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By Shenghui Guo, Jian Chen, Hongbo Zhu, Jinhui Peng, Linqing Dai, Qianxu Ye

"Response surface method (RSM) based on mono-factor experiment was applied for the process optimization of sintering of chromite fines by microwave. In RSM analysis, effects of binder addition amount, sintering temperature and holding time on the compression strength and shatter strength of the sinter were examined. Results showed that the optimal values of the above parameters were determined as follows: binder addition amount of 1.90% (in mass), sintering temperature of 1153? and holding time of 16 min. Under the optimized conditions, the compression strength was 11155.8? and shatter strength was 95.6849%. The results show that the process was optimized by response surface methodology is stable and feasible, and provide a new way for sintering of chromite fines.IntroductionChromite ore is the main feedstock for ferrochrome, and ferrochrome can be used as steelmaking additive to produce a variety of great strength, corrosion resistant and oxidation resistant special steel, which can be widely used in the aerospace, automotive, shipbuilding, military departments[1], and it has important strategic significance. At present, among the annual world's mined chromite the number of lump ore continues to diminish with its price rising sharply, while the proportion of ore fines been always increased, and the difference in prices between ore fines and lump ore is growing[2]. Despite the low price of chromite fines, and its rich in resources, it can be only used for ferrochrome smelting after agglomeration. Thus manufacturing blocks by using cheap chromite fines is an effective measure to reduce the cost of ferrochrome production and use the chromite resources[3]."

Jan 1, 2013

By Laurentiu Nastac, Ruslan Mudryy

"This paper investigates the solidification of cast energetic materials. An active cooling and heating (ACH) technology and a mechanical vibration (MV) technology were applied to achieve unidirectional solidification during casting and to reduce cracks, gas pores, and shrinkage defects. The design parameters of these technologies were developed via Computational Fluid Dynamics (CFD) modeling and thermal stress analysis. Concerning the ACH technology, the number of cooling/heating sections and their temperature profiles and time sequences were optimized based on the thermo-physical properties of the energetic material as well as the riser and mold diameter, thickness and type. The ACH technology will also decrease the thermal stresses during casting of energetic materials and therefore minimize the formation of potential cracks that may form during the casting process. The MV technology will help to remove air entrapped during pouring process and decrease the detrimental gap size between the projectile and the solidified energetic material.IntroductionCasting processes are widely employed in the manufacture of products with intricate shapes and, in particular, in applications where the material of the final product is sensitive to machining. It is especially useful in processing of energetic materials. The cooling conditions applied in the casting process can affect the quality of the final cast in terms of void formation, residual stress distributions, and mold separation. Substantial shrinkage is also observed due to the density change upon solidification [1-3]. Residual stresses are known to be closely related to the formation of cold cracks and hot tears during casting. The formation of a gap between the mold and the cast material is of critical importance due to its deleterious effect on heat removal and on crack formation. In the casting of energetic materials all these defects can significantly impair the detonation velocity, Gurney energy, and insensitive munitions characteristics of the formulation, and lead to catastrophic accidents in explosives handling [ 4-5]. Imposition of carefully controlled cooling condition is thus critical in optimizing the cast quality that could help avoid such destructive effects."

