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By Frame Ritzert, Dennis Keller, Vijay Vasudevan, David Arenas

"An investigation was conducted to describe topologically close packed (TCP) phase instability as' a function of composition in the advanced ·Ni-base superalloy Rene N6. TCP phases are detrimental to overfill high-temperature performance of Ni-base superalloys because of their brittle nature and because they deplete the Ni-rich matrix of potent solid solution strengthening elements. Thirty-four variations of polycrystalline .Rene N6 determined from a design-of-experiments approach were cast and homogenized at 13 l5°C for 80 hours followed by exposure at 1093°C for 400 hours to promote TCP formation. The alloys had the following composition ranges in atomic percent: cobalt 10.61 to 16.73, Mo 0.32 to 1.34%, W 1.85 to 2.52%, Re 1.80 to 2.11%, Ta 2.36 to 3.02%, Al 11.90 to 14.75%, and Cr 3.57 to 6.23%. Physical and chemical characteristics of all microstructures obtained were described using various analytical techniques. From these observations, a mathematical description of TCP occurrence (s and P phase) was generated for polycrystalline Rene N6.IntroductionNi-base superalloy single crystals represent the state-of-the-art for turbine engine airfoil application as they offer the best balance of properties to allow for the high operating temperatures required: for efficient engine operation.1 Current trends in alloy design take advantage of improved creep rupture strength with the addition .of higher levels of refractory elements. 2 In .particular, the addition of significantly higher levels of Re in third generation superalloys is key for both microstructural stability and creep rupture strength. 3 While the presence of the refractories is thought to provide strength benefits from solid solution hardening, a tendency for alloy instability in the form of topologically-close-packed (TCP) phases or secondary reaction· zone (SRZ) ·phenomena accompanies the high refractory content. 3 The formation of these phases in sufficient amount is detrimental to the overall high temperature performance of Ni-base superalloys because of their brittle nature and because they deplete the Ni-rich matrix of potent solid solution strengthening elements.4 The tendency for a particular composition to form TCP may not be immediately known since the precipitation of TCP phases in Ni-base superalloys is nucleation controlled, thereby requiring long times at elevated temperatures to precipitate. 5 They preferentially nucleate along the octahedral planes of the Ni-base superalloys, usually in areas of refractory metal enrichment at grain boundaries or inside dendrites.5-6 In Rene N6, two closely related TCP phases, a and P, have been observed.2"

Jan 1, 1998

The Mt Lyell Mine at Queenstown, Tasmania was re-opened in 1995 by Copper Mines of Tasmania Pty Ltd, a wholly owned subsidiary of Mt Lyell Mining Co Ltd. The re-opening followed over 100 years of copper and gold mining at Mt Lyell. Major changes in practice were implemented across the site. Preventing further damage to an already disturbed environment was a major priority. Sublevel caving, at a lower cut-off grade, replaced open stoping for the deep underground mining. Development and later stoping are handled by a contractor, National Mine Management Pty Ltd, in the largest underground contract awarded at the time. Large scale sublevel caving was new to Mt Lyell and not widely practised in Australia, requiring studies and systematic development of the method, particularly in drilling and blasting. Rehabilitation and upgrading of mine infrastructure have been and will continue to be a challenge. The mine has, since 1995, returned to being a stable producer with potential for growth.

Jan 1, 1998

By C. M. Jones

Cyprus Sierrita Corp. has developed a training program that has led to several significant improvements in safety performance and productivity. Truck productivity has increased 6% as measured by truck cycle times. Increased skill levels and awareness on the part of the mine's operators are due to the new training effort. Costs associated with productivity training have been about $185,300. This includes program development and execution costs, as well as lost productivity during the training itself. These costs are offset by $1.9 million in savings attributable to the increased skill levels of technicians due to the training effort. Cyprus Sierrita is a subsidiary of Cyprus Amax of Englewood, CO. The company operates a copper and molybdenum mining and processing facility south of Tucson, AZ, near the town of Green Valley. The Cyprus Sierrita operation produces about 109 kt/a (240 million lbs/ year) of copper, 11.3 kt/a (25 million lbs/year) of molybdenum, 31.1 t/a (1 million oz/year) of silver and 1.8 t/a (4,000 lbs/year) of rhenium. The opera¬tion employs 770 people at the site. About 200 of these employees work in the mine operations. Mining at Sierrita uses standard open-pit techniques. Crews of 43 people rotate on 12-hour shifts. Hourly technicians are nonunion and do not use rigid job classifications to define pay. Rather, the system is designed to pay employees for what they are able to do. Administering this effort requires that training opportunities are provided to those people who desire them. Successful training opportunities al¬low people to gain skills. The more skills an employee can demonstrate, the higher his or her "tech level." A technician's pay is commensurate with his or her tech level. Much of Sierrita's training in past years concentrated on building basic

