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By D. R. Torgoson, Th. G. Sahama

"This paper contains some new thermodynamic data for silicates in the series Mg2SiO4-Fe2siO4 and MgSiO3-FeSiO3 and gives the results of a thermodynamic attack on the problems of stability end parageneses.. Although some data are lacking satisfactory agreement with mineralogical and petrological observations is indicated.The use of thermodynamic methods in mineralogy and petrology has been rather limited, because accurate thermal data, especially for the more complicated and more important rock-forming minerals, have been too scanty to permit any systematic application to problems in those fields. It is, nevertheless, a fascinating task to investigate to what extent the mode of occurrence and the stability relations of the minerals and mineral parageneses, as revealed by petrological and mineralogical observations, agree with predictions of thermodynamics. At the present stage of development calorimetric data are needed for most of the abundant silicate minerals.Measurement of the heats of solution in hydrofluoric acid of minerals in the series Mg2SiO4-Fe2SiO4 and MgSiO3-FeSiO3 affords a ready means of obtaining their heats of formation from the oxides. Combination of such data with entropy and heat-capacity values gives a means of obtaining free energies of formation from the oxides, which, in turn, are connected di¬rectly with stability and paragenoses.The two silicates of magnesium, Mg2SiO4 and MgSi03, occur as rock-forming constituents as forsterite and clinoenstatite or enstatite. The orthosilicate (forsterite) forms a series of isomorphic mixtures with ferrous-orthosilicate (fayalite). The continuity of this series, suggested by petrological observations, has boon proved experimentally by Bowon and Shairer.4/ The present work shows that those minerals constitute a series of perfect solid solutions - that is, a series of solid solutions for which heats of formation from the individual pure silicates, Mg2Si04 and Fe2SiO4, aro negligibly small.The metasilicates of magnesium and iron also form an isomorphic series. However, this series differs from the forstorito-fayalite series in the fact that the most iron-rich mixtures, between about En10Fs90 and pure Fs, appear to be unstable with respect to the paragenesis iron-rich olivine plus quartz. The supposed instability of pure FeSiO3 as a crystalline compound, at least at high and at moderate temperatures, is remarkable, as no crystal struc¬tural reason for such instability is apparent. The present work indicates, also, that these minerals form a perfect series of solid solutions and throws additional light on the instability question.In the following, the samples used in this investigation will be described. For each of the natural olivines and orthopyroxenes, with the exception of sample L, a chemical analysis was made of the purified and actually used fraction. All the analytical work was carried cut by Oleg v. Knorring, and the specific gravity determinations, by moans of a pycnomctcr, by Oiva Joensuu, both of the University of Helsinki, Finland. The determinations of the optical properties were made by Mrs. Toini Mikkola, of the Geological Survey of Finland."

Feb 1, 1949

By Charles W. Briggs

The steel foundries of Germany were investigated for the purpose of ascertaining (1) the type and classification of steel structures produced as castings, (2) processing methods, (3) the mechanical properties of carbon and alloy cast steels, (4) the type and character of defective castings, (5) the appearance of castings, (6) research in steel castings, and (7) plant lay-out and equipment.

Jan 1, 1946

By Sara J. Davenport

With the increased demand for mercury incident to preparations for national defense and the reduction in imports from some of the usual sources owing to war conditions, many small mines in the United States Pure now being worked that ordinarily would be unprofitable. This is indicated by the following table on mercury produced in the Unite States in 1939-40 (1)4/

Jan 1, 1941

By M. Boodman, E. Gertner

"At first glance, the activities related to mining and mineral exploration appear to be local or domestic, rather than international, in nature. Minerals, as corporeal or tangible property, form an integral part of the land in which they are found until extracted and exploited commercially. Even in the latter phase, the tangible nature of minerals gives the impression that the law governing the commercialization of minerals is the law of their situs at any given time. The nature of minerals appears to negate the international aspect of mineral enterprises.The fundamental flaw in the above analysis is its focus upon the nature of minerals, rather than the role of persons in mineral enterprises. The high costs of mineral exploration and commercialization invariably require the involvement of international consortiums or joint ventures. Governments may not have access to the funds necessary to exploit the mineral resources that they control. Local or domestic enterprises may not have sufficient expertise for mineral exploration. Further, markets for various types of minerals are far from localized or static. For these and other reasons, the tangible and localized nature of minerals belies the fundamentally international nature of mineral exploration and commercialization."

