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By R. Mensah-Biney

The kinetics of loading of gold from bromide solution onto an anion exchange resin, PAZ-4, were investigated in a batch stirred reactor. The initial loading rate was described mathematically by a first-order reaction rate equation. The effect of agitation speed, temperature, resin particle size, resin concentration, initial concentration of gold and bromine in solution on the rate was investigated. The model described fairly accurately the loading process in terms of the variables investigated. The rate constant for the initial loading ranged from 0.5 to 1.3 x10-3 sec-1 and the half-time was 9.3 to 56 minutes. The initial rate constant increased with increasing temperature with an activation energy of 15.7 kJ/mole (3.8 kcal/mole). The rate constant was directly proportional to the concentration of the resin in solution. The subsequent reduction reaction was also modeled by the first-order rate equation and the apparent rate constant was estimated to be 3.0 x 10-6 sec-1 with a half-time of about 44 hours.

Jan 1, 1994

By R. W. Smith, A. M. Raichur, M. Misra

Mycobacterium phlei has very good potential as a hematite flotation collector. The flotation recovery of hematite is dependent upon the solution pH and concentration of the microorganism. The critical pH for maximum recovery of hematite is around three, which corresponds to the point of zero charge of the microorganism. An excellent correlation between the flotation recovery and bacterial adhesion on hematite is observed. The adhesion of Mycobacterium phlei on hematite can be described by the potential energy of interaction calculations using an extended DLVO theory.

Jan 1, 1994

By Robert H. Peters

This U.S. Bureau of Mines report identifies the types of serious accidents that occur most frequently at small underground coal mines and describes the strategies that could help prevent these accidents. A wide variety of methods for improving safety are suggested, including improvements in the design of equipment, work procedures, work schedules, safety programs, and emergency response plans, as well as techniques for diagnosing the potential hazards associated with new technologies and work procedures. Some of the papers in this volume focus on preventing specific types of mining accidents--ones associated with materials handling (primarily back injuries), equipment maintenance, improper machine guarding, and ground failure during retreat mining. Although the recommendations in this volume are heavily influenced by research performed at underground coal mines in the Appalachian coalfields, most of the papers contain advice that is equally pertinent to almost any type of mine.

Jan 1, 1994

lbis new concept in geology is introduced by a reinteipretation of the Archaean stratigraphy of the greenstone belts of the Yilgarn Craton of Western Australia. Evidence is presented to show that the recorded Archaean succession of the Eastern Goldfields Province is composed of two distinct groups of mafic/ultrarnafic and felsic igneous rocks which, together with sediments, form alternating sequences represented by Cycles 1 to 4; Cycle 5 consists entirely of sediments. Recorded stratigraphy for the Murchison and corre1atives of the Southern Cross Subprovinces conform to this pattern. The five basic components are referred to as Unit 1 to Unit 5. A major erosional unconformity between Units 3 and 4 extending across the Craton is identified as a locus of potential major gold occurrence, including fossil placers, where suitable structural situations exist; Units 1 and 3 are identified as potential hosts of gold and nickel deposits; Units 2 and 4 for gold and base metals.

Jan 1, 1994

By A. V. Reddy, C. Beckermann

"The DC continuous casting of a grain refined AI-4.5%Cu round ingot with realistic boundary conditions is numerically simulated. Of particular interest are the effects of the transport of free solid in the form of equiaxed grains on the macro segregation patterns and the final grain size distribution. The study uses a previously developed two-phase model that incorporates descriptions of heat transfer, solute redistribution, melt convection, and solid transport on the system scale with microscopic models of solutal undercooling, microsegregation and grain impingement. The numerical results indicate that grain transport inhibits the formation of inverse segregation in the ingot shell and promotes negative centerline segregation. This is explained by the reduction in the solid coherency next to the mold and the advection of solute-lean grains towards the centerline. Comparisons with the experiments of Finn et al. [5] illustrate the need for considerable improvements in the model. IntroductionMacrosegregation continues to be one of the concerns in DC continuous casting of aluminum ingots. The variation in composition over the ingot cross section results in the need to adjust alloy composition in order to meet mechanical property specifications in finished products. The extent of macrosegregation is greatly affected by the casting conditions, such as casting speed, superheat, cooling rate, mold size, alloy composition, and grain refining practices. Thus, it is of great interest to develop a comprehensive mathematical model to simulate the casting process, enabling the selection of conditions that minimize macrosegregation while maintaining a high productivity."

Jan 1, 1994

By J. E. Allen

The trend in refractory technology for the copper and nickel industries has been to higher quality raw materials and improved processing technology. These changes have been dictated by the changes in pyrometallurgical processes in these industries. For example the introduction of flash smelting, reaction type smelting and auxiliary slag cleaning furnaces havedemanded better refractories materials. Extensive field applications and improved laboratory testing procedures have helped make this transition possible. Changes in refractory technology, primarily in basic refractories, are followed from the late fifties to the present and into the future.

