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By Jason Ganley, Yingjia Liu, Adam Dekich, William Tilson, Jeffrey Fergus, Dileep Kumar CJ

"Manganese cobalt spinel oxide coatings have been shown to be effective for preventing chromium volatilization from interconnect alloys, and the associated cathode poisoning, in solid oxide fuel cells. During high temperature exposure a reaction layer consisting of chromium containing spine! forms due to reaction with the chromia scale formed on the alloy. The electrical conductivity of this reaction layer is much lower than that of the coating material and thus can increase the overall area specific resistance (ASR) of the system. The approaches to reducing the ASR are to reduce the thickness and/or increase the electrical conductivity of the reaction layer, which includes both the high-chromium spinel phase and the chromia scale. In this paper the effects of transition metal dopants on the amount and properties of reaction products formed during the reaction of spine! oxide coating materials with chromia are presented.IntroductionThe high cost and difficulties involved with the processing of chromia based ceramic interconnect materials for SOFCs are driving the search for metallic interconnects [1, 2]. The reduction in the operating temperature of SOFC has allowed for the use of high chromium alloy steels for this application [3]. However, the volatilization of chromium from the chromia scale, and the associated poisoning of the cathode, remains a problem which needs to be addressed [ 4]. Though the application of manganese cobalt oxide spine! coatings on the alloy surface substantially reduces chromium poisoning of the cathode [5], the low electrical conductivity of the reaction layer formed between the chromia scale and coating affects the performance of interconnect. Incorporating transition metal ions in the reaction layer could alter the electrical characteristics and improve the performance. Copper and nickel doped manganese oxide spinels are widely used as thermistors due to their high electrical conductivity and negative temperature co-efficient of resistance characteristics [ 6, 7]. Hence doping of copper and nickel in manganese-cobalt spine! oxide composition may improve the electrical characteristics of interaction layer as well and is attempted here."

Jan 1, 2012

By J. E. Danoczi

Shore Gold Inc. (Shore) is presently designing a diamond processing plant for the Star and the Orion South kimberlite deposits in the Fort à la Corne (FalC) area in central Saskatchewan. The first step in the plant is diamond liberation and occurs in the comminution section. Diamond liberation is the process of breaking up the kimberlite rock, as gently as possible so as not to damage the diamonds. Autogenous grinding mills (AG mills) use a combination of impact crushing, abrasion and attrition to break up the kimberlite. The forces that occur during the actions of abrasion and attrition cause the kimberlites to break up preferentially along lines of weaknesses which offers a ?diamond friendly? method of comminution. Hard competent kimberlite is commonly found in the diatreme zone as well as the root zone of the volcanic pipe and is the source of kimberlite for most of the Southern African diamond mines. Softer kimberlite is typically found in and around the crater area of a volcanic pipe and it is this kimberlite that makes up the majority of kimberlite for both the Star and Orion South deposits. These softer kimberlites can be readily broken up using abrasion and attrition imparted by AG mills. In order for Shore to benefit from the softer kimberlite found in the Star - Orion South diamond project, two large (10.97 m diameter x 7.10 m long) AG mills were designed for the comminution section based on extensive test work and simulations by Metso Minerals (Metso).

Jan 1, 2012

By Sudhir Kumar Kashyap

In underground activities ground control is a challenging problem. It affects safety, production, and efficiency. As per statistics of accident data, ?fall of roof/sides? is one of the major causes of mine accidents. In many cases, our experiences and understanding of soil and rock behavior still fall short of being able to predict how the ground will behave. Presently, empirical approaches to design are widely used in estimating mine support parameters. Under these circumstances, expert judgment plays an important role, and such accidents can be obviated with accurate measurement and optimization of data and analysis using the neuro-fuzzy technique of artificial intelligence. Recently, a neuro-fuzzy hybrid approach has become one of the major areas of interest in engineering fields because it gets the benefits of neural networks as well as those of fuzzy logic systems, and it removes the individual disadvantages by combining them on the common features. Neural network and fuzzy logic technologies have common features, such as a distributed representation of knowledge, the ability to handle data with uncertainty and imprecision, etc., like in ground control. Fuzzy logic technique has tolerance for imprecision of data, while neural networks have tolerance for noisy data. In this paper we have focused an intelligent technique, i.e., neuro-fuzzy technique, to approximate the setting load given to the standing support (props) erected for the purpose of supporting freshly exposed roof during underground mining. We have used twelve input variables of rock parameters, and after having trained using a neural network with a sigmoidal function as an activation function, simulation was done to find the output parameter, i.e., the pre-load (setting load)to be applied on props. Outputs of the neural network were again fed to the fuzzy system together with the twelve parameters, incorporating five triangular membership functions for each parameter. Final optimum output was approximated using the MATLAB program, which was found to be satisfactory. Neuro-fuzzy technique has better performance over individual neural networks or fuzzy logic technique.

