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By Jeffrey W. Fergus, Shiqiang Hui

"Aluminum is an important alloying addition to the zinc used in the hot-dip galvanization of sheet steel to control the properties and appearance of the resulting coating. Optimization of the galvanization process requires control of the alloy concentration which can be improved through the use of chemical sensors. Aluminum sensors based on molten electrolytes are commercially available but are not widely used because of their high cost. One approach to reducing the cost is to use a solid electrolyte which can simplify the sensor design and thus reduce the cost of fabrication. In this paper, the development of an aluminum sensor based on a solid fluoride electrolyte, specifically magnesium fluoride, will be described.IntroductionThe concentration of the zinc bath used in hot-dip galvanization affects the galvanization process as well as the properties of the resulting coating. Thus, accurate in situ measurement of the alloy composition can be used to improve process control. This paper describes a solid-electrolyte-based aluminum sensor for monitoring the bath composition during hot-dip galvanization."

Jan 1, 1997

The major proportion of South African coal is extracted by the bord-and-pillar mining method which requires that the overlying strata be supported by pillars of coal. The stability of the pillars is a major safety concern. One of the factors which affects the strength of coal pillars is the intensity and nature of discontinuities in the coal seams. Current design methods for pillars assume that al the coal seams have equal strength and are equally disturbed by natural discontinuities, resulting in over-designed pillars in some cases and potentially unstable pillars in others. Research was carried out to determine the nature of discontinuities in coal seams and to assess their potential effect on pillar strength. It was found that large variations exist in the intensity of discontinuities in the different coal seams being mined. In addition, numerical model studies showed that the discontinuities could significantly reduce pillar strength if the width-to-height ratio of the pillars is small, but the effect decreases as the width-to-height ratio increases.

Jan 1, 1997

By D. O. Murchu

Outokumpu Tara Mines located near Dublin, Ireland is Europe's largest producer of lead and zinc concentrates. To reduce dewatering costs and to improve environmental and working conditions, elimination of the lead concentrate thermal dryer was required. This paper describes the development and implementation of the pressure ceramic technology at Tara to replace a conventional vacuum filter/oil-fired dryer system. In 1996 the pressure ceramic filter dewatered 66,600tonnes of lead concentrate, producing a cake at 6 % moisture. Substantial operating cost savings have been realized. Commissioning of a second pressure ceramic filter to handle over 300,000 tonnes/year of zinc concentrates is scheduled for the first quarter of 1997.

Jan 1, 1997

By LaBrooy SR

A number of gold processing plants in Western Australia have nickel in their ores, leading to significant levels of nickel on their loaded carbon. The presence of nickel during leaching, adsorption and elution'may have detrimental effects on cyanide consumption, carbon inventory requirements, stripping costs, electrowinning efficiencies and may contaminate the gold bullion.This paper discusses the competitive adsorption of gold and nickel cyanides onto activated carbon and investigates changes in solution parameters that may improve gold adsorption and/or inhibit nickel adsorotion.

