Search Documents

By André Chagnon, Yvon Héroux

"Résumé - Cette étude porte sur l'altération de la matière organique et des argiles dans les boues carbonatés dévoniennes du faciès ""F"" de la Formation de Pine Point et ses équivalents stratigraphiques la Formation d'Evie et l'unité bitumineuse de la base de la Formation de Horn River. La matière organique se compose principalement de bitume solide et de quelques fragments de fossiles (organo­ clastes). La majorité des échantillons ne renferment que de l'illite et des interstratifiées illite/smectite.Si on compare les températures d'homogénéïsation (Th = l00°C) des inclusions fluides de la sphalérite et des dolomites associées à la minéralisation aux températures estimées à partir de la réflec­ tance de la collinite (84°C à ll7°C), l'on ne peut pas conclure à la présence d'une anomalie ther­ mique dans le district minier de Pine Point. De plus, la réflectance des organoclastes n'est pas plus élevée dans le district minier de Pine Point que dans les localités plus éloignées des gîtes. L'analyse des minéraux argileux conduit à la même conclusion : aucune anomalie thermique n'est décelable dans les unités échantillonnées à l'intérieur du district minier de Pine Point quelque soit l'indicateur utilisé.La kaolinite et la matière organique altérée, affichant des valeurs anomales de sa réflectance, se trouve essentiellement en présence de soufre et de sulfures. Cela suggère une origine authigène de la kaolinite et une altération de la matière organique reliées au phénomènes de minéralisation.Abstract- The alteration of organic matter and clays is studied in the Devonian Pine Point Formation carbonate muds, ""F"" facies, and its lateral equivalents the Evie Formation and the biturninous unit at the base of the Horn River Formation. The organic matter is mainly composed of solid bitumen with few fossil fragments (organoclasts). Most samples contain only illite and mixed layer illite/smectite.If we compare the Th(l00°C) from fluid inclusions of sphalerite and dolomites associated with mineralization to the temperatures calculated from the reflectanœ (Ro) of the collinite (84°C to 117°C), we cannot detect a thermal anomaly in the Pine Point mining district. This result is based on the reflectance values of organoclasts from the mining district that are not higher than those reflectance values measured on organic matter (OM) away from the ore deposit. A similar conclusion is reached from the clay study: none of the parameters used allow us to identify a thermal anomaly in the samples from the mining district.The kaolinite and the altered OM showing anomalous Ro values mainly occur with sulfides and sulfur. This association suggests an authigenic origin for the kaolinite and an alteration of the OM due to the mineralization events."

