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By K. J. Gill, P. Chiotti

Thermal, metallographic, and vapor pressure data were obtained to establish the phase diagram for the thorium-zinc system. Four compounds corresponding to the stoichiometric formulas Th2Zn, ThZn2, ThZn4, and Th2Zn17 were observed. The melting points of these compounds under constrained vapor conditions were found to be 1055°, 1105°, 1095°, and 1015°C respectively. Four eutectics exist in this system with the following eutectic temperatures and thorium contents in wt pct: 1040°C, 89 Th; 945°C, 79 Th; 1045°C, 55 Th; and 995°C, 35 Th. The standard free energy, enthalpy, and entropy of formation for the compounds were determined from zinc vapor pressure data. ALTHOUGH the thorium-zinc system has been of technical importance in the commercial production of thorium and more recently of interest to some proposed pyrometallurgical separations processes for reactor fuels or blanket materials no detailed investigation of this system has been made in the past. Some previous work has been reviewed by Hanssen.1 The existence of four compounds, Th2Zn17, ThZn4, ThZn2, and Th2Zn has been established and their crystal structures have been studied by X-ray diffraction techniques.2-4 Smirnov et al.,5 determined the solubility of thorium in zinc and investigated the two-phase region between Th2Zn17 and zinc. They calculated some of the thermodynamic properties for these alloys from emf measurements on the cells Th/ThCl4(fused)/Cl2, C and Th2Zn17(s)+ Zn (l)/ThCl4(fused)/Cl2, C. The possibility of reaction between the anode materials and fused thorium tetrachloride to produce a lower valent thorium salt would have to be resolved in order to evaluate the results obtained. The purpose of the present investigation is to establish the phase diagram for the thorium-zinc system and to determine the standard free energy, enthalpy, and entropy of formation for the compounds formed. MATERIALS AND EXPERIMENTAL PROCEDURES The metals employed in the preparation of alloys were Bunker Hill slab zinc, 99.99 pct pure and Ames Lalboratory thorium. The major impurities in the thorium in parts per million were oxygen—1250, carbon—350, iron—100, nitrogen-75, and silicon—70. The metals in the form of several small massive pieces, total weight about 30 g, were cleaned with acid, washed with water and acetone, and dried just prior to their use for alloy preparation. Tantalum containers were found to be suitable for all the alloys studied and were used throughout this investigation. The metals were sealed inside of small 1-in.-diam tantalum crucibles by welding on preformed tantalum covers. A small thermocouple well made from 1/8-in.-diam tantalum tubing was welded in the bottom of each crucible. These crucibles were enclosed in

Jan 1, 1962

By Rudolph P. Frizzi

Quality control is essential for augered cast-in-place (ACIP) piles (also known as continuous flight auger (CFA) piles outside the United States) and drilled displacement (DD) piles since the pile is constructed below the ground surface out of the direct sight of the personnel constructing and inspecting the pile. ACIP piles are being successfully constructed to support high-rise structures, hospitals, arenas and stadiums, mass transit systems, and power and industrial facilities. The use of DD pile technology is also gaining ground in the United States, typically utilizing proprietary systems such as Omega (currently utilized by Richard Goettle Inc., and LG Barcus and Sons, Inc.), Berkel, and DeWal (currently utilized by Morris-Shea). Different types of ACIP/DD pile installation equipment are shown in Figures 1 and 2. ACIP piles are installed into granular and cohesive soils, and soft rock to lengths currently approaching 130 ft (39.5 m), with diameters up to 24 to 36 inches (610 to 915 mm), and sustaining design loads approaching 900 kips (4000 kN). Current DD pile installation equipment in the United States is capable of installing up to 79-ft-long (24 m) piles with diameters ranging from 12 to 18 inches (305 mm to 460 mm).

