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By T. A. George, David J. Sellmyer

"The concept of achieving a useful high-energy-product magnet through appropriate nanostructuring of known hard and soft phases has been tantalizing researchers since the idea was first proposed. The fabrication of exchange-coupled nanocomposite magnets faces several challenges including aligning the easy anisotropy axes of the hard-phase grains. Here we investigate experimentally two-phase nanostructures of hard Lio-ordered FePt and soft iron-rich/cc Fe(Pt). The Fe-Pt thin films were produced by epitaxial cosputtering onto MgO (001) single-crystal substrates which lead to strong (001) texturing. The measured hysteresis loops indicate nearly ideal exchange coupling. Excellent magnetic properties are obtained, with largest values of coercivity (51 kOe), saturation magnetization (1287 emu/ cm3, J, = 16.2 kG), and nominal maximum energy product (58 MGOe).1. IntroductionA key figure of merit for permanent magnets is the maximum energy product (BH)rrw.x. The achievable maximum energy product is determined by a magnet's saturation magnetization M, and its magnetic anisotropy. For example, it is well known that (BH)rrw.x :S 4n2M,2• In the past, record energy products have been the result of discovering new compounds with high values of magnetization and anisotropy. However, finding new compounds with better magnetic properties than the current record-holding magnet Nd2Fe14B has proven to be difficult. A different approach is to exploit the exchange coupling mechanism between known hard and soft magnetic phases to enhance the maximum energy product [1-5]. In such a composite system, high coercivity is achieved due to the anisotropy of the hard phase as well as a nanostructure which prohibits large-scale domain wall reversal mechanisms. Magnetization is enhanced by the soft phase and loop squareness results from texturing of the hard phase easy-axis as well as complete exchange coupling between the coexisting hard and soft grains."

Jan 1, 2012

By Ben Fahrman

The classical approach to engineering design involves the purely deterministic calculation of the factor of safety, the ratio of strength to stress. The factor of safety is an easy calculation to perform in many circumstances, and it is very easy to interpret the results. The simplicity of the method is both a strength and a weakness. The results of the deterministic factor of safety calculation are simple to determine and interpret, but they have no ability to account for the uncertainty present in the inputs or outputs. Uncertainty is prevalent in geotechnical engineering applications. This uncertainty can stem from spatial variability, poor sampling, a dynamically changing environment, etc. Probability analyses allow input parameters to take the form of a distribution rather than a single value, making them uniquely equipped to handle the uncertainty inherent in geotechnical engineering design considerations. A stochastic approach also has the benefit of providing results as a probability of failure, which is more meaningful than a factor of safety. Though stochastic modeling is becoming more common in many geotechnical applications, it is still not widely used for coal pillar design. The objectives of this study are to justify the concept of using a stochastic approach to coal pillar design and to compare the results of a simple stochastic analysis to those of standard industry practice. A simple synthetic study was performed to compare the results of a probabilistic analysis of coal pillar design to the results obtained from running ARMPS, which is published by NIOSH. Normal distributions were assigned to each input parameter that is required to determine the factor of safety of a single coal pillar. The probability of failure resulting from the synthetic study was found to be more conservative than the ARMPS stability factor. A probabilistic approach to coal pillar design is discussed in comparison to the traditional deterministic approach. The greatest strengths of the probabilistic approach were determined to be the effective handling of uncertainty and the increased meaning of the inputs and outputs inherent to a probabilistic approach.

Jan 1, 2013

By Josée Dartois

En 1988, à l?instar de plusieurs états du monde industrialisé, le Québec décidait d?accélérer la cadence de l?assainissement des rejets industriels et lançait un programme intégré de réduction de la pollution industrielle visant, à la fois, les rejets dans le milieu aquatique, les émissions atmosphériques et les matières résiduelles. Ce programme fut intitulé le Programme de réduction des rejets industriels.