Jan 1, 1994

By Stephen B. Castor

The rare earth elements (REE) which include the 15 lanthanide elements (Z = 57 through 71) and yttrium (Z = 39) are so called because the elements were originally isolated in the late 18th and early 19th centuries as oxides from rare minerals. Most REE are not as uncommon in nature as the name implies. Cerium, the most abundant REE (Table 1), comprises more of the earth's crust than copper or lead. Many REE are more common than tin and molyb¬denum, and all but promethium are more common than silver or mercury (Taylor, 1964). Promethium (Z = 61) is best known as an artificial element, but has been reported in very minute quantities in natural materials. Lanthanide elements with low atomic numbers are generally more abundant in the earth's crust than those with high atomic numbers. In addition, lanthanide elements with even atomic numbers are two to seven times more abundant than adjacent lan¬thanides (Table 1) with odd atomic numbers. The lanthanide elements traditionally have been divided into two groups: the light rare earths (LREE), lanthanum through eu¬ropium (Z = 57 through 63); and the heavy rare earths (HREE), gadolinium through lutetium (Z = 64 through 71). Although yttrium is the lightest REE, it is usually grouped with the HREE to which it is chemically and physically similar. The REE are lithophile elements (elements enriched in the earth's crust) that invariably occur together naturally because all are trivalent (except for Ce+4 and Eu+2 in some environments) and have similar ionic radii. Increase in atomic number in the lanthanide group is accompanied by addition of electrons to an inner level rather than the outer shell. Consequently, there is no change in valence with change in atomic number, and the lanthanide elements all fall into the same cell of the periodic table. The chemical and physical differences that do exist within the REE group are caused by small differences in ionic radius, and generally result in segre¬gation of REE into deposits enriched in either light lanthanides or heavy lanthanides plus yttrium. The relative abundance of individual lanthanide elements has been found useful in the modelling of rock-forming processes. Comparisons are generally made using a logarithmic plot of lanthanide abundances normalized to abundances in chondritic (stony) meteorites. The use of this method eliminates the abundance vari¬ation between lanthanides of odd and even atomic number, and allows determination of the extent of fractionation between the lanthanides because such fractionation is not considered to have taken place during chondrite formation. The method is also useful because chondrites are thought to be compositionally similar to the original earth's mantle. Europium anomalies (positive or negative departures of europium from chondrite-normalized plots) have been found to be particularly effective for petrogenetic modelling. REE were originally produced in minor amounts from small deposits in granite pegmatite, the geologic environment in which they were discovered. During the second half of the 19th century and the first half of the 20th century, REE came mainly from placer deposits. With the exception of the most abundant lanthanide el¬ements (cerium, lanthanum, and neodymium), individual REE were not commercially available until the 1940s. Since 1965, most of the world's REE have come from two hard rock deposits: Mountain Pass, United States, and Bayan Obo, China. GEOGRAPHIC DISTRIBUTION OF REE DEPOSITS More than 70% of the world's REE raw materials come from three countries: China, the United States, and Australia. China emerged as a major producer of REE raw materials during the 1980s, while Australian and United States market share decreased dramatically (Fig. 1). Table 2 gives recent annual production figures along with estimated reserves by country, and Fig. 2 shows loca¬tions of significant REE mining. MINERALS THAT CONTAIN REE Although REE comprise significant amounts of many minerals, almost all production has come from less than ten minerals. Table 3 lists minerals that have yielded REE commercially or have po¬tential for production in the future. Extraction from a potentially economic REE resource is strongly dependant on its REE miner¬alogy. Minerals that are easily broken down, such as bastnasite, are more desirable than those that are difficult to dissociate, such as allanite. In general, producing deposits contain REE-bearing min¬erals that are relatively easy to concentrate because of coarse grain size or other attributes. For more thorough discussions of REE¬bearing minerals see Mariano (1989a) and Cesbron (1989).

Jan 1, 1994

By B. J. Jody

Each year, about 11 million tons of metals (ferrous and nonferrous) are recovered in the U.S. from about 10 million discarded automobiles. The recovered metals account for about 75% of the total weight of the discarded vehicles. The balance of the material or shredder residue, which amounts to about 3 million tons annually, is currently landfilled. The residue contains a diversity of potentially recyclable materials, including polyurethane foams, iron oxides, and certain thermoplastics. This paper discusses a process under development at Argonne National Laboratory to separate and recover the recyclable materials from this waste stream. The process consists essentially of two- stages. First, a physical separation is used to recover the foams and the metal oxides, followed by a chemical process to extract certain thermoplastics. The status of the technology is discussed, and the process economics are reviewed.

Jan 1, 1994

By L. L. Probert

A three-year project focusing on the depth profiling of respirable coal mine dust particles using scanning electron microscopy coupled with energy dispersive x-ray analysis resulted in the development of statistically classified particle-behavior models. The models depict the changing silicon fraction for 5-, 7-, 9-, and 11-keV accelerating voltages, thereby giving a clear indication of the nature of various types of particles. This paper will focus on the results for respirable quartz particles that occur in underground coal mines across the U.S. The relationship between the amount of surface-available quartz and coal seam rank is well established for Pennsylvania

Jan 1, 1994

The dissolution kinetics of cobalt in iodine/iodide solutions was investigated using a rotating disc technique. Variables studied here included temperature, rotating speed, concentration of lixiviants, and pH of the solution. The overall dissolution reaction was found to be limited by mass transfer of tri-iodide through the diffusion boundary layer with Arrhenius activation energy of less than 16.2 kJ/mol (4 kcal/mol) over the temperature range, 2-42°C. The pH of the solution had little effect as long as the pH of the solution was less than 8. However, when the pH of the solution became greater than 8, the dissolution rate decreased dramatically due to passivation. The rate of dissolution was in good agreement with the dissolution model developed by the authors earlier.