Jan 1, 2013

By Herbert F. ?Buck? Darling

A bridge replacement project in Rochester, NY, encountered difficulties when it was determined that rock below one pier was sloping downward toward the river at an angle of 42 degrees versus anticipated 12 degrees. Cofferdam design and construction became very difficult. The unanticipated subsurface conditions delayed the project by eighteen months and increased the cofferdam cost by almost $3.0 million ($US) when direct costs and associated delays were taken into account. The initial approach after discovery of the problem was to use the same type pier design and modify the cofferdam accordingly. This resulted in a cofferdam 12 meters (39.4 feet) deep on the shore side and 18 meters (59.0 feet) deep on the water side. The design used a master pile system to attain required wall strength and used rock anchors to prevent the cofferdam from moving toward the river. The pier foundation was then redesigned by the owner using revised seismic parameters. The original stepped footing carved into rock was replaced by caissons socketed into the rock beneath a large tremie concrete placement. The revised pier and cofferdam designs caused a shift from a mostly land based cofferdam, excavation, and rock removal project into an almost entirely water based cofferdam, caisson drilling, and tremie construction project. These design changes resulted in a reliable, safe, and unusual cofferdam and construction method. All of this was accomplished within a very narrow worksite with a railroad on one side, and the river with its public and commercial freighter traffic on the other. In addition, the existing two-leaf drawbridge was to be maintained in place which put further limitations on the water borne equipment. The engineering and construction considerations, problems, and solutions related to these cofferdams and pier foundations are presented.

Jan 1, 2013

By R. W. Leonardson

Tectonic activity in northern New Mexico during late Oligocene and early Miocene time presaged events which led to the development of molybdenite deposits at Questa. East-northeast directed crustal extension produced north-northwest striking tensional fracture systems paralleling the early Rio Grande rift. A sequence of Oligocene andesite flows and breccias is overlain by a thick early Miocene rhyolite ash-flow tuff. Eruption of the tuff initiated collapse of the Questa cauldron: the south margin of which occurs as an east-northeast striking, north-dipping structurally weak zone. Continued east-northeast post-cauldron extension permitted the high level emplacement of granite stocks with coeval rotational deformation of fault blocks composed of cauldron fill and [ ] floor. The stocks occupy north-northwest fracture zones in the south margin of the cauldron, and porphyry dikes occupy east- northeast striking faults that define the south margin. These two fracture systems have played a dominant role in localizing the intrusive porphyries and associated mineral deposits at Questa. A molybdenite-bearing breccia matrix and related stockwork mineralization generally occur within volcanic rocks. Mineral deposits are spatially related to fault zones and the upper con- tact of their source intrusives. Deposits are localized in fault zones up to several thousand feet long and 100 to 500 feet in diameter. Magmatic-hydrothermal solutions from the source aplite porphyries have produced potash metasomatic alteration which is strongly centered on the mineral and ore zones. Alteration in ore is represented by orthoclase, quartz and secondary biotite. This pattern grades into secondary biotite and propylitic zones forming successively weaker alteration assemblages away from ore. Younger phyllic and argillic assemblages are particularly widespread only where strong north-northwest extensional fracture zones cross the south cauldron margin.

Jan 1, 2013

By Bowen Li, Matthew D. Andriese, Jiann-Yang Hwang, Zhiwei Peng

"Magnetic iron sulfide ore particles heat rapidly by microwave (MW) irradiation generating plasma during oxidation of surfaces. The high temperatures produced by the exothermic event decompose local portions of samples forming a differentiated flux of partially melted silicate (si-mt) with entrained metal-sulfide (sul-mt) droplets. The si-mt forms crystals of olivine (01) in Ca-rich pyroxene (Cpx) melt that resorbs a portion of iron sulfide (Po). The immiscible sul-mt droplets of (Fe,Ni,Cu)1-xS contain magnetic subsolidus Ni-pyrrhotite (Ni-Po) with Cr-bearing ferrospinel (Mag). Sub-micron sized flecks of Au are found on the surface of a sul-mt droplet with scanning electron microscope (SEM).IntroductionSulfide ore deposits supply the world's mineral resource in the production of non-ferrous metals. Particularly, Cu-Ni deposits are chemically enriched in metals from high sulfur saturation during magmatic formation that creates the proper geochemical environment for metals enrichment [1, 2]. The sulfur and oxygen fugacity control redox conditions of a differentiated silicate/sulfur magmatic melt with the concentration of iron playing a dominate role in the chemical partitioning of metals in sulfide liquid [3, 4]. The initial magnetic crystallization of (Fe,Ni)i-xS monosulfide solution (mss) from metal-sulfide liquid has an exclusive effect on the fractionation of mineral assemblages (zoning) [5].Phase equilibria of sulfide melt (sul-mt) components are related by a miscibility gap with mss forming Ni-rich pyrrhotite (Ni-Po) followed by the crystallization of (Fe,Cu)1-xS intermediate sulfide solution (iss) [6]. Precious metals form stable chacogenides and are retained in solution until the final liquid solidifies. The redistribution of metals now occurs by subsolidus cooling of mss and iss that exsolve low-temperature Fe-Cu-Ni bearing mineral assemblages [7]. The proper interpretation of ore genesis increases processing capabilities by isolating chemically enriched zones during extraction and should be used to aid in sustainable mine site development [8-11]."

