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By Binxu Zhaug, Mark Jolly, Xiaojun Dai

"In conventional investment casting process of aluminium alloys for the application of the aerospace industry, to assure the quality of the final casting, usually the foundry uses large runner system which results in low yield, high energy consumption and high GHGs emission. In one case of this investigation, the yield is between 5 ~ 10% which means that the current casting process wastes large amount of energy and generates lots of scraps. By applying a new casting method, the bulky runner system and the melting/holding time are significantly reduced, the quality of the casting is improved, and in the meantime the related energy consumption and GHGs emission are significantly decreased. In the investigation, the energy efficiencies and GHGs emission between the current and traditional processes are calculated and compared.1. IntroductionAs one of the conventional casting process, Investment Casting Process (ICP) and its applications can be traced to thousand years ago [l]. In current casting industry, ICP still plays an important role in the production of small and precious castings with high quality requirements in automobile and aerospace industries. Both casting quality and manufacturing costs which mainly consist of energy costs have crucial effects on the competitiveness of castings in the market. In the production of aluminium alloy castings using ICP, the energy cost and energy efficiency of a casting facility depend mainly on the efficiency of its melting and heat treating performance. In association with the two performances, more than 60 % of the total process energy costs are symbolised in a typical casting facility [2]. Additionally, in conventional ICP of aluminium alloys for the application of the aerospace, to assure the quality of the final casting, typically the foundry uses huge runner system including big risers/feeders which cause low yield, creates lots of scraps and generates high energy consumption. Consequently, there are huge opportunities for casting industry to choose the best practices for potential energy saving. Furthermore, the reasons such as the stringent limitation of environmental legislation in Europe and the pressure of the rising energy price force the casting industry to reduce the energy consumption and greenhouse gases (GHGs) em1ss10n."

Jan 1, 2012

By M. S. Safarzadeh

Over the last fifty years, the treatment of enargite concentrates has not received much attention primarily because of the availability of other clean concentrates suitable for processing with existing smelting and/or leaching technologies. As traditional copper ores have become scarcer, copper-arsenic ore deposits have garnered more interest. Arsenic release is a significant concern during the treatment of enargite by pyro or hydrometallurgical methods. Enargite is also very refractive in standard leaching procedures. Thus, economical treatment options for enargite concentrates are needed. Preliminary experiments have shown that the acid-bake leach process could be adapted and used for the treatment of enargite concentrates. In this study, low-temperature (100-400 ºC) sulfuric acid baking of an enargite concentrate followed by water-leaching has been evaluated. The results indicate the thermal transformation of enargite to copper sulfate during sulfuric acid baking, with most of the arsenic being released from the concentrate into the gas phase for baking at 400 ºC. The condition for maximum copper extraction (~100%) from the concentrate was found to be 400 ºC, sulfuric acid amount of 0.5 mL/g of concentrate, and 2 h baking time. Part of the arsenic was captured in the form of arsenopyrite (FeAsS). XRD analysis proved the presence of some arsenic in the form of claudetite (As2O3) in the baked concentrate. Acid baking of pure enargite behaved in similar fashion.

Jan 1, 2012

By B. Schoevaerts

The ever-increasing depth of mineral extraction presents a challenging environment for hard-rock underground mines. High in situ stresses and associated seismicity with potential rockburst hazards are the major decisive factors contributing to the choice of a ground support regime. Conventional ground support systems, designed primarily for static loads, are not always capable of providing safe working conditions for underground personnel in seismically active mines. Systems specifically developed to resist dynamic loading and allowing for larger deformations are therefore preferred alternatives. High-tensile chain-link mesh has a proven record of successful use in open cut operations in various rockfall barrier installations due to its high energy absorption capacity. It has also been used in underground operations in various parts of the world. Its application in South African underground mining, however, is limited due to the high labour intensity. This paper describes a method of mechanized installation of a chain-link mesh as evaluation at Gold Fields' South Deep Gold mine situated some 45 km south-west of Johannesburg. A purpose-built mechanized roll mesh handler, developed in Australia, was used in this trial. The handler is compatible with all standard multi-boom underground drill rigs and is operated utilizing the hydraulic circuit normally used for the feed arrangement. A number of key performance indicators have been specified as success criteria by Gold Fields: ? A 30% faster installation compared to the conventional methodology ? The mesh should sustain any blast damage when applied to the blasting face ? No unravelling of the mesh when cut ? No failure of mesh under normal conditions ? Reliability of the MESHA® installation handler (availability >90% ? Compatibility of the MESHA® installation handler with AC 282 boomers. Although the energy-absorbing mesh combined with yielding rockbolts is a ground support system of choice for rockburst-prone conditions, the operational upsides recognized during the trial imply that this product can also be competitively used in less demanding ground conditions where weld mesh or shotcrete are customarily used as a primary surface support.

