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By T. K. Mukherjee, C. K. Gupta

"The importance of the processing of secondary resources such as solid industrial wastes and liquid effluents as well as byroducts for the recovery of the associated metal values hardly needs any elaboration. Such processing contributes in no small measure towards the augmentation of the availability and the supply position of resources. As an added benefit, it leads to a reduction in environmental pollution caused by the undesirable waste materials. As some typical examples of secondary resources in the Indian scenario, mention can be made of spent catalysts, metal/alloy scrap, ash, consumed batteries, flue dust, slag, sludge and slime, pickling solutions, spent acids, plating rinse solutions, spent etchants, waste water from synthetic fibre manufacture and from tanneries etc .. These wastes constitute a source of a variety of non ferrous metals. In the processing of secondary resources like these, the techniques of hydrometallurgy such as solvent extraction playa pivotal role.This paper outlines the efforts made to use solvent extraction to recover (1) base metals such as copper, zinc, nickel and cobalt from a number of secondary resources like cake, and sludge (2) refractory metals like molybdenum and vanadium from sulphidic byproducts and spent catalyst and (3) nuclear metal like uranium from phosphoric acid. In the case of base metals, process flowsheet involving the use of acidic extractants such as DEHPA and PC88A have been optimised. The problem of iron removal from the leach liquor, which influences the metal recovery process significantly, has drawn a special emphasis. In the case of refractory metals, basic extractants like Alarnine 336 has been pressed into service to produce kilogramme quantities of pure salts of molybdenum and vanadium. Finally, the paper gives a brief account of plant experience in recovering uranium from phosphoric acid, using a solvent system comosed of DEHPA and TOPO."

Jan 1, 1996

By Graham W. Marks

The general positions of the absorption maxima of aqueous solutions of the violet and green isomers of chromic sulfate the visible spectral region have long been known, but, to the knowledge of the writer, no comprehensive studies have ever been made. To gain further knowledge concerning these inorganic complexes and to investigate the possibilities of developing an analytical method for determining the concentrations of the violet and green isomers in a mixture, a more complete investigation was made in the spectral range from 325 to 850 millimicrons.

Jan 1, 1951

By Michael S. Moats, John Bailey Fletcher

The performance of grinding media can be misrepresented in marked ball wear tests due to galvanic interactions between dissimilar media. The possible galvanic interaction of media materials during marked ball wear tests has not been adequately explored. Corrosion rates and potentials of modern high carbon steel and high chromium white iron grinding media materials were measured using electrochemical testing as a function of pH and chloride content in a simulated mill water. The results replicate previous research with the high chromium white iron sample being more noble (higher corrosion potential) and corrosion resistant (small corrosion current) than high carbon steel. Using the experimental data and corrosion theory, the effects of galvanic coupling on corrosion rates were calculated to examine what could happen during a marked ball wear test or when a mixed media charge is present. This analysis indicates that high carbon steel can cathodically protect high chromium white iron leading to significant decreases in the corrosion rate (up to 99%) of this material during marked ball wear tests. The magnitude of the protection is a function of the pH of the mill water.

Dec 21, 2022

By J. Koster

[In lQ jG thc E'lcct,ro:~(: L7.l :~u..-ic:ll S;%cti ?n of t?c :I. tcIl~tr,-;lcal 3:vi cioa, ?U~CE~U of lv!irtos, bc,~m an 9.ct iv.t In-:?*t ik7;5i GI of r.:ct.l-;c?;is for rccovcrin,; niclrel, cop?ir, an2 ?? cciou:; ~ot-1 c 1;-on or; :; of tile 3unl~crvi~.l~~ tiistrict in C1ni.k Coult:r, !Icl.r. ]

Jan 1, 1939

By J. Koster

[In 1178 thn S-00n of thr !~Viluralcal Divicion, pur--'11 cf Mines, bcran an o. 't iv in': n-t!Y_Vnn of vothod; for recoverin'-1, Achol, copp~r, nK precioun notnin Zycn o;. -z of tic Bunkcrvillo KOH& in Clark County, Tcv. Tho Bunkcrvillo ran arc of t,-j)(,e of -iincrilization similar to that of 02 SWbury, Ontario, CannO, nichvl dc-?o?-:.t,. At prcoont, only n anall tonnes? p of ore has loan cxDr)scd in t*ic' :hui:er7ilIp rc: inn, ann. there is decided nce! for orjn: izod OrospectiAg ina drvclo-nnnt "crk there. It wann believod, howevar, t4it the dc,cuits varo 3ilficUntly siSnIficant to warrant an investigation iito their]

Jan 1, 1939

By Charles E. McCarthy, MORTON T. PAWEL, E. A. GEE, FRANK S. RIORDAN

Large tonnages of the magnesium silicate mineral , olivine, are known to exist in the mountains of western North Carolina and in the Puget Sound region of Washington. The North Carolina deposits alone are reputed to contain at least 230 million tons of ore averaging 45 to 49 percent of magnesium oxide In both areas the mineral is readily accessible and can be mined by the simplest methods ; one of the largest of the Washington deposits is located at tidewater .

