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By Dobias B

A new separation method based on a combination of coagulation and colum flotation was used to treat fine sphalerite in the range 90 per cent - 15 pm with a relative high superfical gas velocity and a thick froth layer. Minerals studied include sphalerite, calcite, kaolinite and baryte. A new developed sedimentometer was used for sedimentation analysis to characterise hetercoagulation of mixture and coagulation after addition of active ions or reagents. A comparison between use of selective frother and depressant (SHMP) was made to deactivate activated minerals. Selectivity of frother for sphalerite was found in flotation test. The depression function of Flotanol for activated minerals was confirmed in sedimentation alalysis. The use of small quantities of HPAM can improve the flotation of fine sized sphalerite particle and reduce recovery of activated gangue minerals in the neutral or alkaline pulp. A satisfactory separation of fine sphalerite from its gangue was achieved by using alkylpolyglycolether (Flotanol) and copolymer polyacrylamide (HPAM hydrolysed polyacrylamide) as frothing and flocculating agents Respectively.

Jan 1, 1993

By Schofield N. A

The cross-sectional method of stope grade estimation at Cobar Mines has consistently had several shoneomings, me most imponant of which being mat stope grade is significantly overestimated in the high grade lenses.The use of mree-dimensional ore lens modelling improved the grade estimation and ore waste definition but significant overestimation still occurred in me high grade stopes, particularly those wim extremely variable grade distribution. The implementation of an indicalor kriging based method for mapping of me high grade copper mineralization has significantly improved the quality of copper grade estimates and provides a mineralisation geometry similar to that generated manually by me mine geologists. This paper presents the results of a test case study in the application of indicator kriging to the mapping of the copper grade in two stopes in the QTS North mineralisation. The results are encouraging in that they prov ide coofi rmation of the geometrical model developed by the geologists and much improved estimates of the grades of me stopes whencompared to me grade reponed from mining these stopes.

Jan 1, 1993

By Ault A. R

The recent modernisation program at the Risdon electrolytic zinc smelter of Pasminco Metals - EZ (PMEZ) inyolved significant changes to the composition of cell electrolytes. The most significant were increased acidity and sulphate level, a reduction in Co level, and the replacement of 2-naphthol in the additive mixture with licorice. In determining acceptable operating ranges, a relatively large number of industrial deposition tests under controlled conditions was required. The cathode zinc deposits so produced were examined in terms of overall appearance, crystal structure according to X-ray diffraction, and a micro-roughness parameter. Beginning with typical deposits produced in the presence of an excess of one of the addition agents glue or antimony or a mist suppressant (licorice or 2-naphthol), a simple classification system was developed. In this system, the deposits are divided into the following types: Doughy, Pinholed, Compact and Stressed. There was a weak correlation between deposit type and crystal orientation. In terms of ease of stripping, observations in plant operations showed that only Compact and Pinholed were consistently acceptable. Current efficiency was normally maximised by producing a Compact deposit. Process variables such as zinc concentration, temperature and the use of strontium carbonate were found to cause changes in deposit type if the reagent mixture used was unchanged. From the knowledge gained, guidelines were developed to allow glue and antimony additions to be altered to fit new circumstances. The simple classification system was first used to expedite recovery from undesirable morphologies and then to optimise individual cell units operated under substantially different conditions. It is believed that finer control could be exercised by determining the micro-roughness of Compact deposits. However, difficulties can arise if sudden, large deviations occur and go undetected. Suggestions are given for an improved additive control system. The classification system developed has been compared with published information in the literature, and good correspondence was noted suggesting a predictable relationship between short-term, laboratory deposition tests and observable phenomena in industrial electrowinning cells run under steady conditions.

Jan 1, 1993

By Thomas W. Camm

The U.S. Bureau of Mines has developed a system for estimating mining and processing costs as a function of process feed rate with the objective of applying this system to abandoned mine tailings and to evaluate the benefits, if any, of metal recovery. Cost analysis was applied to the mine wastes of Smelterville Flats: an extensive area of mine tailings in the Bunker Hill Superfund Site with high concentrations of lead, zinc, and other sulfide minerals. Results from previous site characterization and metallurgical processing studies were used as the input for the cost analysis. This analysis indicated that processing this site at an optimum production rate of 3,500 short tons per day (st/d) could generate a positive cash flow.

