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By E. C. Truesdale

A FEW years ago H. M. Cyr, working in the Research Laboratories of The New Jersey Zinc Co., produced a few pounds of zinc1 of such purity that no other elements were detected in it by spectrographic analysis, using the facilities then available. This zinc contained less than one ten-thousandth of one per cent of metallic impurities.2 During the decade that followed upon the laboratory production of this "spectro-graphically pure" zinc, commercial developments brought about the production of large tonnages of zinc of purity exceeding 99.99 per cent, and today zinc of 99.999 per cent purity is produced and marketed as "chemically pure" zinc. Typical analyses of present supplies of high-purity zinc are given in Table 1. TABLE 1.-Typical Analyses Percentage by Weight Sum of Zinc Pb, Fe, Pb Fe Cd Al Cd Special High Grades 0.007b 0.005b 0.0056 none 0.0106 C.P. (chemically pure) <0.0002 0.0005° 0.000052 S.P. (spectrographically pure).. <0.0002d <0.00005d a A.S.T.M. Standard Specification for Special High Grade Slab Zinc (A.S.T.M. Designation: B 6-37). b Maximum. c Fe chemically determined. Pb and Cd are spectrographically determined. d Differences between composition of C.P. and S.P. zinc are discussed later in this paper. The availability of commercial tonnages of special high-grade zinc has been the basis for the development of the zinc-base die-casting alloy industry which, in the year 1936, consumed one-eighth of the zinc used in the United States for all purposes. This and the C.P. and S.P. grades have given impetus to scientific investigations into the properties of pure

Jan 1, 1939

By W. M. Wojcik, R. F. Kowal

Oxygen and sulfur distributions in commercial, 5-ton ingots of killed, medium carbon steel are described. Oxygen distribution is found to vary with deoxidation practice. Irregular distribution of oxygen within ingots makes necessary special precautions in sampling of rolled products for analysis of oxygen. Oxygen distribution is discussed in terms of recently published solidification concepts which had been successfully applied to simpler cases of segregation. These concepts have been found inadequate to explain observed oxygen distributions. Convective movements of the liquid metal, as determined by tracer elements, are shown to be capable of accounting for the observed distributions of oxygen. IN an effort to explore the origin of surface and subsurface imperfections in pierced steel products, a study of oxygen and sulfur segregation was made on ingots cast in open-top and hot-top molds. The results of our previous investigations1"3 have indicated the importance of the location and amount of oxide inclusions in an ingot. Inclusions close to the surface of the ingot have been found to contribute greatly to the formation of imperfections in the surface of finished products. This study of the effects of deoxidation and casting practice on segregation and the resulting oxygen distribution in ingots was initiated to determine the parameters controlling the location of inclusions in an ingot. Segregation of solute elements during solidification of low-melting binary alloys has been studied in the past.1, 5 Formation and growth of inclusions in iron melts have been studied under specific conditions."- In spite of these and other recent studies,10-12 segregation during solidification of commercial, killed steel ingots is not well understood. Consideration of solidification rates, of segregation during solidification of the chill, dendritic, and central zones, and of material balances for the segregated elements has indicated that a simplified theoretical solidification model is not adequate. However, the observed high oxygen contents in localized volumes of the dendritic zone can be rationalized if additional effects of convection currents in the ingots, precipitation, and rapid growth of new phases are considered. EXPERIMENTAL PROCEDURE Steelmaking and Processing. A group of nine killed. medium carbon steel heats having compositions listed in Table I have been studied. The deoxidation and mold practices used were varied to give a wide range of steel oxygen contents. The amounts of aluminum added to the ladle and the ingot casting practices (hot top and open top) were the main variables. The steel was made by a duplex practice in 160-ton tilting basic open-hearth furnaces. All nine heats were top-cast into 24 by 24 in. big end down, fluted molds, to a height between 60 and 76 in., using both open tops and exothermic hot tops. The deoxidation practice and the tapping and teeming details for each heat and ingot studied are given in Tables II and III, respectively. Hot-top practice is indicated by the letter H following the heat designation. Furnace and ladle temperatures were measured by standard disposable-tip, Pt/10 pet PtRh thermocouples. Teeming-stream temperatures were obtained as described by Samways et al.,13 by immersing a Pt/10 pet PtRh thermocouple, covered by a silica sheath, into the teeming stream under the nozzle. The output of this thermocouple was recorded with Leeds & Northrup Speedomax potentiometer. Calibration of the latter thermocouples was based on the freezing point of a pure iron/oxygen alloy (2795°F). The accumulated errors of measurements were within ±10°F. The thermocouple measurements were supplemented in this investigation by continuous recording of a ratioing, two-color pyrometer (Shawmeter), protected from smoke by a blast of clean air within the sighting tube, and calibrated to read with better than ±10°F accuracy. Following teeming of three heats, P, R, and T, tracer elements were added to the steel in the molds to obtain a record of the progress of solidification. As soon as the teeming stream was shut off, a 0.010-in.-thick steel can containing a mixture of crushed standard ferro-titanium and ferro-vanadium (0.05 pet of each alloy element) was plunged into the middle of the steel pool to a depth of 6 in. In about 30 sec no indication of the can or its contents remained. The surface of the open-top ingots solidified in 20 to 30 sec. A study of liquid metal movement and the precipitation of oxides was facilitated materially by use of the tracer technique as titanium has a low distribution coefficient between solid and liquid steel while vanadium has a high distribution coefficient.