Jan 1, 2012

A clay binding agent has been investigated to enhance flotation recovery of bitumen from Canadian high fines oil sand in the Clark Hot Water Extraction (CHWE) process. Selective adsorption on fine particles and subsequent agglomeration are critical for the success of clay binder enhanced oil sand flotation. A number of flotation tests have been performed at different reagent dosages under different operating conditions such as pulp pH to evaluate the reagent performance. Dissipative Quartz Crystal Microbalance (QCM-D) analyses of clay binder adsorption on quartz were carried out to better understand process mechanisms. It has been found that use of clay binder in flotation resulted in an absolute bitumen recovery increase of 18%, 25%, and 11% for the high-, medium-, and low-grade oil sand samples, respectively. The QCM-D analyses have revealed that the clay binder was strongly adsorbed on the SiO2 surface.

Jan 1, 2012

By Drew Martin

In March 2010 the Boral Linwood Quarry, Adelaide South Australia, implemented the blasting contractors Monte Carlo Blast Vibration Model as part of their blast design process. The Linwood Quarry was developing an area where blasting activities were marginally complying with the statutory vibration limits. Compliance to the statutory limits was only being achieved through the use of small blasts (less than 15 000 T (14 763 ton)) at a high cost to the quarry.

Jan 1, 2012

By Jarrod Bonsmann

"This paper presents the results of small scale testing to examine the effect of various importantparameters on the response of a vehicle due to the detonation of an explosive charge buried inthe soil below the vehicle. In particular, we were interested in examining what effect change instandoff distance, change in mass, and change in surface area would have on the loading applied.We examined the impulse delivered to the target in all cases and for the change in mass andchange in stand-off distance we examined impulse, kinetic energy, and acceleration."

Jan 1, 2012

By Zhang Hanbo, Niu Liping, Zhang Zhiqi, He Jicheng, Dou Zhihe

"Rutile, ilmenite and Al-Ca complex reducer were used to prepare high titanium ferrous alloy by enhanced reduction-SHS method. The effects of the complex reducer compositions and slag types on the enhanced reduction-SHS process were investigated. The high titanium ferrous alloys were characterized by XRD and SEM. The results indicate that the high titanium ferrous alloys consist mainly of TiFe2, AlTi3 and Al2O3. The oxide inclusions exist resulting in directly the high oxygen content and micro-structural defects in the alloys. The titanium and oxygen contents decrease, but the aluminum content in the alloy increases while the mass ratio of calcium in the Al-Ca complex reducers increases. When the mass ratio of Al/Ca in the Al-Ca complex reducer is 6:1, titanium, oxygen and aluminum contents are 63.75%, 3.01% and 10.72% respectively. When the mass ratio of Al/Ca is 5:1 titanium content is 55.00% nearly and aluminum content is higher than 14.00%, but oxygen content is lower than 2.0%.1. IntroductionThe high titanium ferroalloys with 65%~75% titanium have the advantages of low melting point and high titanium content. They are widely used in special steel refining, while they are also a kind of very important quality orientation alloys in the rage of aviation and aerospace. At present, the methods of preparing high titanium ferroalloy include vacuum remelting and thermit reduction. The alloys prepared by the vacuum remelting method have good qualities and low oxygen content, so it is widely used in Russia, Western Europe and other developed countries. In China, there are abundant rutile resources, but waste titanium is lack, therefore, the preparation method is the thermit reduction. But there are many quality defects in the high ferrotitanium alloy, including high oxygen content, unstable quality and so on. In order to improve the qualities of the high titanium ferroalloy, especially to reduce oxygen content, the domestic and overseas have done a lot of further researches. For example, Sichuan E-mei ferroalloy plant and Beijing Nonferrous Metal Research Institute have prepared high titanium ferrous with 73.77% titanium with natural rutile, but the oxygen content is high. Through controlling the quality of raw material, they obtained the better qualities, but the oxygen content is still very high. South Africa Mintek company have prepared high titanium ferrous alloy with low nitrate by plasma heating under the isolation air conditions, but they couldn’t also remove effectively oxygen in the alloy. The oxygen exists in the form of Al2O3 and titanium protoxide. So it can be speculated that except TiO2 not being fully reduced, the no-sufficient alloy-slag separation is the direct reason resulting in high oxygen and poor microstructure. In view of present technical difficulties during preparing high titanium ferroalloy by thermit reduction, this paper proposed a new method of preparing high titanium ferrous with low oxygen by enhanced reduction-SHS with Al-Ca complex reducer. Ca in Al-Ca complex reducer has stronger reductive ability, it can effectively strengthen the reductive degree of TiO2. The slagging agent CaO CaF2 and MgO can effectively reduce the viscosity of Al2O3 slag to improve its liquidities to strengthen alloy-slag separation effects so that to remove inclusions and oxygen. In this paper, effects of slagging agent type on the reduction and the qualities of high-titanium ferroalloy were studied."