Jan 1, 1994

By T Davids, B J. J Botha

The presence of an extensive soft siltstone layer in the middle of the inter-burden sequence of rocks at Syferfontein Colliery in South Africa prompted tests to determine the effect of different mid-column decks of inert material in the siltstone layer. The objective was to achieve significant cost savings in explosives use whilst not degrading dragline productivity. An important factor that had to be considered was that the initiation systems available in South Africa are not accurate enough to ensure simultaneous initiation of explosives decks in a hole.

Jan 1, 1994

By A. R. Laplante

A novel methodology to estimate gold recovery by gravity is presented. The methodology makes use of a population balance model which represents gold liberation, breakage and classification behaviour and applies pre-concentration and recovery performance curves to gravity-recoverable gold to predict overall recovery. Derivation of the necessary parameters is explained and demonstrated using data from an actual gravity circuit and one projected application. The methodology makes it possible to estimate the performance of circuits with large gold circulating loads and relatively low unit recoveries (e.g. jigs), or with high recoveries on a bleed of the circulating load (e.g. Knelson concentrators).

Jan 1, 1994

By J. Vaughn Barrie

Placer mineral deposits may exist in the nearshore and shelf regions off western Canada. These deposits could contain gold, ilmenite or zircon as well as sand and gravel aggregate. Two deposit types typical of the British Columbia offshore are: (l) modem and relict gold/titanium beach deposits; and (2) reworked relict titaniferous shelf deposits. The preservation of drowned beach heavy mineral concentrations resulted from a rapid relative sea level rise across the shallow shelves approximately 10 500 years ago, particularly off the Queen Charlotte Islands. This same transgression submerged an outwash fluvial system that had been exposed for at least 3200 years, draining areas of known gold placers.

Jan 1, 1994

By B. E. Penrod

The main constituents of flat glass are the eight commonest elements of the earth's crust. Five of these, silicon, sodium, calcium, magnesium and oxygen are essential. Two more, Aluminum and potassium have beneficial properties. For colorless glasses iron is undesirable, in standard clear glasses a small amount of iron is tolerable, while for most tinted glasses iron is essential. These elements are present in glass as oxides and because they are so common there is no foreseeable resource shortage. The availability of supplies of materials at particular sites at prices which enable a glass manufacturer to be competitive may be another matter. In this paper it is intended to provide a historical perspective to the current situation, to contrast some of the traditional North American and European practices, and to progressively review some of the driving forces for future change and to attempt to assess their effects upon both raw material supplier and consumer.

Jan 1, 1994

By Andrew L. Puwis

Methodologies were presented for computing the thermal gradient associated with single crystal solidification in macroscopic computer modeling. The. heat transfer, and solidification of a shaped investment casting model were simulated using properties from three different alloys. Following the simulation of solidification, the resultant thermal gradients (G) and rates of solidification (R) from representative points were extracted in various ways and compared: It was discovered that alloy properties have a strong influence on the computed thermal gradient and rate of solidification for the three methods investigated. Data also showed that the computed gradient for each model was very different depending on the temperature range used to compute these values.

Jan 1, 1994

By Guo-Zheng J

This paper describes the risk management strategies adopted to control unstable slopes in the east open pit of the Daye iron ore mine. Extensive experience has been developed over the last 35 years in the management of pit wall instability resulting in the successful excavation and reinforcement of pit slopes over 350 m in height.

Jan 1, 1994

By John J. McClelland

The U.S. Bureau of Mines formed a team in 1991 to begin developing a long-range research plan for computer-assisted mining that would benefit the metal-nonmetal mining industry. This report details the team's accomplishments, specifically, the development of a model that identifies metal-nonmetal mining research needs that could be addressed by the application of automation technology. The report also provides a summary of automation needs and applications based on visits with mining company representatives. The status and future direction of this work is also presented.

Jan 1, 1994

By J. A. Gonzalez-Dominguez

During the electrorefining of lead by the Betts process, ionic concentration gradients become established within the slimes layer. These gradients contribute to precipitation of secondary products and to gradients in electrode potential applied to slimes filaments, and thereby affect the dissolution of noble impurities. This paper describes the experimental results obtained when a typical lead anode was dissolved under galvanostatic conditions with concurrent interruption of current at preset slimes thicknesses. Reference electrodes were incorporated within the lead anode to follow the potential gradients across the slimes electrolyte. Samples of the slimes electrolyte were withdrawn in-situ and their compositional changes were related to transport processes across the slimes layer. Upon current interruption the anodic overpotential decays, first abruptly (as the uncompensated ohmic drop disappears), and then slowly (due to the presence of a back E.M.F. created by ionic concentration gradients that decay slowly). Current interruption measurements showed that: (A) concentration gradients exist across the slimes layer, (B) inner solution potentials within the slimes layer can be larger than those measured from reference electrodes located in the bulk electrolyte, (C) secondary products can shift the inner solution potential to negative values that reverse upon re-dissolution and (D) ionic diffusion is seen upon current interruption but it is complex and difficult to model due to the presence of processes that can support the passage of internal currents. SEM and X-ray diffraction analysis of the slimes filaments indicated that secondary reactions leading to the formation of Si02 and PbF2 take place (mainly at the anodelslimes interface). The onset of these reactions and their relationship to the Pb-F-Si-H20 Eh-pH diagram are linked to the industrial operation of the Betts process.

