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By K. O. Fagerlund

Theoretically and experimentally determined copper matte settling rate in iron silicate slag has been discussed. Separation and settling rate measurements of sand, homogenised slag and 25%Cu concentrate, 63%Cu industrial, and 71%Cu synthetic copper mattes were carried out by mixing crushed slag and matte samples with silica sand in an alumina crucible and melting at 1300-1350°C. Two different types of slag compositions were employed, with Fe/SiO2-ratio 1.4 and 1.7. The separation rate was followed by taking samples from the .melt. As expected, the settling rate of copper matte in fayalite slag depended on the slag composition, where the increasing silica decreased the matte settling rate. Microanalysis of solidified slags showed that the rate of separation of low grade matte was low compared with high grade matte and the presence of a very small size fraction of matte droplets in slag remained unsettled in stagnant fluid. The production of sulfur dioxide gas inside the molten bath was found to be possible up to a certain iron sulfide content in the matte. Also, copper matte settling rates in industrial furnaces have been discussed.

Jan 1, 1999

By D. J. MacKinnon

"The Canadian Copper Company, formed in 1885, began mining the nickel-copper ores of Sudbury in 1887 and producing nickel-copper matte from its smelter in 1888(1). Although it was quickly appreciated that the separation of nickel and copper (i.e. refining) was critical to the production of a marketable nickel product, refined nickel was not produced in Canada until about 1918. From the beginning of the industry, there was considerable political agitation to refine nickel in the Province of Ontario(2). The companies, however, claimed that the existing processes, viz. the sodium sulphide ""tops and bottoms"" process operated by the Orford Copper Company of New Jersey, U.S.A.(1,3,4) and the carbonyl process(5,6) developed by the Mond Company at Clydach, Wales, were too costly to operate in Canada. Nickel was first refined in Ontario about 1918 when the International Nickel Company opened a nickel refinery at Port Colborne, Ontario(6). Initially, however, the refinery at Port Colborne employed the Orford sodium sulphide process, and the first electrorefined nickel in Canada was produced in 1920 by the British America Nickel Corporation whose mine and smelter were located in Sudbury, Ontario, but whose electrorefinery was located at Deschenes, Quebec, near Ottawa, Ontario. The purpose of this article is to outline the early history of nickel electrorefining and to trace the significant developments which led to the first successful commercial electrolytic nickel refinery in Canada. The development of an electrolytic process for refining nickel is due largely to the efforts of four individuals, viz. Carl Hoepfner, Hans A. Frasch, D.H. Browne and ultimately N.V. Hybinette, and the contribution of each is discussed separately below."

Jan 1, 1999

By David A. Newman

Severe roof control problems have plagued a West Virginia underground mine since its initial development in the late 1970's. Adverse roof conditions in the Eastern portion of the reserve result from a combination of mining: - perpendicular to the major principal horizontal stress direction, - near lineament intersections, - in areas where the ratio of horizontal stress to vertical stress exceeds 2.00 to 4.00, and - where laminated strata are present in the immediate roof. The focus of this study is to identify the engineering (mine orientation, roof safety factor) and geological parameters (lineament and horizontal stress orientation, horizontal to vertical stress ratio, and immediate roof lithology) causing poor roof conditions and to quantify their influence on projected mining conditions in the Western portion of the reserve Rose diagrams were used to illustrate the correlation between the orientation of eight hundred thirty-six (836) roof falls with that of forty-four (44) lineaments and the principal horizontal stress Similarly a composite map was used to demonstrate the relationship between roof falls and the ratio of horizontal stress to vertical stress The immediate roof strata across the property were categorized as either laminated or non-laminated based upon a thorough examination of one hundred sixty-two core logs. The presence or absence of fireclay, a rider coal, and carbonaceous shale was also noted because of the historic correlation with poor roof conditions. Rock strength and physical property tests were conducted on selected immediate roof strata recovered from coreholes drilled along the mains projected to the Western portion of the reserve Potential roof control problems in the Western reserve were quantified based upon the correlations developed by analyzing engineering and geological data The main conclusion is that laminated roof strata, the rider seam, and its associated fireclay will have the greatest influence on mining conditions. Roof problems attributable to horizontal stresses will not be as severe in the West due to an increase in overburden depth and corresponding decrease in the stress ratio. Recommendations are provided for mining orientation, the layout of mains and submains, panel location, and roof support based on intended service life.

