pre t&apos;--:e na.torials considered. in ohis in¬vestigotion. T&apos;.-.r, heavier fractions of the vas ier,,refuse a rd. the large pieces of slate a n i roc _r contain little carbcnacaous r..aterinl -.nd axe ~vir¬ tually worthless ra&apos;., :,atcria1. for activated carbon. In the E i 1i 11?&apos;ar 1 dictrict~ n1ab a :1 ut irfl percent of the&apos; coal mined is wa^,hed., and in district rc_a e -c-cnuatcs at the r..-ate of I to 2 Million tons a year?]

Jan 1, 1941

By H. Y. Sohn, Hang Goo Kim

Computer simulations were carried out using calcium ferrite slags containing 25 wt% CaO, and the results compared with those obtained using fayalite slags. There was little difference in overall elimination of Pb and Bi, but elimination of Sb and As was much lower with calcium ferrite slag. When calcium ferrite slag is used only in the converting stage and fayalite slag in the smelting stage, as in the Mitsubishi process, the contents of Sb and As in the blister copper can be kept to reasonable levels. This allows advantage to be taken of the considerably higher iron oxide-holding capacity of calcium ferrite slag than of fayalite slag at the high oxygen potential under converting conditions, thus preventing precipitation of magnetite. Satisfactory agreement was obtained between predicted values and observed data from a Mitsubishi converter

Jun 18, 1905

By Alvin Kaufman

To aid industry and Government in planning water developments the Bureau of Mines in 1963 canvassed mineral producers to determine water use in 1962. Water use by the mineral industry comprises only 2 percent of the water withdrawn by industry as a whole. The major water-using mineral industries are natural gas processing, phosphate rock, sand and gravel, and iron ore. Analysis indicated the following conclusions: 1. Total water use and new water intake is dependent on the quantity of material processed and the process water requirements of the particular industry or commodity. 2. Recirculation is dependent on the processing requirements of a particular commodity, the manner in which the water is used, cooling and condensing requirements in certain large industries, the quality of new water intake, and the need to treat new and discharged water. 3. Consumed water is dependent on the quantity of water recirculated, the temperature and humidity in the area, and the proportion of water used for cooling and condensing. 4. A threefold increase in water use by the mineral industry by 1985 is forecast

Jan 1, 1966

By Anil K. Ray

Roof falls are one of the greatest hazards in underground coal mines worldwide. Due to stringent safety measures and extensive support system development, roof falls have been reduced significantly but they still persist in many underground coal mines. Some of the roof falls initiate with cutter roof or guttering. In the past, many factors have been identified as being responsible for the development of cutters and roof fall. These responsible factors can be broadly classified as stress related or non-stress related. In this paper the finer details of mining technique have been taken into consideration for better understanding of cutter roof and roof fall problems. Three dimensional finite difference modeling has been used to explain the mechanism of cutter development. Strain softening material behavior has been used to realistically simulate the cutter formation, and common cutting sequences as implemented in the field have been simulated. This was done with an objective to determine whether the cutting sequence has really any significant control over cutter formation or not. In addition to cutting sequences, the effect of cut length is also studied. The effect of step cutting and turning of crosscut into and away from major and minor horizontal stresses is also examined to see its influence on cutter development.

Jan 1, 2009

By M. Fan, M. Mankosa, G. Luttrell

"Column and other non-conventional flotation approaches continue to provide benefits where conventional flotation processes have exhibited limited success. This is particularly evident with respect to flotation of ultrafine and coarse particles. Advancements in air sparging technology have provided the ability to produce finer bubbles than previously possible. The generation of finer bubbles coupled with the froth washing capabilities of a flotation column has demonstrated improvements in ultrafine particle recovery while simultaneously producing a high-grade float product. On the other side of the spectrum, the use of these sparging technologies while applying flotation fundamentals to a fluidized-bed reactor has increased the maximum floatable particle size up to and in excess of 3 mm. Benefits of higher recoveries and reduced reagent consumption have resulted from the use of these technologies. An additional benefit includes a reduction in plant grinding requirements. As such, this paper describes the application of Cavitation-Tube sparger technology and fluidized-bed flotation (HydroFloat). A review of data from industrial and pilot-scale applications is also provided.INTRODUCTIONConventional (mechanical) froth flotation is considered the workhorse of the minerals processing industry. This low-cost process makes it possible to selectively recover minerals by exploiting the difference in surface characteristics (e.g., wettability) of the valuable component and the waste material. Unfortunately, the upper particle size limit for flotation rarely exceeds 0.600 mm, and is typically maintained at less than 0.300 mm for most industrial applications. For many commercial base metal plants, the particle size range for optimum recovery is typically between 0.01 and 0.1 mm (Lynch et al., 1981). This finding is not novel. In fact, the effect of particle size on flotation recovery was studied as early as 1931 by Gaudin et al. who showed that coarse (+0.250 mm) and extremely fine particles (-0.010 mm) are more difficult to recover than particles of an intermediate size. The loss of recovery is due to inherent limitations associated with the flotation process, including bubble-particle adhesion and collision, detachment, buoyancy, and transport."

Jan 1, 2010

The principle activities of the Explosives Research Laboratory from July 1, 1961 to June 30, 1962, are described briefly in part 1. Part 2 gives short abstracts of publications that appeared during fiscal year 1962; in general, the research reported in these publications antedates the report period. Part 3 gives the results of an investigation which, although too limited to warrant separate publication, merits presentation in some detail because of current interest in ammonium nitrate-fuel oil compositions.

Jan 1, 1964