Jan 1, 2013

By Stephen C. Tadolini

Effective barrier pillar design is an essential component for safe and productive underground coal mining. Barrier pillar design methodologies that incorporate sound engineering judgment have been used for practical everyday usage. The next logical step is to utilize numerical modeling techniques that help combine practical experience and empirical observations into barrier pillar design analysis. A case study is presented that describes the barrier pillar design process, but also highlights the importance of considering the global mine response by evaluating: adjacent pillar stabilities, impact of intersection and entry widths, capacity of primary and secondary bolting systems and rib stabilization used for the safe and efficient removal of the longwall face equipment.

Jan 1, 2013

By D. Krippner, C. Nexhip, D. George-Kennedy, P. Gebski, R. Kaur, W. L. Ying

ABSTRACT Water-Cooled Tapblocks Are Essential Components Of Modern Smelting Furnaces. Uninterrupted Operation Of A Tapblock Is Critical For The Optimal Operation Of A Furnace. This Critical Function, Together With Exposure To Extreme Conditions, Drives The Need For An Efficient And Reliable Means For Tapblock Monitoring. The Main Objective Of Tapblock Monitoring Is To Help Optimize The Life Of The Tapblocks By Better Scheduling Inner Refractory Relining And Protecting Operators By Preventing Sudden Deterioration Of The Tapblock. A Taphole Acoustic Monitoring (TAM) System Was Developed To Meet The Above Requirements. This Paper Describes The Principles Of The TAM System And Selected Case Studies.