Nov 1, 2002

By Monserrat Rebolledo, John L. Uhrie, Candice Simms

Jetti Resources has developed a catalyst which overcomes the passivation of primary sulfides, enhancing the heap leach recovery of copper from chalcopyrite. It is important to emphasize that heap leaching of copper sulfides, whether with or without the Jetti catalyst, is a biooxidative process. We have demonstrated the efficacy of Jetti’s technology in bioreactors, with a chalcopyrite-dominant porphyry ore. In the presence of Jetti’s technology, optimal bioleaching conditions significantly increase copper extraction by 2.6 times that of the baseline.

Feb 1, 2025

Discussion of the paper of L. O. HOWARD, presented at the Salt Lake meeting, August, 1914, and printed in Bulletin No. 91, July, 1914, pp. 1785 to 1790. E. P. MATHEWSON, Anaconda, Mont.-I would like to add a few words of praise on Mr. Howard's work at the Old Dominion. Mr. Howard has given this particular converter shell his personal attention, and the results are shown in the figures given. Similar converter shells, a little different in shape and of about the same size, have been tried in many plants throughout the United States. The results have been highly satisfactory, but there is no shell of the size of the one described by Mr. Howard that has given anything like the results that Mr. Howard's shell has given. I know of larger shells that have given very good service, and are still in operation, and require very little repair. The main thing about the whole process of using the basic lining in copper converting is to keep the temperature within reasonable bounds, particularly not to get the furnace too hot. If it is overheated a little bit, for say half an hour, an entire lining may be ruined. It is very easy to keep the temperature regulated 'if the mass is large. If you have a large mass in your converter you can easily prevent it from getting over-heated, and that is the big argument in favor of the extra large converters. Of course, there is a limit to what a plant can turn out in the way of matte. Very few plants can supply matte sufficient to keep a converter of 20 ft. in diameter in operation constantly, but the 20-ft. converter is very much superior to the 12-ft. converter in easy handling and absolute control of the temperature. I think Mr. Howard is to be congratulated on the excellent showing he has made.

Jan 12, 1914

By Thomas E. Howard

Tunneling is at the threshold of a new era. An exciting new technology is becoming available. And, supplying the increasing quantities of minerals required by a growing and socially advancing world population, together with providing the subsurface facilities attendant to the rapid urbanization of the more developed countries of the world, will require underground excavation during the next decades on a scale that would have seemed fantastic a few years ago. It is estimated that world mineral consumption will increase fivefold by the year 2000. Projections for the United States indicate that domestic consumption of nonfuel minerals may increase two to three times by the end of the century. Meeting these requirements will entail opening up many new underground mines, even if present trends toward surface mining continue. And, at least in the United States, new factors that are becoming increasingly important may modify these trends. We are depleting our shallow easy- to-find and easy-to-mine mineral deposits; and, if we are to avoid becoming dangerously dependent on imports, we must turn more and more toward deeper deposits that are not amenable to surface mining. Growing public concern with environmental quality is apparently leading toward increasingly stringent regulation of surface mining which also will tend to make underground mining economically more attractive. The world market for underground construction is also growing rapidly. The most conservative projections indicate that in the United States alone more than $7.0 billion will be spent on excavation for underground facilities during the next ten years. And these estimates do not include any of the bold, imaginative new applications for underground excavation that have been proposed, such as extensive underground power transmission, the Chicago Deep Tunnel plan, and the Northeast Corridor Transportation project. There can be little doubt then that the market for tunnels for conventional applications is increasing rapidly and that the trend will continue. It