Jan 1, 2012

By O. F. Ochonogor

Laser metal deposition (LMD) is an additive manufacturing technique whereby a stream of metal powder is consolidated by a focused laser beam on the surface of a substrate or engineering component. The interaction zone between the laser beam and powder particles is scanned superficially, generating tracks of deposited material. The tracks are overlapped in a deposition strategy in accordance with slices of a CAD model. Successive layers of material are built up to fabricate a near net shape part. In this work, the technique is used to fabricate metal matrix composites (MMCs) by using an elementally blended feedstock combining metal and ceramic powders in the melt pool, which melt and solidify to create the required morphology. Ti6Al4V + TiC MMCs were produced with 10, 20, and 30 vol.% reinforcing ceramic, and Zr + TiC MMCs were fabricated with 10, 20, and 30 vol.% TiC. The deposited thin walls were analysed using optical microscopy, scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS), and indentation testing. In both systems, the analysis revealed the presence of partially melted TiC particles embedded in the metal matrix along with fine dendrites of re-solidified ceramic. The dendritic structures in the Ti-based composites were confirmed as TiC, whereas in the Zr-based composite the Zr metal reacts with theTiC to form ZrC, leaving Ti in solid solution. Both the MMCs show an increase in microhardness with increasing ceramic (carbide)content, reaching a peak HV0.1 value of 500 in the Zr- based MMC and HV0.1 of 550 in the Ti based MMC.

Jan 1, 2012

By Scott Scovira

All flyrock incidents have the potential to result in injuries or fatalities that can result in loss of company reputation, license to operate with clients, and bear the exposure to high cost liability. From 2007 to 2009, one NA Quarry and Construction Business experienced a series of flyrock incidents. In the Spring of 2009, this business declared that the frequency and severity of Flyrock Incidents had reached an unacceptable level. A Flyrock Elimination Program was launched.

Jan 1, 2012

By Andre Zingano

The variation in pillar behavior at underground coal mines working in the Bonito coal seam is observed in both research and mining company case studies. There is no consistency in pillar behavior, as it varies from mine to mine. In some cases, it is possible to find rib yields for both excavation modes and pillar sizes. This paper?s objective is to investigate pillar behavior for different load conditions and pillar sizes. Three-dimensional numerical simulation models considering these factors were built. A matrix was then assembled to compare pillar behavior between loading conditions, as well as between different pillar sizes with the same loading condition. The results showed some pillar rib plasticity due to vertical loading and stress relief independent of the pillar size and load. For the same load conditions, the yielding thickness is the same for different pillar sizes.

Jan 1, 2012

By C. Norden

The purpose of this article is to show how a representative overall equipment effectiveness (OEE) measurement can be calculated for an underground coal mining bord and pillar batch process. The calculation method, the typical losses (which include planned and unplanned availability losses, coal quality losses, and process rate losses) and the underlying logic are presented and discussed. It is argued that the current traditional underground bord and pillar mining process can currently provide a maximum theoretical OEE of only 49 per cent, while a realistic benchmark target should be in the order of 37 per cent, which relates to an average of 2400 t per shift or 1.2 Mt/a. In addition, it is argued that the current bord and pillar process is the current bottleneck to further improvement past the 2400 t per shift benchmark, and that fundamental process changes will be required to eliminate this bottleneck.