Jan 1, 1965

By C. O. Burgess, W. D. Forgeng

The results of an investigation of the ternary system iron-chromium-silicon were reported in 1936 by the present authors.l Partly for the sake of theoretical interest, and partly because of the possible commercial importance of these alloys, the present investigation was undertaken to determine the effect of some of the commoner elements likely to occur, deliberately or otherwise, in such alloys if made on a commercial scale. The elements thus added were carbon, nickel or manganese. The alloys studied were, therefore, parts of quaternary systems. This investigation was concerned primarily with the effect of these additional elements on the alpha-iron phase and the boundary between this phase region and the alpha plus sigma two-phase region. The sigma phase is a ternary solid solution based upon the compound FeCr. The work was performed mainly by X-ray methods, but a number of microscopic examinations were also made and are reported. While isolated alloys in the composition ranges studied may have been discussed in metallurgical publications, no systematic investigation of any assistance to us was found. Of the earlier work, the investigations on the iron-chromium-carbon system and on the chromium carbides by Westgren and his coworkers2&apos;3 enabled us to identify the carbide phase. Several articles appeared after the present experimental work had been completed. Lucas and Wintrup4 determined the solubility of carbon in molten iron-chromium-silicon alloys. Tofaute and his coworkers5&apos;6 have made detailed studies of the iron-chromium-carbon system, which will be referred to later. Materials and Methods Materials.—The iron, chromium and silicon used were essentially the same as those used in the investigation of the ternary system.l The

Jan 1, 1938

By N. A. D. Parlee

The diffusion rate of hydrogen in liquid iron has been measured by a gas-liquid metal diffusion cell technique. The diffusion cell was formed by immersing an alumina tube containing hydrogen gas at 1 atm in a bath of stagnant liquid iron. The change in the composition of the melt in the cell was determined by measuring the rate of absorption of the gas in the cell. The appropriate solution to Fick&apos;s second law was used to examine the data and calculate diffusivi-ties. The absorption of hydrogen in stagnant pure liquid iron has been found to be diffusion-controlled. The results show that the chemical diffusion coefficient, D, of hydrogen in pure iron in the range of 1547" to 1726°C can be represented by the following Arrhenius relation: D(sq cnz per sec) = 3.2 x X exp(- 3300 i 1800/RT) where the uncertainty in the activation energy corresponds to the YO pct confidence level. Oxygen in the melt (above 0.015 pct 2) increased the apparent rate of absorption of hydrogen. The importance of diffusion data on liquid metals for predicting the rates of certain metallurgical processes has been recognized for a long time. Moreover, these data are much needed to test and develop theory for diffusion in liquid metals. Despite this practical and theoretical interest, however, relatively little reliable information about diffusion in liquid metals is available in the literature. This is particularly true for gas components such as hydrogen, oxygen, and nitrogen in liquid metals, where almost no data on chemical diffusion coefficients are to be found. This is probably due to a multitude of experimental difficulties particularly associated with high-temperature melts. In an effort to fill this gap in information, a research program was undertaken to study the diffusivities and rates of solution of gases in liquid metals. This paper presents the results of a study of the diffusion of hydrogen in liquid iron. EXPERIMENTAL METHOD Two methods for the study of the kinetics of dissolution of gases in liquid metals are being employed in this laboratory. Both involve the measurement of the volume of gas absorbed by the melt as a function of time and as such both avoid the uncertainties involved in chemical analyses of quenched samples for relatively small amounts of gas. In the first method, the gas dissolves in an inductively stirred melt and, in the absence of a slow surface reaction, the results are often interpreted in terms of mass transport across a liquid "boundary layer" between the homogeneous gas phase and well-stirred part of the melt. Other interpretations of the results of such experiments have also been described in the literature.1&apos;5 In the second method a gas-liquid metal diffusion cell is used.&apos; The gas dissolves in a cylindrical column of stagnant liquid metal and, in the absence of a slow surface reaction, the results are interpreted in terms of a non-steady-state diffusion solution to Fick&apos;s second law. The weakness of the first method is that while it gives information on the mechanism of absorption by stirred melts it yields an overall rate constant which even in the simplest cases depends on the nature and the thickness of the "mass transport layer" or "boundary layer". It yields no values of diffusion coefficients. The second method was used in this research because in many cases it is possible to determine the diffusion coefficient of the gas component in the liquid metal. In this research it has been utilized to measure diffusion coefficients of hydrogen in liquid iron. The apparatus used was essentially the same as that described by Mizikar, Grace, and par lee but certain modifications have been introduced to meet the elevated temperatures and special conditions of this research. Fig. 1 is a schematic drawing of the apparatus and Table I gives the identification of various parts in this figure. The diffusion cell, shown in detail in Fig. 2, was formed by immersing an impervious alumina tube (hereafter called absorption tube) in a bath of pure liquid iron contained in an alumina crucible. Two types of tubes were used, Morganite triangle RR and McDanel AP35. The crucible was contained in a vertical impervious alumina combustion tube (32 mm ID by 914 mm long) which was closed at both ends by water-cooled brass heads employing O-ring compression seals, Fig. 1. A protection tube enclosing a Pt, 5 pct Rh-Pt, 20 pct Rh thermocouple was introduced through the lower end of the combustion tube

