Search Documents

By K. K. Kelley

The collection and correlation of thermodynamic data concerning substances of metallurgical interest have constituted one of the major activities of the Pacific Experiment Station of the Bureau of Mines, at Berkeley, Calif., for the past several years. Earlier bulletins (32, 33, 34, 36, 36, 37, 38) s in this series are entitled: (1) Contributions to the Data on Theoretical Metallurgy. I. The Entropies of Inorganic Substances; (2) Contributions to the Data on Theoretical Metallurgy. II. High-Temperature Specific-Heat Equations for Inorganic Substances; (3) Contributions to the Data on Theoretical Metallurgy. III. The Free Energies of Vaporization and Vapor Pressures of In¬ organic Substances; (4) Contributions to the Data on Theoretical Metallurgy. IV. Metal Carbonates--Correlations and Applications of Thermodynamic Properties; (5) Contributions to the Data on Theoretical Metallurgy. V. Heats of Fusion of Inorganic Substances; (6) Contributions to the Data on Theoretical Metallurgy. VI. A Revision of the Entropies of Inorganic Substances-1935; and (7) Contributions to the Data on Theoretical Metallurgy. VII. The Thermodynamic Properties of Sulphur and its Inorganic Compounds. The present paper collects and discusses thermodynamic data relating to metal carbides and nitrides, with the view of obtaining usable heat and free energy of formation relationships. Pertinent data on both classes of substances are difficult to obtain experimentally and consequently are extremely rare; it is therefore necessary in many cases, if equations are to be derived, to introduce certain approximations and assumptions. Lack of adequate means of checking results by utilizing data of different types, such as was done frequently in the bulletins dealing with carbonates and sulphates, are readily apparent to anyone who has made even a cursory examination of the available information. Consequently, some of the relationships derived undoubtedly will be found to be inaccurate when more or better data become available. Nevertheless, in view of the importance of some of these substances, it appears worth while to consider the information available at present and to attempt the formulation of as complete a

Jan 1, 1937

By John W. Wagner, Robert K. Willardson

Single crystals of Pbl-xSnxTe have been grown from nonstoichiometric, cation-rich melts with the objective of producing as-grown, bulk material containing carrier concentrations ranging from 1016 per cu cm to 1018 per cu cm. Three specific crystal composi-tions were investigated in detail; x = 0.00, 0.10, and 0.17. Pull rates of from I to 3 mm per hr were used. Single crystals were successfully pulled from melts containing as little as 30 at. pct Te. Hall coefficients, resistivities, and carrier mobilities of these materials were determined. The relationship between the composition of the melt and the carrier concentration in the as-grown crystal has been studied for the three crystal compositions of interest. BULK single crystals of Pb,-,Sn,Te have previously been grown from stoichiometric melts.1,2 Such crystals are p-type and have relatively high carrier concentrations ranging from -9 x 1018 per cu cm for PbTe to -8 x l020 per cu cm for SnTe at 77°K. These carrier concentrations result from deviations from stoichiometry (lead vacancies) in the as-grown crystals. Since lower carrier concentrations are desirable for electrooptic device applications, these crystals are usually subjected to long-term, isothermal anneals.' This paper reports on the growth of Pbl-xSnxTe single crystals from nonstoichiometric melts with the primary objective of producing as-grown material containing relatively low (1016 to 1018 per cu cm) carrier concentrations and also reports on the general characteristics of these crystals. The phase relationships in the Pbl-xSnxTe systems are such that materials solidifying from nonstoichiometric, cation-rich melts will have smaller deviations from stoichiometry than materials grown from stoichiometric melts. Fig. 1 is the T-x phase diagram for PbTe in the vicinity of the stoichiometric composition.3 A crystal grown from a stoichiometric melt will solidify at a melting point maximum at which the solid will contain -0.5002 atom fraction of tellurium. PbTe single crystals grown in our laboratories from stoichiometric melts have carrier concentrations of 9 x 10" per cu cm, indicating that the excess tellurium in the crystals is as expected from this phase diagram. However, growth of PbTe from a lead-rich melt will result in material having a more nearly stoichiometric composition. Although the addition of Sn to the melt shifts the solidus curve further toward the tellurium-rich side,4 the general discussion given for PbTe applies to the Pbl-xSnxTe systems as well. EXPERIMENTAL Single crystals of Pb1-xSnxTe have been grown in our laboratories from nonstoichiometric, cation-rich melts using the Czochralski technique and boric oxide liquid encapsulation. The details of the growth apparatus and growth technique have been reported in a previous paper on growth of these alloys from stoichiometric melts.2 In the present study, three specific crystal compositions were investigated in detail; x = 0.00, 0.10, and 0.17. Growth of alloy crystals from nonstoichiometric melts requires considerable care, and good quality single crystals were obtained in this study only by optimizing the mechanical and thermal stability of the growth system and by using pull rates of from 1 to 3 mm per hr (Pbl-xSnxTe crystals are easily pulled from stoichiometric melts at rates of from 5 to 10 mm per hr). The liquid encapsulation technique was found to yield near-ideal conditions, since the B2O3 layer increased the thermal stability at the growth interface, permitted easy attainment of near-ideal thermal gradients, and dampened vibrations at the melt surface. The hygroscopic character of the B2O3 was a slight problem and vacuum heat treating was necessary to completely remove the water from the boric oxide. During initial growth, the seed diameter was reduced and a narrow neck (1 to 2 mm diam) of several millimeters length was grown. The latter steps were found to be necessary for the growth of single crystals, i.e., if either of these two requirements were

