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By A. C. Wadhawan

In the present context of rapid industrialization, production of Lead-Zinc metals from low grade materials, residues and wastes can make substantial contribution to the supply of these metals in India. Recovery from secondary sources also plays an important role in conservation of mineral resources and lower power consumption. Conscious effort is therefore, required to increase the secondary metals which, besides saving in energy cost will also help in waste material management and keeping environment clean. The major thrust is, therefore, needed in this direction. During all these years, the Indian Lead- Zinc industry has made sustained efforts for recovery of metals from low grade ores and from metallurgical wastes and residues. The paper identifies the treatment of low grade ores by various technologies and techniques and the treatment of metallurgical residues and wastes generated during primary Lead and Zinc smelting in India. Some of the major achievements in past decade have also been elaborated in the paper. The strategies to be followed for continuing treatment of low grade ores and waste materials by adopting newer, environmental friendly technologies, in consonance with the rigid standards being adopted by most of the countries including India. have also been dealt with in the paper.

Jan 1, 1994

By Vinod K. Sikka, René Cooper

"Cohoes, New York 12047 Intermetallics are an attractive class of advanced materials. The aluminide intermetallics offer advantages including: (1) lower density, (2) oxidation resistance, (3) carburization resistance, and (4) interesting mechanical properties because of their ordered crystal structure. Even though the attractive properties of the aluminides and other intermetallics have been known for nearly four decades, their practical applications have not been developed for two reasons: (1) the poor ductility (in some cases, both ambient and high temperatures) and (2) the lack of processability into meaningful components. Recent advances such as ductilization of Ni3Al by small additions of boron and the knowledge that environmental effects are the major cause of poor ductility in Fe3Al and FeAl systems have brought the intelmetallics into the forefront of research and their commercial applications. This paper has described a method for melting Ni3AI-based alloys that successfully utilize the exotherrn for the formation of NiAl from the elemental materials. The reaction-synthesis method has also been utilized for the production of NiAI and NiAI-based alloy powders from the elemental powders. The reaction-synthesized powders of NiAI and NiAI-based alloys were consolidated by hot extrusion and evaluated for tensile properties over a temperature range from room temperature to 1050ºC. The powder-processing conditions have been found to have more influence on the ductile-to-brittle transition temperature of NiAI than the powder-production method.IntroductionIntermetallics are an attractive class of advanced materials [1-11]. The alum in ide interrnetallics offer advantages including: (1) lower density, (2) oxidation resistance, (3) carburization resistance, and (4) interesting mechanical properties because of their ordered crystal structure. Even though the attractive properties of the aluminides and other interrnetallics have been known for nearly four decades, their practical applications have not been developed for two reasons: (I) the poor ductility (in some cases, both ambient and high temperatures) and (2) the lack of processability into meaningful components. Recent advances such as ductilization of Ni3Al by small additions of boron and the knowledge that environmental effects are the major cause of poor ductility in Fe3Al and FeAl systems have brought the intermetallics into the forefront of research and their commercial applications. The paper will briefly review the processing techniques being pursued for the commercial applications of Ni3Al-based intermetallics. The major emphasis of the paper will deal with synthesis of Ni3Al and NiAI intelmetallics."

Jan 1, 1994

Abouleid,A.F.327 Ajdic, I.451 Albert, L.F. 221,307 Alem, A. 525 Asama, T. 431 Avgherinos, P. J. 373 Baker Jr, C.N. 331 Balossi Restelli, A. 171 Beckwith,G.H.33 Bellini, A. 469 Bermingham, P. 481 Bertero,M. 171,535 Beyer, M. 503 Bottiau, M.41 Botto, G. 205 Bruskeland, O. 337 Budhu, M. 349 Bullivant, R.A. 181 Bustamante, M.G. 185, 475, 535

Jan 1, 1994

By Liane L. M. Kacinuck

This U.S. Bureau of Mines publication is intended to provide mining industry representatives and regulatory authorities with a reference package dealing with studies on hydrology and underground mine subsidence. An annotated bibliography and a list of additional sources are given and represent references published prior to June 1993. Ninety-two references ware identified and 72 obtained for assessment. Annotating the references included evaluating the study methodology and summarizing the basic results. The references are also compiled based on geographic location to aid the user in identifying articles of particular interest.