Sep 1, 1946

[A Editor's Note: Annual Reviews of various subjects and areas are found in February issues of Mining and Metallurgy and Mining Engineering. These Annual Reviews are not listed per se in the Index. Abating Stream Pollution in Anthracite Coal Fields. ME Mar 50 Abbadia San Salvatore mine, Italy. T178, 297 Abbott, C.E.: Limestone Mine in the Birmingham District. With Discussion. T129, 62 ABC Typifies Trend to Mechanized Mining and Coal Preparation. ME Dec 50 Abel, J.F.: Statistical Analysis of Tunnel Supporting Loads. T235, 288 Sulzbach, J. F., and Walker, D.K.: Ice Tunneling in Greenland. ME Jun 59 Aberfoyle tin mines, sphalerite, chalcopyrite, stannite, as intergrowths. T214, 1147 Abnormal Behavior of Some Ore Constituents and Their Effect on Blast Furnace Operation, The. T241, 1 Abrams, C.J.: Industry's Responsibility in Postwar Economy. M&M Mar 45 and Haley, D.F.: History of Crushing and Milling at Climax. M&M Jun 46]

Jan 1, 1972

By Sib N. Mukherjee

Main ventilation fans are used in all the mines and they run continuously 24 hours a day and 365 days in a year. Any improvement in their performance can lead to considerable power saving. The basic principle for selection, operations, and related measures are discussed in brief in the paper. The contributions of different elements of mine fan on its performance are discussed in brief. The means to improve efficiency of a running fan is also discussed and the importance of saving even 1 Kwh is elaborated. It is found that the cost of the energy saved may even permit a replacement fan to be procured in a few years time.

May 1, 2007

By Jian Li, Guo Chen, Bingguo Liu, Hongying Xia, Jinhui Peng, Libo Zhang

"Decomposition of ammonium tetramolybdate to prepare Mo03 using silicon carbide crucible in microwave fields was investigated. The results were analyzed Using TG-DTG and X-ray diffraction. Meanwhile, the effects of heating rat, material thickness, socking time, socking temperature on the structure of preparing Mo03 were studied. TG-DTG curves show that the decomposition process of ammonium tetramolybdate is only one stage, in the temperature range 300-350°C, whose begin to decompose when temperature increases beyond 300°C. The molybdenum trioxide was prepared by thermal decomposition. The quality ofMo03 was not affected under the heating rat is 12°C/min. It was beneficial for decomposition ratio with the lower material thickness, longer soaking time, and higher soaking temperature. XRD curves showed that it is viable method for preparation of Mo03 by decomposition from ammonium tetramolybdate in microwave fields.IntroductionMolybdenum is widely used in national defense, aviation, industrial and agricultural production as rare refractory metal. Molybdenum trioxide is vital raw materials for the process of preparation of molybdenum. The traditional production technology of molybdenum oxide is that ammonium tetramolybdate is calcined in rotary kiln or 4-tube furnace [J,2J. But the longer production time, the higher production cost, the lower furnace thermal efficiency, and bigger the energy consumption, especially the powder is easy to leak, the working environment is poor by using rotary kiln [ 3 l _ The particle of molybdenum oxide is non-uniform by using 4-tube furnace because of the uneven temperature of every tube and the poor exhaust of boat bottom [4l _ However microwave heating is quick and uniformity, it is a meaningful research that the microwave is used in the process of calcining ammonium tetramolybdate."