Jan 1, 2004

By D Caley

During the response to the Moura No 4 disaster, use was made of the New South Wales Mines Rescue Service’s ‘Mineshield’ inertisation equipment. The equipment had to be transported from Newcastle, approximately 1400 kms, and the liquid nitrogen a similar distance. The time taken, and therefore availability of the liquid nitrogen, became a significant problem. Operational issues were also experienced during use. Typically the liquid nitrogen is converted to a gas (vaporised) before being injected into the mine. However, as the propane gas tanker used for the vapourising unit was delayed, an attempt was made to inject the liquid nitrogen directly down uncased boreholes. This proved unsuccessful.Following the Moura No 4 disaster and the Moura No 2 disaster, recommendations were made relating to having inertisation capacity for the Queensland coal mining industry. Today the Queensland industry has multiple options available for inertisation, including the high-volume GAG and smaller volume units such as boilers and membrane separation units. Although it ultimately aided re-entry into Moura No 4, most likely due to the issues associated with supply to Central Queensland, liquid nitrogen has not found favour within the Queensland industry as an inertisation tool.Coregas has commissioned an air separation plant in Mackay, improving the availability of liquid nitrogen to Central Queensland. Based on the availability of this nitrogen, recent sealing operations at Kestrel have trialled using liquid nitrogen and associated vapourising units. This paper details the practical application and findings of using liquid nitrogen during routine longwall panel sealing.CITATION:Caley, D, 2017. Using liquid nitrogen for the inertisation of goafs, in Proceedings Australian Mine Vent Conference 2017, pp 35–40 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 28, 2017

By J. P. Morris

The Bureau of Mines investigated the mechanics of fuming of iron-carbon melts during top-blowing with oxygen. Melts weighing 45 lb were prepared in an induction furnace and blown with oxygen by means of water-cooled lances. The rate of fuming was measured and correlated with the operating variables. The data showed that the primary cause of fuming was a boil at the bath surface in the impingement zone of the oxygen jet. Nucleation of the carbon monoxide bubbles producing the boil was apparently brought about by the precipitation of an oxide phase. The actual fuming mechanism involved partial oxidation and vaporization of bubble films and fine metal spray generated by the bursting of the bubbles. Bubbles that formed outside the impingement zone produced little fume. The distribution of trace elements between the metal and fume strongly indicated that the fume contained fine spray particles as well as particles that had condensed from vapor. The rate of fuming was found to be proportional to the carbon content of the metal) the concentration of oxygen in the jet) and the bath temperature) provided that a continuous boil occurred. In the absence of a boil) very little fume was produced.

Jan 1, 1967

The need for the hydraulic transportation of coal in the New South Wales coal industry, both from the coal face to the surface and from the coal mine to the consumer or the port for export, is explained. Details of research projects currently in'progress and involving the hydraulic transportation of New South Wales coals are given together with information on the hydraulic transportation of coal in the United States of America.The potential of hydraulic transportation as a viable alternative to the proposed expansion and upgrading of the New South Wales railway system to meet the projected New South Wales coal production to the year 2000 is described.

Jan 1, 1980

By S. J. Page, R. A. Jankowski, J. A. Organiscak

The U.S. Bureau of Mines investigated the relationship of bituminous coal seam parameters and the amount of airborne respirable dust generated at longwalls. Dust and coal samples were obtained from 20 longwalls operating in geographically representative coalfields throughout the United States. Statistical analyses of coal seam parameters and airborne respirable dust measurements indicate a likely causal relationship between seam type and respirable dust. Low-ash, high-volatile coal seams were associated with higher airborne respirable dust levels. A negative linear correlation (significant at the 95-pct confidence level) was observed between the seam's ash content and airborne respirable dust, explaining up to 18 pct (R2 = 0.18) of headgate dust level variation and up to 15 pct of tailgate dust level variation. Volatile matter was found to have a positive linear correlation with tailgate dust level, explaining 16 pct of the variation. Further data examination indicates that these relationships with dust are most likely nonlinear, because of improved R2 values over the linear correlations. However, a notable portion of longwall dust production is influenced by other operational parameters, so additional research under more controlled conditions is needed to determine the seam's causative functions.