Jan 1, 1993

By J. M. Goris

The U.S. Bureau of Mines, in a cooperative project with the University of Utah, Salt Lake City, UT, and Homestake Mining Co., Lead, SD, conducted in situ monitoring and numerical modeling of rock masses supported with cable bolts in two mechanized, cut-and-fill stopes and a shaft pillar at the Homestake Mine. Extensometers were used to measure rock displacement, while cable bolt strain gauges were installed to measure loads on both conventional and birdcage cable bolt supports. These instruments provided an assessment of rock mass behavior during mining as well as essential data for verifying results from computer analyses. The numerical modeling program FLAC was used to analyze cable bolt patterns and supports. Results from the evaluation study indicated that cable bolt strain gauges and extensometers were effective instruments for monitoring the behavior of rock masses supported with cable bolts. Also, numerical modeling of the 4S-48N stope using the FIAC code provided displacement values comparable with measurements from field extensometers.

Jan 1, 1993

By G. Andrews

This case study details the process that was used for project planning and permitting for the Greens Creek Mine, located near Juneau Alaska, as seen through the eyes of one of the primary environmental consultants. This case shows how a Company could involve the public and the agencies in the early 1980's and develop a project sensitive to concerns expressed with a high level of environmental protection. Comparisons are made to the current environmental permitting situation. Initial baseline studies performed during the exploration phase provided helpful information for more detailed environmental work in 1980-1981 as planning and permitting formally got underway. Since the mine was in a National Monument and abuts up to a designated wilderness, the Monument Manager administered the project for the lead agency, the USDA Forest Service. Planning and permitting progressed smoothly to a Final Environmental Impact Statement (FEIS) in 1983. Metal prices were depressed when the FEIS was completed and the project permitting proceeded slowly. Ownership changed several times in the mid-1980's. New owners re-evaluated the project and suggested five changes that required a supplemental EA prior to development. The project was fully permitted and started construction in 1988. Operation began in 1989. Today the environmental process in southeast Alaska is now much more complex, detailed, expensive, and time consuming than in the early 1980's. Significant issues discussed that may impede development and operation include overlapping agency jurisdictions, personal agendas of agency staff, conflicts between agencies that impede project progress, changing regulations, and a well organized environmental opposition.

Jan 1, 1993

By R. V. Ramani, K. V. K. Prasad

Forecasting mined grade variability from exploration information is a challenging task in mine planning. For effective planning of activities, such as workplace scheduling, ore grade quality control, etc., development of realistic numerical simulation models of in situ variability from exploration information is an essential first step. Geostatistical conditional simulation (GCS) is one of the well known methods to develop such simulations. Recently, stochastic fractal models based on the assumptions of scale-invariance and self-similarity have been used for developing simulations of several natural phenomena. It has been suggested that these models might permit the generation of short-scale variability information from exploration data with greater fidelity when the data satisfies the attendant assumptions. In this paper, stochastic fractal models are reviewed, and their relationship to geostatistical variogram models is examined. A comparison of the two simulation techniques has been performed using coal sulfur data from a mined-out coal property. The results of this comparative analysis are also presented in the paper.