Jan 1, 2012

By D. Royston

Reducing SAG Mill feed size has been a major trend in recent years. ?Mine to mill? strategies have reduced blasted-rock size, and in a growing number of operations reducing the primary crusher CSS and/or adding additional crushing upstream of the SAG mill have reduced rock feed size. While reducing feed size will increase SAG mill throughput, issues arise in terms of retaining charge in the mill, exposing the shell lining to impact damage, and maintaining milling performance should the pre-crush system shut down. This paper reviews the past experience on pre-crushing for SAG mills and provides an analysis of liner design (in particular grates and shell liners) for pre-crushed feed.

Jan 1, 2012

By S. P. Pereira

The mechanized mining cycle using loaders and shuttle cars had its peak in terms of usage in the mining industry during 1950 through 1960. In Brazil, this system is still used at underground coal mines in southern Santa Catarina coal basin. With the aim of investigating the benefits of a new mining scheme using the room and pillar method for these local mines, a computational simulator model was developed in order to investigate the mining cycle. This paper presents the methodology used to develop the simulator and the results that the simulation shows regarding impact of the proposed new scheme on mining productivity.

Jan 1, 2012

By J. Utt

Recent developments in circulating fluidized bed (CFB) once-through supercritical technology (OTSC) have enabled this technology to be offered as a utility-scale alternative competing head-to-head with pulverized fuel (PF) OTSC offerings. One clear example is the CFB supercritical unit at the Lagisza Power Plant in Poland, owned by PoludniowyKoncernEnergetyczny SA (PKE). This unit has now been in commercial operation for three full years, exhibiting very good performance, and has validated Foster Wheeler's performance model at this utility scale as well as for units in the 600 MWe and 800 MWe size ranges offering net efficiency of -43 per cent (LHV basis). This operating unit has also proven the use of the world's first FW/BENSONTM vertical-tube OTSC low mass flux technology. Since the Lagisza original international tender specified OTSC PF technology, it is important to note that the alternative selection of CFB OTSC technology over conventional PF technology is of historic significance, not only for the validation of the CFB supercritical platform as a viable alternative to conventional PF technology, but it also positions the CFB OTSC with fuel flexibility for offering of sizes up to and including 800 MWe units. This paper explores the differences between CFB OTSC technology and standard PF OTSC in utility power generation. Selection criteria, fuel burning range in both technologies, and other selection drivers are discussed. Economic analysis of both technologies, based on existing cases, is also provided. Also discussed are the technical advantages and uses of each technology. Foster Wheeler has recently been awarded a contract for four units of CFB OTSC technology, which utilizes a 2 on 1 configuration of two 550 MWe CFB OTSC boilers on two single 1000 MWe turbines. Essentially this provides a fuel-flexible low-emissions alternative to a 2 x 1000 MWe solid fuel power block.