Jan 1, 1998

By Malcolm J. A. Swallow

In June 1997, Mount Polley Mining Corp., a division of Imperial Metals Corp., completed an 18-kt/d (20,000 stpd) gold-copper mine in central British Columbia. Fast-track construction and extensive off-site construction were combined with an aggressive project schedule to build the mine in one year. This was three months ahead of schedule and 7% below the original budgeted cost of C$123.5 million (US$86 million). The Mount Polley Mine was the first of a crop of new open-pit mines in British Columbia. The Mount Polley deposit has been explored since the mid-1960s when it was known as the Cariboo Bell property. From 1988, Imperial Metals completed drilling and metallurgical testing on the deposit. This led to a positive feasibility study and the issuing of a Mine Development Certificate in 1991. The project was later shelved due to falling metals prices and the strength of the Canadian dollar. In late 1994, Imperial merged with Bethlehem Resources Corp., bringing a strong project team to the company. The deposit was then re-evaluated, ore reserves revised and additional metallurgical testing was performed. The result was a revised project plan. It indi¬cated that a financially feasible gold-copper mining op¬eration could be constructed at Mount Polley operat¬ing at 18 kt/d (20,000 stpd). In May 1996, an agreement was reached with Sumitomo to jointly fund and develop the project. By early 1996, final plans and permits were being prepared for construction, scheduled to begin in June 1.996. On-site work commenced on May 28th, 1996 following lifting of the road restrictions. Mount Polley Mining acted as its own project manager. Construction was completed in June 1997. Plant runup took place in July and full production began in August. Through the use of off-site construction and the careful selection of contractors who cooperated to complete some 12 major contracts, it was possible to reduce the mine and mill construction time from 16 to 13 months. Off-site construction for all possible aspects of the work and the use of used milling equipment allowed significant savings in overall capital costs of construction. Total costs for the mine, mill and tailings dam equated to C$6,100/t/d of throughput. The mill design incorporates several innovative features that will aid maintenance and allow flexibility of operation. The operation is designed as a closed system and meets the latest environmental standards. Concentrate is shipped by truck to the port of Vancouver. Revenues for the mine come from the mine's production of about 3.1 t/a (100,000 oz/year) of gold and 10.8 kt/a (24 million lbs/year) of copper during the first four years of the 12-year mine life.

Jan 1, 1998

By S. Mason

Many organizations are realizing that continual improvement in health and safety relies on addressing the potential for various forms of human error. Of these, violations are often the most frequent form associated with accidents. These occur when an individual, or individuals, deliberately contravenes established and known safety rules. They have been associated with up to 90% of accidents and incidents in some industries and yet rarely receive the systematic attention they deserve in the promotion of safety. This paper presents underlying motives which cause violations. These can vary significantly from mine to mine and from job to job. Managers need some measure of attitudes to determine the underlying motives behind violations if they are to determine effective strategies for promoting safe behaviour. Questionnaires form the starting point to address attitudes and the motives behind rule violations. The choice of the most suitable questionnaire, however, will vary from organization to organization. Guidelines on the choice of questionnaire are offered.

Jan 1, 1998

Drilling and blasting operations have historically been viewed as a necessary 'evil' part of mining, whose costs should be minimised by whatever means possible. In the past, when operations depended primarily on crushing and milling for ore re

Jan 1, 1998

By Kiyoshi Shibata

A new assessment model has been proposed for metal production and its recycling system. The model consists of three processes, smelting of ore, cascading and upgrading of metal scrap. The present approach is to assess the total energy consumption of the system, by introducing two equations for describing the relationships between critical impurity content and the mass of production or scrap recycling. The total energy consumption in the system can be described as a function of recycling rate and performance of the upgrading process. The present model suggests that the impurity removal efficiency and yield in the upgrading process are essential to reduce the energy consumption in the systems. Especially, such points should be explicitly controlled in recycling of aluminum. The potential capability of this model was also discussed by obtaining several quantitative information required for the process design and the operational control of beneficial recycling of metals.

