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By E. Molleman

This paper reports on testwork exploring the dissolution/reprecipitation reaction: ZnS + 2HCl ? ZnCl2 + H2S, as part of a process for the production of pure ZnS. In spheroidal form, this would constitute a premium fonn of zinc refinery roaster feed enabling the production of pure ZnO. The research focused on the influence of proton activity on dissolution of zinc concentrates from Brunswick Mining & Smelting, Red Dog and Tara. The results and thermodynamic data suggest that the three concentrates contained significant amounts of the more reactive mineral wurtzite, although XRD analysis showed mainly the presence of the mineral sphalerite.

Jan 1, 1997

This paper will examine the prospects for Queensland's non-fuel mineral industries as we approach the 21st century. The opportunity for growth is unprecedented. Exploitation of recent discoveries, proposals and developments in downstream processing are predicted to contribute to a doubling of the State's mineral exports to around $10 billion by the year 2000. In 1995 - 96 the value of Queensland's mineral production was $6 billion, comprising $1892 million metallic minerals, $127 million non-metallic minerals and $4 025 million total fuel minerals. For many years Queensland has been among the world's major producers of copper, silver, lead, zinc, bauxite and mineral sands. Recently Queensland has become an important producer of magnesia. Queensland's ability to compete results from its location close to rapidly developing Asian markets, the diversity of its major minerals and an increasing ability to add value to the resources base using competitively priced energy. Northwest Queensland is one of the richest base metal provinces on earth following the recent discovery of five world-class orebodies. Of these deposits, Osborne (copper-gold) has commenced production and Cannington (silver-lead-zinc) and Ernest Henry (copper-gold) are scheduled to be developed by 1997. Century Zinc Limited and the Queensland Government are negotiating with native title claimants on the development of Century (zinc-lead-silver). Expansion is in progress at the Mount Isa copper mine (renamed the Enterprise) and copper smelter and a high analysis fertiliser project may be developed based on Phosphate Hill. Korea Zinc Company Limited has reached agreement to construct and operate a 350 000 Mtpa zinc smelter/refinery near Townsville. There are future expansion prospects for the vertically integrated major industrial mineral operations based on Weipa bauxite and Kunwarara magnesite. Upgrading of the Boyne Island aluminium smelter will require a doubling of alumina consumption. Downstream processing options for Kunwarara magnesite are being investigated and are expected to lead to increases in production and the manufacture of a range of value-added products. At the Yabulu refinery near Townsville, nickel and cobalt production using imported ore is to be increased and a commercial cobalt plant is to be built. Additional opportunities for further processing and manufacturing are associated with proposed new mines at Ely (bauxite), Skardon River (kaolin) and Goondicum (ilmenite). Recently discovered resources of zeolite and perlite also offer exciting development possibilities. Other manufacturing opportunities such as glass and ceramics based on local and plentiful clay and silica sand could replace imports. Silica sand at Cape Flattery is currently exported and production is expected to double.

Jan 1, 1997

By Marcondes Lima Costa

The Amazon region is characterized by the development of deep chemical weathering represented by widespread lateritic covers and soils. Two distinct periods of laterite formation can be distinguished: mature laterites from the Eocene-Oligocene (and locally from the end of the Cretaceous), and immature laterites from the Pleistocene. The older laterites occur on plateau landscapes,and the younger ones on widespread hilly to ?at lowlands. Both types show complete or truncated pro?les, generally covered by deep yellow to brown topsoils. The mature laterite pro?les contain high concentrations of gibbsite and/or aluminum phosphate, whereas the immature ones are poor in these minerals. The Amazon region is rich in mineral deposits related to lateritic pro?les. Some mineral deposits are of primary origin but were concentrated to economic grades by lateritic processes. The most important ore deposits are of iron, aluminum (bauxite), kaolin, manganese, gold, nickel, copper and phosphate. These are mainly related to mature pro?les. The wide spectrum of ore deposits and mineralogical and geochemical complexity of the Amazon laterites has been promoted by: (1) the prevalence of ideal conditions for laterite formation throughout much of the Tertiary; (2) the presence of varied basement lithologies due to contrasting geological environments; and (3) a variety of epi-genetic alteration types. The lateritic pro?les show a well-developed ore zonation which is related to speci?c lateritic horizons. Iron and gold deposits occur in the ferruginous horizon, which is nearest the surface; the central aluminous horizon hosts bauxites, aluminum phosphate, strontium and gold;and the lower clayey horizon contains deposits of manganese, nickel, copper and kaolin. Resistate phases which residually accumulate throughout entire pro?les include titanium (as ilmenite andanatase), chromium (as chromite), tin (as cassiterite), yttrium (as xenotime), and niobium (mainly asilmenorutile). Epigenetic alteration, caused by swamp environments developed above truncated lateritic pro?les, has led to the formation of high-grade kaolin and refractory bauxites. The laterites inthe Amazon region contain most of all known kinds of ore mineralization related to laterite processes.