Jan 1, 2012

By H. C. Liang

Reverse osmosis (RO) and nanofiltration (NF) are widely regarded as being best available technologies (BATs) for removing contaminants of concern from water. In recent years, NF or RO treatment has increasingly gained more acceptance in the mining industry for treating mine water to remove a wide assortment of contaminants, either for meeting discharge standards or for internal re-use in mining processes. Consequently, the number of NF or RO membrane mine water treatment facilities has steadily increased. Although NF or RO membrane filtration can be a powerful tool in mine water treatment, especially when multiple contaminant removal is required, it also has many potential disadvantages. Besides the generally higher capital and operational costs for the high pressure membrane processes, organic constituents in mine water may foul the membranes, while inorganic compounds such as gypsum, calcite, or silica are liable to scale the expensive membranes if proper pre-treatment processes are not implemented. Additionally, because these membrane treatment processes generate a substantial reject or brine waste stream in addition to the clean treated water or permeate stream, brine management also needs to be considered carefully when deciding upon the viability of an NF or RO mine water treatment process. Because of these issues, it is important to conduct detailed analyses of the trade-off between selecting NF or RO vs. using chemical treatment processes when designing a mine water treatment facility.

Jan 1, 2012

By A. Choudhury

Deep open-pit mines are becoming increasingly common in the highly mineralized arctic and sub-arctic regions. Air inversion is a frequent occurrence in these regions, and is exacerbated by the natural topography of an open-pit mine. Due to such inversions, the air quality in open-pit mines deteriorates very rapidly. Transport of gaseous pollutants under arctic air inversion is complex and involves an interaction between flow, thermal and convective transport systems. This paper discusses the construction and validation of a three-dimensional model that simulate the flow of air and the transport of gaseous contaminants in an arctic open-pit mine and the effect of low influent velocity and large gust velocities on the contaminants profiles in the mine. It was found that while higher velocities may remove contaminants from the pit bottom, they may not remove the contaminants from the pit entirely, necessitating artificial mitigation measures.

Jan 1, 2012

By H. Ogasawara

Information on rock stress is important for safe mining in seismically active ground. On a major gold mine, a few tens of crews are continuously conducting geological drilling with small pneumatic machines. However, stress measurements are not often carried out in South African deep-level gold mines. One of the reasons is the drilling diameter that overcoring requires, which is much larger than the diameters used in regular geological drilling, e.g. Boart Longyear Metre Eater, which drills A[O] or B[O] holes. Larger diameter holes result in slower drilling advance, more load in transportation and handling at sites, and higher cost. In order to enable overcoring in BX size (60 mm diameter), we modified the compact conical-ended borehole overcoring (CCBO) technique that has been suggested by International Society for Rock Mechanics (ISRM) and was originally designed for NX drilling (76 mm diameter). With a single overcoring, the 3-D stress tensor can be determined. We tested this modified method at a depth of about 3 km at Moab Khotsong mine in South Africa. We worked with drilling crew who usually work at geological drilling with the Metre Eater. In January 2011, we tried using regular geological drilling tools (a sequence of a normal BX bit, reamer, and rod) without success. In August and September 2011, introducing stabilizers and thin BX bits, we succeeded. We could complete a cycle of procedures necessary for an overcoring, including shaping the borehole-end conically, glueing a 16-element strain cell, and overcoring, within 2.5 hours. Only 10 cm overcoring is needed, which increases the chance of successful overcoring in heavily fractured conditions. This modified method is suitable for up-dip holes to depths of 10-15 m from tunnels, and has the potential to be widely used at the initial stage of geological exploration drilling at many localities.

Jan 1, 2012

"Pilot plants for pressure hydrometallurgy represent special design and project execution challenges. Over the past twenty years, Zeton has designed and fabricated a variety of world-class pressure hydrometallurgical pilot-plant facilities, and this paper discusses design considerations and strategies related to such projects. Project execution methods are also discussed, and guidance is given for the selection of materials of construction and for the selection of appropriate pressure and temperature design points for pressure hydrometallurgical pilot equipment. The paper concludes with a discussion of the need for process similarity with future commercial operations and the realities of pilot-scale equipment.INTRODUCTIONThe process technology developer or owner and the designer/fabricator of a new pilot-plant facility are faced with some difficult technical choices even after the decision to build a dedicated plant has been taken. A pilot-plant project is usually on the critical path of a large commercial project involving investments many multiples greater than the capital cost of the pilot plant. Schedule savings in the design, manufacture, and commissioning of the pilot plant or in a rapid completion of the experimental program can be disproportionately beneficial to the overall development project. However, inappropriate shortcuts resulting in major oversights can be disproportionately problematic.A number of considerations and suggestions for both the project execution approach and the process engineering design of pressure hydrometallurgical pilot-plant facilities are presented as a guide for potential owners and operators of new pilot-plant equipment and facilities."