Jan 1, 1968

By C. John Sullivan

Is there a relationship among the Sudbury nickel ores, the Cobalt deposits, and the Huronian, Athabascan and North Australian uranium provinces? All are within intracratonic basins, with ore near basal unconformities. There are similarities in the geochemical "fingerprints" pointing to basic igneous rock affiliations. Some show a time relationship to basic igneous activity and to great rift systems. Many basic dykes show radioactivity at their edges. A spatial relationship between the uranium-cobalt-nickel ore at Midwest Lake, Athabasca, and basic igneous rock is reported. These remarks are not meant to imply, necessarily, a direct genetic connection between the basic dykes, etc., and the ore. In some cases, the relationship may be similar to that noted between basic and ultrabasic intrusives and volcanic massive sulphide ore deposits. Crustal thinning in these areas, associated with graben, appears to have favoured volcanic activity, as well as basic intrusives. Probably, the potential of the Huronian should be re thought . Athabascan-type ore may be present . New data on mineralization in Turner Township, Ontario, suggest this. The mineral possibilities of other basins should be reconsidered. It is to be remembered that the Athabascan and Kombolgie basins were neglected for many years. Intracratonic sedimentary-igneous basins contain many of the greatest mineral fields of the world.

Jan 1, 1979

Silver-lead ores are widely distributed through- out the Mount Lofty and Flinders Ranges, but none of the deposits is large. Historically the Glen Osmond Mines are the most significant as the site of the first metalliferous mining in Australia, but Talisker was one of the three largest producers of silver-lead in a state whose mining history is dom- inated by copper. The mine is located in a magnificent natural setting on Talisker Conservation Park, near Cape Jervis, southwest of Adelaide (Figure 1). It is exempt from the operations of the Mining Act and listed on the Register of State Heritage Items. The mine and associated township of Silverton were dominated by Cornish influences during the period of principal activity between 1862 and 1872. Silverton, located on a ridge overlooking the mine, grew to a population of about 300 at its peak in 1870 and the area was very much another &apos;little Cornwall&apos;.

Jan 1, 1987

ASHBEL WELCH, LAMBERTVILLE, N. J.: Dr. Dudley has given the wear of steel rails under four different conditions. He arrives at the conclusion that the softer rails, or those that from their composition ought to be softer, wear better than the harder. But there is another condition which has an important bearing on the subject, and, should not be overlooked,-the weight on a wheel. With the lighter weights of the past, the softer rails may have worn best; with the heavier weights of the future, the harder may wear best. Weights will probably be increased up to the capacity of steel to bear; then doubtless the harder steel will wear best. A leaden rail with ten pounds on a wheel might carry millions of tons, but with one hundred pounds on a wheel, it would be destroyed by a few thousand tons. So in the days of iron rails, my experience was that the softer rails under light machinery stood better than some of the harder; but under heavy machinery the softer were much the most rapidly destroyed. His doubtless the same with steel. The pounding motion of the wheels loosens or spreads the particles of a thin film of steel; the pull lengthwise on the rail de- * Metallurgical Review, vol. i, page 1. † The remarks as here given, as in the previous discussion on steel rails, have all been written out or revised by the participants in the discussion, and represent, therefore, their mature views. It has been thought that this plan, when it can be carried out without doing any of the speakers injustice in debate, is much to be preferred to a strictly verbatim report. The remarks of Mr. Chanute were sent to the secretary after the. meeting, and although they did not form a part of the actual discussion, there can be no doubt of the desirability of including them in this report. The papers under discussion were “Rail Specifications and Rail Inspection in Europe,” by C. P. Sandberg ; " The Wearing Capacity of Steel Rails in Relation to the Chemical Composition and Physical Properties," by C. B. Dudley, and a Rail Patterns," by A. L. Holley. T. M. D., Secretary.