Jan 1, 1994

The knowledge of aggregate size under various chemical and hydrodynamic conditions is very important for selective agglomeration, flotation and water clarification processes. Traditionally, aggregate size measurements are conducted using an ex-situ technique or in a diluted suspension. In either case, the measurement occurs in an environment that does not resemble the actual conditions under which the aggregates are formed. In this study, an on-line scanning laser microscope has been used to study the coagula size of micronized coal suspensions as a function of pH, solids concentration and agitation intensity. A maximum aggregate size of 310 µ m was obtained under relatively quiescent conditions and at pH values near the iso-electric point (iep) of the coal. The aggregate size results compare well with the coagulation efficiency measurements obtained under the same pH conditions.

Jan 1, 1994

By Jerry D. St. Clair

A multidisciplinary team of scientists and engineers at Wont has been working to understand heavy metal contamination of DuPont process waste streams and technologies for abatement of these metals. As part of this effort, an extensive study was made of a specific waste stream of importance in DuPont's environmental commitment. This 200 gpm stream contains 5-5000 ppm of nickel plus a variety of inorganic and organic constituents. The chemical complexity of the waste rendered conventional. alkaline precipitation ineffective, and only through the simultaneous application of analytical characterization, fundamental chemical understanding, and process engineering did effective technical approaches emerge. In this instance, ion exchange, sulfide precipitation, and caustic digestion ultimately proved successful in reducing the nickel to below the 1 ppm target. The results of this study will be presented, along with key learnings about the process of solving heavy metal contamination problems.

Jan 1, 1994

[ENGLISH active earth pressure adapter additive adhesion admixture, addition adsorbed water aggregate air air entrainment air hose allowable bearing value allowable pile bearing load]

Jan 1, 1994

By H. Sevim

In a recently developed long term open pit production planning model, the optimum plan is found by exhaustively searching through nested pits of maximum-metal contents. A more efficient, dynamic programming (DP) based search algorithm now replaces the exhaustive search algorithm which was requiring prohibitively long execution time in real life cases. The logic and the formulation of the newly developed search algorithm are illustrated through a small hypothetical case. A real life gold deposit is treated to demonstrate that the algorithm does indeed find the optimum production plan among all possible plans. A comparison, in terms of computational savings between the two algorithms is also given.