Jan 1, 1970

By S. Devereaux, P. Gover, S. Everett

Having real-time data of blast furnace burden profile with respect to burden height and temperature is critical to making informed decisions on blast furnace operation. Given the high temperature and gaseous environment within the blast furnace shaft, traditional instrumentation has been limited at providing the level of real-time feedback information needed to optimize blast furnace operations. Infrared thermal imagery technology provides non-contact temperature measurement across the entire burden profile, allowing for better understanding of the dynamic movement of the burden within the blast furnace shaft. This technology increases blast furnace performance by improving the decision-making process for hour by hour operations. This paper will discuss the development of incorporating infrared thermal imagery technology into the operating strategy of a lead blast furnace.

Jan 1, 2015

By W. R. Hardwick

This paper describes mining methods and practices of the Morenci Branch, Phelps Dodge Corp., Greenlee County, Ariz. It is one of a series being prepared by the Bureau of Mines on mining methods, practices, and costs in various mining districts in the United States. A similar program, conducted from 1928 to 1939, was generally conceded to have contributed substantially to improving the efficiency of mining operations. The morenci open-pit mine (see photograph, fig. 1) is in southeastern [zona] (fig. 2), on U.S. Highway 666 about 5 miles north of Clifton, county at of Greenlee County. The concentrator and smelter are near the mine at an altitude of about 4,400 feet. Figure 3 is a map of the mine and plant.