Jan 1, 2013

By H P. Rossmanith

This contribution addresses the advanced blasting technology which is based on wave propagation theory and fracture mechanics. The new concept of sonicity and the principle of maximizing sonicity in blasting as well as the energy or work of a blast operation will be introduced. It is shown that - in contrast to common belief – it is not the velocity of detonation which controls the blast but the relationship between velocity of detonation and the wave speeds, in other words, the Mach numbers of the blast operation. Based on numerous practical blasts in Germany, the authors show that, when using wave dynamic concepts, there is a linear relationship between peak particle velocity and the work of a blast operation and this linear relationship is controlled by the sonicity of the blast. Extensions to layered and faulted rock masses are presented. It will become clear that a second change of paradigm is enforced, the first one being the implementation of short time delaying. Again, the acquisition of knowledge in wave progation theory and fracture mechanics becomes mandatory in advanced blasting technology, where the art of blasting is now fully transformed into a science of blasting with little room for methods of trial and error.

Jan 1, 2010

By Per Hedvall, Jan-Eric Ståhl

"The main objective of this study is to introduce the new Sandvik’s production cost-model within Crushing & Screening (C&S) technology. So far, there have been different ways of determining different production costs in the industry, however, the previously published and presented methods have not been very efficient in calculating the costs per product and metric ton. Accordingly, the current study has been planned and started in collaboration with Lund University to provide an accurate and easy to implement cost estimation program to determine the costs for crushing and screening plants worldwide.The proposed model has been adapted to fit the C&S processes of different rocks/ores fractions. The result is presented as cost per ton of the end product(s).Within this paper the cost estimation results for 3 different crushing and screening plants are presented based on the information obtained from the following sources: a) documents at Sandvik SRP, b) Sandvik’s crushing & screening internal/external machines/plants data and information, c) literature studies, including the use of Sandvik’s internal/external simulation and software programs, d), visiting the crushing and screening plants ,e) interviews, information systems’ data, and, f) testing and observations by ourselves.In order to improve the level of accuracy and the validity of the attained results, simplistic Monte-Carlo simulations have been used, where needed. The achieved results, so far, have proven the reliability of the model. The calculated cost estimations have shown an accuracy over 80% when they compared with real cost data obtained from plant practices.The current cost calculation model, will offer the possibility of:•,Calculating the production costs in proposed and/or existing C&S plant.•,Making detailed cost analyses for the end product(s) in proposed and/or existing C&S plants.•,Determining the profitability of each finished product when it’s required.•,Cost optimization by potentially cutting the cost for part of C&S plant with an existing plant practice"

Jan 1, 2016

By A. Koning, P. Lauzon

Pressure hydrometallurgy operations require vessels to be lined with an impermeable membrane for corrosion protection and one or more courses of refractory or ceramic brick. Examples of unit operations that utilize composite lining systems include pressure oxidation autoclaves, sulphide precipitation autoclaves, chloride leach reactors, flash vessels, cyclone separators, and direct contact condensers (heater vessels and quench vessels). The refractory lining must satisfy multiple requirements: it must thermally insulate the membrane from process fluid, be structurally stable, provide erosion resistance, be chemically compatible with process fluid, and provide an economic service life. New hydrometallurgical processes are pushing the pressure, and temperature, with each new generation of plants. A fundamental understanding of all factors affecting the mechanical stability of the lining system is essential as lining designs move further away from the industry's experience base. The impact of irreversible chemical swell, operating factors, design factors, and installation factors are presented based on modifications to the traditional one-dimensional mechanical stress model. A new stability criterion - that the brick lining remain in contact with the steel shell membrane - is presented. This new stability criterion imposes new restrictions on the lining design.The effect of geometry and adding additional degrees of freedom to the analysis is explored using two-dimensional and three-dimensional Finite Element Analysis (FEA). The effect of these additional degrees of freedom on the results of the one-dimensional model are discussed.

Jan 1, 2004

By Alfred L. Anderson

Thorite and rare earth deposits in the Lemhi Pass area of southeastern Lemhi County, Idaho, are contained along complex shear and fracture zones and in reopened gold-quartz veins and copper lodes in quartzitic and phyllitic rocks of the Pre-cambrian belt series. Some of the shear and fracture zones are several tons of feet across and comprise broad zones of irregularly mineralized rock. These lodes contain a notable concentration of thorium and rare earth elements along with considerable amounts of barium, .potassium, calcium, iron, aluminum, phosphorus, sulfur, and silicon. The principal minerals are thorite, locally allanite, monazite, xenotime (?), apatite, specular hematite, barite, potash feldspar, occasionally calcite and quartz. Exept for some of 'the specular hematite, barite, reddish feldspar, calcite and quartz, the minerals are not distinguishable without the microscope. The thorite and locally allanite were deposited first, then the monazite and other phosphates, which were in turn followed successively by barite, potash, feldspar, calcite, and quartz. In exceptional cases, deposition of thorite and specular hematite was repeated after the feldspar. Some of the deposits contain several percent thoria, but the average os generally under one percent. The rare earth content is comparable with that of the thoria. The deposits appear to be of hydrothermal origin and are probably related genetically to late Cretaceous or early Tertiary igneous activity, manifested locally by a few dioritie and lamprophyric dikes.