Jan 1, 1998

By J. Gao, H. O. Gekonde, S. V. Subramanian

"The functional role of inclusions at low cutting speeds is to promote ductile fracture in chip formation process, whereas the role of inclusions at high cutting speeds is to prevent tool crater wear by suppressing the tribological phenomenon of seizure at the tool-chip interface. Glassy oxide inclusions are engineered into the workpiece to form a viscous layer in-situ at the tool-chip interface at high cutting speeds. The viscous layer lubricates the tool-chip interface to prevent the seizure. In comparison with the large volume fraction of inclusions needed for promoting ductile fracture at low cutting speeds, the amount of inclusions required for lubricating the toolchip interface at high cutting speeds is very small and is in the range that is typical of clean steels. The chip fracture process at high cutting speeds is aided by strain rate hardening of the matrix, which facilitates chip disposal of relatively clean steel.Inclusion engineering for high speed machining involves the control of the rheology and composition of inclusions to meet target viscosity at the tool-chip interface. The application of thermodynamic models in controlled production of inclusions in steels designed for high speed machining is discussed."

Jan 1, 1998

By H. H. Murray

Industrial usage of clays for current and new applications will continue to grow into the next century. The rate of growth will be highest in the less developed areas of the world. Transportation costs are a significant part of the delivered price, so the location of reserves and processing facilities for kaolin, bentonite, and palygorskite (attapulgite) are reviewed relative to serving these emerging markets. New value added applications will increase in the more developed areas which will require high quality raw materials, more sophisticated processing, and rigorous quality control.

Jan 1, 1998

MIM Holdings Limited (MIM) committed to a long-term future in copper in the Carpentaria Mineral Province in 1996 with the development of the Enterprise and Ernest Henry mines, and an upgrade of MIMsÆ copper smelter in Mount Isa, and copper refinery in Townsville. The upgrade of the copper smelter will enable the smelter to produce 250 000 tpa of copper with a single primary smelting unit, the copper Isasmelt furnace installed in 1992. The copper Isasmelt furnace currently smelts concentrate containing 145 000 tpa copper. To reduce the risk associated with the copper smelter upgrade, and shorten the ramp up time of the upgraded smelter, two high-rate trials were undertaken in 1997 to demonstrate that the copper Isasmelt furnace could, with an additional 525 tpd of tonnage oxygen, treat concentrates containing 250 000 tpa copper. During the trials the concentrate feed rate to the Isasmelt furnace was increased from its average rate of 100 tph of concentrate to 150 tph of concentrate. The increase in the capacity of the furnace was achieved by: supplementing the installed tonnage oxygen capacity of 595 tpd with an additional 300 tpd supply; reducing variability in the furnace feed rate from ¦25 per cent to less than ¦5 per cent; and reducing tramp air. The Isasmelt furnace smelted concentrate at a rate of 140 to 150 tph for four hours 25 minutes during Trial 1, and at a rate of 150 tph of concentrate for five hours and 30 minutes during Trial 2. The oxygen utilisation was 100 per cent during the trials with the process remaining under control. As a result of the development work for the trials the average treatment rate of the furnace under normal conditions increased by ten per cent.

Jan 1, 1998

By B. J. Madden

Over 206 million tons of hard coal were mined in South African collieries in 1996. Some 132.5 millions tons came from underground operations and approximately 120 million tons came from bord-and-pillar workings resulting in between 100 000 and 150 000pillars being formed. Coal pillar design remains a significant feature of South African mining. This paper reviews South African coal pillar design procedures in the light of 90 pillar collapses that have occurred since 1904. It shows that, while the current pillar strength formula is still valid within the original empirical range of Salamon1,cognisance must be taken of local conditions. Current South African coal pillar research is attempting to account for the variations in local conditions with the emphasis on the effect of discontinuities and pillar deterioration. It is suggested that a more holistic approach to pillar design be adopted to include a design methodology that examines the stability of the roof, pillar and floor of the underground workings. Using this approach, deviations from the empirical database used by Salamon and Munro will be incorporated into the design methodology resulting in more stable underground workings.