Jan 1, 2004

Jan 1, 1998

By H. B. Jensen

STUDY of the thermal-solution process was begun by treating crushed oil shale in a small autoclave at temperatures of 700° to 950° F. The effect of temperature, reaction time, type of solvent, and richness of shale upon the amount of organic matter that was removed from the oil shale was thus determined. Following this orientation work a semicontinuous, bench-scale apparatus was built so that heated solvent could be pumped through a bed of shale under elevated pressure, thus removing the converted organic matter from the spent shale. After some operating experience had been gained, a continuous unit was constructed. This permitted treating a slurry of shale oil and pulverized oil shale at about 300 p. s. i. and temperatures of 750° to 850° F. for various retention times. Considerable cracking and polymerization of the shale oil were found to take place during the process. In an attempt to prevent this, a study was made of extraction of the shale in batch-type autoclaves under high partial pressures of hydrogen at total gas pressures of as much as 4,300 p. s. i. at 850° F. The thermal-solution process was found to convert over 90 percent of the organic matter in oil shale to oil and gas. The highest yields of gas and oil obtained without hydrogen pressure were equivalent to 119 weight-percent of those obtained from the same shale by Fischer assay. With a high partial pressure of hydrogen, yields equivalent to 126 weight-percent of Fischer assay were obtained. However, the oil produced by thermal solution has a higher boiling range than that obtained by other retorting methods, particularly so if the thermal-solution process is used without a high partial pressure of hydrogen. Nondistillable oil (all benzene-soluble material that would not distill under 2 mm. Hg absolute pressure without cracking) equivalent to over 100 percent of the organic matter in the shale was obtained without hydrogen pressure in the system. When the process was carried out under hydrogen pressure, the yield of nondistillable oil amounted to 60 to 70 weight-percent of the organic matter. Part of this heavy material is formed partly by polymerization and condensation of the shale-oil solvent used. These reactions, as well as cracking of the solvent to form gas and a carbonaceous deposit on the shale, are unfavorable features of the process.

Jan 1, 1953

By C. Vipulanandan

With the aging infrastructure, there is a need to maintain and extend the service life of steel structures in general and steel piles in particular. Steel piles support not only vertical loads but also dynamic horizontal loads in onshore and offshore applications. In order to select the appropriate methods to repair corroded steel piles used in onshore and offshore application, corrosion mechanisms were investigated with the rate of corrosion in various environments. The corrosion rate of steel in soil, water and soil-water interface varied from 2 to 500 µm/year. Based on literature review and analyses, the repair methods can be broadly characterized as protective coating, electro-chemical methods, wrapping and encasement and partial replacement of steel. Also, methods to evaluate the repair materials and the repair configuration have been documented.

By W. B. Berwald

The United States Bureau of lanes, in cooperation with the Natural Gas Department of the American Gas Association, has been studying actively for the past several years the problem of the flow of natural gas through high-pressure transmission lines. Numerous data on gas flow through pipe lines under many conditions of operation have been obtained by carefully conducted tests, and these data, together with all other available information, have been analyzed Carefully to secure practical facts for the use of operators in designing pipe lines and determining the effects of different operating conditions on pipe-line capacities. The first procedure in initiating this problem was to review, compile, and analyze all of the existing data on the flow of natural gas through pipe lines. Actual data applicable to pipe and operating conditions normally used in the transmission of natural gas were meager, and the several pipe line flow formulas developed by different investigators gave widely varying results when applied to problems of pipe-line design. Therefore, further experimental work under conditions comparable to those found in transmitting natural gas was essential before any definite recommendations could be made. The problem, as originally planned, included flow tests on pipe lines in operation, and in each test the measured delivery vas to be compared with the delivery calculated from several common pipe line flow formulas.

Jan 1, 1931

By W. B. Berwald

The United States Bureau of Mines, in cooperation with the Natural Gas Department of the American Gras association, has been studying actively for the past several years the problem of the flow of natural gas through high-pressure transmission lines. Numerous data on gas flow through pipe lines under many conditions of operation have been obtained by carefully conducted tests, and these data, together with all other available information, have been analyzed carefully to secure practical facts for the use of operators in designing pipe lines and determining the effects of different operating conditions on pipe-line capacities. The first procedure in initiating; this problem was to review, compile, and analyze all of the existing data on the flow of natural gas through pipe lines. Actual data applicable to pipe and operating conditions normally used in the transmission of natural gas were meager, and the several pipe line flow formulas developed by different investigators gave widely varying; results when applied to problems of pipe-line design. Therefore, further experimental work under conditions comparable to those found in transmitting natural gas was essential before any definite recommendations could be made.