Jan 1, 1970

"Initiated as a part of the Bureau of Mines program for development of strategic minerals for national defense, various mines in the Poughkeepsie Gulch and Mineral Point mining districts were examined by C. R. Wilfley, W. R. Hamilton, .and N. E. Wvvlwy, Jr., Bureau Of 'Mines engineers, in July and August 1943, July 1944, and September 1945. In a subsequent report a proposal was made to evaluate this isolated area 'of some 15 square miles located in Ouray and San Juan Counties, Colo.Reconnaissance work in the area was begun in June 1946. Mapping and sampling were begun in July and was completed in Pougkeepsie Gulch and extended westward to include the Hendrick Gulch area of the east side of Ironton Park. Project work was recessed for the winter on October 15, 1946 after approximately 6 square miles of the Poughkeepsie Gulch,district been mapped and 801 samples had been taken.In this report the physical features, climate, and ore deposits districts are described, and a brief history of mining and production lead, zinc; and silver is given.The individual mines and prospects in, the area are described in detail.A list of patented claims and ownerships is given in appendix I, and analyses of samples are tabulated in appendix II.The San Juan preliminary project was directed by Paul T. Allsman, chief, Salt Lake City Branch, Mining Division and was supervised by William M. Traver, Jr., supervising engineer, Colorado Field. Office.Chemical analyses were made by the Salt Lake City laboratory under the direction of H.E. Peterson, chemist, and S. R. Zimmerley, chief, Salt Lake City Branch, Metallurgical Division.Harold A. Waddington, president, Great Divide Mining & Milling Corp., and Ernest Miller, owner, Como Consolidated Mines, were particularly cooperative in making available maps and data concerning their properties."

Sep 1, 1949

By Thomas M. Garland

Reports that set forth the pertinent facts of existing secondary-recovery operations are an integral part of the work of the Bureau of Mines in promoting conservation and efficient utilization of the petroleum resources of the Nation. Knowledge of the success or failure of waterflood projects in an area is very useful to other operators. Although projects will not have identical results, information concerning the flood performance, method of operation, and difficulties encountered on one project will help operators to determine the feasibility of flooding a similar sand and to select the methods of operation most likely to prove successful. The increasing cost of discovering and developing new oil reserves, as well as the unending effort to reduce operating costs and increase ultimate oil recovery from known petroleum reservoirs, has required the petroleum industry to evaluate continuously the performances of various secondary-recovery methods. Waterflooding was recognized early by the petroleum industry as a possible means of increasing oil recovery. From the early accidental floods in Pennsylvania and through many haphazard attempts to inject eater into oil-bearing formations, waterflooding emerged as one of the more important methods of oil recovery. Waterflooding is important not only to the oil industry but also to the economy of the area concerned.

Jan 1, 1962

By D. A. Barr

"Most of the lode and placer gold production in the Canadian Cordillera has been derived from mines and placers in the Intermontane and Omineca belts. Gold has been produced from rocks of Precambrian to Eocene age, but the preferred host environment contains Upper Paleozoic to Upper Jurassic eugeosynclinal or arc-type sedimentary and volcanic rocks adjacent to plutonic complexes which have a wide variety in both size and composition. Auriferous quartz lodes occur in fissures and shear zones which are commonly subsidiary to strong fault zones. In common with most vein-type deposits, structural complexities are an essential part of the mine environment.Gold production from the Canadian Cordillera to the end of 1978 totals 35.0 million ounces, of which 47 per cent has been produced from placer mining, principally in the Klondike and Cariboo districts. The balance has been derived from lode gold (80 per cent) and base metal (20 per cent) mines.Gold reserves in producing mines and deposits committed for production as of January 1, 1978 were 87.4 tons, or 21.6 per cent of total Canadian gold reserves contained in all types of deposits. Although more than 100 lode mines have operated in the Canadian Cordillera since the turn of the last century, over 75 per cent of the lode gold produced by 1978 was recovered from five mining camps, namely the Rossland, Hedley, Bridge River, Premier and Barkerville.The average grade of the principal producers in these camps was about 0.45 ounce of gold per ton. Individual camps yielded from 3 to 8 million tons during their operating lives, which varied from 28 to 43 years. The last of these mines ceased operating in 1971.Most of the total lode gold production has been derived from quartz veins, frequently with associated carbonate and ankerite, occupying fractured and faulted zones in Mesozoic volcanic and sedimentary rocks closely associated with a variety of intrusions. A review of the literature suggests that several deposits may have evolved by remobilization of ore constituents from earlier concordant gold-bearing formations. The principal metallic minerals in the deposits are native gold, electrum, tellurides, pyrite, arsenopyrite, pyrrhotite, sphalerite, galena and chalcopyrite.As the mineralogy suggests, many of the Cordilleran lode gold deposits have yielded important co-products or byproducts, including silver, copper, lead, zinc, cadmium and tungsten. Significant by-product gold production has also been derived from porphyry copper, volcanogenic, replacement and pyrometasomatic deposits, particularly in recent years.No major lode gold discovery has been made in the past 67 years, although little exploration activity for gold has taken place during the last 30 years. Several relatively small lode gold and gold replacement deposits have been discovered in recent years, either serendipitously (Chappelle) or on very low initial budgets (Northair and Carolin). Based on well-established precedents, one or more of these may eventually be developed into a large mine.A detailed study of the Canadian Cordillera gold deposits based on recent genetic models could prove rewarding, not only in up-dating information on their origin and depositional characteristics, but in stimulating the search for undiscovered gold deposits, in the Cordillera and other parts of Canada."