Jan 1, 2013

By Neely H. Bostick

The primary and secondary organic matter in sedimentary rocks changes markedly when it becomes heated as a consequence of thick sediment accumulation and normal geothermal gradients, high geothermal gradients, hydrothermal fluids, or igneous events. Contact zones adjacent to small igneous dikes allow sampling of a single sedimentary bed that has been exposed to temperatures in a range as great as 30-500°C. Dike-heated rocks are, therefore, good sites for research on thermal effects because variation of the original organic matter is minimal, the range of heating is great, and the history of rock heating in a dike zone is relatively well established. In rare cases, such as at the dike near Wolcott, Colorado, described in this paper, the rock samples are sufficiently unweathered to allow analysis of secondary bitumens generated by the heating. We show by optical microscopy, scanning and transmission electron microscopy, and geochemistry the kinds of solid organic constituents in sedimen¬tary rocks and in ore deposits and the effects of heating. The primary phytoclasts that make up kerogen In sedimentary rock and in some ore deposits (pollen, resin, charcoal, humified woody remains, etc.) change in ways that are familiar to coal specialists. Progressive loss of moisture and other volatile matter yields residual kerogen that Is relatively higher in carbon and lower In oxygen and hydrogen, and has greater molecular or polymer ordering. In our contact zone examples, atomic H/C ratios of kerogen decrease from 0.8 (one case from 1.4) to 0.4, the hydrogen index from Rock-Eval pyrolysis decreases from 70 to 5, and the transformation ratio from Rock-Eval pyrolysis increases from 0.06 to 0.5 with increased heating. The visible effects of heating seen by scanning electron microscopy and light microscopy include formation of vesicles and flow structure, the development of optical anisotropy and mesophase, change of color, and increase in the refractive index, absorption, and reflectance. Some of these changes In primary organic matter are observed also in secondary organic matter, for example, in solid bitumens in sedimentary gold ores or In lead-zinc deposits. Quantification of color or absorption changes is difficult because it Is hard to make thin sections of organic matter with uniform thickness. However, natural objects with uniform thickness can be used. We show the colors of pollen In rocks from the Salton geothermal field at temperatures ranging from 100 to 300°C, and of pollen heated in laboratory bombs from 150 to 400°C. Measurement of vitrinite reflectance is a practical way to quantify thermal changes of kerogen and minerals of most sedimentary rocks because vitrinite is fairly widespread In sedimentary rocks of Devonian age and younger. For example, the reflectance of vitrinite rises from the regional level, as low as 0.4 % Ro, to more than 5% Ro adjacent to dikes that cut sedimentary rock. This is equivalent to the rank change from subbituminous coal to extreme meta-anthracite. The rise is most abrupt near thin dikes, but when the distance from the igneous contact is expressed as a ratio of dike thickness the reflectance rise is similar for all dikes. Controlled heating of vitrinite-bearing rocks In the laboratory provides a means to assign known temperatures to vitrinite-reflectance values. The derived plots of temperature In dike contact zones have the same shape and level as those predicted by heat theory, and the temperature lines extend toward dike contact temperatures that are about half those of most magmas, as expected if the intrusions did not flow past the sedimentary rock for a long time. The globular submicroscopic structure of vitrinite and Its heterogeneity, which we show by means of transmission electron microscopy, pose some problems In selecting a uniform type of vitrinite for measurement of thermal changes. At present, routine reflectance values of vitrinite dispersed in rocks have a relative uncertainty as great as 10%. Thermally caused chemical changes in the primary kerogen, especially decrease in the oxygen and hydrogen contents, lead to formation of secondary products in the contact zone. The measured changes of secondary organic products in these rocks include formation of peaks In concentration of total extractable organic matter and in hydrocarbons, and in the saturated/aromatic hydrocarbon ratio over the interval where primary organic hydrogen decreases most rapidly--then destruction or expulsion of these products at high temperatures. The odd carbon-number predominance of the C25-C31 n-alkanes In samples far from the dike disappears by about 1.3% Ro whereas the 13C: 12C ratios of the saturated and aromatic hydrocarbons increase over most of the thermal range. The saturated aromatic hydrocarbon ratio at first increases, corresponding to thermal generation of saturated hydrocarbons, then decreases in the most altered samples. One use of organic petrography, in addition to identifying organic fades or thermal alteration, is recognition of sample contamination such as the solid organic additives used in some drilling muds which may contaminate geochemical samples.

Jan 1, 2013

By Axel Preusse

Due to a political decision, German hard coal mining will come to an end in the year 2018. By then, there will have been more than 150 years of industrial grade mining activities. Located in the western part of Germany is one of the most densely populated areas of Europe. Multiple coal seams have embossed the earth?s surface up to 20 meters (21.87 yards), as mining has subsided. The aftercare of hard coal mining will consist of three tasks: groundwater management, polder management, and groundwater treatment. The Ewigkeitslasten (cost in perpetuity) at the current groundwater level has been determined in the past. The actual cash value is calculated to be about 12.4 billion euros (approximately 16.5 billion dollars). The cost of groundwater management is directly related to the groundwater level. Rising groundwater levels will reduce the cost of pumping water. Known effects of rising groundwater are uplift of the surface, emission of methane gas at the surface, higher risk of cave-ins, and contamination of drinking water horizons. Each of those processes produces cost in order to prevent negative consequences (e.g., uncontrolled methane emissions) or to handle reparations (e.g., damages caused by surface uplifts). In the long run, it is the goal to minimize the Ewigkeitslast. As a first step, all cost-generating processes are specified, and a cost type based characterization is performed. The objective of this case study is to identify key parameters to determine the quality of a cost-generating process (proportional cost, fixed amount cost). Afterwards, it is intended to specify the quantitative impacts of each parameter and to set up an optimization model to minimize the overall cost. The quantitatively specified parameters will form the base out of which the optimization model is created.