Jan 1, 2012

By Monika Patrycja Polak - Micewicz

This paper presents an approach for estimating the fatigue life for the base of powered roof supports (shield) manufactured by the FAZOS roof support company. FAZOS?s powered roof supports are designed to operate on an inclined coal seam in full caving with a medium, strong roof strength. This shield support is utilized in conjunction with a shearer and face conveyor for a complete longwall mining system. To design shield support, it is essential for contractor to know the physical (hardness, toughness, etc.) and mechanical properties of material (tensile strength, Young?s modulus, etc.) used for the shield support as well as the geotechnical properties of the mine site. The fatigue strength of the shield support material depends on the mean stress, alternating stress, cycle frequency, transport dimensions, mine environment and other factors. In order to estimate the fatigue life for a powered roof support system, it is assumed in this paper that the support must keep the roof stable in the mine under variable load cycles. The approach selected in this study contains Goodman?s model (Goodman, 1899) for all blocks in the design housing which is subjected to sinusoidal load. On this basis, the degree of fatigue damage was calculated and compared to the results of experimental tests. It will be shown that there is a significant detrimental effect on the fatigue life of the base of the powered roof supports due to geometrical notches. The Ramberg-Osgood model and damage accumulation rule (Palmgren-Miner) (Miner M., 1945) were used and numerical analyses were conducted, utilizing ANSYS finite element software. These analyses play a very important role in longwall casing design. The proposed method allows assessment of the yield state and forecast of the structure cracking, taking plastic strains occurrence into account. The presented method is universal and can be applied for fatigue life estimation of other subassemblies of powered roof supports. The final portion of the paper presents results of variable amplitude loading simulations on the S355N and S690Q steel used to make powered roof supports. The results of the physical tests were compared with the results from finite element methods. The proposed approach to calculate fatigue life gives the best correlation between the experimental results and calculated values of fatigue life for the powered roof support base. Finally, the design process uses a simple approach to predict fatigue life in a short time, reducing design costs and providing longer service life for roof supports.

Jan 1, 2012

By J. T. Kalala

Particles for heap leaching in conventional circuits are prepared using Cone crushers. Cone crushers are used to crush the ore to the size range between 12-25 mm for heap leaching operations. Leaching from these relatively coarse particles occurs only at the surface and in subsurface regions, which are accessible from the surface by cracks and pores. Since leaching is active in accessible areas, the method of comminution that forms multiple cracks and pores would offer an advantage for heap leach. An investigation was performed in this study to assess if the HPGR forms more cracks and pores than a Cone crusher. X-ray computed tomography (CT) was used to characterize the degree of cracks and pores formed by these two comminution devices that can be used for heap leaching feed preparation. In order to compare the effect of the comminution method on crack network generation, a bulk sample of the zinc ore was crushed by the HPGR at three different pressure settings (45, 95 and 120 bar), the sample ore was also crushed with a Cone crusher for comparison purposes. Products from the Cone crusher and HPGR experiment were then screened into five size fractions ((-25 +19), (-19+16), (-16+9.5), (-9.5+5), (-5+4.75) mm), Subsamples from the ((-25 +19), (-16+9.5), (-5+4.75) mm) size fractions were analysed. The spatial distribution of the crack network of sphalerite particles was characterized using a highresolution industrial X-ray CT system. This paper describes the use of image analysis techniques including image segmentation, which uses a combination of thresholding and other methods to characterize and quantify crack and mineral dissemination in the sphalerite particles after comminution with the HPGR and Cone crusher. The results are validated with those obtained using traditional techniques such as physical gas (with N2) adsorption, mercury intrusion porosimetry, SEM and QEMSCAN.