Jan 1, 1997

By Bob J. MacDonald

The Cape Breton Development Corporation is a federally owned Crown corporation in Canada that operates two coal mines the Prince and Phalen Colliery in the Province of Nova Scotia. Retreat longwall mining was first introduced to the shallower workings (I 80m) of Prince Colliery in the early 1980's. Phalen Colliery started longwall retreating in 1987 and since that time has extracted twelve panels. In 1993 there had been a total of eight longwalls varying in widths from 140-230m mined in Phalen Colliery that is on the Phalen Seam. Up to this point there were only minor ground control problems on the faces except for one of the earlier longwalls that was mining a split seam. There is some interaction on Phalen workings from remnant structures in the overlying Lingan and No. 26 Collieries which worked the Harbour Seam. Induced abutments loads along pillar edges have been observed and resulted in poor face conditions when mining the Phalen Seam. The ninth panel, 6 East was the first panel to suffer a major roof fall from the First Major Weighting. This was also the first panel to undermine a paleo sandstone river channel named the Lower Sandstone Unit (LSU). For the first time in Phalen's history subsequent longwalls began to experience periodic weighting events. The 6 East panel suffered a number of periodic weightings and on two occasions had to use foam cement to fill the cavities that resulted. On the next east side panel, 7 East, there were numerous periodic weighting events, but interestingly there was no significant First Major Weighting. 7 East was the first 260m wide panel and all others were 230m or less. This longwall was 3,400m long and began producing in December of 1994 and was still cutting coal in May of 1997. There were five significant roof fall events on this panel, three of which required foam cement to fill the cavities. Of these three the interruption to production varied from four days to seven months. There were definite precursors to each of the weightings including: 1) an increase in audible noise (termed bumping) on the face, 2) supports went rapidly into yield, 3) roof convergence increased, 4) water percolated from the face roof strata, and 5) severe spalling of the coal occurred resulting in increased tip to face distance. Longwall face weightings are a result of geomechanical factors and cannot be avoided However, the loss of roof control is a different matter and highly subjective to operational procedures. The causes of weightings, their magnitude and impact on the mining at Phalen have been investigated. The following factors have been identified as relevant to these occurrences. 1. The influence of pillars in the overlying Harbour Seam workings. 2. Location of the LSU relative to the Phalen Seam. 3. Thickness of the LSU. 4. Pressure arch effect from the adjacent gobs. 5. Poor operational practices on the longwall including: a) slow rate of retreat; b) inadequate supply of pump pressure to the hydraulic supports; c) premature yielding of the yield valves; and d) poor face alignment practices. This paper will review the events that took place on the 7 East longwall and show that the Lower Sandstone Unit is the primary cause of the weightings. However, other factors contributed to the loss of roof control and the formation of the roof cavities.

Jan 1, 1997

By Robert A. Field

Static-Load Piledriving utilizes a hydraulic push to facilitate the installation of a pile. The pile is not rotated, impacted or vibrated. A smooth pushing force advances the pile incrementally into the ground. Static-Load devices must have a reaction mass to push against. The most simple form of a Static-Load device is a jack; more advanced equipment, such as the Still Worker, also utilizes this approach. This paper focuses on the use of the Still Worker on three challenging projects. In each case, the existing site conditions made it risky, or unattractive, to utilize conventional impact, vibratory, or drilled-shaft equipment.

Jan 1, 1997

By R. P. Mohring

The South African Coal Industry had its beginnings in the Eastern Cape in 1859 when coal was mined to satisfy the fledgling settlements in the Eastern Cape. The growth in the industry was relatively slow up to the early 1970s when, firstly, the export business was expanded coupled with a major increase in the quantity of coal converted to liquid fuels and utilized for power generation. To meet this increased demand the industry developed many new operations employing the latest mining technology and systems. Coal production in South Africa reached 204 million tons in 1996 and revenue from exports reached R8 billion making it the second-largest foreign exchange earner after gold. In his address Rick P. Mohring describes the role coal plays in the international energy scene and outlines South Africa?s position as a producer and consumer of coal, and the challenges facing the industry. A wide range of steam-coals are produced to satisfy both the local market (power generation, coal conversion and the metallurgical industry) and the export steam-coal market. South Africa is in a unique position regarding the export market as it is still a relatively low-cost producer and is geographically well-placed to play in both the European and Far East markets. There are, however, a number of challenges facing the industry. To retain our competitiveness in the international market, ways of minimizing the cost pressures caused by high-cost inflation, increased environmental protection obligations and a decreasing quality resource base need to be sought. Locally the coal mining industry has a major role to play in Eskom?s goal of reducing the real cost of electricity by 15% in the next three years. Safety and health, productivity and the adaptation of the latest technology are issues being addressed by the industry to maintain its dominant position within the South African economy.