Jan 1, 1992

By Panagiota Tsolis-Katagas, Basilios Tsikouras, Tassos A. Grammatikopoulos, C. Katagas

"Mineralogical techniques including microscopic methods, reflected and transmitted light microscopy, Cathodoluminescence (CL) and Scanning Electron Microscopy equipped with an Energy Dispersive Spectrometer (SEM-EDS), are useful in determining the quality of industrial minerals. They are essential for studying ores and metallurgical products including the evaluation of physical characteristics of the mineral, paragenetic relationships, associations with possible deleterious contaminants (e.g., sulphides), spatial distribution within the ore zones and liberation characteristics. The methods are inexpensive, and provide quick identification and distinction among the industrial minerals and the gangue minerals in a section. Additionally, SEM is necessary to reveal complex textural sequences and 3-D measurements of minerals and quick semi-quantitative analysis.Common analytical methods include Electron Microprobe Analyses (EMPA) and Whole Rock Analysis (WRA) (commonly with XRF and ICP) for major and trace elements. The EMPA analyses of industrial minerals provide information on the purity of the analyzed grains as opposed to the bulk chemical analyses that may be misleading due to contamination by other associated common “gangue” minerals. These techniques have been implemented for the case studies of wollastonite, V-magnetite and muscovite. Therefore, these methods can provide extremely useful information and lead to the implementation of a successful pilot-testing programme.MINERALOGICAL EVALUATION OF DEPOSITSDespite their considerable and increasing economic importance, industrial mineral deposits have traditionally been neglected by economic geologists, and are only rarely the subject of the detailed analysis widely lavished on metallic mineralization. Moreover, in that they generally represent concentrations of “normal” rock-forming minerals, albeit commonly with particular textural and/or geochemical features, they have tended to fall between the mainstream of petrogenetic studies and mineral deposit research (Grammatikopoulos 1999). For many industrial minerals, little attention has been paid to the factors responsible for their local concentration as large and high-grade bodies. This comparative neglect has particularly been the case for minerals such as talc and wollastonite, widespread in metamorphic rocks, in which they are reasonably interpreted as components of assemblages derived, respectively, from pelitic sediments, ultramafic igneous rocks and siliceous limestones."

Jan 1, 2003

By Dan A. Brown

Outline ? Basic Concept of ACIP Piles ? Factors Affecting ACIP Pile Performance ? Applications: - Favorable Conditions - Unfavorable Conditions ? Design for Axial Loading ? Lateral Loading Considerations ? Summary & Conclusions

Jan 1, 2004

By Y. G. Qin

In this article an experimental study of axial bearing capacity of half-closed steel pipe pile installed at BKSH dock is presented. In comparison with open and closed end piles, half-closed end pile is considered to have high bearing capacity and good penetration, that is, it not only has a capacity as twice as the same size open end steel pipe pile, but also has blow counts as half as the same size closed end steel pipe pile. It is economic to use half-closed end pile in soft ground without a deep deposit of thick stiff clay. This article also describes a large scale model pile test and preliminarily analyses mechanism of improvement of bearing capacity of half-closed end pile with emphasis on effect of squeezed soil on side friction; an empirical approach is presented in which side friction is related to density of squeezed soil and which is useful for reasonably chosing side friction of different types of piles in design of foundarion.

Jan 1, 2010

The Bureau de Recherches Geologiques et Minieres (BRGM) (a French Government-sponsored geological and mining agency), through international experience gained over many years, has become very skilled in alluvial prospection, particularly for diamonds. The research laboratories within the BRGM have also been active in creating new mineral processing equipment, some of which is directly applicable to such prospection. One such development, the mobile prospection unit, is described and its application in mineral exploration is demonstrated by a consideration of the diamond search in Australia and the general exploration of the Massif Armoricain (France). Because this latter study was fundamental in the development of the concept of 'mineral-geochemistry', and its application in mineral exploration, it is also briefly described.

