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By Thomas M. Harris

Cation exchange is not sufficiently selective to be used for the removal of heavy metal ions from a general industrial wastewater. However, if the metals can be converted to polyvalent anions through complexation, they may be removed both selectively and efficiently by anion exchange. This approach, referred to as chelation-assisted anion exchange (CAAE), has been examined using industrial wastewater samples contaminated with Ni2+ and Cr3+. For this particular application, the Ni2+ is complexed with 8-hydroxyquinoline-5-sulfonic acid, and the Cr3+ with sulfosalicylic acid. Removal efficiencies and adsorption isotherms for both the complexants and the complexes were determined in batch-mode tests.

Jan 1, 1994

By Sorentino C

Mineral valuation may appear to be a special field of financial valuation when in fact it is a subset of general investment decision theory. The only significant difference in mineral valuation is that in the case of valuing an on-going mineral asset, ie a mine, often there is no initial capital outlay involved. One is required to determine what the mineral asset as it stands is worth. But this is the same problem as determining the maximum one could pay today and not incur a loss over the life of the asset. In other words one needs to determine the Net Present Value (NPV) of the asset. The two most widely used discounted cash flow methods, NPV and Internal Rate of Return (IRR) came of age with the rapid adoption of the personal computer and spreadsheet programs. The two methods are directly related as the IRR is a special case of NPV. NPV measures the absolute increase in real wealth that can be expected from a certain investment, which makes it particularly suitable for mineral asset valuation, but ignores the efficiency of the investment. In contrast, IRR gives the expected efficiency of the investment but ignores the increase in wealth aspect. IRR has two serious theoretical weaknesses; multiple IRR's and a very rigid assumption about the rate of return of reinvested proceeds, plus if no initial equity expenditure is involved there is no IRR. The choice of the ""hurdle"" rate can also be a problem and in certain circumstances one can obtain different rankings of mutually exclusive projects using IRR and NPV. Although NPV and IRR supposedly measure financial risk, in fact they only address a very narrow area of risk, namely the time value of money given the real discount rate. They side step the issue of what the real discount rate should be and varying degrees of risk. The classical way to establish the real discount rate is to use the weighted average cost of capital.

Jan 1, 1994

By H. E. Frimmel

Most of the gold in the Late Archean Witwatersrand Basin is of detrital origin but, in its present form, it is metamorphosed. The only relict detrital features preserved are the morphological characteristics of some placer gold particles. Regional burial metamorphism in the shallower and deeper levels of the Witwatersrand Supergroup reached temperatures around 300°C and 350°C at pressures between 2 kbar and 3 kbar, respectively, estimated from phase relations, chlorite-chloritoid exchange thermometry and chlorite thermometry. Metamorphism of the gold involved compositional homogenization of individual gold particles and partial recrystallization. Various infJ.1tration events caused the partial mobilization of the gold at slightly lower temperatures, between 240°C and 300°C. These infiltrations can be related to crustal extension during the deposition of massive carbonate sequences of the Transvaal Supergroup (around 2.5 Ga), and later to the emplacement of the Bushveld Complex, and to the Vredefort event around 2.0 Ga ago. The mobility of the gold was dependent on the sulfur fugacity prevailing in a particular horizon which, in tum, was determined by the amount of pyrite (and other sulfides) present in that horizon. With the sulfur fugacity being controlled by stratigraphy, low fluid rock ratios in a pyrite-rich horizon were most conducive for the mobilization of the gold. Thus, long-range gold mobilization in the Witwatersrand Basin can be expected to be the exception rather than the rule.