Jan 1, 1994

By Murali Thirukkonda, Rahul Shah, Srinivas Tangrila, Shankar Rachakonda, Jan Kajuch, Arthur Gurson

"High-temperature superconductors have potential for a variety of applications such as power generators, superconducting magnets for mine sweepers or ship propulsion motors, and magnetic levitation transportation systems. Interest in the use of superconducting wires and tapes increased dramatically after the discovery of high-critical-temperature (high-Tc) oxide superconducting compounds, which offer operating temperatures above that of liquid nitrogen. Several techniques have been proposed to produce commercially viable high-Tc oxide based superconducting wires. One of the promising methods involves multi-pass powder-in-tube (PIT) wire drawing followed by rolling and heat treatment. This work focuses on the development of a numerical model to simulate the PIT drawing process for fabrication of long lengths of silver sheathed Bi-2212 superconducting wires. The finite element based model was used to predict densification of the oxide powder, wire drawing forces, and silver sheath thickness during drawing. A cap-type pressure dependent constitutive equation was implemented in the model to simulate the powder behavior. The model incorporated experimentally obtained material data for the silver and powder. Results indicate that powder densification is increased by decreasing the initial silver thickness and increasing the silver strength. Data from wire drawing experiments were used to verify model predictions. IntroductionSuperconducting wires and tapes can be used to carry large dc currents with no measurable loss due to resistivity. When used in superconducting magnets for power generators, motors, levitation devices, magnetic detectors, or energy storage devices, they could potentially result in significantly reduced energy losses. In the past, most prototypes were tested in liquid helium at 4.2K [1]. However, the necessity to provide liquid-helium cooling systems proved to be a serious limitation in commercialization. In 1986 high-critical-temperature (high-Tc) oxide superconductors were discovered [2], which could allow for higher operating temperatures above liquid nitrogen (77 K). Since then, both academia and industry have concentrated their efforts on the development of high-Tc oxide superconducting wires, tapes and coils. As yet, large scale fabrication of long lengths of these wires with the required current carrying capacity and mechanical properties remains an enormous challenge."

Jan 1, 1994

By Dale S. Preece

The blast-induced movement and final location of geologic layers that may cause environmental problems can be predicted using discrete element methods. This prediction capability can be used by mine operators to locate the material in the muck pile during excavation which would allow encapsulation to prevent groundwater infiltration.

Jan 1, 1994

By Dale Matthews

The Getchell Mine, near Winnemucca, NR, was discovered in the 1930s and was initially mined to recover gold from oxide ores. During the 1940s and 1950s, gold was recovered from the highly refractory arsenic sulfide ores using horizontal kilns to roast the ores. During the 1960s, fluid bed roasters were used to oxidize the ore and recover the gold. The mine was shut down from 1968 through 1985. In 1985, heap leaching was started on the low-grade oxide ores that were available. In 1989, a pressure oxidation circuit was started to recover gold from the higher grade sulfide ores. Flowsheet The basic plant flowsheet of the Getchell Mine are shown in Figs. 1 and 2. The plant was designed to process a nominal 2.7 kt/d (3000 stpd) of ore with about an 85% onstream availability and a gold production of 15.5 kg/d (500 oz/ day). Run-of-mine (ROM) ore is fed directly to a wet semiautogenuous grinding (SAG) mill after the +457-µm (+18in.) rock is removed on a stationary grizzly. From the SAG mill, the ore goes to a ball mill where it is ground to 80% -75 µm (-200 mesh) and is then sent to a thickener. The SAG and ball mill operate in closed circuit using cyclones.