Jan 1, 1959

By Robert P. Dufresne

Electrolytic cells are used in electrowinning (EW) and electrorefining (ER) of non-ferrous metals such as zinc and copper, and are a critical part of the purification process. The cell is a large basin and has an electrolyte or aqueous solution, an anode and a cathode, an insulator, and incoming high amperage. Cells are exposed to unfavourable internal and external factors that have a direct impact on their lifespan. Their deterioration can be caused by incorrect polarity, insufficient magnitude, their construction, tension stress, thermal shock, corrosion and other, and their maintenance and replacement can be time-consuming, costly, difficult and environmentally unsafe. Occupational health hazards and dangers posed by the maintenance and removal of the cell should also be taken into consideration. Modifying the design and fabrication method of the cell, using chemical-resistant reinforcement, and increasing tensile and mechanical strength will defer maintenance for a very long time. This can be achieved by a double hull system that comprises full-length composite reinforcement, polymer concrete reinforced with fiberglass pultruded rods and rebars, fiberglass structural layers, and special resin matrices. This will provide protection against thermal shocks, corrosion, leakage, cracks. The design of this cell incorporates a lifting system that will afford quick and easy install without having to move a great number of cells in close proximity, since it is strong enough to stand on its own and not have to be bonded to adjacent cells. As well, the cell can be anchored with ease as it remains stable. This is especially important because space is limited to lift and manoeuver between the cell and the double-girder overhead travelling cranes. The lifting system can also prevent electrocution and loss in product quality, while increasing efficiency and safety in the workplace. Considerable savings in terms of production downtime are also part of the equation. INTRODUCTION Maintenance and replacement of electrolytic cells in electrowinning and electrorefining are operations that pose many challenges, health and safety concerns, and give rise to substantial operational costs. These problems have existed since time immemorial. Electrolytic cells are made of conventional concrete or polymer concrete, and because of the very nature of their composition and their exposure to severe and environmental conditions, their lifespan is short. Although polymer concrete is composed of high-quality materials, and has good thermal stability and resistance to chemicals, nonetheless, maintenance is frequently required in order to maintain the integrity of the cell and to ensure the quality of refined metals. Repairing concrete is a non-permanent solution as cracks will reappear, and every repair weakens the integrity of the cell a bit more, until it reaches a knock- down point and the structure is compromised. The cell needs to be replaced, otherwise the cell will collapse.

Jan 1, 2019

By M Logsdon, B Johnson, M Fordham

The underground Neves Corvo copper-tin mine in southern Portugal currently disposes of its tailings in a ætraditionalÆ wet tailings impoundment. With the development of new technologies for preparation and transport of thickened tailings or paste, alternative tailings disposal options have become available that provide a more sustainable water management system and a higher degree of environmental protection. In addition, growing European resistance towards subaqueous disposal may well result in mandatory use of dry disposal methods in the near future. Twenty-four tailings disposal alternatives were evaluated through a cost-effective and easily-implementable bench-scale geochemical screening program conducted at site. Since the tailings are pyrite-rich and highly acid generating, particular emphasis was placed on monitoring likely indicators of sulfide oxidation under the various simulated disposal scenarios. Dependent parameters investigated as part of the program included moisture content, use of alkaline additives (lime, cement), use of a bactericide, and agitation. Response parameters included paste pH, specific conductance, and temperature as indicators of oxidation. The testing was carried out for 30 weeks. Results indicate that a number of relationships between the geochemical stability of the samples (ie sulfide oxidation) and sample characteristics can be readily identified. Based on the results of the screening program, a limited number of tailings mixtures have been selected for further long-term testing in field weathering cells to aid in the identification of the optimal mix design for future tailings disposal at the Neves Corvo Mine. This type of testing provides an inexpensive and reliable methodology for semi-quantitative comparison between tailings disposal alternatives, in particular at locations where more rigorous evaluation through long-term, fully replicated testing is not immediately feasible.