Jan 1, 1994

CVRD was established on June 01, 1942, during the Second World War, through an agreement between Brazil, the United States and the United Kingdom, to produce 1.500.000 tons/year of iron ore from Itabira mines in the State of Minas Gerais. As a result of several circumstances and political problems (the end of the 2nd World War reduced the Anglo-American support to its development and implementation), the venture just reached the originally targeted production 10 years after its establishment, operating within a mine, railway and port integrated system. Currently, this operational system from the South of Brazil owns mines in the State of Minas Gerais with an annual capacity of approximately 65 million tons, 900 km of railways, of which more than 500 km is a double line railway, six pelletizing units and the Port of Tubarao for ships with large carrying capacity.

Jan 1, 1994

By Robert B. Hopler

The history of the first twenty years of the high explosives industry in the United States begins as an illustration of the free enterprise system at its best and ends with the industry virtually taken over by a single company: a company which strongly opposed the new explosive material at the beginning of the period. In the world of the late Twentieth Century we could almost compare this history to the opposition of the mainframe computer manufacturers to the introduction of the personal computer, and their later entry into, and attempted dominance of, that market. With computers in the twentieth century the attempt to dominate the market has not been particularly successful: with dynamite in the nineteenth century it was.

Jan 1, 1994

By Robert Vidal

A model of the homogeneous chemistry and transport processes within the separator of a chrome-alum electrowinning cell is introduced, discussed, and compared to experiment. The influence of diffusion, electromigration, and convection are included; it is found that convection was the dominant mode of transport for the experimental conditions. Simulation results explain experimental observations concerning an apparent disappearance of dichromate ions produced at the cell anode. The relation between potential drop across the diaphragm and the current and fluid flow is also illustrated. The model is used to recommend future experimental and theoretical work.

Jan 1, 1994

By R Bartlett

Process engineering-science originally developed for percolation leaching of ore in heaps is extended to the decontamination of unsaturated soil, either in situ or after excavation and emplacement as a soil heap on an impervious pad. Phenomena considered include: soil matrix porosity and permeability; percolating solution retention, capillarity and flow; washing sweep efficiency; optimum solution application rates during leaching; soil agglomeration to improve soil permeability and soluble contaminant transport by diffusion in soil agglomerates. Practical aspects briefly discussed include leach pad construction, solution distribution and recovery from the soil, and solution containment.

Jan 1, 1994

Underground instrumentation and observations at longwall panels have demonstrated that the growth of main roof causes an extremely high roof weighting on the shields. It can sometimes result in catastrophic effects on the support when the roof weighting intensity far exceeds the support capacity. In this paper, a comprehensive study was conducted on characteristics of main roof breakage and its effects on shields at different locations, based on the monitored shield data, theoretical analysis, and finite element analysis. With the help of theoretical analysis and numerical modeling, stress distribution and redistribution in the main roof were analyzed in detail to define main roof failure modes and understand the maximum roof weighting intensity imposed on the shields. From this study, it was found that the effects of main roof breakage on shields are chiefly related to the shield initial setting condition and the final failure mode of the main roof.

Jan 1, 1994

By D. M. Neil

Road-headers are one of the most popular mechanized excavators used in mining and civil under-ground construction. These machines are primarily used in soft to medium hard rocks. This paper reviews the parameters associated with the application and operation of road-headers and presents a method for estimating cutting performance.

Jan 1, 1994

By M. Jortikka

The smelting process of the old reverberatory furnace including its capacity has been improved over the years in different ways eg. with oxy-fuel burners, parallel reactors with the reverb or with various modifications of the reverb furnace itself. The future reverb modifications with old concepts are difficult or impossible as the increased copper losses in slag call for separate slag treatment and particularly the process modifications do not solve the environmental issues but instead mean unavoidable high capital and operating costs in gas cleaning and sulphur recovery. During the last decades improvement in process performance and increase in capacity of copper flash smelters has been achieved easily by substituting the pre-heated process air by highly oxygen enriched air. The flash furnaces of today, however, are inherently designed to operate with high oxygen enrichment. Further process improvement with a view to production costs and capacity increase as well as to the more stringent environmental requirements is possible with even higher oxygen enrichment. This, apart from the advantages it generates, requires improvements in and careful design of the feed system, concentrate burner, furnace cooling and the off-gas line as well as adaption of the flash converting instead of the conventional Peirce-Smith converters. A logical answer even for the revamping of the reverb smelters in the future is the total replacement of the reverb furnaces with flash smelting together with flash converting. This paper discusses the possibilities for future process improvements of the existing flash smelters taking into account the process concepts, equipment modifications and capital aspects not forgetting the environmental issues. The revamping of the PASAR smelter in Philippines is introduced as an example of a recent success story.