Jan 1, 1881

By Joseph J. Wallace, Lloyd Williams, D. A. Reynolds, James J. Dowd, R. F. Abemethy

"SUMMARY AND CONCLUSIONS1. The investigation shows that the most important beds in Allegany County, from the standpoint of known recoverable reserves are: Lower Bakerstown, Upper Freeport, Upper Bakerstown, Upper Kittraing - less important beds are: Sewickley, Waynesburg, Pittsburgh, and Barton. 2. Known measured and indicated reserves in all beds, based on a minimum thickness of 14 inches and 1,800 tons per acre-foot of coal in place, are estimated to be 556 million short tons, as of January 1, 1951. Of this total, 304 million short tons is in beds 23 inches and more thick. Areas in each bed were omitted from the estimate because available data relative to the bed characteristics are too meager to permit making an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total eat ted reserves.3. Recoverable reserves of coal have been estimated in beds 28 inches and more thick. This thickness is about the minimum now being mined by hand-loading onto conveyors in the Appalachian region. The weighted average recovery for all beds in Allegany County, as determined by this investigation, is 49.8 percent. This percentage is based on the total thickness of coal (less partings 3/8 inch or more thick) in the bed rather than on the thickness of the coal mined. Based on the weighted average percent recovery for all beds in Allegany County, the recoverable reserves are estimated to be 152 million short tons as of January 1, 1951.4. The Allegany County coals are low-volatile bituminous in rank.5. The Allegany County coals are strongly coking."

May 1, 1953

By R. Ricketts, D. G. Vanderveer, F. Kirby

"A program of mapping, sampling and testing to determine the potential of the aggregate resources throughout Newfoundland and Labrador was commenced in 1978. A 6-km-wide corridor parallel to all transportation routes was selected as the study area.The study consisted of a preliminary surficial interpretation followed by field mapping and sampling. Granular resources were sampled at a 500-m interval and non-granular materials were sampled at a 1.5- to 2-km interval. Data were gathered on landforms and stratigraphy as well as a field description of the sample and deposit types. Particle-size and lithologic analyses of the samples were also conducted.The locations of samples and deposits were mapped on 1:50,000 topographic base maps and summarized for publication at a 1:250,000 scale. Surficial geology maps were produced at a 1:50,000 scale. A computer program is being developed for the search and retrieval of field data.The first phase of the Inventory of Aggregate Resources program is nearing completion and to date has collected information on approximately 9,500 samples throughout Newfoundland and Labrador. This data will be used to provide f or the effective management of these vital non-renewable aggregate resources.The mineral aggregate industry in Newfoundland and Labrador is very competitive, but undercapitalized when compared to other provinces. The demand for aggregates is forecasted to increase to in excess of23 million tons per annum by the year 2002.In terms of over-all mineral production, the extraction of sand, gravel and stone has a significant impact when compared to other minerals in terms of value and tonnage produced.IntroductionThe province of Newfoundland has approximately 18,000 km of coastline. A large proportion of the population lives in coastal communities where, traditionally, beaches have been a major source of construction materials. Beaches have, therefore, often been subjected to overutilization, resulting in erosion of back beach areas or adjacent headlands."

Jan 1, 1982

By Törbjorn Naarttijärvi, Bengt Ludvig, Agne Rustan

"Falling rock is one of the major causes of serious injuries and deaths in Swedish mines. The research at the Division of Mining and Underground Construction was therefore directed toward controlled blasting in hard intense jointed rock.The project was started with an extensive literature review. Model tests with a new equivalent model material have been initiated to find ways of improving blasting techniques. The result showed that long cracks arise at the perimeter holes when there is a long time delay between adjacent holes. This led to the theoretical development of a new initiation method with ultra short delays (1,5 ms) f or controlled blasting, called ""Cutblasting"".Full-scale tests have been done at LKAB in Malmberget in hard intense jointed magnetite ore. Four different types of perimeter charges have been tested, namely: tube charges, ANFO mixed with plastic beads, detonating cord and linear shaped charges. Three types of initiation of the perimeter holes have been used, conventional (half-second delay detonators), instantaneous and ultra short ""cutblasting initiation"" (1,5 ms delay). The change in rock strength before and after blasting has been studied with bore hole periscope, vibration measurement and ocular observation of the rock surfaces.Thefull-scale tests showed that ""cutblasting"" with detonating cord in the perimeter holes gave the smallest damage to the surrounding rock. A combination of cutblasting initiation and tube charges are anticipated to give an even better result. A new method of controlled blasting using linear-shaped charges has also been tested, however, this charge type needs further development.The full- scale test also showed that the damage which can be seen on the rock surf ace is about the same for different controlled blasting methods but the not-visual-damage zone varies as much as from 0,1 to 0,7 m.A new classification system for controlled blasting regarding the damage to the surrounding rock has been devised."