Jan 1, 2003

By C. J. H. Brest van Kempen

The techniques developed should provide a useful tool, not only during the initial formulation of a suitable bolting plan for a new section, but also for periodic check¬ing on the utilization factor of hardware installed in the roof. Indications are that with present practice, utilization seldom exceeds 507.. Retro-fittable bolter equipment now available (FCBS?) allows doubling of the utilization factor in many cases. We are also introducing a computer pro¬gram based on the material outlined in this paper. This program can save a great deal of time in examining the real effect of implementing alternate bolting plans or using different installation techniques. It allows fine-tuning of bolt lengths, spacing and installation tension to mini¬mize roof support cost, while maximizing safe life of the mine opening. We have developed a procedure which allows easy, site-specific quantification of the need for reinforcement of a mine roof. The concept is based on the forma¬tion of a direct link between theory and empirical data to custom-fit each mine section. In its simplest form, the proce¬dure requires only recording of roof bolt torques in a sample working place (16 to 25 bolts) several times during the first week or so after initial bolting. The way in which the torque pattern changes during this time can reveal whether or not the bolts carry enough tension to maintain stability in that specific roof. From the same data, the nature of the anchorage horizon is derived. Specifically, shale or limestone can be distinguished from sandstone. If the procedure is repeated a few times (within the same mine section) with different bolt installation tensions, we can numerically characterize the roof in terms of one single value: an "effective angle of internal friction". This number can then serve to calculate trade-offs in bolting plan design, such as bolt length, bolt spacing and optimum bolt tension. Additional refinement is possible if a sagmeter is installed in the sample work¬ing place being monitored and if bolt anchorage capacity is determined. The lat¬ter can be done automatically on each bolt as it is being installed, using a system we developed and patented. Alternately, a number of pull tests could be performed. Using the sagmeter, bolt torque and anchor¬age data, it is possible to project the safe life of the supported opening. The details of the procedures described apply specifically to tensioned roof bolting, but a brief discussion paints the way for a similar analysis of full-column resin bolting also.

Jan 1, 1986

By P. W. A Severin

"The Sturgeon Lake deposit, a partly eroded lens of massive sulphides with an underlying sulphide stringer zone, is one of five orebodies that occur in the Sturgeon Lake area of northwestern Ontario within volcaniclastic rocks of the Archean Wabigoon Subprovince in the Superior Province of the Canadian Shield.The Sturgeon Lake Cu-Zn-Pb-A g-Au deposit was discovered in October 1970 as a result of an I.P. survey. Production from this open-pit mine began in March 1974 and continued until the ore was exhausted in March 1980.The Sturgeon Lake property is underlain by basaltic volcanics, minor amounts of mafic lapilli tuff and rhyolite volcaniclastics. A quartz crystal-bearing rhyolite occurs at the top of the felsic volcaniclastics and is ""capped"" by the Sturgeon Lake massive sulphide deposit. The felsic volcanics have been intruded by a crudely layered sill-like, carbonatized mafic intrusion. Recent work suggests that the felsic rocks that underlie the Sturgeon Lake deposit are lateral equivalents of those in the vicinity of the Mattabi Mine and are not correlative with the dacitic volcaniclastics that underlie the Lyon Lake and Creek Zone deposits. Hydrothermal processes that resulted in the formation of the Sturgeon Lake orebody have resulted in a depletion of Na2O, CaO and FeO and an increase in MgO, K2O, copper and zinc. In the vicinity of the sulphide stringer zone, the rhyolites are ""bleached"" due to silicification and sericitization. The rocks lying immediately below the massive sulphides are locally strongly chloritic.The Sturgeon Lake deposit may have formed on a top ographic high which prevented mafic flows and dacitic volcaniclastics that underlie the Lyon Lake and Creek Zone deposits from inundating the Sturgeon Lake fumarolic vent from the west. Continued or resurgent activity from the Sturgeon Lake fumarole may have resulted in the formation of the Lyon Lake and Creek Zones as more ""distal "" deposits in topographic lows. The Sturgeon Lake, Lyon Lake and Creek Zone deposits were subsequently overlain by mafic tuffs and flows."