Jan 1, 1980

By K. J. Cathro

A hydrometallurgical process is described for the recovery of copper from chalcopyrite concentrates. The process is based on a cupric chloride leach, the concentrate having first been "activated" by heating it with sulphur at a temperature near 400°C. This activation process converts most of the iron of the chalcopyrite to pyrite, which is insoluble in the cupric chloride leachant. The copper is converted to the mineral idaite, which dissolves readily in hot cupric chloride: at 106°C, 98% of the copper is extracted in a three-stage countercurrent leach, the leaching tirqe being 1 hour per stage. The sulphur of the chalcopyrite appears as elemental sulphur, which is recycled for the activation of further concentrate, the final leach residue consisting of pyrite, plus the gangue present in the original concentrate. The copper extracted can be recovered by electrowinning, using a diaphragm cell. Current efficiency (one-electron basis) is about 70% but the cell voltage is only about 1 V, so that power consumption is three times lower than for the conventional sulphate electrowinning process. The leachant is simultaneously regenerated in the anode compartment. The behaviour of minor elements in the concentrate has also been studied.

Jan 1, 1976

By George C. Hawley

Historically, mica usage has been low because of limited availability; as a by-product of many small processors, who have lacked motivation for extensive R & D. The discovery of a 30 million ton deposit of 85-90% pure phlogopite, when existing markets are only 300,000 tonnes annually, forced the search for large volume new markets. Increasing costs of energy, petrochemicals, plastics and glass fibers, and environmental constraints on asbestos usage, have led to new opportunities for mica as a reinforcing filler. Extensive research and developments; in beneficiating, processing and treating mica, has been necessary to satisfy these new markets.

Jan 1, 1981

By L. J. Drew

The plate tectonic setting, regional geology, and certain aspects of the economic geology of the iron-rare-earth-nio-bium ore bodies at Bayan Obo, Inner Mongolia, China, were studied by a team of geologists from the Tianjin Geologic Research Academy and the U.s. Geological Survey between 1987 and 1989. These ore bodies were formed by hydrothermal replacement of Middle Proterozoic dolomite in an intracontinental rift setting. A variety of veins and/or dikes that have a carbonatite-like mineralogy cut the footwall clastic rocks and migmatites. A stockwork of veins occurs at several locations in the footwall. The hanging wall is a shale that has been converted to a K-metasomatite and has microcrystalline potassium feldspar as its principal constituent. This shale served as a sealing caprock that contained the chemical solutions that reacted with the dolomite and that created the enormous concentration of mineralized rock in an 18-kilometer-long syncline. The rocks that host these ore bodies and the associated mineralized areas occur today as roof pendants in granitoid rocks of Pennian age that were emplaced during a continent-to-continent collision during that period.