Jan 1, 1985

By M. M. Papic, G. M. Kimber

"Hat Creek coal was treated by the liquid solvent extraction process in a continuous plant at the U.K. National Coal Board Coal Research Establishment.Extraction levels of over 80 per cent dry-mineral-matter-free (dmmf) coal were achieved.Total light oil yield was around 47 per cent of the dmmf coal. The light oil was shown to be a good feedstock for secondary refining into gasoline, jet fuel and diesel fuel.In spite of the high mineral matter content of the coal the solid residue was successfully removed from the coal extract by filtration.IntroductionBritish Columbia Hydro (BCH) and the National Coal Board of Great Britain (NCB) undertook a joint project to test the Hat Creek coal from British Columbia in the NCB&apos;s coal liquefaction process designed to produce transport fuels and feedstocks for the chemical industry by the liquid solvent extraction of coal(1), In this process most of the coal is dissolved in an aromatic solvent and the residual solids consisting of mineral matter and undissolved coal are removed by filtration. The resultant coal extract solution is fed to a hydrocracker for conversion to light liquid products and a fraction suitable for recycling as solvent. The light liquid products can be converted to gasoline and diesel fuel in a secondary refining stage.The dissolution of the coal is effected by heat-treating a slurry at a temperature in the region of 400°C which causes some bonds in the coal to rupture with the formation of radicals(2,3). These radicals are stabilized by hydrogen transfer from the hydroaromatic groups in the solvent, resulting in a reduction in the molecular weight of the coal. In the absence of donor groups the radicals combine to form an insoluble high molecular weight product(4). From studies of the kinetics of these reactions it has been shown that the formation and stabilization of the radicals is rapid at temperatures around 400°C(2,3). The dissolution of the depolymerizing coal is, however, relatively slow and the need to ensure complete dissolution in order to achieve a high extraction restricts the selection of digestion time(5). Further, it is important that digests do not contain depolymerizing coal as it may re-form under the applied stress in the filter cake inhibiting flow through the bed and resulting in low filtration rates(6).Thus, in practice relatively long digestion times are generally required in order to ensure complete dissolution of the depolymerizing coal, while it is also important to avoid depletion of the hydrogen donor groups in the solvent which would lower the rate of hydrogen donation to the coal and thus reduce the extraction yield and adversely affect the filtration(7). Clearly it is desirable to optimize the digestion time and temperature with regard to the extraction yield and filtration properties.The precise control of the distribution of products from the hydro-cracker is important for the composition of the recycle process solvent. The principal functions of the solvent are to provide a source of donatable hydrogen and a vehicle for the dissolution of the depolymerizing coal. Hydrogen transfer from the solvent, achieved by the conversion of hydroaromatic to aromatic groups, stabilizes the radicals formed by thermal cleavage of some of the bonds in the coal resulting in a progressive reduction in the size of the coal molecules(8,9) and dissolution in the solvent. The combination of radicals would result in the formation of insoluble material and a reduced extraction yield of the coal(4). Thus to achieve a high extraction yield the solvent should contain sufficient hydrogen donor groups to prevent extensive radical combination. The composition of the solvent should also be controlled to allow dissolution of the depolymerizing coal and to prevent precipitation of this material during the subsequent processing of the coal digest and extract solution. The formation of a precipitate not only reduces the extraction yield of the coal and adve"

Jan 1, 1985

By Harold Earle Cook

The purpose of this paper is to state briefly the inspection requirements of the Bureau of Ordnance, the specifications governing the inspection, and the physical and chemical properties of the steel used in the construction of ordnance for our Navy. It would be of interest to evoke discussion on points in these specifications which do not tend to insure the production of the very best material for the purpose intended. In other words, what requirements of our specifications are useless and also in what manner are our specifications deficient? It might be well at the start to answer the first criticism of this paper which will probably be made, and that is that the title does not agree with the subject matter. Considering metallographic work as covering only the macroscopic and microscopic examination of metals, this paper will have gone beyond the subject; but it is believed that a broader definition of metallography is that it is the study of the relation of the internal structure of metals and alloys to their composition and to their physical and other properties. The internal structure of steel is dependent on its physical and its chemical properties. These physical properties are dependent on the chemical composition and the mechanical and thermal treatment of the steel. So it seems that this subtitle would not be entirely necessary and that the title " Metallography of Steel for Ordnance Purposes" would cover a study, not only of what we can learn of macroscopic and microscopic examination, but broadly of the whole subject of the specifications, the fulfillment of the requirements of which produce the structural conditions revealed by macroscopic and microscopic examination. I will refer but briefly at the beginning to the microscope and its uses in our inspection. It is only very recently that the Bureau of Ordnancc has furnished certain of its inspection offices with a portable Tassin outfit for the microscopic examination of steel. Since that

Jan 1, 1916

By Douglas R. Piteau, Dennis C. Martin

Instability of rock slopes may occur by failure along pre- existing structural discontinuities, by failure through intact material or by failure along a surface formed partly along discontinuities and partly through intact material. Although certain fundamental failure modes are recognized, the mechanisms of slope failure are varied and complex. Such mechanisms are governed by the engineering geology conditions of the rock mass, which are almost always unique to a particular site. An understanding of failure mechanisms requires a knowledge of the physical, mechanical and strength properties of the intact material and discontinuities which make up the rock mass, as well as the structural geology and hydrogeology. These engineering geology parameters also must be evaluated with respect to the slope geometry to determine failures which are kinematically possible. Only after obtaining a reasonable appreciation of the possible failure modes can a rational mechanical stability analysis be carried out. Both two-dimensional and three-dimensional failure mechanisms should be considered in assessing the design of rock slopes. Simple analyses methods are used initially to identify those possible failures which could control slope stability. More complex and detailed analyses usually are required for a few critical failure modes which could control stability, or where a more complex type of failure mechanism is envisaged. Complex failure mechanisms are usually identified when assessing previous slope failures. More detailed information concerning slope geometry and engineering geology parameters must be acquired where analyses must be more rigorous.