Jan 1, 1997

By Murphy A. S, Budod A

The Philex concentrator represents the first time Jameson Cells have been used in a cleaner scavenger application or in large scale flotation in roughing and scavenging. This necessitated a major change in Jameson cell design as well as a chan

Jan 1, 1997

By Joseph Irons, David Westfall

Three rock tunnel sewer systems are underway in the Chicago Area. (Figure 1) The three are designed to act independently and to be later connected to the future tunnels of the master plan. The tunnel excavation for each of the systems has been completed. One is in the Northwest area within the City being built by the City, known as the Lawrence Ave. System. Another is in the Southwest suburbs, known as the LaGrange-Brookfield Sewer or Southwest 13A, being built by the Sanitary District, the third is in the South suburbs called the Crawford Avenue sewer or Calumet 18-E, Ext. A- being built as a joint venture between the City and the District. The three are similar in that they have the same purpose, the same component parts and their tunnels were constructed in the nigaran limestone using a mechanical mining machine. The purpose of each of the systems is two-fold. First to provide flood relief for existing inadequate sewer systems, and second to reduce the pollution load to the waterways caused by combined sewer overflows. The existing systems in the areas to be relieved are combined sewers built many years ago. The main outlet for the Village of LaGrange, for example, was built in 1908, is badly in need of repair and lacks the capacity to handle the flood flow from the heavily urbanized area it now serves. The dry weather flow from the area is taken off by intercepting sewers. However during

Jan 1, 1997

By Harold L. Gibson, Don H. Rousell, Ian R. Jonasson

"The Sudbury Structure consists of three major components: 1) the Sudbury Basin; 2) the Sudbury Igneous Complex which surrounds the basin as an elliptical collar; and 3) an outer zone of shatter-coned and intensely brecciated footwall rocks. Although the Sudbury Event which formed the structure may be unique, the area has, in fact, been shaped by a series of tectonic, magmatic and mineralization events which can be considered in terms of two Wilson cycles of continental extension and closure. The first cycle, from 2500 to 1700 Ma, included the following events: doming (uplift of Levack Gneiss Complex); NE-SW extension (Matachewan dikes); N-S to NW-SE rifting (faults, mafic intrusions, sedimentation, and Ni-Cu-PGE and U mineralization); NW-SE extension (Nipissing diabase, and Ni-Cu-PGE, Ag, Co mineralization); and NW-SE and NE-SW closure (Penokean Orogeny, 1900 to 1700 Ma) with superimposed meteorite impact (1850 Ma, Ni-Cu- PGE, Zn-Cu-Pb deposits). The second cycle, from 1700 to 1000 Ma, included: N-S extension (alkali metasomatism, Au); N-S extension (hornblende diabase dikes along the Murray fault set); NNESSW extension (olivine diabase dikes); NE-SW extension (Fecunis Lake fault set); and NW-SE closure (Grenvillian Orogeny).The rich and diverse Ni-Cu-PGE and subordinate Zn-Pb-Cu and Au mineralization of the Sudbury region is related to endogenic and impact-triggered crustal extension and magmatism. The Sudbury Structure apparently was the site of a triple junction or hot-spot. The Sudbury ores, although located within an impact structure, are analogous in terms of age and tectonic setting to Ni-Cu-PGE and Zn-Pb-Cu ores elsewhere in the world. Meteorite impact accentuated on-going ore forming processes and magmatism at Sudbury."