Jan 1, 2013

By David L. Giles

The alkalic igneous province of Montana consists of centers of laccolithic and stock-like intrusive complexes with associated sills, dikes, and breccia pipes (e.g., Judith, Highwood, Little Belt Mts.); isolated plug-like mafic bodies (e.g., Smokey and Eagle Buttes); and clusters of kimberlitic diatremes and ultrabasic dike swarms (Missouri River Breaks). The province extends in a belt throughout central Montana from the North Absaroka Range in the south to the Sweetgrass Hills on the Canadian border. Intrusive activity ranged in age from Late Cretaceous to late Miocene, peaking at about 50 m.y, ago. Diverse types of significant epithermal gold mineralization occur at many of the laccolithic centers. This mineralization took place in large part during the waning stages of, or following, igneous activity. Large remnant travertine blankets in the region attest to comparatively recent hydrothermal activity. The quartz-pyrite-gold mineralization ranges from igneous- hosted stockworks or fracture sets (Zortman-Landusky and Neihart districts) and breccia pipes (North Moccasin Mts.) to replacement zones in flanking and upwarped Madison Group limestone (Gilt Edge and Kendall districts). The latter are mostly localized by intraformational solution breccias in the upper Madison, notably near porphyry contacts. Gold mineralization in the province was accompanied by varying amounts of silver, base metals, sulfosalts, and tellurides, with quartz, fluorite, carbonate, and barite and gangue. Gold occurs as auriferous pyrite, sylvanite, or in native form. Since the 1880's, primary gold production from numerous scattered deposits in the Judith, Moccasin, and Little Rocky Mountains, along with byproduct gold from the Neihart silver district (Little Belt Mountain), has totalled around 2 million oz. The major deposits were in the 1-2 million ton range at an average gold tenor of 0.3-0.6 oz per ton. Most of the ore was mixed oxide or carbonaceous sulfide ore and was treated either by amalgamation or by roasting-cyanidation. Current activity includes heap-leach operations on bulk- tonnage low-grade (approximately 0.03 oz per ton) ores at Zortman-Landusky, and several small-scale, experimental leach or mining operations on carbonaceous replacement ores, as in the Kendall district and Spotted Horse mine. Current exploration efforts for gold are focused not only in the old established districts, but also in and around other alkalic centers, which have been unproductive to date, such as the Crazy Mountains, Sweetgrass Hills, and Bearpaw Mountains. Target concepts in these efforts are porphyry-hosted stockwork or disseminated gold ores and Carlin-type replacement lodes in the flanking Madison or other favorable carbonate units.

Jan 1, 2013

Unlike traditional mining on land or ?dry? mining, relatively little is known of ?wet? or offshore mining within the industry. However, dredge mining has several benefits over dry mining, including high unit capacity, as well as lower operating and transport costs. IHC Merwede, a company with expertise in wet mining, is keen to raise awareness and help the industry move forward from dry to wet mining. The idea of mining offshore is not a new one. With global head grades declining, certain operations still have extensive resources of lower grade mineralization in their concession area. These operations require a lower cost, high volume solution for which dredge mining can provide an economic alternative. Interest in dredge mining has recently returned, and there is an increasing tendency to use dredge mining for the removal of overburden or the rehandling of tailing ponds.

Jan 1, 2013

Mining is big business in Ontario. The province is Canada?s leading mining region. It consistently ranks among the top 10 jurisdictions worldwide for exploration spending, reaching about C$1 billion in 2011. More than 26 percent of all exploration and appraisal dollars spent in Canada are invested in Ontario. Minerals produced include nickel, copper, platinum group elements (PGE), cobalt, zinc, diamonds, gold and silver. It was reported that there are more than 600 mining exploration projects in the province. And, recent discoveries of chromite in northern Ontario?s Ring of Fire will add to the province?s mineral production in the coming years.