Jan 1, 1994

By R. Bhaskar

The objective of the project was to optimize the ventilation parameters of a continuous miner underboom scrubber to further control. the amount of airborne dust discharged during mining, to further reduce the exposure of face personnel for an exhaust brattice ventilation system, and avoid recirculation of contaminants at the face. This research was performed in an underground coal mine in Utah. The tasks included preliminary face ventilation evaluation and optimization of the scrubber system to eliminate recirculation of the scrubber discharge air. Airflow tests were conducted on the currently used dust control system and the modified scrubber system. Tracer gas tests were performed to evaluate face ventilation effectiveness. Confirmatory tests of the scrubber system under actual operating conditions, modifications to the scrubber system, and a comparative evaluation of the scrubber system vs. the existing system were performed. This paper presents the results of the airflow pattern tests and the respirable dust levels in the modified scrubber system and the existing system. The optimized face ventilation parameters and the developed operating guidelines may provide the benefits of dust reduction, better face ventilation, and improved visibility.

Jan 1, 1994

By David Allen

Cable bolting is a relatively new strata reinforcement technique that has been used successfully in Australia and the United Kingdom. Jim Walter Resources, Inc. has examined the principles and can visualize its useful application in many areas, such as: a) Longwall pull-out areas, b) Roadway junctions, particularly those involving yield pillars, c) Rib reinforcement, and d) Possible replacement of cribbing in roadways, especially longwall tailgates. This paper describes the conditions which led to cable bolt testing, the results of tests conducted to date, and conclusions about the direction that Jim Walter Resources, Inc. is heading as far as testing and potential applications are concerned.

Jan 1, 1994

By S. A. Sass

The design and construction of Solvay Minerals (formerly Tenneco Minerals) Soda Ash Expansion Project, which is the world's most modern natural soda ash facility, is detailed. Along with a discussion of design considerations, the international joint venture ownership and teaming arrangement for design and construction companies is examined.

Jan 1, 1994

By M. Ravindran

The Government of India started its deep seabed exploration programme during 1982. This programme was started as one of national importance and several national laboratories were involved to realize the development of requisite technologies for deepsea mining and processing. After a concentrated effort on surveying, using its own as well as hired ships, India succeeded by mid 1980s in identifying a prospective site in the Indian Ocean as an exclusive claim for development. India was registered as a Pioneer Investor and became the first country to obtain this status on 17th August 1987. India has been allocated an exclusive mine site of 150,000 km2 in the Central Indian Ocean. Our country also developed considerable expertise in the metallurgical processing for extracting metals from these nodules. The Department of Ocean Development, Government of India, the organization which is designated as the nodal agency responsible for implementing the deep seabed mining programme has drawn up a long term plan which will enable it to fulfill its obligations as a Pioneer Investor. The work toward the design and development of a mining system has been entrusted to the Central Mechanical and Engineering Research Institute, Durgapur. As a part of this programme they have developed a nodule collector and a riser system which have been tested in very shallow waters only. Since this technology development for deep sea mining applications is highly time consuming and very expensive, this programme is also being used to develop components for intermediate applications. In view of the long timeframe required for perfecting a deepsea nodule mining technology, the Government of India is also keen on developing shallow water mining systems for utilizing the placer deposits. One of the richest heavy mineral deposits in the Indian Exclusive Economic Zone is available on the west coast of South India in the state of Kerala. The coastal stretch between Kanyakumari, on the southern tip of India, and Alleppey along the west coast at a distance from the tip of approximately 210 km, there is a good multimineral reserve. The initial survey indicates that the estimated reserves in the surveyed areas are approximately as follows: Ilmenite 1.4 million tonnes Rutile 0.14 million tomes Zircon 0.13 million tomes Sillimanite 0.53 million tonnes

Jan 1, 1994

By Kal V. S. Sastry

Mathematical and expert system models are being used extensively for mineral process engineering. There exist no standardized methodologies for their computer implementation. In meeting this need, this paper introduces the concept of a process software model, or simply a software model and presents a two-step methodology for its development involving software model specification and development. The software model specification is to be performed after extensive discussions with the ultimate users of process software based on which the software model is developed. These software models provide a formal basis for the design and construction of software objects corresponding to the real world process objects.