Jan 1, 1997

By B. J. Arnold

Utility coal specifications usually contain a requirement for a maximum moisture content in order to prevent coal handling problems and to minimize evaporative losses in the boiler. As most coal cleaning processes are water-based, dewatering and sometimes drying steps are required to meet moisture specifications. Screens are often used for dewatering, with centrifuges and filters used to further reduce moisture in many cases. Algorithms to predict the performance of screens were developed for the Coal Cleaning Simulator running under Aspen Plus during a project sponsored by the U.S. Department of Energy and the Electric Power Research Institute. These algorithms include calculations for the size separation and a calculation for moisture content of the oversize product based on particle size and specific gravity distribution. This paper discusses the algorithm for predicting the moisture content of coal dewatered by screens.

Jan 1, 1997

By David Evans, David Barnes, Robert Raponi

"The Williams Mine processes, on average, 6,450 t/d of gold bearing ore using two parallel grinding circuits, leaching and C.1.P., carbon stripping, electrowinning and refining. At present, each grinding circuit consists of a SAG mill in closed circuit with a spiral classifier and a ball mill in closed circuit with two stages of cyclones.Since grinding has always constituted the largest portion of milling costs, the Williams Mine has been proactive in trying to reduce such costs through innovative changes. One project under consideration is the replacement of one spiral classifier by a vibrating screen.This paper discusses the testwork performed to evaluate the replacement of one spiral classifier by a vibrating screen, and the preliminary engineering performed to date.IntroductionThe Williams Mine, located in northwestern Ontario, approximately 40 kilometres east of Marathon, is part of the Hernia gold camp. The mine is operated by the Williams Operating Corporation and is owned by the Teck Corporation and Homestake Canada Incorporated. Operation of the mine started in October 1985 at a rate of 3,000 t/d. After a mill expansion in August 1988, throughput increased to 6,000 t/d. Production has increased steadily since the mill expansion and in 1995, an average of 6,450 t/d of ore was processed at a recovery of 95.1 %."

Jan 1, 1997

By G. X. Wang

The nonliving dried water hyacinth (E. crassipes (Mart.) Solms) roots were investigated for biosorption of cadmium and lead and other heavy metal ions in aqueous solutions. Dried water hyacinth roots, when suspended in solution, strongly and rapidly sorb several different metal ions. Factors such as reaction time, pH, initial concentration of metal ions, presence of other metal ions and biomass concentration were investigated. Metal ions, including Cd2+ and Pb2+, were bound to the root in a very pH-dependent manner, with the binding increasing after about pH 3. High levels of removal were obtained. The adsorption was shown to follow the generalized Langmuir adsorption equation. The relative affinity of the roots for lead is greater than for cadmium. The maximum sorptions of the roots were about 33 and 86 mg/g for cadmium and lead, respectively. Only 15-20 minutes were required for the process of uptake onto the biomass to occur. The batch sorption kinetics of the uptake of cadmium and lead can be described by an apparent first-order reversible reaction model. The roots could be regenerated after the metal ions were stripped. A solution of CaCl2 in acidic medium appeared to be the best eluant for desorbing the sequestered Cd and Pb completely at pH 3. The kinetics of the metal stripping process was quite rapid. Successful desorption of Cd and Pb from the biomass by acidic CaCl2 solutions revealed that the metal uptake phenomenon is reversible, implying physical sorption of Cd and Pb.