Jan 1, 1991

By J. A. Theron

"This paper provides guidelines on performing mass and energy balance modelling involving coal and coal derivatives. Usually, the inputs to a pyrometallurgical process would be specified in terms of elements and compounds. Reliable thermochemical data is more widely available for species involving uniquely defined, relatively smaller molecules. However, in the case of coal, the molecules are extremely large and not uniquely defined. Consequently, modelling processes involving coal and its derivatives have several potential pitfalls. These are outlined in the present paper. The main findings are as follows:•,Coal proximate analysis should not be regarded as absolute; it could vary with several parameters, including heating rate •,For modelling, the use of ultimate analyses should be considered a preferable option to proximate analyses, where, ‘fixed carbon’ and ‘volatiles’ are not defined in terms of chemical composition •,Significant errors could be made if the larger molecules are neglected during calculation of the calorific value (CV) of coal gas (the gas liberated when coal is heated in the absence of oxygen) •,For elemental analyses, the oxygen content (which is calculated by balance) should be checked to ensure it is within the expected range •,For representation of sulphur in coal, double-counting due to SO3 in the ash analysis should be avoided •,Potentially, oxygen in coal could be represented as O2, H2O, CO, or CO2; however, use of some of these species without considering the experimentally determined gross CV results in significant errors in the energy balance. If coal enthalpy is calculated from elemental analyses without correction, representation of coal oxygen as H2O(l) gives reasonable accuracy (up to 6.9% error for a set of South African coals). Coal volatiles could be represented by a complex mixture of compounds, even using different oxygen-containing species than the abovementioned four, provided the enthalpy is corrected •,It is recommended that an ‘enthalpy correction value’ is incorporated in energy balances involving combustion, devolatilization, or conversion of coal and coal derivatives, e.g. coke, char, or tar. That would imply that proximate analysis, elemental analysis, as well as the gross CV would be required for all solid or liquid coal-derived substances being modelled. No other correction due to the form of carbon being different than graphite should be used, as that would imply doublecounting some effects."

Jan 1, 2014

By C. M. Brinckerhoff

Much has been written in the mining technical magazines about the caving system. Many of these articles were published in the Transactions of the American Institute of Mining Engineers prior to World War II. In recent years little has been written on mining methods or on the detailed planning always required. Block caving had primarily been used to mine deep copper ores in Africa, the United States and in Chile, although other ores had been mined by this same system. Asbestos ore had been caved in Canada, tin ore in Bolivia, molybdenum ore in Colorado, iron ore in Wyoming and Sweden, and limestone in California.

Jan 1, 1984

By Pierre-Yves Declercq, Andre Vervoort

"After the mass closures of entire coal mine districts in Europe at the end of the last century, a new phenomenon of surface movement was observed—an upward movement. Although most surface movement (i.e., subsidence) occurs in the months and years after mining by the longwall method, surface movement still occurs many decades after mining is terminated. After the closure and flooding of underground excavations and surrounding rock, this movement is reversed. This paper focuses on quantifying the upward movement in two neighboring coal mines (Winterslag and Zwartberg, Belgium). The study is based on data from a remote sensing technique: interferometry with synthetic aperture radar (INSAR). The results of the study show that the rate of upward movement in the decade after closure is about 10 mm/year on average. The upward movements are not linked directly to the past exploitation directly underneath a location. The amounts of subsidence at specific locations are linked mainly to their positions relative to an inverse trough shape situated over the entire mined-out areas and their immediate surroundings. Local features, such as geological faults, can have a secondary effect on the local variation of the uplift. The processes of subsidence and uplift are based on completely different mechanisms. Subsidence is initiated by a caving process, while the process of uplift is clearly linked to flooding. INTRODUCTION After the mass closures of entire coal mine districts in Europe at the end of the last century, a new phenomenon of surface movement was observed—upward movement in the area above the past exploitation and in the immediate surroundings. Of course, most surface movement (i.e., subsidence) occurs in the months and years after mining by the longwall method (Peng, 1986). This downward movement continues to occur at a smaller rate many decades after mining has been terminated when the water in the underground excavations is pumped to the surface. This is the case as long as a mine is in operation. However, after the closure and flooding of the underground excavations and the surrounding rock, this movement is reversed, and the surface is uplifted. A total uplift of about half a meter has been recorded to date. This phenomenon has been described in several different coal basins in Europe, for example, in Belgium (Devleeschouwer et al., 2008), France (Samsonov, d’Oreye, and Smets, 2013), Germany (Baglikow, 2011), the Netherlands (Caro Cuenca, Hooper, and Hanssen, 2013), and Poland (Preusse, Kateloe, and Sroka, 2013). To date, research has focused mainly on understanding the phenomenon (e.g., Herrero et al., 2012) and identifying general trends, whereby the link with the rise in water levels is an important issue (Caro Cuenca, Hooper, and Hanssen, 2013). The most accepted explanation is linked to the swelling of clay minerals in the argillaceous rocks in the coal strata (Herrero et al., 2012). Without doubt, the full explanation is complex, and swelling is probably not the only cause of the residual movement. Most coal strata rock is weakened upon contact with water. The increase in water pressure also results in a decrease in the effective stress. Both aspects facilitate the fracturing of rock, which normally would result in further subsidence. However, decreases in the effective stresses also result in the relaxation or expansion of the rock, which induces an upward movement (Fjar et al., 2008). All of these aspects, including the long-term residual subsidence due to compaction under dry conditions, result in a net upward movement. The phenomenon discussed here is clearly different from the upsidence, sometimes observed on other continents (e.g., in Australia, Galvin, 2016). When upsidence occurs, the rock near the surface bends and buckles upwards due to the overstressing of the floors of the valleys."