Jan 1, 1982

By J. M. Singer

The objective of this investigation was to determine minimum air velocities and entrainment rates for coal and rock dust dispersion in wind tunnel experiments under conditions that simulate dispersion from surfaces in coal mines where airflows are induced by weak gas explosions. Dust deposits were bed-or ridge-shaped; particle sizes were 6 to 80 microns (cohesive deposits) or 100 to 150 microns (free-flowing deposits); and wind tunnels were 7.62 cm wide by 5.08 cm high by 300 cm long, and 2.4 m wide by 1.5 m high by 215 m long. The investigation showed that minimum air velocities (directed at mid-height) of separate, layered, or mixed piles of coal dust and rock dust were within the range 5 to 30 m/sec, independent of size of wind tunnel. This finding considerably facilitates scaling of data to mine-size passageways. Free-flowing deposits dispersed relatively slowly by single-particle detachment; cohesive dusts dispersed faster by the breaking and lifting of large clumps along weak failure flames; particle dispersion occurred in flight. Layered or mixed deposits of coal and rock dust did not disperse selectively. Semiempirical expressions were derived relating minimum air velocities and dispersion rates to dust-pile geometry, cohesion, porosity, and bulk density.

Jan 1, 1972

By K. C. Kocsis

"Diesel-powered equipment has allowed the mining industry to raise production rates and significantly improve productivity, as it is rugged, mobile and reliable, but its widespread use in underground mines has generated concerns regarding the exposure of mine workers to harmful diesel engine exhaust gases and particulate components such as diesel particulate matter (DPM), which has recently been classified as a human carcinogen by the International Agency for Research on Cancer. The agency expressed further concerns that workers’ exposure to high DPM concentrations can increase the risk of cardiovascular, cardiopulmonary and respiratory illnesses. Three emerging technologies could have the ability to replace dieselpowered equipment and remove DPM from underground mines: fuel-cell-powered mining equipment, battery-powered mining equipment and advanced material handling systems. This paper reviews them and assesses whether they have reached the point where the pollutants emitted by diesel-powered equipment can be removed from underground mines through the introduction of zero-emission mining equipment and power systems. Information is also provided from the results of a feasibility study, including a detailed cost benefit analysis, carried out at six Canadian and nine U.S. underground mines, which looked at the possibility of replacing diesel-powered production equipment with fuel-cell-powered equipment. The remarkable pace at which battery technology is progressing is also reviewed, and the feasibility of replacing diesel-powered mining equipment with battery-powered equipment is assessed. IntroductionHazardous pollutants in underground mines. Why is it important to remove diesel particulate matter (DPM) from underground mines? Over the past 40 years, diesel-powered equipment has allowed the mining industry to achieve rising production rates and major improvements in productivity, as the diesel engine is an economical source of power and diesel-powered equipment is usually rugged, mobile and reliable. On the negative side, the toxicity of some diesel exhaust gases is well known (Grenier et al., 2001), and the widespread use of diesel-powered equipment in underground mines has generated increasing concerns about the occupational exposure of mine workers to harmful diesel engine exhaust gases and particulate components such as DPM. Diesel equipment also entails other hazards like heat and humidity. Exposure to excessive heat can cause heat illnesses, such as heat rash, heat exhaustion and heat stroke (Donoghue, 2004; Roghanchi et al., 2016), and a hot and humid underground environment negatively affects the efficiency of the workforce, which may result in a decline in production output (Roghanchi et al., 2017)."

Jan 10, 2017

By Abhiram Kumar Verma, Soumya Ranjan Mallick

Generally, waste such as soil and sandstone is used in mines for road construction or haul roads. In many such mines, it is challenging to design haul road pavement to match the dumper capacity. This paper investigates overburden soil to find its utility as a pavement material. It is found that overburden soil is unsuitable pavement material without stabilization; hence, nine composite materials are developed using overburden soil and RBI. Physical, mechanical and microstructural properties of unstabilized and stabilized soil are determined. Statistical analysis is carried out to assess the effect of soil type, RBI and curing period of strength characteristics of unstabilized and stabilized soil. ANOVA tests assess the influence of RBI percentage on soil geotechnical properties, and regression relations are developed. Two-way ANOVA shows the effect of RBI and soil type on soil geotechnical properties, whereas one-way ANOVA shows that the influence of soil type is more than the RBI. The regression relation is developed for CBR, UCS, Poisson’s ratio and modulus of elasticity with a good correlation coefficient. The performance of RBI is more with the finer material and reduces with an increase in the size of soil grains. The performance of the developed composite is better than the earlier developed composite based on overburden with fly ash, lime kiln dust, lime or clinker.