Jan 1, 1994

By Dale S. Preece

The computer program. DMC Qistinct Motion &de), which w&s developed for simulating the rock motion associated with blasting, has been used to study the intluence of row delay timing On rock mOtiOn. The munerical simulations correspond with field observations in that vmy short delays (< 5Oms) and vety long delays(> 3oOms) produce a lower percent-cast thao a medium delay (100 to ZOO ms). The DMC predicted relatio&lp between row delay timing and percent-cast is more complex than expected with a dip in the auve where the optimum timing might be expected. More study is required to gain a full undasranding of this phenomenoo.

Jan 1, 1994

This paper considers the application of recent laboratory gas sorption data to the understanding outburst phenomena in underground coal mining. Previous use of threshold limits based on gas content and coal rank are placed in perspective. Although this work focuses on overseas research and experience, parallels can be drawn for New Zealand coal settings, taking into account localised mining and geological factors.

Jan 1, 1994

By D. D. Xu

A novel system for the depression of pyrite and the ash-forming minerals has been developed. A metal ion, including but not restricted to Fe+2, is added to form a hydroxide coating on the pyrite or ash-forming mineral. A polymeric depressant is then added to attach to this re-surfaced mineral. Nearly 200 flotation tests with a 11 different coals indicate the effectiveness of this system. Many of the important process variables such as the coal source, frother-collector system, grind size and procedure, pH, metal ion, and depressant type and concentration have been studied.

Jan 1, 1994

By C. Patrick

Longwall face-to-face equipment transfers or moves are, for many companies, the largest single source of non-productive time in a longwall mining system. Detailed planning and resourceful thinking are paramount for economical, safe, and timely longwall moves. New equipment and innovative techniques are frequently tested in order to reduce overall move time. Determining the cost effectiveness of these ideas is difficult since the decision is influenced by many subjective factors. A project scheduling simulation model of the longwall move process was developed in order to analyze and assess the economic viability of innovative transfer methods and equipment. The model provides a project duration frequency distribution and lists of critically indexed activities and paths. It compares the monetary savings from reduced transfer time and capital costs for several innovative ideas.

Jan 1, 1994

By Waters A. G, Nightingale R. J

The quartzite added at the blast furnace for the purpose of adjusting the chemistry of the burden inputs is shown to have a disproportionate impact on both the level and the variability of the hot metal silicon (HMSi). This conclusion is supported not only by direct correlation involving data from five blast furnaces, but also by mass balances. In one case the R2 correlation coefficient was 0.96 and the mass balance was accurate to within five per cent for a wide range of quartzite additions. The results indicate that as much as 43 per cent of the silicon in the added quartzite reports directly to the hot metal. Indeed, silicon from quartzite was found to be much more likely to report to the hot metal compared to silicon from regular sources (eg coke and sinter), reflecting differences in the activity of the silicon source.

Jan 1, 1994

By M. L. Sorokin

The thermodynamic of nickel production from laterite ore and from sulfide concentrate can be analyzed using PO2 - PS2 diagram of the Ni-Fe-S-0-SiO2 system. The procedure of the diagram computation is suggested and the diagrams for various temperature and Fe/Ni ratio are calculated. Three-suffix Margules equations are used for the calculation of the thermodynamic properties of three solutions: liquid matte, liquid slag and solid Fe-Ni alloy. The diagrams are used for the considerations about direct one-stage metallic nickel production.

Jan 1, 1994

By V. T. McLemore

The Wind Mountain (WM) nepheline syenite deposit is part of the alkalic complex in the Cornudas Mountains, which ranges in age from 34.6 ± 1.5 Ma to 36.8 ± 0.6 Ma. The WM deposit consists of a complex, zoned pluton that ranges from syenite porphyry to nepheline syenite porphyry. The WM deposit has potential use for ceramics and dark-colored beverage containers and consists of nepheline, k-feldspar, albite, and varying amounts of other minerals. Analcime also is present locally but must be avoided because it is unsuitable for ceramic and glass. Chemically the deposit consists of 56-63 % SiO2 17-21 % Al2O3 and 4.0-5 % Fe2O3. Although initially iron is high, when the crushed rock is passed through a specialized magnetic separator, the iron content drops to below commercial maximum standards of less than 0.5% Fe2O3. The WM deposit is currently under exploration and testing to determine marketability.

Jan 1, 1994