Jan 1, 1993

By McConachy G. W, Wright J. V

During the 110 years since the discovery of the Broken Hill PbZnAg deposit six major mining companies have mined the ore body and explored the ore environment. Despite this activity, no new orebodies have been found at Broken Hill. The failure to discover large new resources cannot be attributed to a lack of activity because major companies have maintained substantial exploration commitments over many decades. This suggests that not only was a unique coincidence of conditions required to form the deposit but also that full recognition and definition of the critical parameters may not yet have been recognised. In an attempt to illuminate some of the more unusual and poorly studied characteristics of the ore environment some new areas of investigation are presented here which may contribute to understanding the ore deposit setting and focus exploration towards different and perhaps more productive targets. Sedimentological characteristics of the host succession of the Broken Hill deposit are apparently unique along the line of lode. An upward-coarsening megasequence reflected in the development of clastic psammites stratigraphically below the ore deposit is one important ingredient which has received little exploration focus. These psammites also host mineralisation and form part of a spectrum of quart-zrich rocks collectively referred to as gametiferous psammites, garnet quartzites and blue quartz lodes. Sedimentological data interpreted from outcrop, drill core and downhole geophysical well logs support a elastic origin for some of these rocks; an interpretation which is at variance with traditional interpretations favouring an exhalative origin. A clastic origin for many of the footwall psammites, and their close spatial association with the orebodies suggests their role in ore formation was important. It is interpreted as a critical part of the fluid flow architecture within the sedimentary basin, which focussed ore forming fluids into an unique environment favourable for trapping mineralisation. Detailed stratigraphic correlation near the deposit has also highlighted that quartzofeldspathic rocks (Potosi gneisses and lode pegmatites) have complex relationships with ore. Suites of stratabound quartzofeldspathic pegmatites have received limited study, but their distribution and voluminous development suggests they may be as important to ore formation as the psammitic lode rocks which host the orebodies. These associations are not in conflict with some recent ore forming models invoking deposition in a shallow water environments of deposition. The geochemistry of parts of the host sequence has been studied extensively in the past but this has not been merged with current stratigraphic subdivisions. A large drillhole data base now permits the geochemistry to be related to the sedimentary succession and reveals that a signature involving stratigraphic vectors best illustrated by changes in MnO, Na2O, Pb and Zn can be detected. This is interpreted to reflect sedimentary basin processes as opposed to a classical volcanic hydrothermal alteration pipe associated with seafloor venting. The stratigraphic setting together with characteristics of some of these poorly understood areas is discussed to emphasise that construction of sound models for exploration requires the total ore environment to be studied with attention directed to the geometry and setting of the full range of host rocks. Control of the greater portion of the line of lode by a single company, Pasminco Australia Limited, now permits disparate datasets and observations to be merged and presents new opportunities and encouragement for model refinement and exploration success.

Jan 1, 1993

By Gemmell J. B

Zinc-bearing massive sulphide deposits have been mined in Tasmania since 1900. The current major producers are Hellyer and Rosebery, with total resource tonnages (mined plus reserves) of 16 Mt (million tonnes) and 24.8 Mt respectively. These deposits belong to the class of seafloor volcanic-hosted massive sulphides (VHMS) and are located within the Mt Read Volcanics, a narrow belt of continental margin calcalkaline volcanics of Cambrian age. Compared to other Australian VHMS deposits, and world-wide MVT and Sedex deposits, the Tasmanian examples clearly stand-out due to their high metal grades, averaging over 17 per cent Pb+Zn. The deposits vary in morphology from mound style (Hellyer) to sheet style (Rosebery) with other combinations including stacked lenses (Que River) and disrupted cross-cutting bodies (Hercules). All deposits show the classic VHMS zonation from an Fe-Cu-bearing base to a Zn-Pb-Ba-rich top. Zinc, gold and silver tenor commonly increases toward the stratigraphic top of the deposits. The ores have been deformed during regional metamorphism, resulting in folding, shearing and recrystallisation of sulphide lenses. In addition to the major deposits, a number of small massive sulphide prospects occur throughout the volcanic belt and the potential for the discovery of further large, deeply buried deposits remains high.

Jan 1, 1993

From a personal view that encompasses both research and assessment of major projects the author outlines the two competitive pressures that will force more rather than less metallurgy viz the increasing difficulty in purchasing the latest overseas developments and environmental concerns. This paper then goes on to argue that Australian metallurgy or more precisely process engineering may be in a unique position to deliver the required results.

Jan 1, 1993

By Y. Xi

In this paper we present an availability approach for determining the capacity of a major bucket wheel excavator (BWE) system to be used in Yuabaoshan surface coal mine in China. Based on previous time studies on other BWE systems for delay times due to internal and external causes, and a four-level maintenance and repair schedule, we develop a model taking into account all random failures and present a fast and simple solution to this highly complex problem. A procedure employing the Markov renewal theory for determination of the distribution of random failure times and failure rate of the whole system, as well as some other factors useful for calculation of the overall system capacity are discussed in the paper.