Mar 19, 2024

By C. Chibwe, M. Tadie

Copper electrowinning models are useful for prediction of process performance, optimisation and improved understanding of complex phenomena such as current distribution without the expense of physical experiments. Recently, finite element models such as those generated in COMSOL Multiphysics have been developed for the electrowinning process. The predictive capacity of these models is improved by incorporating physical and chemical phenomena. Since physicochemical properties of electrolytes can have a significant effect on the quality of copper produced, this work was conducted to investigate the effect of such properties on electrodeposition at varying levels of copper, sulphuric acid concentration, iron concentration and temperature, in the presence of a smoothing agent. Tests were conducted at conditions similar to those for industrial copper electrowinning. Mathematical correlations were developed for the following properties; density, conductivity and diffusivity which were compared to existing models in literature and thereafter applied in a COMSOL generated model. The model predicts, current distribution at the cathode surface, deposit thickness (morphology), concentration of species within the cell and current efficiency. Current distribution output shows the impact of several phenomena on the deposit generated including the relationship between increasing copper concentration and current density and lack of influence of acid concentration on this property. Keywords: Electrowinning, physicochemical properties, electrolyte composition, modelling

Jan 1, 2020

By S. K. Shaha, W. Kasprzak, D. L. Chen, J. Friedman, F. Czerwinski

The role of solutionizing conditions within the T6 heat treatment of the cast Al-Si-Cu-Mg alloy with micro-additions of Zr-Ti-V was assessed in terms of their influence on microstructure and mechanical properties. As a solution treatment, a single step process at 485 and 510oC and a two-step process at 510 and 525oC for varying time intervals from 0.5 to 9 h, were examined. In all cases, solution treatment was followed by isothermal aging at 150oC for 100 h. The microstructural analysis showed that the solution treatment changed the eutectic silicon morphology from needle-like, present after casting, to spherical shape in the T6 state and that the extent of changes was strongly influenced by temperature and time. The Cu- and Mg-rich phases completely dissolved during solution treatment while the Fe-containing phase, Al8Si6Mg3Fe, remained partially in the microstructure. The Ti, V and Zr containing phases, Al13Si2Ti3Zr and Al3Si26FeTiV10, present in as-cast state, were partially dissolved during solution treatment, reducing their size by 10 - 48%. The studied alloy reached the maximum ultimate tensile strength of 335 MPa and yield stress of 303 MPa for two-step solutionizing with a total time of 4.5 h. It is concluded that the two-step solution treatment resulted in higher tensile properties than the single-step process.

Jan 1, 2015

By J. R. Thoenen

This paper outlines briefly results of seismic measurements recorded in the vicinity of quarry blasting under practical operating conditions. The data cover field work done from January to the middle of August 1930, during which time records were made of 61 blasts in 19 quarries. Of the tests made, one was in biotite-gneiss, two in dolomite, two in a flintlike volcanic complex, three in gabbrodiorite, five in trap rock, and six in limestone. One quarry was in Alabama, two were in South Carolina, two in New York, four in Kentucky, five in Connecticut, and five in Massachusetts. Explosive charges ranged from 0.30 pound to 41,900 pounds, and the method of shooting varied from mud caps through hammer and wagon drill holes to churn drill holes and coyote tunnel shots.