Jan 1, 2017

By M. Wasel

The Gross Rosebel gold deposits are located in the Guiana Shield of north central Suriname. Initial discovery of surficial gold in 1880 by local artisanal miners preceded small-scale mechanized mining from 1885 to 1939. The first systematic exploration program was carried out by Placer Development from 1974 to 1977. In May 1992 Golden Star Resources optioned the property. Initial shallow reconnaissance diamond drilling of the extensive surface geochemical anomalies intersected sporadic gold mineralization with no apparent continuity between drill sections. Successive deep augering, trenching and systematic grid drilling based on information from surface mapping allowed development of a preliminary geological model. Further drilling of specific structural-lithologic targets and more complete synthesis of geological data from the trenching and deep auger sampling added to the geological model and defined the multiple controls of gold mineralization. Carefully planned infill drilling on a tighter grid spacing resulted in progressive definition of reserves within six discrete gold deposits. In a complex geological setting, the key to success at Gross Rosebel was persistent, systematic exploration, detailed mapping, careful core logging and perceptive geological interpretation. Reserves now stand at 48.6 Mt at 1.6 glt Au, or 2.4 million ounces of gold. The purpose of this paper is to describe the progression of exploration activity that led to the definition of substantial gold reserves and to summarize the geology of the deposits.

Jan 1, 1998

By P. Latostenmaa, O. Forsén, M. Lundström, J. Aromaa

The history of electrolytic copper production in Finland is closely connected with the industrialization of Finland and events of the Second World War. Production of cathode copper by electrowinning from the processing of Outokumpu ore started in 1913 based on the Hybinette nickel process, however due to the poor performance of this process, the plant was closed in 1929. Outokumpu commenced copper smelting at Imatra in eastern Finland in 1936 producing blister copper for refining outside the country. Due to the threating military situation, a new electrolytic copper refinery was built in 1941 at Pori in western Finland to refine the anodes. This was the first electrolytic copper refinery in Finland. It was built with 108 cells having a capacity of 12,000 tonnes/y. In addition, the smelter was relocated to nearby Harjavalta in 1944–1945. To fulfill the war reparations included in the peace treaty with the Soviet Union, a doubling of the smelter capacity was realised, with the Pori refinery capacity increasing to 20,000 tonnes/y in 1946 by adding additional cells. The cornerstone of Finnish metallurgical technology — Outokumpu flash smelting — was invented with the new technology commissioned at Harjavalta in 1949 replacing the electric furnace and providing a further increase in copper output with subsequent enlargement of the refinery. By 1963, the plant consisted of 380 cells with a capacity of 48,000 tonnes/y of cathode copper. The Pori electrolytic copper refinery has operated continuously since 1941. Commencing in 2004 the Pori refinery has been part of the Boliden group of Sweden. The most recent plant upgrade was in 2007 with the installation of permanent cathode technology. In 2017, the production of the Pori refinery was 133,000 tonnes of copper cathode, 2,300 tonnes of nickel sulphate, along with 66 tonnes of silver and 4.6 tonnes of gold. This paper describes these outstanding achievements. INTRODUCTION In 1809 the Kingdom of Sweden was defeated by the Russian Empire in the Finnish War, and Finland was annexed by the Russian Empire as the autonomous Grand Duchy of Finland. Finland’s commercial and industrial interests were developed to serve the Empire’s needs. Finland had raw materials, but at the start of the 20th century Finnish industry was based on the use of wood as raw material and agricultural products. The mining industry was only a few percent of the country’s industrial production.