Jan 1, 1971

By Albert W. Deurbrouck

The percentage of coal cleaned mechanically has increased greatly in the past 30 years. This technological change in preparation methods, accompanied by mechanical innovations in most phases of coal mining, has enabled the industry to supply quality coals at competitive prices. The Bureau of Mines has contributed to this progress by conducting research on coal-preparation problems, by evaluating the performance of domestic-and foreign-made preparation equipment, and by recording advances as they occur in industrial coal-cleaning practices. The Bureau's work in this field is recorded in the more than 150 technical and scientific publications listed in this volume. These reports, published by the Bureau over the past half century, document the Nation's progress in a vitally important phase of fuel technology.

Jan 1, 1961

By D O. Hayba

Metal-rich slurries discharged from excess-enthalpy geothermal wells at Kawerau (NZ) indicate that an efficient ore precipitation mechanism operates in some feedzones. In our conceptual model, which takes into account the relative permeabilities of liquid and gas phases in boiling fluids, a metal-precipitating liquid phase is effectively immobilised along boiling fronts, leading to the formation of highly concentrated ore. Chemical equilibrium and heat/mass transport modelling demonstrate the general applicability of this conceptual model to hydrothermal eruption environments.

Jan 1, 1995

Reliable and discriminating small, laboratory scale methods of study have been developed and used successfully in the critical evaluation and interpretation of the carbonization characteristics of a wide range of raw and prepared materials, the variable factors in the coking process, and' the mechanical properties of the carbonized products. The simple and highly economic technologies have been successfully and effectively integrated with detailed surface and subsurface geological exploration programmes (particularly in the coalfields of the .Central Bowen Basin of Queensland) as well as with quality and utilization studies of a nUII!ber of representative Australian and Japanese coals. Previously, only the results of comparatively large, laboratory scale studies have provided information reasonably indicative of those to be anticipated hi industrial practice, but these suffer serious disadvantages in terms of economy of material, time and resources; they have been difficult or even impossible to use as an essential part of any normal or comprehensive exploration programme. On the other hand, although previously developed smaller scale laboratory methods derive considerable advantage from their flexibility, amenity to critical control and inherent potential for speed and economy, they have hitherto permitted no effective or direct comparison with the results of industrial practice or full scale assessment. Comprehensive study results achieved through technologies developed recently at the University 'of Sydney demonstrate that carefully controlled small laboratory scale methods of evaluation quite suitable for use in exploration and, other programmes may be used to predict with considerable accuracy and reliability (in some cases exceedingthat of pilot scale study) the principal strength index of one of the established and internationally recognized full sc:ale tests-the Japanese Industrial-Standard Drum Test. It is probable that further study may establish satisfactory correlations with the results of other standard industrial procedures.

Jan 1, 1969

By Rodrigo Toro, Mario Delisle, Claudio Zamora

"The mining market is researching innovative methods to train the workforce for mining which is normally extremely difficult to get. Thus, the dynamic simulation-based technologies become an essential pillar to educate and train the inexperienced staff at the pace required by this industry. Even if Operator Training Simulator (OTS) systems are commonly used in most of industries, knowledge transmitted to operators are unfortunately not ""capitalized"" in general. The OTS systems are usually delivered as a single hardware and software platform and very little as a full service long-term.In this article, an integrated solution to increase the efficiency of the operators is proposed. This solution is based on the combination of dynamic simulation, processes knowledge, virtual reality and the knowledge capitalization through the creation of simulation scenarios and e-learning. The Codelco Ministro Hales plant simulation project for a copper concentrator plant is presented as a real life example.IntroductionDynamic and real-time process simulation have proven to be a must in the development of greenfield projects, providing mechanisms to design and test controls design, interlocks, start-up, shut down sequences and operator training, among others (see (McMillan, 2006) for further details). Early adopters of this technology were utility power plants; in the petrochemical industry have become a standard, and in the mining industry the use of dynamic simulations is growing, especially in new projects and training of operations personnel for the adoption of best practices and new technologies, see (Nikkhah & Anderson, 2001) and (Toro, Ortiz, & Yutronic, 2012).This paper outlines a solution that utilizes dynamic simulations as the base of an integrated platform for operational effectiveness, which takes into account the current scenario of new mining projects and operations, where high turn over rates and needs of specialized workforce have given a special value to this kind of technologies."