Jan 1, 1998

By Patrick Ph. D. Kennedy, Osvaldo A. Ph. D. Bascur

With the revolutionary progress in information and computer technologies, applying the latest information technologies in metallurgical complexes has become a serious challenge to both a major opportunity and a serious challenge to both management and technical teams. The emerging component and object technologies are changing the way everyone can beneficially use their computer and networks to add to their corporate bottom lines. Most mining and metallurgical plants use predictive maintenance policies based on statistical analysis and special techniques, like vibration analysis and oil and lube analysis for critical equipment. Process control strategies are installed in several metallurgical sites. All process equipment and control strategies require maintenance from local personnel at the mine. Integrated use of existing and emerging technologies is making it possible to implement an overall process effectiveness control index. This index is based on key indices such as losses due to plant availability, performance efficiency and rate of quality. The availability of real time and process history to identify the most critical part of the processing system from mechanical integrity is highlighted. An emerging plant integration paradigm is described to simplify the implementation of business enterprise resources management and distributed plant management systems.

Jan 1, 1998

By Nobumasa Kemori

Six kinds of copper '90ncentrates. were treated individually in a ,pilot scale. Outokumpu flsah smelting furnace ~n order to study their ?flash smelting behavior with respect to oxygen efficiency and dust generation. The copper concentrates tested were selected from the more than twenty sources which are treated at the Sumitomo Toyo copper smelter, so as to provide a wide range of chemical composition in terms .of Cu, S,Fe, Pb + Zn + As, and Si~ content. Oxygen efficiency 'and dust generation rates obtained in 'the experiments ranged from 80% ,to 108% and 11% to 20%, respectively. Relationships between these results and experhnental conditions such as chemical and mineral composition of the copper concentrates, flux ratio, fuel consumption and so on are also discussed quantitatively in this paper.

Jan 1, 1998

By Richard J. Haslinger, C. Mark Rebagliati, James L. Oliver

Abstract - Exploration at the Specogna gold deposit has identified a geological resource of 65.0 Mt grading 1.63 g/t Au, which equates to 3 million ounces of contained gold. This resource is hosted in a low-sulfidation epithermal deposit of Miocene age that is localized along the northwesterlytrending Sandspit fault. The fault has juxtaposed Late Cretaceous mudstone of the Haida Formation to the west, with Late Tertiary coarse clastic sediments and lesser andesitic volcanic rocks of the Skonun Formation to the east. A plagioclase porphyritic dacite dike intrudes the Haida mudstone and Skonun sediments along the fault. Gold mineralization, in hydrothermal breccias, veins and stockworks developed mainly in Skonun sediments and dacite. These are formed in an 800 m long zone that roughly parallels the Sandspit fault. The gold zone is funnel-shaped in cross-section, approximately 300 m wide at surface, 220 m above sea level, and narrows to approximately 50 m, at sea level. The deposit lies within an elongate zone of moderate to intense hydrothermal alteration that, at surface, extends over a known area of approximately 2 km2. Its western extent is bounded by the Sandspit fault. There is an asymmetric alteration zonation, with a core of silicic-potassic (adularia) and smectite-illite clay alteration that is bounded to the east by argillic alteration. Similar zoning defined by the distribution of metals reflects the position of the main feeder conduit. Mineralization of altered wallrock is dominated by 1% to 4% auriferous pyrite and marcasite. Gold and silver occur as electrum; individual silver minerals have not been identified. Other sulfides are rare, and are identified only microscopically. The mineral suite is typical of low-sulfidation epithermal systems. Gold occurs in early, multi-phase, variably bladed and banded quartz veins and breccias, which are cut by barren, single phase, drusy quartz veins.

Jan 1, 1998

By McQuade CV, Riley SJ

Acid mine drainage is an unavoidable consequence of some coal mining operations. Typically runoff pH is below 3.5 and at these pH levels heavy metals are mobilised. Leachate from coal reject dumps may require collection and treatment to raise the pH and precipitate the metals before being discharged.A bi-product of coal mining operations at Clarence Colliery is coarse washery reject. At present the coarse reject is deposited above ground and rehabilitated. Adjacent to Clarence Colliery is the Kable's Transport Pty Ltd sand mining operation. It has been proposed that co-disposal of the rejects from both operations may produce a product whose leachate has near neutral pH.