Jan 1, 2012

By H. Paudyal, K. Ohto, H. Kawakita, S. Alam, B. Pangeni

The orange waste after lime water modification was converted into promising adsorbents for fluoride by metal loading reaction. The effectiveness and mechanism of fluoride adsorption on metal loaded orange waste gel from synthetic and real plating solution were investigated. Amount of zirconium(IV), aluminium(III), cerium(III), lanthanum(III), titanium(IV), vanadium(IV) and tin(IV) loaded on orange waste from aquearegia dissolution were evaluated to be 1.62, 1.16, 0.93, 0.95, 1.20, 1.12, 0.97 mmol/g respectively. The maximum adsorption capacity (qmax) of zirconium(IV), cerium(III), lanthanum(III), iron(III) and aluminium(III) loaded orange waste for fluoride ions were evaluated to be 1.74, 0.91, 1.07, 0.98 and 1.01 mmol/g from aqueous solution. The mechanism of fluoride adsorption by metal loaded orange waste was inferred to be ligand exchange reaction. Application of zirconium(IV) loaded saponified orange juice residue(SOJR) for real plating solution showed effective removal of trace concentration of fluoride down to the accepted standard. The negligible interference of co existing anions like nitrate, carbonate, sulphate and chloride makes zirconium(IV) loaded SOJR a promising sorbent for waste water treatment. The adsorbed fluoride from fluoride loaded zirconium(IV)-SOJR was effectively desorbed by using alkali solution for its regeneration. This work shed light on the potential application of metal loaded SOJR to remediate fluoride contaminated water for environmental relevance.

Jan 1, 2012

By M. Tangstad, H. Mølnäs, J. D. Steenkamp

"Temperature affects several aspects of pyrometallurgical systems, including thermodynamics and reaction kinetics. Reliability of temperature measurements in laboratory and plant applications is thus important from process, safety and financial perspectives. This case study briefly introduces different techniques utilized for temperature validation, and demonstrates temperature validation on laboratory scale utilizing the wire-bridge method. Pt/Ptl3Rh thermocouple hot junctions were constructed by mechanically connecting thermocouple wires through a pure metal bridge consisting of copper, gold, nickel or palladium wire. When heating the wire-bridge thermocouple alongside a regular Pt/Ptl3Rh thermocouple, temperature offsets were quantified as the wirebridge thermocouple short-circuited at the melting points of the pure metals. At the melting points of gold (1064°C) and palladium (1555°C), average measured temperature offsets were -2.1°C ± 2.3°C and 0.2°C ± 0.4°C, respectively. Results from the copper and nickel wire-bridges were inconclusive. The paper concludes with a discussion on the potential industrial applications of the technique.IntroductionThermocouples are probably the simplest of all temperature sensors, but are widely utilized due to simplicity, versatility and ability to handle a variety of experimental conditions and industrial applications. Additionally, thermocouples are often the only option in research laboratories requiring high temperature measurements, and a high level of reliability is usually required from thermodynamic, kinetic as well as safety points of view.The study presented here originated from a test program where the compatibility between different types of carbon-based refractory materials and industrial slag produced in silicomanganese furnaces were investigated on a laboratory scale utilizing the static crucible test[l]. Due to the nature of the silicomanganese production process, the compatibility tests were to be conducted at 1600CC[2]. Details of the experimental set-up utilized for the compatibility tests are discussed in the Experimental Set-up and Method Statement section later in this paper."

Jan 1, 2012

By I. Southern, S. Kelebek

"Smelting furnace bricks contain significant quantity of base metals trapped in refractory material. A series of flotation tests were carried out on samples of old bricks from Sudbury area to examine upgrading behaviour for recycling purposes. Depending on the grind size used nickel recoveries varied from 60 to 90.6% with corresponding grades of 20% and 14.7%Ni. There is a trade-off between nickel and copper. The nickel has responded well to fine grinding, however, the copper recovery suffered from it. Mineralogical characteristics and flotation behaviour of the brick material are discussed in reference to those from the primary ore. INTRODUCTIONMineral processing is well recognized as a mature technology not only for the mining industry, but also for the environmental industry for the purpose of remediation and recycling. Materials available for recycling are usually the products of many years ago. There are multiple stake holders in this area. In general, when the processing results in a product that can be reused or sold, the company carrying out the remediation makes a profit, while the regulators and the public are pleased due to a cleaner environment. From these points of view, there have been many papers published over the years on various mineral processing techniques applied to separation of many different materials including from mining and metallurgical industries (Wilson et al., 1994; Tsunekawa et al., 2005; Saikia et al., 2012).Flotation may be viewed as the backbone of the mining and metallurgical industry since its invention for separation of solids from one another almost a century ago. It is capable of recovering a variety of finely divided different solids following their liberation from each other. Its versatility and highly competitive nature in terms of cost per tonne of material processed, accounts for its occasional uses in the environment engineering area. In the mining industry, flotation is the standard method used for the sulphide ores. It can be applied as a bulk flotation and/or differential flotation. Bulk flotation, which refers to co-flotation of several components from their source, is most suitable for environmental cleanup objectives. Desulphurisation of various plant tailings is a typical example of this (Benzazzoua et al., 2000)."