Jan 1, 2015

By Turner WG, Short RR

Obviously, the paramount advantages of contract mining have been recognised by mine developers throughout Australia, as evidenced by surface gold mining operations of significant output almost exclusively being performed under contract. These paramount advantages of using an experienced professionally managed contractor result from the mine developer being freed from financing the required relatively large capital expenditure at current relatively high interest rates or in a capital scarce stock market, and from the need to recruit and sustain a large operating work force in a competitive labour market.

Jan 1, 1990

By L. Vollert

In-situ recovery of metals is presently experiencing a revival not seen since early applications in amenable copper oxide deposits, uranium and generally applications where neither, porosity and permeability, nor process chemistry have been prohibitively difficult. With ever decreasing grades in current mining operations or Greenfields projects and ever increasing capital and operating costs, in-situ recovery is looked to as the processing option that will both unlock these deposits as well as potentially derive revenue from mineralised waste remaining in the ground once traditional mining and processing methods become uneconomical. In-situ recovery is also being looked to as a mining method that minimises the environmental impact sustained in the application of traditional energy and water intensive mining and processing operations where millions of tonnes of ore are mined from the earth, processed on surface and then disposed of in both waste dumps and tailings facilities. The key challenge facing companies like Newcrest is that these low-grade deposits or remnant mines are generally hard rock applications that require costly methods to liberate the valuable minerals. A further challenge includes identifying suitable chemistries that both facilitate the economic recovery of gold and copper and that may be considered environmentally acceptable. This paper presents a desktop study whereby the issues of access creation and chemical extraction are discussed and evaluated with a view to driving future research in the area and unlocking this application as a real processing option. INTRODUCTION Mining companies are increasingly challenged by low grade, deep and complex ore deposits which are no longer economically exploitable by current methods. The large footprint of current open pit operations can present obstacles for permitting and social acceptance. For these reasons in-situ recovery (ISR) technologies are receiving renewed attention as a technology which could be used to exploit these more complex deposits economically and with less environmental impact. The environmental impact may be further reduced if emphasis is placed on use of renewable energy sources rather than traditional grid power, gas turbine or diesel generators are employed to drive the operation. A potential renewable energy driven ISR mine of the future is shown in Figure 1.

Jan 1, 2019

By C. O. Lee, Z. W. Bartlett, R. H. Feierabend

The Grand Isle sulfur mine is located in the Gulf of Mexico, approximately seven miles off the coast of Grand Isle, Jefferson Parish, La. The deposit is on acreage covered by oil, gas, and mineral leases originally issued in favor of Humble Oil & Refining Co. by the State of Louisiana which were continued, maintained, and redesignated by the U.S. Department of the Interior after passage of the Outer Continental Shelf Lands Act. The sulfur deposit was discovered in 1949 when Humble Oil & Refining Co. penetrated more than 200 ft of sulfur-bearing limestone in a zone between 1813 and 2075 ft below sea level. In 1954, Humble drilled ten more sulfur prospect holes, eight of which encountered sulfur ore. On September 19, 1956, Freeport Sulphur Co. acquired from Humble Oil & Refining Co, the sulfur rights underlying the tracts, and the actual design of the installation began the same month. The first structural contract was awarded in December 1957 and offshore erection began in June 1958. The initial phase of construction has been completed and production by the Frasch process commenced in April 1960. The estimated total cost of the project is $30 million, of which $8 million is the extra cost incurred by the necessity of offshore operations. More than $22 million was expended before production was started. GEOLOGY OF DEPOSIT Grand Isle is the third largest sulfur deposit in the U.S. The orebody embraces several hundred acres, but its outer limits are yet to be defined to the northeast, east, and south. Most Gulf Coast sulfur deposits occur in a caprock mantle of calcite (referred to as limestone), anhydrite, and occasionally gypsum, which covers the apex of an intrusive mass of salt. Commercial quantities of sulfur are usually confined to the calcite or limestone member. Most often such limestone is completely enclosed by dense anhydrite below and impervious sediments above, which effectively form a closed reservoir. The depth of the Grand Isle orebody ranges from 1800 ft to 2500 ft below sea level. Within the present boundary, the sulfur-bearing limestone varies in thickness from 220 ft to 425 ft, while the sulfur content varies an average of about 15 pct in the leanest hole to an average of about 30 pct in the richest. Rock containing less than 5 pct sulfur is not classed as ore, and holes assaying less than 20,-000 long tons per acre of sulfur in place are not considered commercial offshore. The sulfur enrich-