Jan 1, 2012

By I. Yutronic

Compañía Minera Doña Inés de Collahuasi's (CMDIC) Concentrator Plant is located at 4300 meters above sea level, approximately 2000 kms north from Santiago, Chile. The concentrator has three grinding lines. Each one, Lines 1 and 2, have one SAG mill at the primary grinding stage followed by a secondary grinding and classification stage consisting of one ball mill, two hydrocyclone batteries and a sump with two pumps. Line 3 has one SAG mill (Gearless Mill Drive), followed by a secondary grinding and classification consisting two ball mills, four hydrocyclone batteries and a sump with four pumps. Average throughput for these three lines is 150 Ktons per day. Peak values of 180 ktons per day have been achieved. Since late 2008 and throughout 2009 and 2010, Operations and Automation areas developed an optimization program for the grinding process, considering the implementation of Model Predictive Controllers (MPC) for the three SAG mills, and later, extending MPC to the secondary grinding and classification stages. The implementation of a MPC solution was based on stability considerations (high variability of the SAG process, high interaction between sump level control and classification efficiency, etc), requirements for an automated and consistent operation, the need to maximize throughput under timevarying scenarios and, in the long term, optimization of grinding process considering Specific Energy Consumption, among other parameters. MPC solutions had proven control robustness and strong optimizing capabilities in terms of helping in discovering new operational points and so achieving all of the aforementioned goals. On the first stage of the program, MPC implementation considered identification of dynamical process control models based mainly on historical data, in order to know the impact of a group of Manipulated Variables over Controlled Variables. Also, the impact of measured Disturbance Variables was modeled in order to take into account the high impact and interaction of these variables over the processes. At the end of this stage, 4 controllers were successfully operating for the 3 SAG mills and the secondary grinding and classification process. In response to challenges made by the working group, the second stage of the development of control applications in the grinding process required to achieve a design and implementation of a solution capable of governing the milling process, in addition to stabilization and optimization of both processes (SAG milling and secondary grinding), to integrate from a point of view of process control and automation. Therefore, in the second stage, MPC performance was continuously monitored and optimized through advanced tuning, inclusion of more process models (with proper step tests), redefinition of specific optimization criteria and adjustment to new process needs. Finally, successful MPC implementation at Collahuasi has proved that fast development and deployment of process control solutions is possible and allows immediate process stability, higher throughput, specific energy consumption reduction, and successful product size control, among many others.

Jan 1, 2012

The Autogenous milling of ores holds an increasing attraction as the focus moves towards reducing energy usage, both direct and embodied in grinding media. However, most of the early AG mills were converted to SAG for improved stability and increased throughput. This imposes a huge penalty in steel grinding media consumption. The LKAB iron ore operations in Sweden process highgrade magnetite through fully-autogenous milling lines to a final product P80 of about 45µm. The outcomes of P9O AMIRA research surveys, covering a wide range of mill fillings and throughputs and with different feed blends, are presented. Insights are provided on operational strategies, opportunities, the influence of feed size control and balancing the blend of competent gangue and softer magnetite. Areas of importance in the successful operation and control of energy-efficient autogenous circuits are highlighted.

Jan 1, 2012

By Jinfu Xu, Youqing Cao, Yuting Lv, Hang You, Peng Jiang

"In present work, we reported the fabrication of composites consisted of M42 powder metallurgy high speed steel and 45 steel at one step via spark plasma sintering (SPS) technology. The interface microstructure, compositions and microhardness with the interface forming mechanism were investigated. The results show that the morphology and microhardness within the M42/45 steel interfaces exhibit a gradient distribution. The interfaces possessed a transition layer up to 10.2 ?m with few distortions and microcracks. The formation of M42/45 steel interfaces were driven by both fusion and diffusion processes. The former one was primary at the early sintering process, while the later one becomes dominant over the followed sintering process.IntroductionPowder high-speed steels have been widely used in cutting tools, cold-hot tools and dies, as well as in cut materials and structure parts with wear resistance and high-temperature resistance, due to its high hardness, good wear resistance, desirable cutting toughness and favorable hot hardness [1-2]. For materials of some parts in practical production, not only the favorable toughness is required to resist the impact action, but also the high hardness and exceptional wear resistance are demanded. According to the functional requirements and working conditions, bimetal composite materials are prepared in a certain mode, proportion and distribution, by designing two metals with different chemical and physical properties [3-6]. Considering the composites exhibit different properties in different positions of the parts with a combination of the advantages of two metals, they can obtain enhanced properties that the single one can not achieve."