Jan 1, 1994

By I. Gaballah

Cadmium is toxic to plant, animals and humans. The council directive of the European Communities No 8315 13lEEC has fixed an upper limit of 200 ppb for the release of cadmium in industrial effluents. The conventional method of neutralization/prccipitation ( NIP ) is inefficient to reach this limit. The objective of this study is to test the efficiency of the trees modified bark to remove cadmium cations from industrial effluents after the conventional treatment by NIP. Laboratory scale tests with synthetic solutions show that the cadmium removal depends upon pH and initial concentration. About 99.9 %, 99 % and 96 % of the metal are removed from synthetic solutions containing 10, 100 and 1000 ppm respectively. Pilot plant trials ( 1 m3 ) with an industrial effluent bearing about 500 ppb of cadmium lead to the almost complete elimination of the cadmium ( final concentration is lower than the analytical detection limits < 20 ppb ).

Jan 1, 1994

By H. B. Miller

Contract Incentives have long been employed in the underground hardrock industry as a tool to influence employee performance, enhance productivity, and control labor costs. While traditionally structured to establish a direct correlation between performance and compensation, many contract programs have evolved into elaborate systems that promote strategies often viewed as independent of productivity. This paper presents the findings of research into these contract incentives and was conducted with the cooperation of 33 mines utilizing a spectrum of employee compensation and incentive programs. Emphasis of this analysis focuses on the types of production contracts observed and their role with respect to employee earnings.

Jan 1, 1994

By H. Cho

There is an indication that high-pressure roller milling promotes selective liberation due to preferential breakage along the mineral boundaries. A study was undertaken to compare the degree of liberation obtained by high-pressure roller milling with that of conventional ball milling. Coals with different HGI&apos;s were ground in a high-pressure roller mill and a ball mill to produce products with similar size distributions. The products were then subjected to float-sink separations to determine the degree of liberation. Also, the relative cleanabilities were compared by separating the ground products by froth flotation. The results from this study are presented in the paper.

Jan 1, 1994

By L. Harris

The gold mining and ore processing operations of Minera Yanacocha S.A. are 10cated in an area 4,000 meters above sea level in the Peruvian Andes same 600 km north of Lima and 20 km north of Cajamarca. The joint venture partners are Newmont Second Capital (USA); Compania Minera Condesa (Peril); Mine Or (France) and the IFC. Newmont manages the operation. The Yanacocha district comprises several areas with mineralization evidence. The first ore with minable reserves of 28 million tonnes of ore assaying about 1.4 gpt Au is called Carachugo and is being mined and treated at the rate of 14,000 tonnes of ore per day by open pit mining methods. ROM ore is dump leached and the gold recovered in a Merrill Crowe plant. The plant design incorporates some unusual considerations to overcome the problems of the high rainfall in this area and assure the protection of the environment.

Jan 1, 1994

By Hutton A. C

Quantitative X-ray diffraction (XRD) analyses using the Rietveld method, a standardless technique for full XRD pattern fitting, showed the mineralogy of the eastern Queensland Tertiary lacustrine oil shale deposits is dominated by detrital cla

Jan 1, 1994

By L. Lü, M. O. Lai

"Mechanical alloying is a dry, high energy ball milling process which has been used to synthesize metallic powders in the solid state. The present study use this technique to synthesize Cu-base shape memory alloy powder from commercial Cu70Zn30, Cu86Zn14 and element AI powders. The evolution and formation of shape memory alloy powder were monitored using X-ray diffraction and microscopy. It was observed that shape memory alloy powder started to form after 1.8 ks of mechanical alloying. ? phase was clearly detected after 3.6 ks of mechanical alloying. The intensity of X-ray diffraction of the y phase increased when mechanical alloying duration was prolonged indicating an increase in the amount of y phase. Microstructure observation showed different stages of formation of alloyed powders: welding between powders and formation of layered structure, deformation and fracturing of layered structure, and finally the formation of alloyed powders.IntroductionMechanical alloying (MA) is a process used for producing powders with controlled and extremely fine microstructure. It was original developed in 1966 (1) to produce aNi-based superalloy combining oxide dispersion strengthening with gamma prime precipitation hardening. In recent years this technique has been used in producing a wide range of materials including intermetallic compounds (2, 3), amorphous materials (4-6) and other materials (7-9). In MA, a blend of powders is subjected to highly energetic compressive collision. The powder panicles are welded and fractured during ball milling. Therefore, it is essential that at least one of powders should be ductile to act as combiner. It has however been found that brittle components without soft element can also be mechanically alloyed (10), even ceramic powders (11).The present work aims to study the mechanism of formation of shape memory alloy powder during MA."

Jan 1, 1994