Jan 1, 1937

By Stephen B. Castor

The rare earth elements (REE) which include the 15 lanthanide elements (Z = 57 through 71) and yttrium (Z = 39) are so called because the elements were originally isolated in the late 18th and early 19th centuries as oxides from rare minerals. Most REE are not as uncommon in nature as the name implies. Cerium, the most abundant REE (Table 1), comprises more of the earth's crust than copper or lead. Many REE are more common than tin and molyb¬denum, and all but promethium are more common than silver or mercury (Taylor, 1964). Promethium (Z = 61) is best known as an artificial element, but has been reported in very minute quantities in natural materials. Lanthanide elements with low atomic numbers are generally more abundant in the earth's crust than those with high atomic numbers. In addition, lanthanide elements with even atomic numbers are two to seven times more abundant than adjacent lan¬thanides (Table 1) with odd atomic numbers. The lanthanide elements traditionally have been divided into two groups: the light rare earths (LREE), lanthanum through eu¬ropium (Z = 57 through 63); and the heavy rare earths (HREE), gadolinium through lutetium (Z = 64 through 71). Although yttrium is the lightest REE, it is usually grouped with the HREE to which it is chemically and physically similar. The REE are lithophile elements (elements enriched in the earth's crust) that invariably occur together naturally because all are trivalent (except for Ce+4 and Eu+2 in some environments) and have similar ionic radii. Increase in atomic number in the lanthanide group is accompanied by addition of electrons to an inner level rather than the outer shell. Consequently, there is no change in valence with change in atomic number, and the lanthanide elements all fall into the same cell of the periodic table. The chemical and physical differences that do exist within the REE group are caused by small differences in ionic radius, and generally result in segre¬gation of REE into deposits enriched in either light lanthanides or heavy lanthanides plus yttrium. The relative abundance of individual lanthanide elements has been found useful in the modelling of rock-forming processes. Comparisons are generally made using a logarithmic plot of lanthanide abundances normalized to abundances in chondritic (stony) meteorites. The use of this method eliminates the abundance vari¬ation between lanthanides of odd and even atomic number, and allows determination of the extent of fractionation between the lanthanides because such fractionation is not considered to have taken place during chondrite formation. The method is also useful because chondrites are thought to be compositionally similar to the original earth's mantle. Europium anomalies (positive or negative departures of europium from chondrite-normalized plots) have been found to be particularly effective for petrogenetic modelling. REE were originally produced in minor amounts from small deposits in granite pegmatite, the geologic environment in which they were discovered. During the second half of the 19th century and the first half of the 20th century, REE came mainly from placer deposits. With the exception of the most abundant lanthanide el¬ements (cerium, lanthanum, and neodymium), individual REE were not commercially available until the 1940s. Since 1965, most of the world's REE have come from two hard rock deposits: Mountain Pass, United States, and Bayan Obo, China. GEOGRAPHIC DISTRIBUTION OF REE DEPOSITS More than 70% of the world's REE raw materials come from three countries: China, the United States, and Australia. China emerged as a major producer of REE raw materials during the 1980s, while Australian and United States market share decreased dramatically (Fig. 1). Table 2 gives recent annual production figures along with estimated reserves by country, and Fig. 2 shows loca¬tions of significant REE mining. MINERALS THAT CONTAIN REE Although REE comprise significant amounts of many minerals, almost all production has come from less than ten minerals. Table 3 lists minerals that have yielded REE commercially or have po¬tential for production in the future. Extraction from a potentially economic REE resource is strongly dependant on its REE miner¬alogy. Minerals that are easily broken down, such as bastnasite, are more desirable than those that are difficult to dissociate, such as allanite. In general, producing deposits contain REE-bearing min¬erals that are relatively easy to concentrate because of coarse grain size or other attributes. For more thorough discussions of REE¬bearing minerals see Mariano (1989a) and Cesbron (1989).