Jan 1, 1931

By J. S. Brock

Magnetic, electromagnetic and gravimetric surveys have played an important role in the mineral exploration leading to the discovery of three major massive sulphide deposits in the Anvil-Vangorda area of the Yukon Territory. During 1964 and 1965 a saturation prospecting program, relying heavily on the integrated use of airborne and ground geophysical survey techniques, led to the discovery of the Faro deposit, which was subsequently proven to be a 63-millionton lead-zinc orebody. Locating the Faro deposit, the largest found to date in this overburden-covered region, involved an exploration sequence requiring the selection of a favourable geologic environment, aeromagnetic and electromagnetic surveys, property acquisition of anomalous areas and detailed ground geophysical surveys, followed by rotary drill testing, detailed gravimetric surveys and diamond core drilling.

Jan 1, 1973

By W. Beckering

IN CHARACTERIZING tars obtained by the low-temperature carbonization or North Dakota lignite, infrared spectra have been an invaluable aid in both qualitative and quantitative examination. Quite early it became evident in the tar-research program of the Bureau of Mines, U.S. Department of the Interior, that the small number of published spectra available for hydroxy aromatics would be inadequate for comparative purposes when dealing with the wide range of compounds present in coal tar; therefore, compiling a catalog of spectra was initiated as a continuing part of the tar program. As these spectra should be valuable to other investigators in this and related fields, they are being presented in this report. This group or spectra (figs. 1-98) represent 97 compounds, largely phenolic materials. The major problem of this project has been the availability of materials for examination. Samples have been obtained from commercial and private laboratories or synthesized at the Bureau of Mines Lignite Experiment Station, Grand Forks, N. Dak.

Jan 1, 1959

For the past 3 years Waihi as a community has been actively engaged in consultation about its future with regard to the environmental, cultural, economic and social viability. This has been made possible through the implementation of the Waihi Community Vision (WCV) process which bought together a diverse range of people and interests.   Through their collaboration and collective energies, they produced a montage of possibilities for the future of Waihi, known as the 2020 Vision. A proceeding evaluation process was adopted by the group to enable the myriad of projects to be assessed and prioritised in terms of the communityÆs social, economic, cultural, environmental and spiritual values.   From this came the desire to be involved in the implementation of these ideas and create an organisation that could facilitate the successful manifestation of the 2020 Vision and other suitable projects.   The Vision Waihi Trust (VWT) was formed in February 2006 and is intended to be a tool through which the community can address issues about its future sustainability. They will work collaboratively with community groups, Hauraki District Council and Newmont Waihi Gold to develop and implement innovative and practical solutions. It should be acknowledged that such outcomes are subject to influence by both external and internal factors and it is important to consider this when looking at sustainability issues.   Waihi is now at a very interesting stage of its development and has the opportunity to proactively design and implement plans to determine its future rather than just let things evolve. A town with a strong sense of its roots and with a strong community identity may be a more attractive as a place live and work. There are additional business opportunities which may also be stimulated by a community that takes charge of its own destiny.   The process that has been worked through over the past three years gives a solid foundation on which to build and must be viewed as positive community development. Waihi certainly has a unique proposition to take to the marketplace, based on its rich gold mining heritage and current modern day mining operations. This requires investigation, refinement and implementation and Vision Waihi Trust looks forward to building to a vibrant and prosperous Waihi in the years to come.

Jan 1, 2006

By P. Nicholls

[This paper sets forth the burning characteristics of coke used as a domestic fuel as shown by work of the U. S. Bureau of Mines and others. Coke is a truly smokeless solid fuel and is held in high regard for this quality. Ways are being found for making commercial coke from a wider range of cools than heretofore, and tale use of coke for domestic heating is increasing. ACKNOWLEDGMENTS The experimental work reported in this paper was conducted at the Pittsburgh Experiment Station of the U. S. Bureau of Mines cinder the authority of O. P. Hood, chief mechanical engineer; M. L. Orr, assistant feels engineer, and W. M. Brewer, junior fuels engineer, assisted by Charles Schramm cooperated in making the tests.]