Jan 1, 1993

By M. S. Greenfield, E. Cocchiarella, S. Chubbs

"At Dofasco sNo.4furnace a variation of the basic oxygen steelmaking process, Klockner Oxygen Bottom Maxhutte (K-OBM), is used to produce steel. Large amounts of hot gases and particulate are evolved during the oxygen blowing phase. A quencher and a venturi scrubber are used to collect over 99.5% of the particulate. In 1990, the authors investigated the effect of foamy slag on the particulate emissions from the furnace. The amount of lime added early in the oxygen blowing cycle was reduced, making the slag more viscous and foamy for a six minute period. Instantaneous particulate emissions were monitored throughout the blow by analyzing quencher and venturi scrubber water samples. Particulate emissions were reduced up to 59% during the foamy slag period.IntroductionThe reduction of the amount of waste generated or control of emissions at source is at the top of the ""3R"" hierarchy of waste management (Reduce, Reuse, Recycle). Process and operating practice changes are often the most economical ways to control emissions. At Dofasco, they investigated the effect of operating practice changes, specifically the formation of a foamy slag, on particulate emissions from steelmaking furnaces. They wanted to determine if a foamy slag changed the quantity and nature of the fume evolved from the K-OBM furnace over the oxygen blowing phase.The Basic Oxygen Steelmaking ProcessesThe basic oxygen steelmaking process (BOP) generates large quantities of very fine metal oxide fume during the production of steel. In this process, scrap steel and molten iron (hot metal) from blast furnaces are charged into a steelmaking furnace. Then pure oxygen is injected and a lime flux added . The oxygen reacts with carbon dissolved in the molten iron to form carbon monoxide. Oxygen lances can have secondary nozzles which introduce oxygen above the bath. This secondary oxygen, known as post-combustion, bums some of the carbon monoxide radiating the heat back to the bath. Particulate and gases rich in carbon monoxide are ejected from the furnace during the oxygen blowing phase and are collected by a gas cleaning system. Typically, more than 99.5010 of the particulate is scrubbed from the gases by high energy venturi scrubbers or electrostatic precipitators. The oxide sludge or dust collected may have elevated zinc and lead which is unsuitable for recycle to blast furnaces. Due to the presence of these undesirable elements, treatment and disposal of steelmaking oxide dust is difficult and costly."

Jan 1, 1993

Some crystal chemical properties of several apatites from Brazilian deposits and occurrences were determined; the samples had different origins (igneous, metamorphic and sedimentary). The aim was to establish relationships to their froth flotabilities behaviour. Detailed X-ray diffraction studies were carried out, to determine precisely the unit cell parameters and the degrees of crystallinity of the apatite samples. A thorough chemical analysis of these minerals was also conducted. Microflotation studies were carried out, using sodium oleate and dodecylammonium chloride as collectors. The crystallinity levels were determined for all samples studied, with the establishment of a crystallinity index, which varied from 10.0 to 4.5, on a normalised scale. A marked dependence was observed between this crystallinity sequence and flotability; for both collectors, flotability dropped drastically for crystallinity indices lower than 8.0. Also, the low crystallinity apatites showed a decrease in floatability, for longer conditioning times.

Jan 1, 1993

By O. E. Humeniuk, A. I. A. Salama, M. W. Mikhail

"Performance testing of prepartion plants is referred to as plant audit. It evaluates plant performance under normal operating conditions and is aimed at improving yield through knowledge of actual process performance and interactions between different processes in a plant.This paper describes the program to evaluate the performance of several Canadian preparation plants. The performance test requires the planning of a sampling campaign that would include all circuits in the plant. Samples are analyzed to determine washing characteristics (screen and float-sink), ash and per cent solids of feed and products of separation units in the plant. Performance characteristics are established based on analysis and material balance. Specific recommendations can then be made to improve recovery, and identify and explain potential causes of apparent deficiencies.The objectives of the program are to reduce the cost of production by improving recovery of clean coal and, in tum, to reduce disposed tailings, establish baseline information on coal preparation plants performance in Canada, and define R&D work needed to optimize plant operation."

Jan 1, 1993

By Taner Sumer, H Altay Guvenir

Fragmentation in rock quarries is tried to be achieved by changing the specific charge, drill pattern and bore hole diameters by different experts. This paper is a brief summary consisting of the utilization of practical experiences of the other group on cost optimization procedure that takes into account blasting, transportation and crushing as a whole process and optimize the cost by defining the optimum gelatin based explosives to be used as a main primer of anfo in three different limestone and granite quarries, with similar rock characteristics.

