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By Ibrahim Alp, Ersin Yazici, Oktay Celep, Haci Deveci

Low extractions (<80%) in cyanide leaching impose the application of physical and chemical pre-treatment methods (e.g., ultra-fine grinding, roasting, alkaline leaching) prior to cyanide leaching to achieve acceptable recoveries. The effectiveness of the selected pre-treatment method is linked intimately with inherent mineralogical properties of ore. In this study, a refractory silver ore assaying 145 g/t Ag was subjected to various pretreatment tests in an attempt to eliminate its refractoriness. Direct cyanidation of the ground ore (d80: 65 µm) produced a low silver extraction of only 29.5% over 24 h indicating its high refractoriness. Previous studies have shown that silver occurs mainly as Sb/As containing sulfide minerals such as pyrargyrite (Ag3SbS3), tetrahedrite (Cu12Sb4S13) and proustite (Ag3AsS3), which do not respond well to cyanide leaching. Also, silver-containing minerals are closely associated with and/or encapsulated in other mineral phases that can restrict the contact of cyanide with silver. Therefore, alkaline leaching (using 3 M of Na2S, NaOH or KOH solution) and ultra-fine grinding as pre-treatment methods were tested to improve the extraction of silver. All the alkaline leaching tests were carried out for 3 h at800C. Neither NaOH nor KOH leaching produced the desired effect on the extraction of silver (i.e., ~30%). Even, a sharp decrease in the extraction of silver (i.e., 10%) was observed in Na2S leaching. On the other hand, ultra-fine grinding (UFG) (d80: 3 µm) substantially improved the extraction of silver in cyanide leaching (95% Ag at 24 h after UFG). It can be inferred from these findings that the refractoriness of the ore is essentially physical in character (i.e. the encapsulation of silver presumably in non-sulphide minerals such as barite and quartz).

Jan 1, 2014

By E. G. King

Thermodynamic calculations involving the oxides of tungsten and molybdenum have been hampered by lack of accurate entropies and high temperature heat contents. This paper presents work by the Federal Bureau of Mines on new low-temperature heat-capacity data leading to the evaluation of the 298.15° K. entropies of tungsten dioxide and tungsten trioxide, as well as high-temperature heat contents (above 298.15° K.) of molybdenum dioxide, molybdenum tri-oxide, tungsten dioxide, and tungsten trioxide. Included are heats of fusion of the two trioxides. The heats of formation at 298.15° K. of these four oxides are tabulated as measured by Mah4 5/ of this laboratory. Included also are the 298.15° K. entropy of Mo02 measured by Kin 6/ of this laboratory, and that for Mo03 according to Kelley and King.7/ These basic data provide a consistent compilation from which to perform accurate thermodynamic calculations involving these compounds. No previous low-temperature- heat-capacity measurements have been reported for tungsten dioxide. Seltz, Dunkerley, and DeWitt8/ measured the low-temperature heat capacity of tungsten trioxide. The only previously-reported high-temperature heat-content measurements for any of the oxides were conducted by Cosgrove and Snyder,9/ who measured molybdenum trioxide to 1,300° K.

Jan 1, 1960

By Valdeci Paula Alvarenga, Sergio Luiz Costa, Itavahn Alves da Silva, Filipe Bueno Carvalho, Varadarajan Seshadri, Carlos Antonio da Silva

Use of fluorspar in steel refining operations is one of the environmental concerns and as such reduced consumption of this material or substitution of the same is one of the objectives. Industrial runs were carried out at Aperam Steel making convertor unit (Timóteo, MG, Brazil) using recycled/briquetted slag for partial or complete substitution of fluorspar. Samples were collected from the metal bath and slag after oxygen blowing to assess dephosphorization with several combinations of recycled/briquetted slag and fluorspar. The results showed that partial substitution of fluorspar by BOF slag briquettes did not affect the efficiency of dephosphorization. In general average Phosphorus content was reduced to 0.010% in the case of partial substitution compared to 0.016% in the regular refining procedure with no substitution. This replacement also resulted in 40% reduction of the fluorspar consumption in the converter