Jan 1, 1929

By Lloyd A. Morley

This seven-chapter document is the first volume of a two-volume report that presents a comprehensive outline of coal-mine electrical power systems from theory to practice. Together, the two volumes contain the vital aspects that go into planning and designing a mine power system. After a short introductory chapter, Chapter 2 discusses the history of electrical use in mining and introduces "typical" mine- power-system arrangements. Chapter 3, 4, and 5 supply basic information on electrical theory, circuit analysis, and motors. Next, the Grounding and Distribution Chapters detail unique aspects of mine power systems. Elements of surface and underground use are included in all these chapters. An index concludes Volume I and is cross-referenced to both report volumes.

Jan 1, 1982

By Pratheesh George

Solid state galvanic cell with CaF2 as the electrolyte was employed for determining the thermodynamic properties of Nb-Al binary alloys in the temperature range of 973-1073 K. The activities and activity coefficients of Al in NbAl3 were determined. The experimental procedure and the design and construction of the experimental setup have been also explained in detail. Aluminum activity in NbAl3 increased with increase in temperature and shows a strong negative deviation from ideality. The activities of aluminum in NbAl3 were determined to be 0.0165 and 0.0289 at 973 and 1073 K respectively. The stability of NbAl3 has been compared with other available intermetallic systems.

Jan 1, 2006

By F. Carew

Accurate knowledge of what mass and grade is to hand and where it is stored is key to mine efficiencies and overall profitability. In order to make the right decisions and align production with stockpile capacity, feed and contract demand, a clear and accurate view from production through blending and processing is required. The use of a mine production management solution can provide you with a high degree of confidence in and visibility into validated data as well as auditable and traceable material movements, activities and surveys. A robust calculation engine enables mass and grade changes to propagate to material movements and stockpiles to ensure you are getting the most accurate view at all times. Tracked changes in material balances can be readily incorporated in revised production schedules to close the loop. The availability of accurate, timely information, coupled with predictive trend indicators, is a significant advance in narrowing the gap between claimed and planned production that is common to many mines, regardless of commodity. This paper provides an overview of a Mine Production Management System (MPMS) and explains how the system helps address the challenges listed above.

Jan 1, 2011

By Louis H. Berkelhamer

"INTRODUCTION In the present war, with increasing demands on foundrymen for speedy production of sound castings, the role of sand in foundries has paramount importance.Foundry sands include both molding sands and core sands. Molding sands are those used in making molds, whereas core sands include those used for ""cores"" that fill the parts of the mold intended to be openings or hollow spaces in the casting. Core sands are, as a general rule, relatively coarse-grained as compared to molding sands. Coarse-grained sands, however, are required in making molds for large castings.Owing to the intimate relationship between properties of the sand and casting defects, it is necessary (for most efficient foundry work) to keep a close check on the molding sands used and to properly select and prepare a sand for a specific job. A mold is essentially an unfired refractory composed to meet specific requirements as to strength, permeability, and resiliency. Good green strength is important in preparing and handling the mold. Low dry and hot strengths contribute to cutting and washing, whereas high strengths cause difficult shake-out, with subsequent loss of sand. When molten metal is poured into the mold: a dried skin is attained, and gases from moisture and combustibles are driven off. Excessive moisture necessary for the proper working of a sand, as well as poor venting due to low permeability, are factors responsible for producing such defects as blows and pinholing. The skin of the mold, upon contact with molten metal, first expands and later contracts; these conditions are favorable for producing scab defects. Contact with the molten metal sometimes causes the skin of the mold to sinter or fuse and may produce a sand burn on the casting. Then again, the mold may develop excessive hot strength rapidly, thereby causing a cracked casting. Experienced foundrymen can other such relationships, too numerous to be included here."