Jan 1, 1994

By Y. Xi

This paper offers an algorithm to determine the optimal panel size with the objective of minimizing the overall stripping cost. The approach is presented both in analytical form for regular layers of coal and overburden, and in graphical form for the cases of irregular and multiple coal seams. When the optimal panel width needs to be changed due to some circumstance, we prove in general that increasing the panel width is better than reducing it in both economics and operational efficiency.

Jan 1, 1994

By P. R. Khangaonkar

The variety of intermediates, middlings, complex materials and wastes produced in the conventional processing of tin ores as experienced in the tin industry in South East Asia is reviewed. The problems associated with the treatment of these materials so as to produce useful products by hydrometallurgical or pyro-cum-bydrometallurgical approaches are discussed. Results of treatment of amang middlings consisting of cassiterite, struverite, ilmenite, zircon, monazite etc by chlorination with carbon tetra chloride are presented. The efforts to leach tin without letting iron coming in, by alkali leaching of certain wastes of tin processing are also briefly indicated. It is felt that pyro-cum-hydrometallurgical approach can help a viable treatment of these materials so as to obtain usable or value added products.

Jan 1, 1994

By M. Niec

Lignite deposits in Poland occur within clastic Tertiary series at the depth suitable for opencast mining. Aboundant aquifers with the good quality waters that should be protected against contamination or depletion often accompany them. Landscape and underground water protection are the main regional environ-mental factors that limit the possibility of exploration and mining; presented on map of lignite bearing series distribution allow to delimit areas "free" for exploration and mining and areas where some limitations can be met up to no admittance of any industrial activity.

Jan 1, 1994

By S. J. Jung

Determining the correct combination of mix components and water for high-density paste backfills with the transport and deposition properties necessary in a mining operation is a difficult task. Rheologic properties cannot be determined without conducting full-scale pumping tests, and data from existing tests are very limited. The following presents the findings of investigations undertaken to determine if paste backfill rheology can be determined using existing techniques and which mix and system variables have the greatest influence on transport pressure loss. Data from lab-oratory-scale pumping tests were used to produce a rheologic model of flow behavior for comparison, and a statistical analysis was conducted to determine the most significant factors affecting transport pressure loss.

Jan 1, 1994

By R. D. Corrans

"Abstract - Africa is endowed with a number of the world's giant ore deposits which have contributed significantly to the development of their host countries. Mineral exploration has a long history in the continent, but mining on an unprecedented scale took off during the latter part of the 19th century, accompanied by the development of lines of communication and other infrastructure to service the major mining centres .The ""Winds of Change"" which swept Africa in the 1950s and 1960s brought in new styles of government and economic management to a number of regions, often with demise of economic viability and infrastructure. ln recent years, with the end of the cold war, collapse of communism and changes in South Africa, new opportunities for mineral exploration are opening up rapidly in Africa. However, due to the large cost, long lead-in time, and high risk of developing new mineral ventures in the continent, it is necessary for the host countries to draft realistic and favorable mineral laws and fiscal codes in order to attract, and not deter, potential mineral investors.There will be an on-going role in mineral exploration throughout Africa for the artisanal miner, the smaller entrepreneurs and mining companies, exploration aid programs funded by the developed countries through African governments, as well as the major mining houses who have the resources to develop larger viable mineral deposits."