Jan 1, 2015

By William C. McBee

Specialized sulfur concretes were developed by the Federal Bureau of Mines as a result of research for the beneficial utilization of sulfur in construction materials. Materials were developed for use in acid and salt corrosive environments where portland cement concrete has been found to deteriorate. Because the mineral aggregates also come into contact with the corrosive media, concretes were developed utilizing both limestone and quartz aggregates. The sulfur binder used with both aggregates was modified by reaction with 5 pct dicyclopentadiene to improve product durability. Sulfur quartz aggregate concrete was found to have moderately high strength characteristics (6,000 psi compressive) and was extremely resistant to chemical attack by both acid and salt solutions. Sulfur limestone aggregate concrete exhibited very high strength characteristics (9,000 psi compressive) and was extremely resistant to chemical attack of salt solutions. Both types of concretes maintained their strength and integrity after long-term testing in acid and salt solutions and exhibited considerable resistance to damage by the action of freezing and thawing. Potential uses include leach tanks, electrolytic cells, thickeners, bridge decking, industrial flooring, pipe, and tile.

Jan 1, 1979

By J. W. Kramers, R. A. S. Brown

"Samples from seven test wells distributed throughout the surface-mineable area of the Athabasca Oil Sands have been evaluated to determine the amounts of heavy minerals present and the titanium and zirconium contents. The samples were treated to yield the size distribution of the titanium and zirconium minerals as well as their spatial distribution. The study has shown that heavy minerals are found throughout the surface-mineable area; concentrations range from 0.24 to 2.29 per cent (by weight), with a mean of 1.02 per cent. Titanium and zirconium contents vary throughout the area, and are found preferentially in the finer size fractions. •on the basis of preliminary calculations, the tailings streams from an oil sands plant would provide sufficient feed for a large-scale titanium pigment plant, and the tailings from one plant would provide sufficient zircon feed to satisfy Canadian demand for. metallic zirconium. Variability of the heavy mineral content and composition is such that the heavy mineral potential must be evaluated in detail for each mine site."

Jan 1, 1976

By P. West-Sells, B. Wassink, N. Fisher

Gold leaching from a commercial cyanide-amenable gold ore was studied at 25°C using sodium bisulfide-hydrogen sulfide solutions containing elemental sulfur. Gold extraction from the ore using 0.55 M NaSH, 4.1 atm (60 PSI) H2S, 1 g/L S8 and 26% solids by weight was about as good as the best extraction obtained by cyanidation. Maximum extraction was achieved in roughly 48 hours. Sulfur dissolves in the bisulfide solutions to form a mixture of polysulfides. Simple speciation calculations indicate that gold solubility as bisulfide complexes should be roughly ten times higher than in the absence of added zerovalent sulfur. The principal bisulfide complex is believed to be [Au(HS)2]-. Gold dissolution is favoured by increasing HS- concentration and by increasing H25 pressure. Polysulfide complexes of gold are also likely to be formed, and may contribute substantially to gold leaching. Two experiments using pure gold were also performed. Up to 100 mg/L gold was dissolved in 140 hours using 0.55 M NaSH, 1 g/L added elemental sulfur and 6.2 atm H2S.