Jan 1, 1959

By T. R. A. Davey

The technologies of lead, zinc and tin extraction have made varying degrees of progress over the past twenty years. Producers of all metals have faced increasing demands for reduction of pollution and environmental degradation, and the level of public concern is rising rather than abating. New processing techniques must therefore be not only economically feasible, but politically acceptable, even when the demands of "conservationists" and ?environmentalists? are unreasonable. A new generation of processing techniques has come into being, which do not rely on an expensive sintering stage, nor use metallurgical coke, which is difficult to make without serious pollution. They utilise intense reactors, conveying materials from one stage to the next preferably within an enclosed space, obviating fume emissions, and avoiding heat losses as far as possible. The acceptability of the new techniques? is increased if lowgrade or complex materials can be treated, along with a variety of returns and wastes. In addition, a good selling and servicing organisation seems to be as important as good process technology in determining the spread of the new processes. In the field of pyrometallurgical refining the need is for more general application of several recently developed techniques rather than a search for alternatives to the existing process technologies. However, there is a need for fundamental work investigating the phenomenon of oxygen anode overvoltage in the electrolytic zinc process, in order to make progress in the further reduction of energy consumption. There is also scope for further development and application of vacuum distillation to up-grade thermally produced zinc. This paper presents a personal view of processes which should be developed to overcome existing problems, as we approach the turn of the century,

Jan 1, 1990

By H. R. Shell, Robert C. Johnson, Wilbur H. Warwick

Alpha silicon nitride fibers , Si3N4 , were successfully grown in graphite crucibles by a new method utilizing silicates and silicon ( S in equations below) as sources of silicon and using carbon , aluminum , and silicon as reducing agents (R in equations below ) . The basic reaction mechanism is believed to be generally as follows : 1,300 - 1,500 ° C S + R + N₂ SiO + RO + N₂ › 3Si0 + R + 2N₂ _1,300 - 1,500° C 3RO + Si¸N • ( 1 ) ( 2 ) A build - up of coatings on the solid raw- material particles hindered the evolution of silicon or silicon monoxide vapor and thereby slowed down further formation of silicon nitride fibers . Free oxygen in the crucible caused the formation of amorphous silicon dioxide ( SiO2 ) fibers . This problem was solved by passing , entering , and exiting gases through layers of lump graphite inside the reaction vessel . The silicon nitride fibers grew best around 1,400 ° C. Nitrogen flow rates from 4 to 6 liters per minute were adequate . The fiber widths were generally only a few microns whereas their lengths sometimes reached one - quarter inch or more . Chemical and X- ray analyses indicated that bulk fiber samples were usually 80 to 90 percent Si3N4 . The fibers had good oxidation resistance to about 1,260 ° C. Thermal shock resistance was excellent . Electrical resistance was determined .

Jan 1, 1964

By John K. Alley, Robert C. Johnson

The primary objective of the research was to grow aluminum borate whiskers or fibers and to determine their properties . Molten salt bath and vapor deposition methods were used for synthesis . Whiskers exceeding 25 mm in length were grown . The best results were obtained by vapor deposition and most of the data presented were determined on whiskers produced by this method of synthesis . Three different aluminum borate compositions ( 4.8A1203 B₂03 , 3.8A1203 B203 , and 2.5A120, B203 ) were identified by X- ray and chemical analyses . The aluminum borates 4.8A1203 B20, X- ray diffraction pattern was indexed . Optical data were obtained on the three aluminum borates . In addition the following whisker properties and growth factors were determined : ideal atmospheric dewpoint for vapor deposition method , near 65 ° F ; temperature range of whisker formation , 1,000 ° to 1,400 ° C for the molten bath method of synthesis , > 1,000 ° to < 1,400 ° C for the vapor deposition method ; whisker growth rates by the vapor deposition method , maximum 12 mm per hour ; raw material vaporization , 50 to 60 percent of the fluoride lost in 1 hour ; tensile strength , maximum obtained 174,162 psi ; melting points , ranged from 1,675 ° to 1,795 ° C.