Jan 1, 1993

By Van Weert G

Ferrous chloride solution pyrohydrolysis is a successful IICI regeneration process which is carried out in either a spray roaster or a fluid bed. Pyrohydrolysis is not restricted to ferrous chloride only, every metal chloride can theoretically be hydrolysed. In practice, however, the conditions for ferrous chloride pyrohydrolysis differ from those of many non-ferrous metal chlorides eg zinc, lead and cadmium. Hence, a pyrohydrolyser could function as a ferrous/non-ferrous separator, eg an iron oxide and zinc chloride separator. Most pyrohydrolysers operate on solutions, in which case more than 50 per cent of the process energy is needed for heating and evaporating water. However, this disadvantage would be diminished by feeding a slurry to the reactor. Against this background it was decided to investigate the chloridisation of zinc ferrite which is an iron bearing solid with a non-ferrous impurity, and subject to processing and disposal problems. Synthetic zinc ferrite was chloridised in a tube furnace. The gas atmosphere in the tube furnace resembled that of a fluid bed pyrohydrolyser and consisted of HCI, 1120 and nitrogen. Gas composition, temperature, residence time and sample mass were varied. The experiments showed that complete (99.6 per cent) zinc extraction from synthetic zinc ferrite was possible in a simplified pyrohydrolyser atmosphere at 1100 K in four hours. The zinc ferrite was converted into gaseous zinc chloride, and hematite and magnetite solids. It was also found that zinc removal from the zinc ferrite lattice caused not only rccrystallisation of the zinc ferrite into hematite, but also hematite crystal

Jan 1, 1993

By Ralph H. Nafziger

The feasibility of smelting a Ni-Co-Cr-bearing laterite ore from southern Oregon was evaluated by the Bureau of Mines. The objective was to prepare a master alloy for subsequent stainless steel production. A mixture of the ore with suitable reductants and fluxes was smelted in a 50-lb-capacity single-phase ac electric furnace under sub- merged arc conditions. The smelting tests produced a metal in which most of the nickel was concentrated. High-chromium recoveries required an excess of carbon. The resulting metal alloys contain sufficient nickel for some stainless steels. Ferrochromium additions would be required to attain suitable chromium levels. This research was conducted under the Oregon Metals Initiative in cooperation with Walter B. Freeman.

Jan 1, 1993

By J. D. Miller

The sedimentary western phosphate deposits of Idaho, Montana, Utah, and Wyoming tend to be calcareous and generally carry a significant amount of dolomite along with collophanite. In some cases, such as the Smokey Canyon Mine, Afton, Wyoming, the ore will also contain mudstone, and in this case the aluminosilicate minerals (clay, feldspar, etc.) together with some dolomite are floated from the collophanite in column flotation cells with an amine in order to meet product specifications (31 % P205) (Service et al.). In other cases, such as the SF Phosphates Limited Mine, Vernal, Utah, the ore is treated by traditional fatty acid flotation of the collophanite with mechanical flotation cells (Weber, 1986). Preliminary tests have now been conducted to evaluate air-sparged hydrocyclone (ASH) technology for the flotation of western phosphate ore. For this preliminary study, samples were taken from the hydrosizer overflow stream (18-21 % P205) at the SF Phosphates Limited Plant in Vernal, Utah for scavenger flotation testing with the 2-inch ASH system in laboratories at the University of Utah. Selected design and operating variables are being studied, and the initial results show that satisfactory separations can be achieved by high-capacity ASH flotation at appropriate operating conditions. For example, with single-stage ASH flotation 80% recovery can be obtained with a scavenger concentrate grade of about 26% P2O5. These results are comparable to, or better than, those obtained at SF plant operations with conventional flotation cells and suggest that ASH flotation technology can be used to good advantage in the phosphate industry. Of course, research should be continued to consider other process streams, optimize the separation efficiency, and evaluate larger diameter ASH units.

Jan 1, 1993

By E. F. Paski

Geological materials are likely the most complex and challenging substances to quantitate by ICPOES (inductively coupled plasma optical emission spectroscopy). For complex materials having widely varying compositions, spectral overlap interferences govern detection and quantitation limits attained by ICPOES based analytical methods.

Jan 1, 1993

By Nickolas J. Themelis

The flash oxidation and smelting of mineral sulfides is a very prominent metallurgical achievement of the second part of this century. Its initial industrial implementation owes much to the work of Petri Bryk, in Finland, and Paul Queneau, in Canada. However, attempts to develop flash reduction pro- cesses, such as the reduction of iron oxide concentrates with hydrogen, have not yet been successful. The author, on the basis of experimental studies on both kinds of flash reaction systems, examines the respective rate controlling phenomena and the relative rates of flash oxidation and flash reduction.

Jan 1, 1993