Jan 1, 1994

By R. W. Lawrence

"The management of acid rock drainage( ARD) to prevent impact when tailings are disposed of in the environment requires understanding of the phenomena giving rise to acidic drainage, a rigorous evaluation of the weathering characteristics of the tailings, and the successful implementation of control measures that will be effective in the long term. This paper provides a brief theoretical background to the complex reactions taking place in mill tailings containing residual sulfide minerals which must be appreciated to enable waste characterization program to be effective in predicting the future behavior of the tailings and in designing control methods which will work. The principals and practice of prediction and control as part of an ARD management strategy will then be discussed.Paper Not Available at Time of Publication"

Jan 1, 1997

By AIME AIME

FREE competition, long the controlling ideal of domestic trade within the United States, has had the fundamental geographical advantage of functioning in the world's largest area of unrestricted commerce. Goods moved back and forth across state lines, unimpeded by customs, and industrial operations have developed rapidly to meet the expanding needs of a pioneer country richly endowed with natural resources. Fifty years ago, antitrust laws were adopted to protect the competitive private enterprise principle. It became illegal for one person to combine with another to restrain trade or commerce among the several states or with foreign nations. The original legislative measures defining this philosophy were the Sherman Act of 1890 and the Clay- ton Act passed in 1914. The development of Europe and other parts of the world was influenced by different conditions which led to a different theory of trade. Here were many small nations, with limited natural resources and a thin market, and they attempted to protect their national economy by tariff walls. International business arrangements for the purpose of diminishing the ups and downs of the more competitive system --crux of the modern cartel operations-seemed a logical device to stabilize production and guard the interests of both workers and consumers. European governments as well as European industrial interests became convinced that if com- petition could be held in bounds the danger of business depressions and un- employment could be reduced.

Jan 1, 1944

By James J. Dowd

During and immediately following World War II, the heavy demands for steel required the mining of unusually large quantities of coal for the manufacture of metallurgical coke. The largest demand for metallurgical coke is in the Appalachian region, which comprises central and western Pennsylvania, Maryland, West Virginia, Virginia, eastern Kentucky, Tennessee, and Alabama. This demand is satisfied by coke made from coals within the region; consequently, the reserves of coking coal in this region are being depleted more rapidly than reserves in other coal-producing regions. The supply A' high-quality coking coal during the war was inadequate, and some coke were forced to use inferior coals. The coke produced from these inferior coals adversely affected the rate of production. Another national emergency probably would produce a similar condition, and in the interest of -national security, the Munitions Board of the National Military Establishment requested the Bureau of Mines to evaluate the reserves of coals suitable for the manufacture of metallurgical coke. All bituminous coals in the Appalachian region are coking, and as the coal that produces the better metallurgical coke become depleted, other coal previously considered inferior will be used. The general trend is toward the use of lower-quality coals for metallurgical purposes.

Jan 1, 1950

By Donald F. Reed

The bauxite deposits of Tippah and Benton Counties in northeastern Mississippi were developed by drilling as a part of the investigation by the Bureau of Mines of the domestic sources of supply of aluminum. The primary purpose of investigations of this nature was to provide essential information to the war agencies of the United States Government and to assist owners and operators of mining properties in the production of minerals vital to the prosecution of the war. These reports are based upon the field work of the Bureau of Mines and upon data made available to the Department from other

Jan 1, 1948

By K Vallo, T Haimi, J Pihlasalo, J Hamuyuni, M Lindgren, F Tesfaye

Decarbonisation of the steel industry has recently attracted a lot of research and technological development. Most of the technological developments are centred around the replacement of blast furnace (BF), which has been the main primary smelting furnace in the ironmaking step of steel production. Replacement of the BF is not an easy task because of BF’s many established capabilities over the years, especially its ability to use low-grade iron feed. In this regard, Metso has developed its own technology, Metso’s Outotec direct reduced iron (DRI) smelting furnace, to tackle this problem. The recently developed six-in line electric furnace for DRI smelting can be used for primary smelting of DRI from blast furnace grade iron ore. Unlike the electric arc furnace (EAF), the DRI smelting furnace can handle larger slag volumes that emanate from the high gangue in BF grade DRI. Therefore, fluxing plays an important role in operating the DRI smelting furnace. This paper presents fluxing options and proposes slag quality and operating windows for the DRI smelting furnace. Also, the effect of slag on refractory durability will be discussed.

Jun 19, 2024