Jan 1, 1997

By Robert F. Randolph

Research on improving haulage truck safety, started by the U.S. Bureau of Mines, is being continued by its successors. This two-part article reports the orientation of the renewed research efforts, beginning with an update on accident data analysis, the role of multiple causes in these accidents, and the search for practical methods for addressing the most important causes. Fatal haulage accidents most often involve loss of control or collisions caused by a variety of factors. Lost-time injuries most often involve sprains or strains to the back or multiple body areas, which can often be attributed to rough roads and the shocks of loading and unloading. Part II will describe research to reduce these accidents, including improved warning systems, shock isolation for drivers, encouraging seatbelt usage, and general improvements to system and task design.

Jan 1, 1997

By M. J. Nicol

Mr Vegter has analysed, in some depth, the approximations made in the treatment of the kinetic data presented in the original by ourselves (ref.1) and has come to the conclusion that ?under the experimental conditions used by Adams and Nicol (1986) the steady-state assumption was inaccurate?. We are acutely aware of the fact that the experimental method adopted does not permit the attainment of a true steady-state in the elution reactor. However, this does not eliminate the attainment of a pseudo steady-state by a suitable choice of the experimental parameters with the accompanying simplification of the analysis of the data with the aim of drawing the reader?s attention to the most important objective of the paper viz. the effect of various operating parameters on the rate of elution of gold.

Jan 1, 1997

By Robert Rautenberg, Paul McDermott

This paper will discuss the construction of 15.9 km (9.88 mi) of tunnels on a project in Chicago, Illinois. The tunnels were driven utilizing two rock and four soft ground TBMs ranging in sizes from 7.39 m (24.25 ft) in rock down to 1.95 m (77 in) in soft ground. In addition to the mining, there are 63 upper level structures and 16 dropshafts averaging 61.5 m (202 ft) deep included on this project. Many diverse mining, excavation, support and lining techniques were employed on this project.

Jan 1, 1997

By Linda Dufour

"Autoclaves have been in commercial use in the mining industry since the early 1950's the initial applications included tin, uranium, cobalt, nickel and copper extraction under both acidic and alkaline conditions. These circuits varied in batch or continuous operation. The geometry has been spherical, vertical, and horizontal type with up to six agitators, with throughput as high as 1000 stpd.Presently autoclaves are a good process selection for many refractory sulphide gold bearing ores. The first application of pressure oxidation in the gold industry was at the Homestake Mcglaughlin's Mine which was commissioned in 1985. This was an acidic pressure oxidation process treating 3000 stpd in three four compartment horizontal autoclaves 14' diameter and 53' long. Since the initiation of autoclaves for the treatment of gold bearing sulphides, there are presently 16 gold autoclaves operating worldwide varying in size up to 18'4"" inside diameter. There are seven autoclaves for the treatment of refractory sulphide gold bearing ores to be commissioned in 1997 and 1998.Autoclave technology has progressed extensively since the mid-eighties. Operational experience has made rapid progress and the result is much smoother and safer autoclave operation. There have been many advances in autoclave technology design. For example, the use of exotic materials for corrosion resistance to reduce down time for maintenance. The instrumentation involved in autoclave operation is very sophisticated which allows for many safety features. The advanced design has allowed for greater availability and as a result operating costs and maintenance costs have decreased. These technological advancements have made autoclave technology more safe and this has resulted in a greater acceptance of this type of operation. Many of the gold autoclave facilities operate up to 9 months continuously without shutdowns. The advancement of autoclave technology has inspired many new applications.Because of the outstanding operation of autoclaves in the gold industry, many other applications for autoclave technology are being considered. The following is a list of autoclave applications:"

Jan 1, 1997

By E. Adam, B. Milkereit, M. Salisbury, L. E. Reed, G. Perron

Integrating seismic reflection, borehole geophysical, and physical rock property studies is an effective means of mapping lithological contacts and structures in the crystalline crust. At Les Mines Selbaie in the northern volcanic zone of the Late Archean Abitibi Subprovince, a high-frequency seismic reflection profile has provided the first images of deep crustal structures of this important polymetallic mine site. Physical rock property and borehole geophysical studies confirm that prominent seismic reflections can be caused by lithological contacts, faults and sulphide mineralization. At Les Mines Selbaie, the first two of these are shown by this study. Clearly identifiable reflection images from sulphide mineralization have not been demonstrated in analysis of the profile. The seismic images provide useful information about gross structure in the vicinity of Les Mines Selbaie. They can also place important constraints on the sequence of tectonic events and, therefore, can aid future deep exploration programs.