Jan 1, 2005

This list is part of the long-range conservation program of the Bureau of Mines and is intended for use by those interested in the Bureau&apos;s publications dealing with oil shale and shale oil. The items included represent 51 years of research by Bureau of Mines employees on oil shale and shale oil and are available at any U.S. depository library. DISTRIBUTION U.S. Bureau of Mines report series contain both free and sales publications. An asterisk (*) designates publications for sale. Such publications can be obtained from Superintendent of Documents U.S. Government Printing Office Washington, D.C. 20402

Jan 1, 1969

By O. B. Bucklen

The Coal Research Bureau of the School of Mines at West Virginia University, using a modified design of a Russian flotation device, was able to obtain a clean coal product containing 7.64 percent ash with 94 percent yield and 97 percent coal recovery. This favorable performance was obtained with the semi-pilot scale flotation cell operating as a simulated three stage unit on slurry taken from the fine coal circuit of a coal preparation plant. This experimental device, consisting of a sheet metal cyclone-like unit mounted on a U-shaped uplift pipe, uses a combined flotation and cyclone action to beneficiate the minus 14 mesh partially cleaned feed product. In addition to providing comparable analytical results, the airlift-cyclone possesses other attractive features among them being a low capital expenditure, utilization of moderate plant floor space, efficient "operation on high density feed slurry, and absence of moving parts.

Jan 1, 1964

By R. C. Bates

Uranium mine workers? daily exposure to radon daughters was estimated by two methods of sampling, detailed and spot-check. Both methods involve time- weighting measured exposure levels to arrive at an average exposure figure. Random sampling, or sampling without regard for the duration of exposure, has proved inadequate for estimating average exposure levels. During the first phase of the study, the breathing zones of eight workmen in three underground uranium mines were sampled for an entire shift; 20 to 36 radon-daughter samples were collected per man-shift, Analysis of these data indicated that a suitably accurate estimate of the full-shift exposure could be made by time weighting a considerable lesser number of representative radon-daughter samples. This analysis led to the spot-check method of estimating full-shift exposures to radon daughters. Additional detailed studies were made in seven mines to Learn more about the full-shift radon-daughter exposures and to test the spot-check method, In all, 617 radon-daughter samples were taken in 10 underground uranium mines during 26 man-shifts, and the spot-check method was tested 35 times.

Jan 1, 1962

By Carolina Conter Elgert

A influência dos parâmetros termomecânicos e da adição de elementos microligantes na relação processo, microestrutura e propriedades de chapas laminadas, do aço DIN 20MnCr5 foi o objetivo de estudo deste trabalho. Os testes foram desenvolvidos em escala piloto, no laboratório de processos metalúrgicos do IPT. Foram testadas variações de composição química, condições de laminação e taxas de resfriamento. Ocorreu alongamento dos grãos austeníticos para os materiais processados por laminação termomecânica e refino de grão e aumento de limite de escoamento para os aços microligados, tanto na condição de laminação convencional, quanto na condição de laminação termomecânica.

Oct 30, 2017

By R G. Jeffrey

The Northparkes, Endeavour 26 orebody is a porphyry copperûgold deposit and comprises a moderately to well jointed rock mass characterised by gypsum veining, the intensity of which decreases with depth. The top 480 metres of the orebody is currently being mined by block caving, the undercut dimensions measuring 196 metres in length by 180 metres in width. Continuous caving was never achieved after the completion of the undercut thus cave inducement techniques were sought to maintain caving so as to safely sustain production. The use of hydraulic fracturing as a cave inducement tool was successfully trialled in December 1997 using existing exploration boreholes located midway up the current lift. Subsequent fracturing campaigns have enjoyed various degrees of success and have yielded in excess of seven million tonnes of ore at a significantly lower cost than conventional cave inducement techniques. Monitoring of both the hydraulic fracture system and the rock mass response has provided considerable insight into the geometry, growth and influence of hydraulic fracture networks above the Northparkes block cave, and has initiated additional research into the use of hydraulic fracturing in other mining methods.