Jan 1, 1997

By Y. K. Yen, J. D. Miller, C. L. Lin

Particle size segregation is a common phenomenon in many particulate processes and has many undesirable effects. The size segregation which occurs on a belt conveyor causes a serious problem for on-line particle size measurement using image-based techniques. Whether particle size distributions measured from the top layer of the belt are representative of the total particle population is largely dependent on the degree of size segregation. Therefore, it is important to understand the nature of such size segregation in order to make appropriate corrections for on-line particle size analysis. Monte Carlo simulation has been used to provide segregation information on particles with simple geometry and the results can help to determine important factors in experiments with irregularly shaped particles. It is expected that the relationship between the particle size distribution of the top layer and that of the entire particle population on a belt conveyor can be formulated as a model based function.

Jan 1, 1997

Considerable attention has been given to the restoration of low-level radioactive (<1000 pCl/g) sites contaminated during the early years of the atomic energy program. Current clean-up activities which involve the relocation of contaminated soils to licensed disposal sites have been shown to be very costly due to the large volumes of soils which must be excavated, transported and stored. Recent characterization studies conducted at Virginia Tech suggest that the volume of soil requiring disposal can be greatly reduced using mineral processing techniques such as classification, density separation and froth flotation. This article discusses the application of these technologies for soil remediation and describes a conceptual flowsheet for treating soil samples from two contaminated sites.

Jan 1, 1997

By A. Feather

The Minataur? Process (Mintek Alternative Technology for Au Refining) is a novel route for the production of high-purity gold using solvent extraction. Following the successful demonstration of the process on a pilot-plant scale, a full-scale 24 t/a production plant has been commissioned at Harmony Gold Mine in Virginia, Free State. The commercial implementation of this process represents not only a significant advance in gold-refining technology, but may be instrumental in initiating important changes in the legislation regulating the marketing of gold in South Africa. Gold of either 99.99% or 99.999% purity can be produced from intermediate process products having a wide range of gold contents. The process comprises oxidative leaching of the solid feed, followed by selective solvent extraction of the gold from the leach liquor to reject impurities, and precipitation of high-purity gold powder. This paper outlines the process, presents selected results of two pilot-plant trials in which 5 kg/d of high-purity gold was produced from silver-refining anode slime and gold-electrowinning cathode sludge, and provides some details of the cost benefits.

Jan 1, 1997

By Dennis Dobson, Keith M. Henderson

Lone Star Industries, Inc. in Cape Girardeau, Missouri operates an open pit mine to produce limestone for its portland cement manufacturing plant. The present mining method, for safety and legal reasons, requires a set back from the property line, a berm, sloped overburden, and vertical rock walls with catch benches.

Jan 1, 1997

By John Wallace

"Monitoring compound semiconductor crystal growth using multifrequency eddy currents for sensing illustrates some of the extreme problems of measurement and interpretation that are not often seen in metallic systems. Using sensor arrays and scanning sensors have produced a qualitative and quantitative understanding of some of the high temperature electrical conductivity mechanisms in several compound systems. A detailed review of the CdTe/CdZnTe data is presented showing some of the complexity in the data as opposed to what is found in elemental semiconductors.HistoryThe most common goal in the use of eddy current measurement in crystal growth is to deter-mine the curvature of the liquid solid interface during growth to test if the heat transfer estimates of the thermal design were adequate for single crystal growth[l]. This aim could be met but represented only a small fraction of the data that was produced observing a growth cycle. A secondary consideration was what could be discovered in the recorded data about the growth and subsequent heat treatment as the boule cooled. This is usually a more difficult task because a crystal growth process is not a controlled experiment so much as a process that continually sees modification. Using a sensor arrays or a scanning loop has produced a qualitative and quantitative basis for understanding some of the high temperature electrical conductivity mechanisms. The implication of the these measurements of electrical conductivity variations are important in that they reflect the complex defect states that will occur on cooling and heat treatment following crystal growth. In contrast to the complex behavior of the conductivity of these compound semiconductors in the solid and liquid state we have the very well characterized system silicon to compare. Initially the interest on using eddy currents to monitor compound semiconductors came from G. Westphal at the Texas; Instruments Company in 1987 to monitor aspects of growth and compounding of GaAs. This was followed by work on solution growth of HgCdTe with D. Witter. The initial interest in the use of eddy cur-rents for monitoring CdTe crystal growth came from Prof. Wilcox at Clarkson University in the practical interest to determine and control the crystal interface curvature during vertical brigdeman growth. The first actual work was done by one of his former students. G. Neuge-bauer at the II-VI Corporation which was carried on by G. Rosen at Clarkson and R. Shetty at II-VI Corporation and with A. Socha at Johnson-Matthey Electronics. The work on CdTe extends over four years and yielded sufficient data to allow one to evaluate the utility of the information produced as compared to what could be obtained from monitoring an elemental semiconductor such as silicon."