Jan 1, 1983

By Henry Rawdon

ONE of the most vital problems in the manufacture of steel at present is the occurrence of the defects that have been popularly termed "snow flakes," "flakes," or "scabs." Particularly is this the problem of many manufacturers who during the past 2 yr. have undertaken large-scale production for the first time. A study of the microstructure of such defective material throws considerable light upon the nature of these defects and is essential before measures may be taken for the elimination of the defects. Flakes do not appear to be found in the plain carbon steels; they have been found, however, in abundance in some of the simple alloy steels that are being used in such vast quantities; viz., nickel steel of the approximate composition, 0.40 carbon and 3.5 per cent. nickel, and in the chrome-nickel type. The present article summarizes the characteristic features of defective steel of the flaky type as they have been found by laboratory study of numerous specimens, and it aims to show the conditions within the metal that are favorable to the occurrence of this type of defect without entering into the details of mill practice (size of ingot, design of molds, rate of cooling, distribution of cooling stresses, etc.), all of which conditions appear to play a role in the production of these defects.

Jan 2, 1919

By R. G. Gillies, C. A. Shook, W. H. W. Husband

"The current state of knowledge concerning pipeline transport of coal in water slurry form is summarized for the four categories: coal-water fuels, conventional fine coal slurries, coarse coals and stabilized mixtures of coarse and fine particles. Surface chemistry is of dominant importance for coal-water fuels and considerable progress in understanding the role of surfactants has been achieved in recent years. Little generalized research on the flow of conventional fine coal slurries has been done in the past 17years, although innumerable conceptual designs and feasibility studies have been undertaken. Coarse coal slurries are fairly well understood but the model which explains their flow requires more data to be established fully. Stabilized flow mixtures should probably obey the same model as coarse coal slurries but experimental results for stabilized mixtures have not yet been incorporated in a comprehensive theory.IntroductionPipeline transportation of coal in a water vehicle has been employed for many years in coal washeries. It has been used less frequently in hydraulic mining and thermal power station fuel supply systems. The suitability of coal for pipeline transport arises from its moderate specific gravity relative to the carrier fluid and the fact that throughputs are often large and steady over long periods of time."