Jan 1, 2000

By Eustaquio Vieira Junior

O Alto-Forno 2 da thyssenkrupp CSA, no Rio de Janeiro, iniciou sua primeira campanha em 16 de dezembro de 2010. No decorrer de sua campanha, verificou-se problemas de deslocamento de staves de ferro fundido, deformação dos staves de cobre e desgaste acentuado do refratário do top cone. Na análise dos eventos adotou-se a inspeção por vídeo endoscopia e em seguida foram tomadas algumas ações para recuperação e preservação do Alto-Forno 2, sendo estendidas também do Alto-Forno 1. Dentre as ações de preservação dos Altos-Fornos destaca-se a projeção robotizada de material refratário, shotcrete, visando reduzir o desgaste acentuado dos staves e deterioração de suas tubulações de refrigeração. O trabalho apresenta o detalhamento das técnicas utilizadas e seleção de materiais assim como os preparativos operacionais que garantiram o bom desempenho do Alto-Forno 2 nos momentos que antecederam a parada e após seu retorno à operação, mostrando que a atividade é viável do ponto de vista técnico e financeiro.

Oct 30, 2017

By J. Douglas Causey

No mines are active in the Hunter Mountain Wilderness Study Area (WSA), and no mineral resources have been identified in the WSA. However, the Monarch Mine has low potential for silver, copper, tungsten, and gold resources in quartz veins; the Shirley Ann Group and Sal Group have moderate and low potential, respectively, for silver, lead, and copper resources in skarn; claims overlying the Eureka Quartzite have low potential for silica resources; and the Tourmaline N1-4 Prospect has low potential for tourmaline resources in quartz monzonite. Copper, lead, silver, tungsten, molybdenum, wollastonite and garnet occur in skarn zones between monzonitic and carbonate units. Silver, tungsten, and copper also occur in quartz veins within monzonite. Known metallic mineral deposits are small, erratic and discontinuous. The J. 0. Mine, adjacent to the northeast corner of the WSA, may contain as much as 26 million tons of subeconomic wollastonite resources. The crest of an open pit to produce that resource would extend into the WSA. No information exists on geothermal potential because no exploration has been done in the area. No occurrences of energy minerals are known within the WSA.

Jan 1, 1983

By T. E. Bernard

The CO2-absorbent canisters used in four approved rescue breathing apparatus were investigated. A breathing machine was used to simulate human expiration with gas flow rates of 26, 37, and 48 1/min of 3.5% CO2 in air. The exit gas CO2 concentration, the pressure drop across the canister, and the exit-gas temperature were monitored. The absorbent capacities of the packed-bed canister designs were found to be dependent on flow rate within the range studied, while the capacities of the other designs were less affected. The radial canister had the least resistance to breathing while the complex bed design proved to be the most effective in utilization of the chemical. The overall results indicated that LiOH (lithium hydroxide) has the highest capacity for CO2 absorption among the absorbents tested. It can be used in a simple packed-bed design while maintaining acceptable levels of resistance and exit-gas temperature. Examination of oxygen supply with respect to CO2-absorption capacity suggested that it is desirable to closely match CO2-absorption capacity with the avail-able O2 supply to minimize the size and weight of rescue breathing apparatus.

Jan 1, 1979

On Dec. 20, 2013, an 8-m (26.2-ft) diameter Robbins hybrid single shield/earth pressure balance tunnel boring machine (EPB TBM) was launched to bore the Grosvenor decline tunnel for Australia?s Anglo American coal mine. The machine was built using onsite first time assembly (OFTA) in order to fit within a tight project schedule. Assembly at the remote jobsite near Moranbah, Australia took about four-and-a-half months, and then the machine was walked down into a launch tunnel. Two decline tunnels, at grades of 1:6 and 1:8, will be used for mine access to new coal seams. The hybrid machine is tackling mixed ground conditions ranging from sand and clay to varying types of sedimentary hard rock up to 120 MPa UCS, as well as coal seams. Methane gas is expected to be present throughout the tunnel, so the machine has been designed as explosion-proof-compliant to ERZ-1. ?Grosvenor is the first underground coal mine in Queensland to use a TBM for drift construction,? said Glenn Tonkin, Grosvenor project director. ?We are proud to be pioneering this technology.? Only about 300 m (984 ft) of ground in each decline tunnel is expected to require EPB mode, while the rest of the tunnel will be bored in hard rock mode. Thus, the design was optimized toward hard rock excavation.