Jan 1, 2013

By M. Mononen, J. Huuskonen, M. Vauhkonen, J. Kourunen, A. Lehikoinen

"A new approach to measure process conditions in flotation cells is presented. Real scale flotation cells in a Zinc circuit are imaged using Outotec LevelSense sensors based on electrical resistance tomography. The latest results from long period plant tests show that the sensors together with FrothControl analysis give new information that correlates well with other process parameters. The sensors can compensate for electrical contact contamination using an automatic calibration technique and they are basically maintenance free. The results indicate that using the LevelSense sensors and FrothControl solution, the process control and optimization can be done automatically, stabilizing and improving the metallurgical performance of the flotation process.INTRODUCTIONThe froth flotation process is widely used in mineral industry for the separation of minerals from low-grade ore slurry. Different property parameters of froth and slurry could be measured to monitor and control the flotation process: air bubble size distribution, flow dynamics, thickness of the froth bed, amount of solids in the froth, etc. Some techniques already exist that can be utilized in studying these important parameters on-line. Examples of the techniques are the high-speed video imaging, simple conductivity probes, ultrasound techniques, floats and pressure transducers (Maldonado et al., 2008). These techniques, however, often suffer from some limitations. For example, the video imaging only gives information from the surface of the froth, simple conductivity probes suffer from contamination and the floats may get stuck and therefore do not give reliable signal for process control and optimization."

Jan 1, 2013

By William Gleason

With more than 20 major mines extracting copper, gold, coal, molybdenum and lime, Arizona is recognized as one of the better mining jurisdictions, not just in the United States, but in the world. However, that is not to say the road to production is always paved with gold, or in many cases, copper. Earning the license to mine in Arizona is a complex process with years of paperwork and permitting before the first tons of ore are ever processed. Now, get the federal government involved and the process becomes even more complex, and the path to production can become even longer.

Jan 1, 2013

By A. R. Sorta, D. C. Sego

ABSTRACT Temperature, solute, texture, and thixotropic effects on time domain reflectometry (TDR) measurements of water content in oil sands tailings are investigated. Results indicate that TDR water content measurements are influenced by temperature, residual bitumen, and percent clay in the tailings. A correction of 0.03–0.10/ °C must be applied to the apparent dielectric constant (Ka) to account for the effect of temperature. The Ka-volumetric water content relationships of slurries differ significantly from the commonly used Topp calibration equation. The age of the tailings and the addition of phosphogypsum did not influence TDR water content measurements.

Jan 1, 2013

By David Hersey

The Paseo Bridge was located at the I-29/I-35/US-71 Missouri River Highway Crossing. It was built between 1952 and 1954 by Massman Construction Company. The 1,232 foot long, self-anchored suspension bridge was the longest of its type when built. On Jan. 22, 2003, a connector pin designed to allow the bridge to expand and contract during temperature cycles seized and caused a portion of the bridge deck to raise up and block traffic. This marked the beginning of the end for the old Paseo Bridge.

Jan 1, 2013

By Pinnaduwa H. S. W. Kulatilake

To exploit an underground mine effectively and safely, it is important to have a good understanding of the geotechnical behavior of the rockmass surrounding the underground mine excavation. The aim of this study was to investigate, at the threedimensional level, the geotechnical behavior around a tunnel excavated in a metal mine in China. A three-dimensional numerical model was built by using the 3DEC software package to simulate a tunnel excavation under a high in situ stress condition and by relying on the information available on lithology, geological structures, in situ stress measurements, physical and mechanical properties of intact rock, discontinuities, and interfaces between different rocks. The authors also investigated the effect of the discontinuity network, possible intact rock and discontinuity parameter variability, representation of rock masses as discontinuum or equivalent continuum material and rock support system on the deformation, and stability around the tunnel. A very good agreement was obtained between the collected field deformation monitoring results and the results of the conducted numerical stress analyses with appropriate geomechanical property values.