Jan 1, 1999

By Jonathan J. Owen

We will describe modifications to air-sparged hydrocyclones (ASH) that enhance collisions and reaction of wastewater contaminants with sparged gas. These new ASH-based reaction chambers are combined with flotation tanks that are designed to optimize separation of bubbles and particles from water. In combination, these systems have achieved unprecedented removal of contaminants from industrial wastewater and process water while requiring smaller footprints with lower capital and operating costs. Real-world examples of chemical and nonchemical water treatments that demonstrate the outstanding flexibility and applicability of these systems are shown. Design enhancements that resolve the operational problems of traditional ASH are discussed.

Jan 1, 1999

By A. J. Stewart, M. Guay, J. W. Critchfield, A. P. Hoddeson

The MetroWest Water Supply Tunnel project includes three main work shafts, excavated primarily in rock. Shaft L is 9.8 m (32 ft) diameter and 124.1 m (407 ft)deep. Shaft E is 7.0 by 12.8 m (23 by 42 ft) and 91.4 m (300 ft) deep. Shaft 5A is 7.9m (26 ft) diameter and 72.5 m (238 ft) deep. Construction methods are compared and contrasted. Lessons learned involve a differing site condition in soil overburden, contractor-proposed modifications, and remedial slurry wall work. Other aspects discussed include noise and vibration control, groundwater inflow, water treatment, muck handling and contract administration issues.

Jan 1, 1999

By Baron Miya, Keith Hanks, William Edgerton, Francis Fong

The City of Los Angeles capital improvement program includes the construction of a new 35-km interceptor sewer. This sewer will be built as a deep tunnel with finished diameters ranging from 2- to- 4 meters. The project will be constructed concurrently in two phases; an 18-km East-West and a 17-km North-South segment. The new sewer provides additional conveyance capacity for an existing deteriorating sewer that is scheduled for rehabilitation. Large sewage spills during the El Niño storms of 1998 resulted in a Cease and Desist Order that established an aggressive schedule for the completion of the project.

Jan 1, 1999

By A. H. Castillejos E., F. A. Acosta G.

Filtration is widely used as a terminal refining step for metals, particularly for the casting of aluminum alloys, but still more knowledge is required to understand how several factors affect the efficiency of removal of inclusions. In this study, both, initial and long term filtration efficiencies of a ceramic foam filter have been obtained from the computed trajectories of solid particles suspended in molten aluminum. The complex structure of the foam filters is represented by a unit cell which is formed by a pair of pores with average dimensions. The fluid flow field was determined from the numerical solution of the Navier-Stokes equation, and periodic fully developed flow was assumed at the inlet of the calculation domain, as a boundary condition. This flow field corresponds to laminar flow as that found in ceramic filters operating under normal conditions. Computed initial filtration efficiencies showed that filtration efficiency decreases sharply with fluid velocity for particles larger than 30 µm, but smaller particles are better trapped at higher fluid velocities. Finally, it was found that long term filtration efficiency for particles of 8 µm decreased with time, in spite that perfect particle-wall attachment was assumed. Filter aging was considered in this study, and it was found that the distorted flow field, around the already trapped small inclusions prevented further collection.

Jan 1, 1999

By Don Bachman, Larry Heywood

Artificial release of snow avalanches, through the use of explosives, is a necessary component of safety planning and operations for ski areas throughout the Western United States, as well as in other alpine regions of the world. Climatic, meteorological and terrain factors leading to the development of avalanche conditions, in addition to release mechanisms and magnitude of the avalanche problem to ski areas will be discussed.