Jan 1, 1994

By M. Beale

Fuzzy logic and neural networks are new technologies being applied in many areas of engineering and business. While it is not always clear which kinds of problems are best suited to these technologies, and which problems are best approached with more standard methodologies, both fuzzy logic and neural networks appear to show great promise in the field of control systems. This paper demonstrates two advantages that these technologies offer: Easy controller design in the absence of a mathematical model of the plant to be controlled, and adaptive control capable of quickly responding to changes in the plant.

Jan 1, 1994

By Kot F. Unrug

In the premining stage of engineering design, the only available data are obtained from core drilling. It is often not sufficient for a realistic design of strata control. During the development, an access to the geological formation is created, enabling in situ testing. Obtained data can be utilized accordingly to improve preliminary design. The available methods for testing are described with emphasis on their application for a longwall system. The optimum design ensuring continuous operation of the high output longwalls is critical because their downtime is very expensive. Optimization of ground control measures also has the potential for substantial savings by elimination of unnecessary support.

Jan 1, 1994

General Gold was discovered in quartz veins at Wiluna in 1896, and the first lode was discovered in 1904. Since 1896, some 2.5 million ounces of gold have been produced from the Wiluna area. The mining operations at Wiluna are 100 per cent owned by Wiluna Gold Pty Ltd, a wholly owned subsidiary of Wiluna Mines Ltd. Oxide and sulphide gold ore is extracted by conventional open pit mining techniques, and ran-of-mine ore is processed through two separate circuits. The oxide circuit has a capacity to treat 600 0(X) tonnes per annum and the sulphide circuit has a capacity to treat 400 (XX) tonnes per annum. Additional gold is won by dump leaching sub-grade oxidised ore and by retreating of primary ore flotation tailings from previous operations. Testwork carried out in 1990 indicated the viability of leaching dumps of run-of-mine oxide ore, and in June 1991 Signet Engineering of Perth, WA, was awarded an EPCM contract to construct a nominal 2.5 million tonne dump leach facility, for a total construction estimate of 51.75 million.

Jan 1, 1994

By A. Putz, F. Vincent, A. R. Laplante

"This paper briefly reviews some of the gravity research done at McGill University and current Canadian operating practices, with emphasis on results of interest for operators. The following topics are addressed: security, economics, predicting recovery, circuit optimization, unit selection and final upgrading. Emphasis is placed on the Knelson Concentrator.The topic of security and economics are addressed jointly, in terms of the place of the gravity circuit in the mill flowsheet. Actual plant experience is drawn upon to identify potential problems and actual solutions.Predicting primary recovery is linked with a characterization of the ore, the choice of a circuit, and the fraction of the bleed used. Factors such as feed preparation, preliminary upgrading, fraction of recycle treated, ability to recover fines and location of the bleed are discussed.Final upgrading is achieved almost only by tabling and smelting. This can lead to fine gold recovery problems when more effective units are used upstream. Alternatives are discussed.IntroductionResearch on gold recovery by gravity over the past eight years has associated McGill University with a number of gold producers. This paper attempts to review the information gathered from a practical perspective. Some of the information was generated in McGill University's labs, some gathered at plant site, and some was shared by operators."

Jan 1, 1994

By Bradford H. Miller

Separation and Recovery Systems, Inc. (SRS) provides on-site waste minimization and resource recovery using its state-of-the-art MX-1500 centrifuge and MX-2000 thermal desorber. The MX-1500 can process over 450 feed tons of material per day, resulting in centrifuged cake containing 20% to 60% by weight. The MX-2000 is a hollow-flite thermal processor indirectly heated by either steam or hot oil. SRS has dewatered and/or deoiled over 1,000,000 feed tons of material in the refining, chemical, and energy industries using the MX-1500. SRS estimates that over 300,000 barrels of reusable oil have been recovered from that material. Additionally, SRS has dried and/or detoxified over 150,000 wet tons of solids or soil to regulatory or customer-specified limits using the MX-2000.

Jan 1, 1994