Jan 1, 1994

By A. P. Grobbelaar

Andalusite is a member of the sillimanite group of minerals consisting of andalusite, kyanite, and sillimanite. These minerals are the structural polymorphs of Al,Si05 (the anhydrous silicate of aluminium) and although chemically similar, they differ in physical properties due to their different crystal structures. For further information on the sillimanite group, see the chapter on Kyanite and Related Minerals that follows. The minerals are generally the products of the metamorphism of alumina-rich sediments and are found in schists, gneisses, or hornfelses, which have undergone either regional or thermal metamorphism from their original form. Sedimentary deposits may also form since the minerals are chemically and physically resistant to breakdown. When heated to a sufficiently high temperature the sillimanite group minerals convert to mullite with a resultant volume expansion and the liberation of silica. Due to the stability of the mullite formed, its high hot strength and resistance to chemical and physical erosion, they are widely used in the manufacture of refractories and special ceramics (Table 1). The reaction can be represented as follows: [ ] The worldwide use of these minerals depends to a large degree on their availability (Fig. 1). Andalusite, with its lower conversion temperature and the lowest volume expansion on being heated is the natural choice as a raw material to produce energy-saving refractories without prior calcination. The Republic of South Africa holds by far the largest minable andalusite deposits of the world, estimated at some 70 Mt of known in situ reserves. The only other large commercial production of andalusite comes from France, with known reserves of about 5 Mt. Potential new deposits are known from China, Ireland, Australia, and South America. World consumption of andalusite in special performance refractories has risen from less than 10 ktpy in 1960 to nearly 300 ktpy in 1990, which is due to cost effectiveness in many industrial applications compared to other conventional refractory products. Andalusite-based refractories have traditionally been used in Europe, South Africa, and the Far East; usage in America was limited in the past due to relatively high delivery costs and availability of other local refractory minerals. However, there is a significant trend towards greater use of andalusite in North America, thus opening new markets and replacing other traditional refractory raw materials. GEOLOGY Andalusite occurs in metamorphosed rocks of clay-like com- position, as in the andalusite-hornfelses in thermal aureoles (contact metamorphism), formed under conditions of high temperatures and low stress, and in regional metamorphic rocks, such as the andalusite-schists. These schists are mostly unconnected with definite igneous intrusions but were presumably also formed at high temperatures and under low stress. Andalusite can also appear in alluvial deposits associated with the primary deposits. At depths of 10 to 20 km, temperatures of up to 450°C might be expected. Another result of increasing depth is an increase of pressure due to the load of the rock cover. The load stresses involved in metamorphism is generally believed to lie in the range 0 to 10 000 bars. During contact metamorphism the increase in temperature is brought about by the injection of magma. The temperature reached in the country rock at some distance from the igneous body will always be less than the initial temperature of the intrusion, which is presumably less than 1 200°C, and will vary with time and distance from the contact. A simple metamorphic reaction involving dehydration of an aluminous sediment can be: [ ] At higher temperatures sillimanite would form at the expense of andalusite, while kyanite would be the mineral formed at higher pressures, as can be seen in the phase diagram of A12Si05 (Fig. 2).

Jan 1, 1994

By G. Van Weert

Refractory gold ores and auriferous concentrates containing silver tend to form refractory silver jarosites during pressure oxidation. Earlier work with pure Ag2S has shown that the addition of iodine species to the autoclave feed yields cyanide soluble iodargyrite (Agl) instead. Near complete silver extractions from the autoclave product were obtained at a I-/Ag+ ratio of 5 or more. This paper reports on the pressure oxidation and cyanide leaching of two industrial refractory (arseno) pyritic silver-bearing concentrates: 1. from Peru (sulphosalts) and 2. from the USA (pyrite, with acanthite occlusions). While using a I-/Ag+ mol ratio of only 1 in the feed, it has been possible to obtain 98 and 97% Ag extraction from the two autoclave products by cyanide leaching, respectively. This compares to 11 and 54% Ag extraction from the as-received concentrates and 4 and 15% Ag extraction, respectively, after pressure oxidation without KI present. The results of the testwork are discussed in terms of concentrate mineralogy and pressure oxidation conditions.

Jan 1, 1994

By Marion Loomis

Environmental regulation is an ever growing cost to the mining industry. Requirements for such items as air quality modeling, hazardous waste disposal, selenium concentration in water and sagebrush planting consume more of the mining industry’s resources each year. The mining industry is willing to make the necessary financial commitments to assure that the air, land and water resources are adequately protected and restored. However, it is sometimes difficult to explain to management and stockholders why money should be spent on a specific issue when science and common sense indicate it is being wasted. Common sense and sound science should dictate how mining is regulated.

Jan 1, 1994

By R. Srikanth

Dust control in high production longwalls is a major problem requiring, among other things, careful attention to the design of operating practices, and ventilation schemes. Several studies have shown that the shearer is the major source of dust on a longwall face. Support movement has not been regarded as a major source of dust in U.S. longwalls; yet under certain conditions, 31 percent of the shearer operator's dust exposure can be due to support movement. Several methods have been developed for the control of shield-generated dust. Yet the need for better methods is apparent. In this paper, the amount of airborne respirable dust generated per shield move is estimated from specially designed experiments on longwall faces. A total of ten experiments were conducted in five longwall faces in four different mines. Each experiment involved one face visit and lasted three to six hours. The contribution of shield movement to the airborne respirable dust concentration immediately downwind of the shield moved, varied between 0.12 and 1. 75 mg/m3 in the five longwall faces. The mass of airborne respirable dust generated by shield movement was found to vary between 39 and 386 milligrams per shield move. The results from this study reveal that control of dust from longwall shields requires a combination of approaches involving alternative operating practices, reducing shield dust generation rate, increasing face air flow, and decreasing personnel exposure.