Jan 1, 2019

By Zhijing Zhang

A thermodynamic structure model for alkali borate melts is developed to describe the distribution of structural groups in the alkali borate melts as a function of compositions. Fractions of threefold coordinated boron atoms and fourfold coordinated boron atoms in the potassium borate melt are calculated for the entire composition range and compared with results reported in the literature. The model has been used for structural interpretation for the borate anomaly in viscosity, which regards the borate anomaly as a manifestation of the various antithetical effects caused by the introduction of alkali oxide into boric oxide. It has been found that the viscosities of alkali borate melts increase or decrease according to the changes in rigidity and spatial connectivity of the glass network structure, which is a function of temperature and composition.

Jan 1, 2001

By Thirumalai, K.

Although the term "spalling" has long been known, Norton l first referred to its usage for the fracture or disintegration of materials subjected to rapid temperature changes. Spalling of ceramic materials at high temperatures has received attention in the past. Removal of the char formed during ablation in re-entry of space vehicles has been referred to as mechanical spalling. The first experiments to evaluate the process of rock fragmentation by thermal spalling were conducted by Stoces using a series of gasoline burners on the quartz veins of the Zinnwald deep mines in Germany. After the development of rocket-jet burners, the principles of 'thermal spalling combined with high fluid momentum found wide practical application in rocks. The well-known jet piercing process for drilling blastholes in taconite and for jet channeling in the quarrying of granite are among the more notable of these application^.

Jan 1, 1970

By T. C. Vogt

Earlier we described the uranium mineralogy of an areally broad sampling of Crownpoint ore, including the characterization of organic carbonaceous material associated with the uranium mineral. (1) We also reported on the leaching behavior of Crownpoint ores with a mild alkaline leaching system, oxygen (02)-sodium bicarbonate (NaHC03). (2) There was a wide range of leaching responses, with samples from some areas leaching at a slow rate with low uranium recovery. Evidence indicates that in these samples the organic material is intimately associated with the uranium mineral and shields it to some extent from contact by the leachate. (1,2) One method to obtain faster leach rates and higher recoveries is to use a chemically severe leaching system such as sodium hypochlorite (NaOCI) as an oxidant. (3) The use of sulfuric acid (H2SO4) and an oxidant for leaching ore in surface milling operations is widely practiced to effect high recovery of uranium (U308) from the ore. (4,5,6) The U308 is mobilized as the disulfate complex, U02(S04)224-, or possibly, the trisulfate complex, U02(S04)34-, is the soluble species. (7) Sulfuric acid leachate formulations were used in the first in-situ leaching operation in the Shirley Basin in Wyoming. (8) More recently H2S04 formulations have been used in the Rocky Mountain Energy field tests in the Powder River Basin (Bear Creek) and in the Teapot forma¬tion at Nine Mile Lake site near Casper. (9,10) Laboratory studies related to the use of H2SO4 for in-situ leaching have been reported (11-17) and Yan has .reported packed column leach studies on Crownpoint ore using H2504 and oxidant. (18)

Jan 1, 1981