Jan 1, 2012

By Merete Tangstad, Gabriella Tranell, Jeff Kline

"Raman spectroscopy as an instrumental technique for the determination of silicate structure is widely accepted. This method was utilized for analysis of structural modifications associated with the addition of network modifying species. Silicate melts are described by the extent of oxygen bridging. Therefore, understanding the effect different oxides have on modifying the silicate structure will provide valuable information regarding the removal of boron from silicon in slag refining processes. Samples ranging from CaO/SiO2 = 0.56-1.2 were evaluated with and without varying concentrations of B2O3. The addition of CaO to SiO2 revealed Q2 species constitute 45% of the Qn species and addition of B2O3 to the high concentration CaO system results in an increase in Q2 and a decrease in Q0 . The disappearance of the Raman band associated to the three-member ring in the low concentrated CaO system indicates boron addition and destruction of the ring.IntroductionExtensive studies on the structure of silicate systems have been performed using Raman spectroscopy with consensus on the Raman shift associated with different bridging oxygen units [1]. Most of these studies are motivated by the lack of a fundamental understanding of the processes involved in petrology. Due to this, an opportunity exists to build on the knowledge obtained from these studies and conduct more research on slag structures relevant to industrial applications, as these systems are often compositionally similar to magmatic melts. Raman spectroscopic studies of industrial slags will provide insight into the possible structural modifications necessary to enhance removal of impurity species from the metal phase to the slag phase."

Jan 1, 2012

By J. M. Wempen

Booster fans in underground coal mines are often located using the concept of a neutral point. Normally, intake airways are maintained at higher absolute pressure than return airways, so air leaks from intake to return. By adding a significant pressure force to a region of a ventilation system, booster fans installed in a return airway can increase the pressure in the return so that air leaks from return to intake. This is commonly referred to as recirculation. The neutral point occurs at the location in the system where the pressure difference between the intake and the return airway(s) is zero and at this point there is no leakage or recirculation. Ideally, placing a booster fan near the neutral point minimizes leakage and recirculation; however, in practice the position of the neutral point is not static and it changes as the ventilation system parameters change. This paper presents a study of how changes in the system parameters affect the location of the neutral point in a model coal mine ventilation system. First the effects of booster fan pressure and location on the neutral point are evaluated. Next the effect of increasing mine distance, and therefore mine resistance, on the location of the neutral point and the magnitude of recirculation is evaluated.

Jan 1, 2012

By D. Cronin, A. Plumtree, A. Hosseini

"Crack in corrosion (CIC) linepipe defects are hybrid defects not directly addressed by existing assessment methods. To investigate the collapse pressure of these defects, CIC defects were formed in 508 mm (20 in) diameter, 5.7 mm thick API X52 linepipe. These defects were 200mm long and varied in depth from 3.0 to 3.8 mm. The respective failure pressures decreased from 14.3 MPa for the plain pipe to 7.9 and 6.2 MPa respectively. A standard FAD method was applied to evaluate these defects as equivalent length and depth cracks, predicting the rupture pressure conservatively by 18% on average. However, when assessed as equivalent cracks with a reduced wall thickness corresponding to the corrosion depth, the predicted collapse pressures were more accurate, approximately 14% conservative on average.INTRODUCTIONPipelines are a safe and efficient method for transporting high volumes of oil and gas. However, aging pipelines may experience defects, such as cracks or corrosion. Present approaches include detection, assessment and repair of defects before they may become critical to the integrity of the line. There are different codes and standards for assessing pipeline defects, depending on the type of defect, with API 579 (API, 2000) being the most common code for the assessment of cracks in oil and gas pipelines . Corrosion is commonly assessed using RSTRENG (Kiefner & Vieth, 1989). Other methods such as the Finite Element method and the CPS method (Cronin & Pick, 2002) may be used for crack and corrosion, respectively.At present, there is no specific method or procedure for assessing crack in corrosion (CIC) defects, and as a consequence there is a need to provide an assessment and evaluation of the integrity of these defects in order to determine the requirements for defect repair or hydro line testing. Hence, the goal of this study was to provide guidance for the assessment of CIC defects for linepipe.CRACK IN CORROSION DEFECTS (CIC)Significant amounts of corrosion and cracking are not generally found together (Hosseini, 2010). However, a new hybrid defect including cracking within corrosion (CIC) has been identified in operating pipelines. In this case, cracking coincident with corrosion (schematic shown in Figure 1) provides the motivation for the current study."