Jan 1, 1997

By T. F. Torries

The primary merit criteria used by the mining industry is internal rate of return (IRR) rather than net present value (NPV) although NPV is favored by academicians. This paper discusses the problems with IRR and NPV and compares the multi-goal nature of decision makers and their need for information with the characteristics of NPV and IRR. Conclusions are that both NPV and IRR are needed for investment ranking, that NPV suffers the same multiple root problem as does IR.R, and the determination of incremental IRR to reach NPV consistent project ranking is misguided in practice.

Jan 1, 1997

By R. Lanza, M. Hytros, N. Saka, I. Jureidini, J. H. Chun, D. Kim

"A novel method for delineating the solidification front in metal casting has been developed using the attenuation phenomenon of electromagnetic radiation (y-rays or x-rays) and computed tomography (CT). The densities of the liquid and solid phases that exist during metal casting may differ anywhere from 4 to 12 % depending on the metal. As in the medical imaging field, CT provides an excellent means of mapping this density variation in a solidifying casting into two-or three-dimensional images.In an effort to develop an industrial-scale sensor, laboratory-scale experiments have been conducted using a cobalt-60 (Co60) radioisotope and a sodium-iodide (Nal) scintillation detector. The CT image reconstruction was performed on a crucible containing pure tin in a two-phase state. Although the spatial resolution and data acquisition speed were not optimum, the CT images clearly differentiate the liquid and solid phases of the tin in the crucible. To maximize resolution and minimize data acquisition time, a linear accelerator (linac)-based CT sensor is being developed and tested for application in the continuous casting of steel and aluminum alloys.IntroductionIn all casting processes, the quality of a finished product and its production rate depend upon the shape and movement of the solidification front. From a quality perspective, it is well documented that solidification kinetics (heat and mass transfer, fluid flow, microstructure evolution) greatly influence the final properties of castings [l,2,3]. Product shortcomings, such as surface defects, cracks, macro-and microsegregation, and inclusions are directly controlled by the solidification process. By understanding the role the solidification front plays in the casting process, product quality may be dramatically increased through the reduction of defects."

Jan 1, 1997

The general principles of technical due diligence best practice that are involved in assessing a mineral property in the early stages of its development are described and a bibliography of relevant papers is attached. The issues specific to the evaluation of gold deposits are highlighted. The Australasian Institute of Mining and Metallurgy&apos;s (The AusIMM) initiatives in this area, dealing with the proper public reporting of Reserve/Resource information (JORC Code) and property assessment/valuation (VALMIN Code), will be used as a framework against which the illegal tampering with drilling samples to artificially boost their gold content (salting) from the Busang gold deposit (Kalimantan, Indonesia), owned by Bre-X Minerals Limited (Calgary, Canada), will be reviewed. While the Busang saga was based upon fraud, through salting the samples, the general lessons to learn from such a scam are worth documenting. In Australia, most of those working in the mineral industry belong to long established professional institutes and consultant associations (eg The AusIMM or Mineral Industry Consultants Association [MICA]) that require their members to work within their technical limits and to comply with best practice guidelines, or risk being judged and found wanting by their peers in the context of strong Ethics Codes. There is also a strong interface between such representative professional bodies and the corporate and financial market regulators (ASC/ASX), which closes the monitoring loop. Canada has only now seen the wisdom of having this type of early warning system in place. Fraud and deliberate deception will be always possible, but deception on the enormous scale that occurred at Busang is most unlikely with proper surveillance systems in place and the use of accredited technical professionals. There should have been more hard data available about so big and rich a deposit owned by a C$6Bn company.