Jan 1, 1994

By Larry Ng, Keith McDonald

The benefits of controlled blasting techniques have gained increasing recognition by the mining industry in recent years. The utilization of an effective controlled blasting programme can result in a safe work environment with less loose rock and a reduced level of scaling and ground support.

Jan 1, 1994

By P. Myllykoski, J. Nylander

"A commercial program package called Crownoff for the simulation of temper rolling in four high mills has been verified against measured data. The agreement between measured and calculated transversal strain distributions of the strip was found to be good. Effects of the strip crown and work roll bending force on the strain distribution were simulated. The results showed that when a single ground camber of work rolls is used for all strip widths; the strip crown should be parabolic, excluding the edge drop. An increase or decrease of the strip crown by 30 % during a coil can be compensated by a 2 to 5 t change in the work roll bending force. The ability to control the strip crown by work roll bending was insensitive to strip width. IntroductionCold rolled steel strips are usually temper rolled after recrystallization annealing, which follows cold rolling. The purpose of temper rolling is to suppress the yield point, finish the strip surface and correct possible flatness errors. The presence of a yield point might otherwise cause problems during subsequent forming processes. The in homogenous yielding in non-temper rolled steels leads to the formation of Lüders bands in the strip surface.The rolling force is influenced by the rolling speed and changes in frictional conditions in the roll bite. Therefore it is very important to plan carefully the mill settings and control algorithms during rolling. The purpose of mill control algorithms is to ensure constant reduction and the best possible strip flatness during the entire coil.Correctly predicting the rolling force is important for determining the mill presettings. Torque, forward slip and power requirements are not usually critical, if the reductions are small. However, the large elastic deformations occurring in the roll bite make the physical description of the process difficult. Physical rolling models developed for cold rolling contain assumptions that lose their validity as the reductions decrease to the level of one per cent."

Jan 1, 1994

By Raymond F. Dalton

Despite the ready availability of numerous zinc sources, the process of solvent extraction- electrowinning (SX-EW) has as yet found little favour in the zinc industry. It is suggested that this is largely due to the previous lack of availability of suitable selective reagents having the particular features required to enable them to fit in to a solvent extraction-electrowinning based process for zinc, particularly with regard to strength and selectivity for zinc over iron. This paper describes work on the development of new selective extractants for the recovery of zinc from both sulfate and chloride aqueous solutions and suggests how they might be integrated into new zinc processes.

Jan 1, 1994

By L. D. Robbins, M. L. Murphy, A. C. Campbell, L. Murphy

This paper reports on what appears to be the first discovery of prehistoric mica-schist mining in southern 4frica. The mine concerned was found in a location very rich in rock art that is one of the most important archaeological sites in the Kalahari. The authors conclude that the oval pieces of mica schist that were found at the mine site were used by Khoisan peoples to scrape fatty tissue from hides that were to be cured. Radiocarbon datings seem to indicate that such ovals were used for at least 20 000 years.

Jan 1, 1994

By E. H. Cho

Pittsburgh #8 coal cleaned by the conventional froth flotation was oxidized in a 2-liter Parr Stirred Top Bench Reactor. The oxidation time was varied up to 5 hours; the temperature, from 150 to 225°C, the oxygen pressure, from 15 to 500 psi; and coal dosage, from 15 to 60 grams in 600 ml of distilled water. The oxidation of coal was evaluated by measuring total acidic group formed on the coal surface as well as by measuring the adsorption of calcium ion from a solution under standard conditions. It was found that the oxidation increased with increasing oxygen pressure without much leveling-off effect. However, the oxidation of coal increased sharply from 150°C to 175°C and then tended to level off above 175°C. The adsorption of calcium was reached more than 3% on the coal oxidized under favorable conditions. The adsorption of calcium on coal increased sharply with increasing equilibrium pH. The BTU loss was sensitive to oxidation temperature. This study concludes that the optimum oxidation of coal should be conducted at high oxygen pressures around (e.g. 500 psi) 170°C for 3 hours. This study also concludes that the oxidation in an autoclave is far superior to that in a fluidized bed in terms of calcium adsorption, BTU loss and reaction time.