Jan 1, 1999

By Jerry Wallace

A highway bridge demolition project to allow shipping access to a new container port in Puget Sound ran into trouble when contract-stipulated mechanical means of demolition failed. Blasting was then employed under less than ideal conditions and was successful.

Jan 1, 1999

By D J. Corp

The Halmahera Contract of Work is a sixth generation contract held 82.5 per cent by Newcrest Mining Limited and 17.5 per cent by PT Aneka Tambang and takes in the Gosowong Project area. In 1991 Newcrest Mining Limited established a small exploration office in Jakarta and proceeded to seek exploration opportunities. The Halmahera area was identified as a substantial prospective ground position in a relatively unexplored area. In late-1991 Newcrest Mining Limited and PT Aneka Tambang agreed to explore in Halmahera. Initial field work commenced in July 1992. A vigorous ground reconnaissance programme led to the discovery of the Gosowong deposit a little over 12 months later in September 1993. In April 1997 the Contract of Work was approved covering much of the island of Halmahera. Between September 1997 and November 1998 activities were directed principally towards obtaining the necessary permits required to commence construction activities. Some particularly ambitious targets were set for achieving this outcome. An aggressive construction programme commenced in late-1998. Construction took place during a period of unseasonally high rainfall, which in itself presented additional challenges to the construction team. A key milestone for the project was achieved on 1 July 1999 when wet commissioning of the process plant commenced. Construction of the Gosowong Mine was achieved on time and within budget. A period of some six years elapsed from the initial discovery of the Gosowong deposit to the time of the first gold pour. Much of the permitting, construction and commissioning activity took place between September 1997 and July 1999. This coincided with a period of significant social, economic and political upheaval in Indonesia. During the construction period a high level of importance was placed on the structured recruitment and training of local people, as well as fostering appropriate community and local business development programmes in the communities nearby the project. Emphasis was also placed on environmental management with detailed long-term planning and progressive rehabilitation commencing during the construction phase. The permitting and subsequent development of the Gosowong Project has demonstrated that even during the difficult times, with commitment, it is possible for mining and exploration companies to conduct business in Indonesia.

Jan 1, 1999

By K Thorpe

Amorphous silica deposits have been identified at Tikitere and Taheke near Rotorua. Two areas at Tikitere have been surface sampled and drilled to establish a resource of amorphous silica in excess of one million tonnes. A pilot plant was established to develop a process to manufacture a high quality super pozzolanic material. This development process took two years before a commercial product was introduced to the construction industry in 1996. The amorphous silica product, marketed as Microsilica 600, is used as a pozzolanic material to produce high quality strong and durable concrete, sprayed tunnel linings, mortars and grouts. Microsilica 600 has been used locally and exported to 11 countries.

Jan 1, 1999

This is an abstract from Environmental Service and Technology (Vol 32 No 20 1998) which will be o finterest to South African Mining and Metallurgical Scientists, involved in chromium mining and Metallurgical processing. Maybe the scourge of our dams and reservoirs?the water hyacinth can be put to good use! The novel technology of phytoremediation embraces plant accumulation processes for the cleanup of toxic heavy metals and organic chemicals. Several plant species have been identified that are excellent hyperaccumulators of a number of heavy metals, e.g., Brassica juncea (Indian mustard) and Thlaspe caerulescens (Alpine pennycress). Other speciesincluding Myriophyllum brasiliense(Parrot?s feather), Salixsp. (willow), and Popullussp. (poplar) have also demonstrated phytoremediating abilities.

Jan 1, 1999

By Chengliang Jliang, B. K. Parek, Xuxin Shao

Of the impurities present in phosphate ore, dolomite is the most difficult to remove due to the similar chemical compositions of the impurities and also adsorption of dissolved species of dolomite onto phosphate. A new amphoteric surfactant was found to be a suitable collector for separation of dolomite from phosphate. Flotation results showed that the new amphoteric collector had a high flotation selectivity for dolomite in wide pH ranges. The flotation study of francolite and dolomite in each other's supernatant demonstrated that the dissolved ions had little effect on the selectivity of the new collector, but were detrimental to the flotation separation using sodium oleate as collector. A phosphate concentrate with 35.2% P2O5 with 90% recovery was obtained using 290 g/t of the amphoteric collector from a mixture of francolite and dolomite containing 26.2% P2O5. The rejection of MgO was 81.41%.