Jan 1, 2012

By Timothy Fogarty, Gregory Poole, Roger Reeder, David Switz

This project involved the construction of a new pump station and intake structure at an existing water treatment facility. Although the project involved a significant amount of rock removal, the specifications said no blasting.

Jan 1, 2012

The SFR system utilizes a skimmer or extractor placed at or near the slurry-froth interface where there is a higher concentration of valuable mineral particles. With assistance of hydrocyclones, it is possible to classify the extracted particles into coarse and fine particle streams, that can be handled separately. It also allows the coarser solids to be separated from entrained low-value fines. The first test results with the SFR system significantly improved both coarse and fine particle recovery in a flotation cell. The SFR system was tested in the flotation circuit at a copper-moly concentrator, and the results show that the use of the skimmer has huge potential to increase the froth recovery (Rf) of both molybdenum and copper.

Jan 1, 2012

By Francois Barthelat, Sam Goroshin, David Frost, Alexander Cappozi, Atefeh Nabavi

"In this study, a novel chromium–chromium sulfide cermet was produced by self-propagating high-temperature synthesis (SHS). Conventional techniques for manufacturing metal sulfides are complex, environmentally harmful, and not suitable for producing complex-shape articles. To overcome these disadvantages, a new method for the preparation of the metal-sulfur precursor charge is proposed, which can be described as reactive casting. The first cermet samples produced with the SHS process were found to be very porous, brittle, and have low mechanical strength. The possible sources for the generation of porosity were identified and analyzed and the process for manufacturing the cermet was modified. By improving the manufacturing process, the porosity inside the produced cermets was reduced from 70% to 12%.IntroductionMetal sulfide composites are in high demand in the chemical, metallurgical, and electrical industries because of their valuable characteristics such as hardness, semi-conductivity, electroluminescence, infrared transparency and catalytic properties. Current manufacturing methods for metal sulfides usually involve one of two different principal methods, including a complex multistage wet chemical process involving the precipitation of the corresponding salts from an aqueous solution with hydrogen sulfide, or hot sintering of the respective elemental reactant powders in a resistive furnace in a high-pressure inert or hydrogen-sulfide atmosphere [1, 2]. These conventional methods for synthesizing ceramic metal composites are complex, extremely time and energy consuming, environmentally harmful, and rarely able to manufacture articles with complex shapes. Therefore, in order to overcome these disadvantages, self-propagating high-temperature synthesis (SHS) was considered as an alternative method that offers significant improvements over the traditional cermet manufacturing methods [3]. SHS, which is a relatively new and attractive method for producing a wide range of advanced materials, is based on the self-sustaining feature of the highly exothermic reactions of the reactants. The SHS process results in high product purity, since the high temperatures generatedin the reaction cause any impurities to volatilize [4, 5]. SHS has low energy consumption and doesn’t require an external energy source and complex equipment, and it is self-contained [1, 5]. Since combustion synthesis has low power requirements, it is one of the few methods of materials synthesis that is feasible in outer space. Also, the process has a low cost and is capable of directly synthesizing articles with the desired shape, size and structure [5, 6]. The chemical reactions associated with SHS are typically completed in a few seconds leading to the formation of the condensed product. The high reaction rates and relatively rapid cooling in SHS reactions can avoid undesirable grain growth in products which often occurs with the conventional sintering method [3, 5, 7]. The traditional method for sample preparation in the SHS technique is to compact the reactant mixture powders in a steel die by a press to a typical density of about 80% of the theoretical maximum value, before igniting the mixture [8]. This method requires a large compression force to increase the green density and to minimize any pores in the green compact. To overcome these disadvantages, a new method for the preparation of the precursor charge in metal-sulfur by SHS is proposed which can be described as melt casting of a reactive mixture, or reactive casting in short."