Jan 1, 1990

By M. D. Flavel, J. C. Motz, G. V. Jergensen

Introduction Compared to the gyratory crusher, the cone crusher is character¬ized by its higher speed and a flat crushing chamber design which is intended to give a high capacity and reduction ratio for materials suitable to this type of processing. The aim is to retain material longer in the crushing chamber to do more work on material as it is being processed. A concept of how a piece of stone might flow through a secondary crushing chamber is shown in Fig. 45. The number of times material will be nipped during crushing will depend on material size, friability, and the geometry of the crushing chamber as well as its speed and eccentric throw. Cone crushers are usually specified in terms of closed-side setting (CSS) and a given quantity of material passing a particular square-mesh screen size. A criterion of product passing closed-side setting is often available. This value will vary according to the particular crusher design and the details of its applica¬tion. Essentially, cone crushers can be classified into distinct types, depending on their duty. Crusher sizes for all duties are described by terms arising out of common industry usage, such as 3-ft, 7-ft, etc., which refer to the crushing-head (mantle) diameter. At present the range of sizes available varies from approximately 2 to 10 ft diam. Weights vary in the range of 5 to 200 tons, and connected horsepowers range from 10 through 700. There are so many variations that specifics should be obtained from machine manufacturers. The crushing chambers that are fitted to various machines are also often referred to by terms arising out of common usage, such as standard for secondary crushers, and short head for tertiary crush¬ers, which refer specifically to the Symons design. Also used are more specific but equally vague descriptions, such as coarse, intermedi¬ate, and fine chambers. Some manufacturers such as Allis-Chalmers with their Hydrocone crushers refer to the model number of the machine by the feed opening and the diameter of the mantle. For example, a Model 10-84 Hydrocone crusher has an 84-in. diam man¬tle, and is capable of accepting a 10-in. diam sphere at the feed point to the crushing chamber. Rexnord and Telsmith define crushing cavi¬ties in their capacity tables as feed openings at minimum recommended discharge settings (closed-side settings). Each practice offers guidelines which should be carefully defined for the specific crushing problem. The utilization of a cone crusher depends on how well it is controlled and the features of the circuit in which it operates. Normally, it will operate in the range of 75 to 85% of the peak capacity. It is likely that industry pressures will call for a standarized de¬ applied crushing power. Experience has shown that the crushing process is more controllable if certain reduction ratios are adhered to for each stage. Technically, this is defined as that size of feed (in. or mm) of which 80% will pass, divided by the size of the product (in. or mm) which 80% will pass. Secondary Crushers These are the cone crushers which accept suitable feed size material either prepared by a primary crusher or occurring naturally, and reduce it to a size suitable for marketing in one stage, or make feed for subsequent crushing or grinding stages. Secondary crushers have feed openings of 4 to 25 in. in the larger (7-ft) models down to a 2&apos;/a to 4 in. in the smallest 24-in. models. Reduction ratios normally range between 3:1 and seldom more than 5:1. In the 7-ft models, the cone crusher typically makes a product all passing 2 in., but this is dependent on the machine design and properties of the material being treated. Secondary crushers most commonly operate in open circuit. They also are operated in closed circuit with a vibrating screen, depending upon product requirements and conditions where the reduction ratio does not cause excessive power draw and build-up of circulating load. Screening ahead of secondary crushers is generally recommended, especially where the feed contains more than 25% material smaller than the desired closed-side setting. Tertiary Crushers These are cone crushers that normally take secondary crusher product and reduce it to a marketable product or make it suitable for subsequent comminution steps. The reduction achieved is a func¬tion of the crusher design and the properties of the material to be treated. The reduction ratio is normally in the range between 1.5 and 2 to 1, and seldom more than 3 to 1. The tertiary crusher normally operates in closed circuit with a vibrating screen and makes a product smaller than all passing &apos;h or 5/8 in. Fine Crushers Sometimes these machines are called sand crushers and are called by various manufacturer brand names, such as Gyradisc, Hydrofine, V.F.C., and others. A cross section of a Symons Gyradisc crusher is shown in Fig. 46. Essentially, these crushers would be used in a fourth-stage crushing operation, but could be called on to reduce a screened feed size fraction from a secondary or primary crushing operation. This type of crusher normally receives feed no coarser than 1&apos;h in. that is scalped of all over-sized material and operates in closed circuit with a vibrating screen. For average materials, typical product is &apos;/e in. top size, although a -10 mesh product can be produced on those materials having suitable characteristics. The crusher is nor¬mally operated in a separate circuit from the main crushing plant because of the variations in output rates that are caused by varying physical properties in the feed. The reduction ratio is generally less than 2:1, and circulating loads are generally high. More interparticle crushing takes place in these machines than with conventional cone crushers and capacities can be more sensitive to changes in moisture content, feed size graduation, and other physical properties. Design Features For the various applications, crusher manufacturers normally have a range of crushers of different sizes and power ratings to select from.

Jan 1, 1985

Remnants of Plio-Pleistocene hot spring systems in Northland, New Zealand contain sulfide minerals, principally pyrite, marcasite and cinnabar. The climate is warm temperate to subtropical, with up to 3 m of rainfall per annum, and rocks are deeply weathered. Decomposition of the iron sulfides in natural outcrops and human excavations results in acid rock drainage with pH typically between 2 and 5, and locally down to pH 1. Deeply weathered basement greywacke is clay-rich and has negligible neutralisation capacity. Some overlying volcanic flows have resisted weathering, and pH is kept near neutral by relict secondary calcite in small areas. Natural rainforest soils commonly have pH between 4 and 5 over mineralised and unmineralised greywacke. Mineralised zones are enriched in arsenic, which occurs in solid solution (up to 1 wt per cent) in sulfides and phosphate minerals. Mercury also occurs in solid solution in some of these minerals, as well as in cinnabar. Base metals are present in low (background) concentrations only. Decomposition of the iron sulfides and phosphates releases the solid solution arsenic and mercury into the acid rock drainage solutions. Arsenic is readily adsorbed on to iron oxyhydroxides formed in acid rock drainage situations, and can be effectively removed from the biosphere. However, this arsenic is released back into the environment if the pH rises, as adsorbed oxyanions become less strongly bound and are displaced by hydroxyl ions. Behaviour of dissolved mercury is similar to that of arsenic but less well understood in these settings. Both arsenic and mercury are readily leached into pH 6 solutions from solid material collected from acid rock drainage sites. These observations suggest that neutralisation of acid rock drainage sites is undesirable in this setting, as arsenic and mercury will become more mobile in the environment. The naturally low pH of 4 to 5 of the forest floor, or even lower pH of natural acid rock drainage, is a preferable management option.