Jan 1, 1997

By Steve Hubbard, Brad Marchant, Rolando Cuadra

"Triton Mining Corporation acquired the rights to Mina El Limon in Nicaragua in 1993 by international bid. The bid included the gold operations at Limon and an exploration concession of approximately 4000 km2. Triton assumed control of operations and exploration in May 1994.The Limon mine is located in west-central Nicaragua, approximately 100 kilometers northwest of Managua. The climate is tropical, characterized by a wet season from May through October, and a dry season November through April. Gold at Limon is associated with both banded quartz and silicified breccia veins in Tertiary volcanic rocks, belonging to the lower Coyol Group. Mining is from two open pits and one mechanized underground operation. A second underground mine is currently under development for production during 1997.This paper describes the expansion of the milling facility at El Limon from a nominal capacity of 400 tonnes/day, producing approximately 20,000 ounces of gold annually, to the existing 900 tonne per day mill operation. Engineering of the new mill facility was initiated in September 1994 and construction was completed a year later."

Jan 1, 1997

By Barlow S

The Kelian Gold mine project won two excellence awards from the Victorian Division of the Institution of Engineers, Australia. It was a challenging project, fast tracked in a remote and inhospitable tropical environment. The creation of a profitable and efficient mine was a significant engineering and project management achievement. The difficulties encountered and the way they were managed provide valuable lessons. These include the importance of sufficiently detailed engineering in all aspects of the job to enable the best estimates possible to be prepared during feasibility studies, the need to prepare the project scope and execution plan with disciplined and rigorous attention to detail by a highly experienced team and the value of identifying, assessing and mitigating risk and uncertainty during execution. The practical benefits of applying these lessons were demonstrated in the successful management of technical uncertainty on the recent diversion of the Kelian River to allow the expansion of the Kelian mine.

Jan 1, 1997

By C. J. R. Braithwaite, Giancarlo Rizzi

"The Navan zinc-lead ore deposit (70 million tonnes) is hosted principally (97%) by the Meath Formation (Lower Carboniferous, Courceyan, Navan Group), comprising a lower, mainly carbonate mudstone unit, the Stackallan Member, and an upper grainstone-dominated unit. TheStackallan Member, about 60 m thick, comprises about 35 peritidal cycles including an oolitic grain-stone interval. Grainstones forming the upper part of the formation, about 150 m thick, comprise at least six shallowing-upward ramp cycles. Emergence horizons are indicated by subaerial dissolution surfaces, in situ breccias, and a single palaeosol.Most dolomitization at Navan is con?ned to the Meath Formation. The linear dolomite body,trending NE-SW, has a ?attened, laterally limited, tabular geometry in cross-section, suggesting that dolomitizing ?uids initially rose vertically, cross-cutting stratigraphic and sedimentological bound-aries, although ?uid ?ow was subsequently controlled by these features.Three stages of dolomitization are indicated by textural relationships, cathodoluminescence (CL),oxygen isotopes, and ?uid inclusion data. Stage 1 crystals, with generally dully luminescing cores and up to six overlying subsidiary zones, are the main replacive phase. Crystal surfaces are commonly corroded and overlain by bright stage 2 rhombs (which also form new nuclei lining molds and fractures). Three subsets of zones are present in stage 2 crystals: bright, non-luminescent, and dull; these are locally separated by additional corrosion surfaces. Stage 3 comprises relatively large baroque crystals, generally dully luminescent but with up to seven sub-zones. Isotopic and ?uid inclusion data suggest growth of successive stages from waters which became progressively hotter(60°–160°C).The distribution of the ores follows the dolomite trend. Ores were precipitated between Stages1 and 2 of dolomite growth, following Stage 2, and also during the nucleation and growth of Stage3 crystals. Dolomitization and mineralization appear to have been temporally and genetically related. The cyclic sedimentation of the host rocks, which accentuates lithological and petrographical contrasts between depositional units, controlled dolomitization. The relationship between dolomitization and mineralization, which is closely associated with faults, provides powerful exploration criteria. The recognition of these features in limestones elsewhere in the Irish ore ?eld may point toward unrecognized zinc-lead prospects."