Jan 1, 2013

ABSTRACT The inevitable uncertainty in modelling spatial variables decreases as more data become available. This reduction depends on the properties of the variable being modelled. Spatially continuous variables show less uncertainty for a given spacing than erratic variables. A geostatistical simulation based approach is developed to quantify the relationship between uncertainty and data spacing. Reference realizations are sampled to condition additional realizations and quantify uncertainty. The procedure is automated, making it straightforward to consider sensitivity and different geological domains. A case study of the relationship between uncertainty and data spacing for net oil sands thickness data from northern Alberta is presented. _ KEYWORDS Simulation, Sampling,

Jan 1, 2013

By Tao Zeng, Jianchao Li, Chang Jie, Jieyu Zhang, Jifang Xu, Kuochih Chou

"The densities of the selected quaternary Ca0-5%Mg0-Alz03-Si02 slag with low silica were measured by the Archimedean method in a wide temperature range from l 723K to 1823K. Slag compositions were chosen based on five different levels of Si02 content between 0.00 pct and 11.40 pct. The MgO content was equaled to 5.00 pct. The mass ratio of CaO/Alz03 was varied from 0.67 to 2.14. The effects of temperature, Ca0/Alz03 ratio and optical basicity were studied. It is shown that density decrease approximately linearly with an increase in temperature. With the same Si02 content, the density decreases with increasing of CaO/Alz03 ratio and optical basicity. Based on the experimental data as the boundary of the homogenous phase region predicated by F ACTSAGE software, the mass triangle model is used to calculate the density of selected limited homogenous phase region. The results showed that the mass triangle model is working well.IntroductionIt is of great importance to measure density of slag melt not only to the theory research for melt, which that is directly amenable to the structure correlations of molten slags, but also to the industrial application. Many metallurgy phenomena such as inclusion formation in molten melt and its removing, slag foaming, slag-metal reaction are closely related to the density of slag. Density is also required to estimate other fundamental properties, like surface tension, viscosity, and thermal conductivity from thermal diffusivity so that a relatively complete picture in regard to the behavior of high-temperature molten oxides could be made."

Jan 1, 2013

By Xu-ling Chen, Qian Li, Yong-bin Yang, Zhao Jing, Tao Jiang, Guang-hui Li

"It is generally known that alkali metals are harmful to blast furnace production resulting in aggravating RDI of sinters, abnormal expansion of pellets, deteriorating blast furnace lining, etc. Sinters regarded as dominating burden of blast furnace are determined as the main source of alkali metals. In this study, the removal behavior of potassium and sodium oxides by pre-reduction sintering during the sintering process was studied. The removal ratio ofK20 and Na20 was greatly influenced by coke powder content, carbon species, coke powder adding ways, additive and so on. Under the conditions of carbon rate 12% and 5% dosage of CO supplied in the sintering process, the corresponding removal ratio ofK20, Na20 was 69.00% and 32.79%, and metallization ratio could reach 4.65%. This technology provided a novel process for reducing the content of alkali metals in sinters and dramatically improving the quality of blast furnace burden.IntroductionSinter is the main iron-bearing charge of blast furnace for iron-making in China, making up about 80% of the total burden; therefore, its quality has a significant influence on the quality of pig iron and blast furnace operation. Research and practice of numerous years prove that potassium and sodium coming from ores are brought into blast furnace and upgraded, which is one of the essential reasons that lead to blast furnace nodulation and influences its strength. Currently, effective flow sheet to remove potassium and sodium is weak magnetic separation-intensive magnetic separation-flotation [l], while iron ore concentrate is still ofhigh levels of potassium and sodium. As sintering process is also not effective to remove potassium and sodium, blast furnace in China is of high alkali burden, e.g. it reaches 5.6-6.2kg/tFe in Baotou iron making plant, which is greater than international tolerated level of2.55kgltFe [l]."

Jan 1, 2013