Jan 1, 2003

By Andrew Cormier

"The Early YearsThe Grand Lake coal fields in New Brunswick undoubtedly can claim the distinction of being the first part of North America from which coal was mined and exported. The diaries of the Governor of Massachusetts during the first half of the 17th century clearly establish this fact. There is also a reference in the Massachusetts Colonial Records which indicate that coal exports to New England were carried on as early as 1639.It has generally been believed that Cape Breton mined and exported the first coal; but no account has yet been found to show that this took place earlier than 1676. Both at Grand Lake and Cape Breton the coal was near the surface and removed by hand.When the country passed entirely into British control, Joseph Garrison, a grantee of Maugerville in 1765 moved to Jemseg. While surveying the north side of Grand Lake he discovered outcroppings of coal on the shore of the lake and further inland along the banks of streams. It was he who named Newcastle Creek in reference to Newcastle in England, which was widely known for its coal mines. Joseph Garrison died in 1783, the same year that an influx of United Empire Loyalists increased settlement in Newcastle Creek in the area now known as Minto. Many Loyalists also settled on the shores on both sides of Grand Lake.At a number of points where streams cut channels through the overlying strata, the coal seams were exposed and it was at such outcroppings that the early operations were carried on. A tunnel was driven in the seam from the foot of the bank, affording both an outlet for the coal and natural drainage from the workings. The coal was loaded into boxes and wheeled over wooden tracks to a point on the surface where it could be dumped into wagons and hauled either direct to destination or to where it could be loaded into boats and conveyed via Grand Lake, Jemseg and Saint John river to points of distribution.In the latter part of the 18th century and first years of the 19th century, farmers were undisturbed by mining the coal found on their lands. This was soon to change and resulted in many years of contention between landowners and the Legislative Assembly.New Brunswick became a separate province from Nova Scotia in 1784 and the seat of government moved from Saint John to Fredericton in 1788. The new province had its first priorities; the establishment of counties, the building of roads, and the development of its natural resources. From 1805, records of coal and land development are fairly complete. These records show the increasing interest of the Province in developing the coal fields. This interest resulted in the granting of coal leases to many friends of the government, without any regard for the wishes of the farmers who owned and had occupied the land for many years. The farmers fought back with lawsuits and other forms of dissension but with little success. By the end of the 19th century there were very few farm operators left in the area."

Jan 1, 1992

By R Graber, R Johnson

North American steelmaking practices have evolved based on access to iron ore raw materials containing very low phosphorus contents, typically less than 0.025 per cent P. Cleveland-Cliffs managed Tilden iron ore operation produces iron ore pellets exceeding 0.030 per cent P, which by global standards would be considered low phosphorus, but has limited penetration in the North American iron ore market due to phosphorus content. Recently cathodoluminescence microscopy has augmented more standard ore characterisation techniques enhancing our understanding of the genetic history and process mineralogy of TildenÆs complex martite ore. This paper highlights the unique capabilities that cathodoluminescence microscopy provides for phosphorus mineral identification in fine-grained iron ores.

Jan 1, 2005

By G. R. Davidge

"Falconbridge Mine has a history of significant microseismic activity dating back to 1955. Since mid-1981, a microseismic monitoring system has been operating in the area around the No .9 Shaft hoist room located 25 m from the are zone at a depth of 1200m. Several mine wide faults dissect this area and have been shown to be microseismic-active due to mining. The microseismic monitor has been interfaced with a small dedicated personal computer and a communications device to perform routine data evaluation and to produce graphical output. The programs are described and selected result s from the monitoring program are presented.IntroductionFalconbridge Mine is located on the southeast rim of the Sudbury Basin. The nickel-copper sulphide ore zone is essentially a tabular orebody striking approximately east-west and dipping at 80 degrees north near surface and rolling to 75 degrees to 80 degree s south by the 1000 level. (Mine level number s represent the approximate depth in feet below ground surface .) This dip is maintained down to the 6000 level. The north wall is comprised of jointed norite and a faulted contact up to 1 m thick exists between the ore zone and the norite. The south wall rock is a greenstone with highly siliceous lenses and often has a faulted contact with the ore zone. No less than five mine wide faults exist, as shown in Fig. I.Mining ha s been carried out from virtually the bedrock contact to depths of 1830 m although the majority of current activity is between 900 and 1500 m below surface. A winze provides access below the 4025 level and the cage hoist room is located on the 3850 level in the north wall 25 m from the contact. Because of concern for the stability of this hoist room, there has been no mining activity within 60 m of the hoist room and by 1980 this block of ore was one of the major blocks of high-grade ore remaining in the mine . Mining of this block was originally scheduled for very late in the decade.Prior to a six-month shutdown in 1982, this mine produced approximately 450,000 tonnes of ore annually, mainly by cut and- fill techniques. Following the shutdown, annual production has been reduced to approximately 200,000 tonnes and production is now mainly by undercut and fill techniques .Mining-induced seismicity has occurred at Falconbridge Mine since at least 1955 and reviews of the microseismic problems for the periods from 1965 - 1970 and from 1971 to 1979 were made by Singh (1971) and Vongpaisal et al. (1980), respectively. The need for instrumentation was addressed by these authors. Following several large events during the spring of 1980, a decision was made to investigate existing microseismic monitors and to apply micro seismic monitoring techniques in Falconbridge Mine. Application of microseismic monitoring to Falconbridge Mine was to concentrate on the No . 9 Shaft hoist room area of the mine, particularly around the 4025 level where a large mechanized cut-and- fill stope was approaching this level. By mid - 1981, the microseismic monitor was fully installed and with in a year , a short-period seismograph and a personal computer had been added to the system."

Jan 1, 1984