Jan 1, 1994

By Luis W. Pommier

The developed processes, the subject of this paper, extract the hydrocarbons, halogenated organic compounds and metal contaminants from hazardous soils, rendering them non-hazardous and ready to be placed back on the ground. The processes first segregate a non-contaminated fraction from the contaminated soil. This initial task is performed using available minerals processing technology: sizing, gravity separation, magnetic separation, froth flotation, etc. The remaining contaminated fraction, is submitted to two leaching operations for the removal of organic and metal contaminants, whenever both are present or to a single leaching operation if only one type of contaminant is present. The decontaminated soil fraction is mixed with the non-contaminated fraction and is placed back on the ground. The leaching liquors, used at neutral pH, are non- hazardous. After decontamination the liquids are processed to extract the contaminants, now valuable materials, for commercialization. Organic contaminants are removed by distillation of the solvents. The metal contaminants are precipitated in their oxide form. In both cases the regenerated solvents are recycled. The decontamination processes are economically competitive with transportation and disposal of the soils to permitted facilities for hazardous materials, and most importantly the developed processes remove the liabilities from the Responsible Parties. The law establishes that these liabilities do not disappear with either fixation nor with transportation and disposal since the environmental liabilities are of the ? cradle to grave? type.

Jan 1, 1994

By J. Z. Keating

There are close to two million tons of Industrial Minerals processed and sold in North America wherein the processor/marketer has no affiliation with the source mine. The largest quantity, about 800,000 tons, is barium sulfate, which is sourced in lump ore form mainly from China and India. The Alumina Trihydrate Industry sources several hundred thousand tons from various alumina refineries. Substantial quantities of bauxite, zircon, magnesite, and fluorspar arrive in North American ports each month. There are also rapidly growing quantities of offshore talcs and calcium carbonate ores being processed in U.S. plants. These feedstocks are usually quite pure, have unique properties, and enjoy bulk rail or waterborne freight economies that allow successful competition with locally sourced raw materials. With increasing restrictions on mining activities, and the increasing need for sophisticated functional minerals, the importation of minerals will continue to grow.

Jan 1, 1994

By J. E. Brownhill

This paper does not deal with the typical start-up issues of equipment, production capacity or work force. This is a description of the challenges faced and the changes made by the project team to bring to fruition the reconstruction of Port Inland. Many honored traditions and norms had to be overturned to find the winning combination that provided the productivity, flexibility and cost necessary to survive in today's competitive minerals environment. This paper covers the innovation in terms of machinery, operations, and management philosophy that permitted the renovation and reopening of Port Inland as a commercial limestone producer in the spring of 1992. Port Inland, constructed by Inland Steel in 1930, operated as a captive source of metallurgical grade limestone for the steel industry until its closure in 1989. Located in the Upper Peninsula of Michigan on the north edge of Lake Michigan, the operations consist of a deep water port facility with crushing, screening and stockpile storage for 500,000 tons of finished product at the port. Ninety-nine percent of the stone is shipped via lake boat to ports within the Great Lakes. The operation is unique in that both metallurgical Dolomite and Limestone are produced on site. In 1930, Port Inland was at the fore front of technological advancement. It was the first major mining operation to use roller bearings and other equipment innovations. Over the 60 years of operation, Inland Steel placed emphasis on steel making technology and iron ore mining at the detriment of the limestone operation. By the early 80's, Port Inland was no longer a leading competitor. Inland Steel, unable or unwilling to spend the capital to modernize, closed the facility in the fall of 1989.

Jan 1, 1994