Jan 1, 1997

By T Barnes, K D. Sexton, T J. Tope

For the past decade, the U.S. Department of Defense (DoD) has been under increasing pressure from state and federal regulatory authorities to develop management strategies for waste streams generated at its bases, installations, and ranges. Since passage of the Federal Facilities Compliance Act (FFCA) in 1992, concerns have focused in particular on military munitions and energetic waste streams.

Jan 1, 1997

By B. M. Loftus

An investigation into the use of impinging stream (jet) reactors for the leaching of a free milling ore produced an increase in gold recovery by 10% while decreasing leaching time by up to 90%.Tests on refractory ores demonstrate no apparent improvement in recovery. However, leaching kinetics are dramatically increased when these ores are subjected to jet reaction prior to agitation.

Jan 1, 1997

"AQUILA Mining Systems Ltd. is a Canadian company that designs and develops monitoring, control and navigation systems for the surface and underground mining industries. In 1992, AQUILA Mining Systems began the development of technology for monitoring, controlling and positioning mobile mining equipment. In 1993, AQUILA completed its first field test with GPS receivers onboard ablasthole drill, and thus demonstrated the viability and strategic relevance of this technology in surface mining. Since then, AQUILA has installed GPS-based technology on drills and shovels in several Canadian mines. This paper will review the development of these systems and discussthe benefits the mining industry could realise through their production implementation."

Jan 1, 1997

By R Simcock

Why Rehabilitate? Legislative Requirement Land rehabilitation is a condition of resource consents for mining. Clause 17 (1) of the Resource Management Act 1991 (duty to avoid, remedy, or mitigate adverse effects) provides the legislative basis for local authorities to impose resource consent conditions requiring land to be rehabilitated to approved uses during and after mining.

Jan 1, 1997

By Mark Rebagliati, John Payne, Jim Oliver

The Campo Morado precious-metal-bearing, volcanogenic massive sul?de deposits occurin a lower Cretaceous, bimodal, calc-alkaline volcanic sequence in a major northerly trending belt inthe Guerrero Terrane in northeastern Guerrero, Mexico. During upper Cretaceous to Early Tertiary greenschist-facies regional metamorphism, the rocks were deformed strongly into a northeast-verging fold-and-thrust belt. Three later stages of weak deformation were dominated, respectively, by kink folds, broad warps, and extensional faults. Most deposits occur in the upper part of a sequence of felsic ?ows and heterolithic volcanoclastic rocks or at its contact with overlying chert and argillite-sand-stone. The Reforma and El Rey massive sul?de deposits are on the overturned limb of a major, thrusted anticline, and the Naranjo and El Largo massive sul?de deposits are to the south on the upright limb of the same major fold. The La Lucha and San Rafael massive sul?de occurrences are in an upper plate to the southwest which was thrusted over the plate containing the Naranjo and El Largo deposits. In several of the deposits, Au, Ag, Zn, and Pb are concentrated near the stratigraphic top, andCu is concentrated near the stratigraphic base. Major minerals are pyrite, quartz, ankerite, sphalerite,chalcopyrite, and galena. Minor minerals are tennantite-freibergite, arsenopyrite, and pyrrhotite. Goldand Ag occur in argentian gold, and Ag also occurs in tennantite-freibergite. The cumulative inferred resource of massive sul?de for the Reforma, Naranjo, El Rey, and El Largo deposits exceeds 30 Mt, with the latter two deposits incompletely delineated. Underlying pyrite-quartz stockwork zones contain chalcopyrite, chlorite, and sphalerite. Hydrothermal alteration minerals in the stratigraphic foot-wall are pyrite, quartz, chlorite, ferroan dolomite, and ankerite. In the stratigraphic hangingwall, hydrothermal alteration minerals are sericite, calcite-dolomite, and lesser clay minerals and quartz. The deposits belong to a low-sul?dation, volcanogenic massive sul?de system formed in a subaqueous environment, and are of the bimodal, siliciclastic type.

Jan 1, 1997