Jan 1, 1999

By Arthur G. Hunt

Smelting using the direct-to-blister process commenced at Olympic Dam on 31 July 1988. The unique nature of the Olympic Dam ore body led to the selection of the direct to blister smelting process. Significant improvement in the design of the furnace and the understanding of the fundamentals of the process and its operation has occurred in the 10 years of operation. The paper will discuss the operation of the #1 Smelter and the design, preparation for start up and early operating experience of the #2 Smelter.

Jan 1, 1999

By D R. Swinbourne, T Lehner

Study of the distribution of minor elements between copper matte andfayalite slag is important in determining appropriate methods tomaximise the recovery of valuable metals and the rejection of harmfulelements. Boliden Mineral AB operate a large copper smelter in northern Sweden, where they had noted that the loss of silver to the slag in the settling furnace appeared to be a direct function of the tin content of the slag. This work was aimed at determining whether or not this was a cause-and-effect relationship. Copper matte containing approximately 50 wt per cent copper and small amounts of silver and tin was equilibrated with silica-saturated fayalite slag at 1250¦C, then quenched. The matte and slag were then analysed for their silver and tin contents. It was found that there was no relationship between the silver distribution and the tin distribution. The silver matte/slag distribution ratio had a value of 120 ¦ 40 while that for tin was 2.8 ¦ 0.3. It is suggested that the most likely cause of the relationship observed at the Boliden smelter was matte entrainment in the slag.

Jan 1, 1999

By P. E. Donaldson

Since 1992, Falconbridge has made available to the international copper industry, Kidd Creek's licensed refinery process technology under the name of the Kidd Process. This has resulted in the supply and installation of permanent cathodes and associated product handling equipment to refineries in Canada, the United States, South Korea, Chile and Mexico. These installations accommodate both electrorefining and electrowinning processes. The growth and industrial acceptance of the Kidd Process has generated technical advancements in the areas of product random sampling, corrugation, marking, labeling, product tracking and data acquisition. In a different area, the expanded development of custom materials processing at Kidd created a need to advance technologically. The process-related problem of high nickel concentrations in refinery electrolyte compromised an increase in current density to >300 A/m2. The need for nickel removal resulted in Kidd Creek's newly developed Nickel Recovery System. The effective and economical extraction of nickel, along with reduced antimony and bismuth levels, reduces bleed stream volumes and/or neutralization costs and simultaneously produces a marketable nickel carbonate product.

Jan 1, 1999

To design an apparatus that advances the state of the art in gas content testing equipment. The goal of the design is to incorporate improvements in testing sensitivity/accuracy, durability, and ease of operation over existing equipment. It is also desirable for the new design to successfully perform gas content determinations of multiple chemical species from a rock sample.

Jan 1, 1999

By D Vrkljan, Z Ester

Excavating the building pit for the World Trade Center at Rijeka, it was necessary to blast over 160000 m3 of hard mass in fused condition. The building pit is located at a densely populated residential part of the main Croatian port Rijeka, close to the railway-track and traffic routes of the town. The permanent seismic monitoring points are foreseen on endangered housing and infrastructure facilities around the pit during designing and excavation of it. The seismic monitoring has been performed on 15 permanent points by occasion of over a hundred production and continuous blasting operations. The article considers the speeds of ground oscillations depending on applied maximum quantities of explosive charge according to fire degree, total quantities of explosives at the mine-field, structure of explosive charge, applied delay of mine boring and lines initiation mode and rock mass structure