By Vinicius Oliveira dos Santos

Este trabalho tem como objetivo estabelecer um quadro comparativo – baseado na literatura científica vigente – entre o comportamento mecânico sob irradiação neutrônica dos Aços Inoxidáveis Austeníticos e as ligas de Zircônio empregados ostensivamente em componentes estruturais de instalações nucleares, como reatores e submarinos. O conhecimento do dano induzido pela irradiação nos materiais é de fundamental importância para os projetos de engenharia para minimização das probabilidades de risco de acidentes.

Aug 8, 2018

By W. K. Katoto

The Tailings Leach Plant (TLP) of the Zambia Consolidated Copper Mines Ltd at Nchanga was commissioned in 1974 as the world&apos;s first largest successfully operated agitation leach SX-EW plant for copper production. The design, development and operation of the plant soon after commissioning termed as TLP stage II has been described by Holmes et al (1). In the initial phase the plant was designed to treat approximately 25,000 tonnes per day of current flotation tailings from the Nchanga Concentrator operations, and had a design capacity to produce 75,000 tonnes per annum of copper. Further expansion took place in 1986, and TLP stage III was successfully commissioned to treat an additional 20,000 -25,000 tonnes per day of large reserves (over 135m tonnes) of reclaimed tailings stockpiled since the early 1930&apos;s in four paddock type tailings dams (T01 to T04). The salient feature of TLP stage III expansion described by S K Mwenechanya et al (2 -3) was the installation of the world&apos;s largest Horizontal Belt Filter Plant with 26 filters each of 80 m2 filtration area.

Jan 1, 1996

By N. Wahl, D. M. Blackketter, R. Thornton

This paper evaluated using a water-filled abandoned mine (Orphan Boy) as a heat source for a 240- kW closed-loop heat pump with the goal of heating a 2,000-m2 building. The mine has a 245-m vertical shaft connected to a large stope by three horizontal cross-cut shafts. There is 1,250 x 106 L of water at a consistent temperature of 24-26° C that is available mostly in the stope. The only heat exchanger placement option is in the vertical shaft. Therefore, the focus was to model heat exchanger placement in the vertical shaft to determine the extent to which the systems will induce thermal currents between the stope and vertical shaft. Modeling of thermal currents, temperature profiles and heat contribution from the ground was done using finite difference and computational fluid dynamics. An optimal configuration was determined showing sufficient water movement and heat transfer will occur with a low water temperature in the shaft above 20° C. This project supports a U.S. Department of Energy (DOE) grant that will implement the full-scale system.

Jan 1, 2013

By Pedro Hugo Tumialán

El presente artículo señala la aplicación del zoneamiento en yacimientos hidrometales en el Perú. Para ello, se realiza una variación de leyes en una estructura mineralizada y se describen los resultados en la mina de Ocoña (Arequipa), Pasto Bueno (Ancash), Compañía minera La Virreyna, San Genaro (Huancavelica), Mina Madrigal (Arequipa), Patricia (Recuay- Ancash), Mina Pacococha (Lima), Huarón (Cerro de Pasco) y Sayapullo (Cajamarca).

Nov 1, 1983

Projections of coal reserves in Central Appalachia are essential for long-term planning in the region. Annual production is declining in some states, such as Virginia, and mineable reserves for the Central Appalachian Coalfield are challenged by difficult geological, mining, and market conditions. In order to project coal mining longevity in this region, interviews with mining companies were conducted to assist in the determination and assessment of technical and economic factors that impact coal seam mineability. This information was applied to seam and coal reserve data developed by state and federal governments. The results were carefully analyzed to determine the effects of various factors on the overall mineable coal reserve base.

Jan 1, 1998