Jan 1, 1961

By Charles L. Guild

I will add a few facts about the use and development of the Osterberg Test Load Cell and my association with Jorj. I first met Jorj in 1965 when the Guild Construction Co. drove 12" diameter cast-in-place shell piles for him at the Marquette Cement Co. in Nashville, Tennessee. When I met Jorj at the DFI Trustee's meeting in 1985 at Longboat Key, Florida, he showed me a sketch of his idea about using a test cell at the bottom of a caisson to test the end bearing and side friction on a caisson. He had made a successful trial test in Case International's equipment yard and wondered whether a similar device could be made for a driven pile. At first I was skeptical that it could be done but after thinking about it overnight I told him I felt it was feasible and we would do some work on it. At that time, there was a large bridge job going out for bid in Rhode Island using 14" square prestressed concrete piles'. Based on a record of the Guild Construction Co. Inc. driving over 3,000,000 feet of piling on work for the State of R.I., we felt we would have an excellent chance to be allowed to use them so we designed, detailed and fabricated three for 14" square prestressed concrete piles. As things worked out, we did not test them on this job and have not to date.

Jan 1, 1989

By T. R. Curr, R. T. Jones

Keywords: Pyrometallurgy, Mintek, DC arc furnace, plasma, smelting, chromite, ilmenite, cobalt, slag, zinc fuming, dust, magnesium, laterite, ferronickel, arc modelling, Pyrosim, thermodynamics The Pyrometallurgy discipline at Mintek was initiated in the early 1970s, to support a growing ferroalloy industry in South Africa. In addition to a range of pyrometallurgical options, Mintek specialises in DC arc furnace technology and has pilot plant facilities up to 5.6 MVA, as well as a strong base in process and arc modelling. Industrial processes have been developed for ferrochromium production, ilmenite smelting, and cobalt recovery from slag. Recent work has been done on such processes as the production of ferronickel from laterite ores, the fuming and condensation of magnesium, and the recovery of platinum group metals from 'difficult' feedstocks.

Jan 1, 2006

By Peter Zhang

Shield recovery in a longwall move is normally conducted from tailgate to headgate. However, if the face is wide and the immediate roof is weak, difficult conditions with considerable roof sag, excessive shield load, and local roof falls could occur as the shield recovery proceeds to the middle of the face, causing delays in shield recovery. The situation could be aggravated when a pre-driven longwall recovery room is employed. Alternatively, a bi-directional approach for shield recovery, i.e. shield recovery starting from the middle of the face towards both tailgate and headgate, can alleviate the roof sag significantly by quickly withdrawing the shields towards the lower abutment pressure zones at the headgate and tailgate sides. In this case, the bi-directional shield recovery approach was used in a longwall move for a 1450 ft wide face under weak roof conditions. Shields were successfully withdrawn within five days without experiencing significant roof sag. The time-dependent roof-to-floor convergence, shield pressure, and roof conditions were monitored during shield recovery. 3-D finite element modeling was conducted prior to longwall move to evaluate the difference between a uni-directional and a bi-directional shield recovery during a longwall face move. Vertical stress, yield zone in and around the recovery room, load on the shields, and convergence at the center of the shield canopy were obtained from computer modeling, and compared with the data from field monitoring. Finally, the advantages of the bi-directional shield recovery are discussed.

Jan 1, 2007