Jan 1, 1998

By Larry M. Southwick

Steel mill electric arc furnace dust is a RCRA listed hazardous waste and its treatment and/or disposal are regulated by a complex set of rules. These regulations were originally established to encourage recovery and recycling of valuable components. For EAF dust, the more valuable constituents include zinc, lead, cadmium and iron. In fact, current trends are in the opposite direction, as the regulations have complicated the ability to commercialize new treatment technologies and created substantial roadblocks and liabilities for processors. As a result, almost half of the EAF dust generated in 1997 will be landfilled. The problems are compounded by difficult processing requirements, less than sterling examples of technology development and mechanical and operating problems. This paper explores some options to simplify the processing requirements and thereby easing difficulties in commercializing new technologies and expediting the recycling of recovered metals. Dust processing usually includes a simple step followed by two complicated steps. The simple step is fuming of heavy metals away from iron and other residues. The complex steps are (1) separating and purifying the heavy metals and (2) upgrading the iron residue. The first complex step can be simplified by producing an intermediate product that is amenable to processing by zinc refiners. This route benefits from the currently underutilized (by dust processors) resource offered by refiners, who have experience in and existing processes for separation and purification of zinc-based heavy metals. Various processes and their associated product options are reviewed and compared. Future directions for dust processing developments are suggested.

Jan 1, 1998

By R D. Morri, D J. Alexander

The design and optimisation of mineral flotation circuits is currently performed using a combination of laboratory, pilot plant and full scale testing. Owing to the variable nature of flotation circuits and the complex nature of the flotation process, it is difficult to interpret the data collected from flotation testwork. JKSimFloat is a computer modelling package which is being developed to interpret flotation testwork data collected at the various stages of the mining cycle. The parameters derived from the program can be used to assess potential circuit configurations in both the design of new flotation circuits and in the refinement of existing operations. The aim of this paper is to outline the modelling methodology used in JKSimFloat and to outline how it can be used effectively to model data collected from either the laboratory, the pilot plant or the existing flotation circuit. The use of flotation model parameters in circuit evaluation will be demonstrated via the use of a case study based on data collected from ComincoÆs Red Dog lead flotation circuit.

Jan 1, 1998

By B Cronin, M Gao, M F. Young

Fine grinding technology has become extremely important for Mount Isa Mines Limited in the last decade for flowsheet development for the McArthur River deposit and in rejuvenating the Lead-Zinc Concentrator at Mount Isa. Regrinding products with 80 per cent passing seven microns and 12 microns were required, respectively, for the McArthur River ore and the Lead-Zinc Concentrator at Mount Isa. Development of the ISAMILL, a horizontal stirred mill with a gross mill volume of 4000 litres (a net volume of 3000 litres), has been successful in delivering the required grinding product sizes with an energy consumption acceptable to a mining operation. The ISAMILL performance for processing both lead and zinc streams at Mount Isa is discussed in this paper, including the milling energy efficiency, the media wear and the size-by-size recovery data for one flotation process following the fine regrinding stage. The potential use of the ISAMILL technology at various phases of the mining cycle is also discussed.

Jan 1, 1998

By Michel Boisvert

Noranda Metallurgy is presently completing construction of the new Noranda Converter (NCV) at its Home Smelter in Rouyn-Noranda. This capital investment of CDN$56M is the continuation of the Emissions and SO2 Reduction Program that was initiated in the late 1980s with the acid plant for Reactor off-gas treatment. The Patented Noranda Converter was developed and pilot tested at the Home Smelter in the early 1990s. The project will replace the Peirce-Smith Converters and enable sulphur fixation to be 'increased from 70% to over 90% by 2002 with an accompanying reduction of dust emissions to the atmosphere. The construction site is an extension of the present Noranda Reactor area. A number of existing facilities including the acid plant and process air supply were used to minimize the capital cost of the project. This paper provides a brief history of the Noranda converting process, the Home Smelter Emissions and SO2 Reduction Program, ,project implementation and construction, a description of the different facilities, and preparation of human resources for start-up.

Jan 1, 1998

By Garth James

Bacterial consortia capable of degrading cyanide and metal-cyanide complexes were obtained from gold mine process waters using enrichment cultures. The cultures contained either cyanide, tetracyanonickelate, or ferrocyanide as a sole nitrogen source. Several bacteria were isolated from the consortia, but none of these organisms were capable of degrading cyanide or cyanide-metal complexes at rates equivalent to those of the intact consortia. The consortium from the cyanide enrichment was capable of completely degrading cyanide from an initial concentration of over 100 ppm in less than one day, when cultured using a fed-batch method. Tetracyanonickelate and ferrocyanide were degraded more slowly. Overall, these results demonstrate that bacteria capable of degrading cyanide and cyanide-metal complexes can be isolated from mine process solutions and are capable of significantly reducing cyanide concentrations under appropriate conditions.

Jan 1, 1998