Jan 1, 2012

By L. A. Cornish

Pt-based alloys for high-temperature applications in aggressive environments have been under development for over 10 years, and are targeted to be used as either as bulk, or as coatings. The alloys comprise Pt, Al, Cr, and Ru, and the microstructure has been improved by composition to a best possible analogue of the nickel-based superalloys, which these alloys could partially replace. This was necessary because the previous best alloy had a strengthening precipitate volume proportion of only approximately 40 vol.%, whereas the nickel-based superalloys have around 70 per cent, and a lower volume would mean that the strength would not be the best that could be obtained. The microstructures were assessed using electron microscopy, and have been related to the alloys? hardness values. The current microstructures are much more like those of NBSAs, with a high proportion of the strengthening ~Pt3Al precipitates. Since the samples have to be small (platinum is expensive), hardness has been used as an indication of strength. Nano-indentation studies showed that the hardness and Young?s modulus were higher for ~Pt3Al than the (Pt) matrix. More extensive oxidation studies have been undertaken on the previous optimum sample, and the effect of cooling rate after heat treatment has also been ascertained. In addition, the samples were studied after different heat treatment times, and cross-sections were made in order to characterize the alumina scale that formed. The oxide scales of Pt-11Al-3Cr-2Ru (at.%) up to 100 h exposure did not spall, and were at least as good as those of the ternary alloys. There was no discernable Al depletion zone in the substrate, although it could have been at a greater depth than thickness of the samples studied. Further additions to the Pt-Al-Cr-Ru alloys have been studied, to increase the melting temperature as well as to reduce the platinum content without compromising the properties. Reduced platinum content would have the benefits of reduced density and cost. The target elements include vanadium and niobium, of which vanadium is of special interest, since it is a South African product. Before these additions could be made, phase equilibria studies were undertaken so that the maximum addition could be ascertained, and also to check any possible ternary phases, which could be deleterious. Work on the Pt-Al-V system revealed a ternary phase, ~V27Pt54Al19 (at.%), which has a eutectic reaction with (Pt). The maximum V addition is likely to be around 15 at.%, otherwise ~Pt3V or the ternary phase will form, and not the required (Pt)/~Pt3Al phases.

Jan 1, 2012

By C. Musingwini

The South African mining industry continues to be a major source of employment at a time when at least 25 per cent of the working age population is unemployed. At the same time the industry faces a skills shortage in many of the disciplines necessary for its future health. The University of the Witwatersrand, University of Pretoria, University of Johannesburg, and University of South Africa have historically produced mining graduates for the South African industry, with any shortfall being met by the recruitment of overseas graduates. More recently the global shortage of engineers and other mining industry professionals has seen a reversal of this trend and a very significant emigration of well-educated and highly skilled personnel. The traditional career path for mining graduates is in production and mine management. However, there is the parallel and possibly more pressing need for specialized skills in such fields as ventilation, rock engineering, mine planning, mineral resource evaluation, and mineral asset valuation. It is in these essential areas that chronic shortages continue to hamper the development of the industry and may well frustrate its ambitions to be safe, healthy, and profitable into the future. The permeability of skills across sectorial boundaries within the mining industry requires that skills shortages in the platinum sector are not looked at in isolation, but within the context of the entire industry. This paper reviews the efforts being made by the universities at both undergraduate and postgraduate levels to meet the needs of the South African mining industry, in terms of the required numbers and the range of specialized skills.

Jan 1, 2012