Jan 1, 2012

By S. J. S. Ferreira

Anglo American Platinum's Khomanani 2 shaft changed over from down-dip mining to breast mining in 2004. The changeover was made to ensure that production targets were met, as it was said that predevelopment for down-dip mining was not fast enough to sustain the required ore reserves; nevertheless, production performance did not increase as expected. In this study a trade-off was performed between down-dip mining and breast mining on the Merensky Reef at Khomanani 2 in order to find the most suitable method for mining the Merensky Reef. Data was gathered by means of a literature survey, underground observations, and interviews with personnel as well as data from various departments on the mine. The two mining methods were studied and then evaluated in terms of the following criteria: safety, mining rate, cost and other factors which were identified as the main drivers of the mine. A scaling system was used to rate the performance of the two mining methods. Analysis of the results shows that down-dip mining and breast mining have the same safety performance ratings. Breast mining has a better mining rate performance than down-dip mining. Breast mining was found to be costly in comparison with down-dip mining, which has a good cost performance rating. The overall ratings of the two mining methods are very similar, with down-dip mining achieving a rating of 76 and breast mining 75.5 out of an optimum 102. Khomanani 2 currently practices breast mining, and with such a slight difference in performance rating between the two methods, it will not be worth changing over to down-dip mining as production is likely to be adversely affected during the changeover. Down-dip mining does, however, have potential for improvement in its performance rating. Further studies focusing on the improvement of the mining rate performance for down-dip mining are needed to see if this potential can be realized. If significant improvement can be made in the performance rating for down-dip mining, a changeover to down-dip mining can be reconsidered.

Jan 1, 2012

By R. E. Mitchell

The environmental impact assessment (EIA) is the accepted method for evaluating proposed mining and other industrial projects to obtain regulatory approval and to help companies plan for responsible development. Another increasingly common evaluation system for proposed projects is the environmental, social and health impact assessment (ESHIA). An ESHIA differs from an EIA for its generally more comprehensive and inclusive approach to evaluating potential impacts, such as on public health, and other features such as an ecosystem services approach to assessing biophysical and community impacts. An ESHIA may also be required by certain lenders for financing major projects. In this paper, EIA standards for the province of Alberta, Canada are discussed and compared to ESHIA. It concludes with several recommendations for consideration.

Jan 1, 2012

By Signe Kjelstrup, Leiv Kolbeinsen, Marit Takla, Odne Burheim

"This paper presents a Seebeck-type solid state thermoelectric power generator unit, designed to investigate the possible recovery of radiant waste heat at a silicon plant in Norway where roughly 703 of the total input energy leaves the process as waste heat. The unit is 0.5 m x 0.5 m and is built of 36 commercially available thermoelectric devices based on bismuth telluride p - and n - type semiconductors. Thermoelectric devices directly convert fractions of a heat flux into an electric current (and vice versa) and may therefore be convenient for recovery of waste heat when the heat source is discontinuously available. The purpose of the thermoelectric unit is to give a proof of principle of direct thermoelectric energy conversion on a large scale. We present the initial test results for the generator. At an average temperature difference between the heat reservoir and the heat sink of 98°C, we measured an open ciruit potential of 23.44 ± 0.06 V and the matched load power output was 39.4 W. At a temperature difference of 220°C, we predict the generator open circuit potential to be 40.8 V, which corresponds to an efficient Seebeck coefficient of 242 µV /K, and matched load power output to be 120 W.IntroductionThe world's power demand increases, driven by population growth and increase in living standards and simultaneously global warming is recognized as one of our most serious environmental problems. According to the International Energy Agency[l], the industrial sector accounted for approximately one third of the total global power consumption in 2005. Increasing the energy efficiency of industrial processes thus represents a benign and substantial route for addressing environmental concerns and energy security.In accordance with the second law of thermodynamics, all real processes are associated with lost work which is energy being dissipated as heat to the surroundings[2]. Improving the energy efficiency of industrial processes is about finding the process path associated with a minimum of lost work. The more evenly the losses are distributed, the smaller are the losses [3, 4]. In addition, exploiting the unavoidable waste heat will contribute to improve the energy efficiency. The waste heat may be utilized for heating purposes and/or it can be upgraded to work for instance via some sort of heat engine."

Jan 1, 2012