Jan 1, 1965

By M. A. Upham

"MINING is Canada's second largest basic industry, producing material with a gross value of 2.5 billion dollars, led only by agriculture with 2.9 billion dollars. It pro-vides employment, directly and in-directly, for three quarters of a million people. Since the Second War, the value of mineral production in Canada has tripled. Economists forecast that over the next 15 years its value will triple again. Canada is a basic and leading supplier of nickel, iron, copper, zinc, lead and uranium. It is also a major oil producer, leads the world in the production of asbestos and in five years will be the leading producer of potash, a basic constituent of fertilizer.It can be seen that Canada's wealth and economic progress lies in being a primary producer of economic minerals and in building secondary industries to manufacture finished products from these raw materials. Canada's future in the field of mineral production looks bright, with our resources just starting to be tapped. Outside of the large expanse of Soviet Russia, we are by far the world's most fertile mineral exploration area."

Jan 1, 1967

By Colin Dessemond

Since 1950, the traditional process has been dominating the production of lithium compounds from spodumene ores to sustain the lithium market because of its economic viability and the markets need for technical grade (99.5% purity) product. This traditional process includes thermal conversion, acid roasting and lithium leaching. However, this process has not been challenged and very few studies have tried to explain its limitation (95% lithium yield) or optimize the thermal treatment. Here, α to β spodumene conversion and lithium extraction were performed in a rotary kiln on a 2 mm to 2 cm spodumene concentrate instead of a micrometric one using a 1050 °C, 30 min conversion treatment and 250 °C, 30 min, 30% H2SO4 excess leaching treatment. X-Ray Diffraction analyses were performed on the converted material to determine the conversion rate by Rietveld analysis. It was observed after thermal treatment that the α-spodumene particles fractured and divided while the impurities remained compact. A sifting was performed after thermal treatment and it was determined that 65% of the initial mass became finer than 180 μm. X-Ray diffraction analyses and lithium content measurement were performed on both fractions and it was determined that the finer fraction had a very high lithium content of 3.24 wt%. Lithium extractions were performed on both fractions separately. While the coarser fraction’s lithium yield was only 61% the finer fraction’s lithium yield went up to 99% without any additional treatment. These observations may open more economical ways for the traditional process by potentially bypassing two third of costly steps such as grinding.

By K. C. Dean

A semiquantitative test for the presence and identification of cesium and rubidium in rocks, clays, and mineral waters has been developed by the Bureau of Mines. The test can be used in the field, as a guide for the prospector, geologist, or mining engineer engaged in location or development [w]ork. It comprises two simple spot tests of a solution prepared from the [m]ineral sample. Phosphomolybdic acid, added to a drop of the test solution, [d]etects cesium, rubidium, and potassium in quantities as low as 60 parts per [m]illion. Silicomolybdic acid, added to a second drop of test solution, enables the operator to distinguish between cesium and/or rubidium and potassium. Test procedures, equipment requirements, and limitations of the method are described in this report. Cesium and rubidium were discovered in 1860 and 1861 by Bunsen and Kirchhoff with a spectroscope. The elements usually occur together, particularly in granite and granitic pegmatites. Rubidium does not occur as an essential constituent of any known mineral, yet it is found as a minor element in so many minerals that rubidium is 16th in abundance in the earth&apos;s crust. Cesium, which ranks as the 37th most abundant element, is the principal component of pollucite and a minor element in a wide variety of minerals.

Jan 1, 1960

By A. J. Ren

The ore, dealt with in this paper, is a certain rutile in Shanxi province, China. A trunk flowsheet with gravity concentration is used, and the TiO2 grade of rutile concentrate is about 90%, but the TiO2 recovery is less than 50%. In order to increase the rutile recovery, the laboratory test, using the truck flowsheet with flotation, is carried out. The flowsheet is that firstly floatable gangue is re-moved by flotation; secondly rutile is recovered by flotation; and thirdly impurity is separated by LIMS, HIMS, gravity concentration and flotation from the rutile concentrate. In rutile flotation, BK423, a phosphonic acid, is used as rutile collector, and Na2SiF6 is used as silicates depressant. The experimental result shows that the recovery of rutile concentrate is improved obviously, and the recovery of ultimate rutile concentrate is 68.01% TiO2 and 84.88% rutile. The TiO2 grade of first concentrate is 95.98%, and the TiO2 recovery is 45.60%. The TiO2 grade of second concentrate is 80.53%, and the recovery is 22.41%. Furthermore, magnetite and ilmenite are recovered in the flowsheet.

Jan 1, 2014