Sep 1, 1944

By Y. C. Kim, F. Szidarovszky

G.M. Philip and D.F. Watson The article cited above reflects the difficulty that is often encountered in interpreting different aspects of kriging. Baafi et al. write : "Due to negative kriging weights, negative block grades may be obtained in some extreme situations, which makes no practical sense." Their solution to this particular problem is to constrain the kriged estimates to data values that have positive weights, i.e., reduce the subset size contributing to the estimation. As Journel (1986, p. 133) has already observed, "Negative weights are no evil." Indeed, they are an ineluctable result of the Lagrangian multipliers in the system of simultaneous equations. The fact that data distant from the estimation point may be given negative weights simply means that the influence of such distant values must be negated because their influence is contradictory to closer values (as illustrated by Baafi et al. in their Figs. 3 and 4). Of course negative kriging weights applied to distant grade values will not in themselves induce negative grade at some central interpolation point. Negative grade values, rather, seem to be a particular artifact of automatic methods of estimation involving accu¬mulations (Philip and Watson, 1985a, 1985b, 1987b). The elimination of negative weights, suggested by Baafi et al., is likely to exacerbate a quite different problem of kriging and piecewise spline interpolation discussed elsewhere (Philip and Watson, 1987a). In interpolating large data sets of scattered observations, changing local subsets or neighborhoods must be selected automatically. Because of the mathematical formulation of kriging and spline interpolation, discontinuities then occur between closely-spaced estimation points as the subset used in the estimation changes. If this subset is reduced in number and size, the discontinuities will be amplified and more common. ? References Journel, A.G., 1986, "Geostatistics: models and tools for Earth Sciences," Journal of Mathematical Geology, Vol. 18, No. 1, pp. 119-139. Philip, G.M., and Watson, D.F., 1985a, "Theoretical aspects of grade-tonnage calculations," International Journal of Mining and Geological Engineering, Vol. 3, pp. 149-154. Philip, G.M., and Watson, D.F., 1985b, "A deterministic approach to computing ore reserves. I, Grade Estimation," Earth Resources Foundation, Occas. Paper 2, The University of Sydney, 24 pp. Philip, G.M., and Watson, D.F., 1987a, "Neighborhood discontinuities in bivariate interpolation of scattered observations," Mathematical Geology, Vol. 18, No. 1, pp. 69-74. Philip, G.M., and Watson, D.F., 1987b, "Estimating interactions of topological functions," Mathematical Geology, Vol. 18, (at press). Reply by Y. C. Kim Before replying to the comments by Philip and Watson, it is desirable to establish the original perspective of our paper, which was intended primarily for the practitioners of mining who possess a working knowledge of ordinary kriging. The paper tried to convey the following practical points: (1) there are circumstances in which one observes negative weights, (2) illustration of circumstances under which one can expect negative weights, (3) should one obtain a negative estimated grade, one can resort to elimination of negative weights using the technique outlined in the paper, and (4) one could normally select only the first layer of surrounding assays to estimate the block grade. Under such a perspective, most of the comments by Philip and Watson are irrelevant and misdirected. For example, the practitioners do not find it difficult to "interpret" the results of ordinary kriging, as evidenced by the fact that they have been using the results for nearly a decade. Nor are the practitioners concerned with discontinuities in estimated block grades due to changing neighborhood of assays during kriging. What matters to the practitioners is the fact that kriging does provide the best estimate among all the estimation tools available to them as of today. ?

Jan 2, 1987

By A. McLean, M. Barati

In this paper, examples are presented of pyrometallurgical research and associated teaching activities during the past century within the Department of Metallurgical Engineering, now the Department of Materials Science and Engineering, at the University of Toronto. Throughout these years, pyrometallurgical research has been characterized by recognition of the importance of the interdependence of measurements and models as well as the development and application of sensors, for the generation, validation and practical implementation of new knowledge. The important role played in the delivery of lectures and participation in joint research by Adjunct Professors with strong backgrounds in the pyrometallurgical industry is described. Projects conducted in close collaboration with the industrial sector and opportunities for students to obtain practical experience working as teams on a "round-the clock" shift basis within an industrial pilot plant environment are outlined. These activities, together with the involvement of students in poster competitions and the presentation of papers at society conferences and technical meetings, are still vital elements in the development of pyrometallurgists equipped with the appropriate professional skills for subsequent employment within academia, government laboratories or the industrial sector.

Jan 1, 2015

By J. M. West

Increased leisure time and increased interest in the out-of-doors is leading more and more families to experiment with placer mining of gold, and some- times even to going on into small-scale production. This Bureau of Mines report supplies basic information un areas of occurrence, equipment needed, prospecting, sampling, mining, and regulations concerning the possession and sale of gold. Selected references are given for further study.

Jan 1, 1971