Jan 1, 1999

By Gabriel Voicu, Marc Bardoux, Ross Stevenson, Nuno Machado, Jean Lafrance

"Abstract - Paleoproterozoic gold is found in two different volcano-sedimentary sequences and intrusive bodies separated by 600 km within the Guiana Shield. The 2148 Ma St-Élie granite intruded volcanic-arc sequences of the Paramaca Group, whereas the 2096 Ma Omai stock penetrated backarc/ island-arc sequences of the Barama-Mazaruni Group. Positive ?Nd values suggest that both suites lack Archean crustal contaminants, which is consistent with an origin in an oceanic arc setting.The St-Élie deposit is characterized by quartz-dominant vein systems with minor metallic minerals, represented chiefly by pyrrhotite and pyrite. Biotite, calcite, and chlorite are the main gangue minerals. The alteration haloes at St-Élie feature a strong potassic zone, which is absent at Omai. The ore-controlling structures are ductile and the vein emplacement is related mainly to contemporaneous, high-angle ductile shear zones. The St-Élie deposit formed at temperatures >350°C. The stable isotopes values are compatible with a magmatic or metamorphic source.The Omai deposit is characterized by quartz-dominant vein systems with minor metallic minerals, represented mainly by pyrite. Ankerite, scheelite, albite, and chlorite are common gangue minerals. The vein emplacement is syn- to post-deformation and it is related mainly to brittle shear zones with low-angle, stockwork networks and breccia zones. The Omai deposit formed in a temperature range between 250°C and 170°C, much lower than the St-Élie deposit. The stable isotope values are compatible with mixing between deep-seated fluids of metamorphic or magmatic origin with surface- derived fluids.These differences between St-Élie and Omai are interpreted in terms of their depth of formation. Alteration patterns, structural elements, and paragenetic assemblages indicate that the gold at St-Élie was most probably emplaced at a mesozonal depth, whereas the Omai setting yields evidence for epizonal conditions."

Jan 1, 1999

By P K. Smith, R J. Ryan, W R. H Ramsay, D C. Arne, F P. Bierlein

Turbidite-hosted, mesothermal lode gold deposits in Paleozoic metasedimentary rocks of the Buller Terrane, western South Island have a similar geological history and genesis to the Paleozoic lode gold deposits ofVictoria, Australia and Nova Scotia, Canada. In all three regions the gold deposits are hosted by interbedded meta-sandstone and meta-argillite that have been folded and regionally metamorphosed to greenschist facies, and locally in Nova Scotia to amphibolite facies. The gold deposits are typically narrow, structurally controlled quartz veins associated with dilatant zones in reverse faults or fold-related fractures. The principal vein types include: bedding parallel or concordant veins, discordant veins, saddle reefs, and stockwork veins. En-echelon and "ac" type veins are sometimes also gold-bearing in Nova Scotia. The contrasting competency of the host meta-argillite and meta-sandstone beds is an important factor in vein formation, particularly for the bedding parallel veins, which are typically developed within meta-argillite beds or along the contacts between meta-argillite and meta-sandstone. Veins found within meta-sandstone units are generally discordant. The deposits in Victoria are well known for their bedding-parallel veins, saddle reefs ( Bendigo ) and leather jacket reefs (Ballarat). Bedding-parallel veins are also common in Nova Scotia , along with a few examples of saddle reefs. In contrast, vein formation probably occurred later in the deformation history of the Reefton and Lyell goldfields, with most veins being bedding discordant and more typically aligned with the axial plane cleavage of the folds rather than bedding planes. The quartz lodes in one deposit, Globe-Progress, strike approximately perpendicular to the bedding and fold axes. No saddle reefs have been recorded from the Buller Terrane. Mesothermal vein morphology reflects the amount of fmite strain, the strain rate, competency contrasts, lithotypes, and the confirming pressures to which the system was exposed. On the basis of comparable depositional depths and rheologies of the host rocks, a controlling factor influencing the development of different vein styles (and timing) might be finite strain, as exemplified by the tightness of folding in the host rocks. Folding appears to be tighter in the Victorian rocks than in either the Buller Terrane or Nova Scotian rocks.

Jan 1, 1999