Jan 1, 1997

A Mineração da Trindade (Samitri) is a major Brazilian iron ore producer. Founded in 1939, privately owned Samitri operates six mines with a total production capacity of 14.5 Mt/a (16 million stpy). The mines are located in southeastern Brazil in the state of Minas Gerais. They are operating in the iron ore quadrangle, Brazil's primary iron ore-producing region. In addition to iron ore production, Samitri has the capability to produce 350 kt/a (386,000 stpy) of ferruginous manganese ore from two mines, also located in the iron ore quadrangle. Historically, about 70% of Samitri's production of lump ore, sinter feed and pellet feed is exported. Destinations include Belgium, Luxembourg, France, Germany, Trinidad and Tobago, China, Turkey and the United States. Alegria Mine In September 1989, Samitri started a new processing plant to treat itabirite, a low-grade iron ore. The goal of the plant was to produce sinter feed (coarse fraction) and pellet feed (fine fraction). Primary separation of sinter feed from pellet feed was accomplished with conventional vibrating screens making a 0.4-mm (40-mesh) cut. The screen oversize was stockpiled as sinter feed. The undersize was deslimed with hydrocyclones and upgraded by conventional froth flotation. Resulting pellet feed grades ranged from 3% to 3.5% Si02. A change in pellet feed requirements by Samarco Mineração SA, a Samitri subsidiary, called for Si02 levels below 1 % and increased production levels. Moreover, market demands called for a change in sinter feed size distributions. Unfortunately, lower pellet feed Si02 levels could not be achieved with the existing process. This was because of the presence of 35% +0.15 mm (+100 mesh) in flotation feed. Flowsheet development. Laboratory and pilot-plant studies conducted at Samitri's research facility found that to achieve lower Si02 levels, the +0.15 mm (+100 mesh) in flotation feed must be kept below 5% to 10%.

Jan 1, 1997

By L. M. Amaratunga, G. G. Hein, D. N. Yaschyshyn

Fine tailings produced in the milling process have traditionally been disposed of in tailings ponds. Attempts have been made to use these fine tailings in backfill, however, to date the majority of backfill operations have utilized only a small percentage of fines. The remaining fines are, therefore, being sent to tailings ponds creating a waste disposal and environmental problem. This disposal practice is even more acute in the gold milling industry where fine grinding, required for value liberation, results in the production of large quantities of fine tailings, of which a large percentage cannot be used in backfill. Through Cold-Bond Tailings Agglomeration (CBTA), these fine tailings can be agglomerated into pellets which can then be used as a coarse aggregate in back-fill. This paper presents the results of using these pellets to create an Agglomerated Tailings Paste Fill (ATPF) made entirely of fine gold mill tailings and cementing binders. Through this process, supplementary imported aggregates such as sand, gravel, rock-chips are not required while still maintaining adequate back fill strength. By using this CBTA technology, fine tailings are diverted from tailings ponds and becomes utilized as a value added resource in the form of aggregates for use in paste fill.

Jan 1, 1997

By Ching L. Wu, Joseph Penzien

An analytical procedure is presented for evaluating the stresses in linings of bored tunnels caused by kinematic soil-lining interaction. Three cases of interaction as produced by the following conditions are treated: (1) relaxation of in situ soil stresses near a lining following its installation; (2) overburden pressure at the soil surface; and (3) free-field soil response resulting from an earthquake. Non-dimensional formulas and graphs resulting from parametric studies are presented for practical tunnel design applications. The procedure is applied separately to a steel lining and a concrete lining for a site located at the lower end of Market Street in San Francisco through which a BART (Bay Area Rapid Transit)tunnel passes.

Jan 1, 1997