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By W. M. Williams

The Canadian steel industry is now in many ways a mature one, having achieved many technical successes during its hundred-year history. It is interesting to look back over this period, to learn something of the histories of the different producers and of the people and forces that shaped their development. The following article provides a thumbnail sketch of the Canadian steel industry as it exists today. It is intended for the general reader, not for the specialist who will want to consult the several books and theses written on the development of the industry during the last hundred years. The famous Les Forges du Saint-Maurice, an important iron producer for a century and a half, provides a natural historical starting point for a look at the four major players - Dosco, Algoma, Stelco and Dofasco - who have provided most of the hundreds of millions of tonnes of steel, in every form from horseshoes to tinplate, needed in the twentieth century. The smaller companies which have sprung up in the last 20 or 30 years are dealt with briefly - but only because their history is so recent. Not so long ago the mini-mill, based on scrap rather than on the blast furnace, was thought to be specially suited to the economies of the smaller developing countries of the Third World. However, recent history has made it evident that the small plant, specializing in a few basic products (e.g. reinforcing bar) or taking advantage of special circumstances, can successfully compete with the large blast furnace/primary steel producers.

Jan 1, 1999

By Celeste Powell

Liquid carbon dioxide can be used as a replacement for organic solvents in the extraction of anionic PGM complexes from an aqueous phase. This can be achieved only if highly carbon dioxide-soluble chelating agents are developed because conventional chelating agent-metal complexes, such as trioctylamine-gold chloride, are not soluble in liquid carbon dioxide (although trioctylamine is CO,-soluble). Our novel CO,-soluble chelating agents have a fluorinated tail and a conventional amine head group. Both the chelating agent and the chelating agent-metal complex are soluble at ambient temperature at pressures between 7-35 MPa. Equilibrium constants in the 105 range have been measured (in Freon 113, a low pressure screening liquid for carbon dioxide), indicating that these compounds will strongly bind the metal chloride. For example, 93% of Pt-chloride was extracted into Freon 113 using a 3.5:1I ratio of a double-tailed fluoroalkyl amine chelating:metal chloride. 88% recovery of Pt-chloride into liquid carbon dioxide was achieved using the same chelating agent at a 3.5:1 ratio.

Jan 1, 1999

By J. K. S. Tee

Using a novel method, zinc has been selectively removed from galvanized steel scrap on a laboratory scale. The separation is based on thermodynamic principles: during chlorination in air-chlorine (10:l) mixtures at 800 OC, zinc forms a volatile product (zinc chloride) while iron does not chlorinate as its oxides are more stable than the respective chlorides. As much as 92 % of zinc is removed from the surface of steel within 10 minutes. This process overcomes tedious and costly preparatory stages associated with leaching - electrowinning methods.

Jan 1, 1999

By B. Erdem, N. Çelebi

An important problem associated with tandem dragline systems is that of matching the productive capability of individual draglines in the combination. In this paper, a dependence mechanism among draglines in a tandem system is described, and possible consequential problems in a poorly-matched system are defined. The rate of linear advance and the cost of stripping are determined as two major indications for an efficient operation. The proposed decision criteria and the underlying mechanism to select a synchronous couple are introduced and used in simulating tandem dragline systems. The developed model is tested on a hypothetical strip mine where pullback stripping is applied with a tandem dragline system.

Jan 1, 1999

By A G. Cuison, B V. Andam

Three well-known copper and gold deposits in northern Luzon, Philippines are located in the Mankayan Mineral District. These are the Lepanto Copper-Gold Deposit, the Far Southeast Porphyry Copper Deposit and the newly discovered Victoria Gold Deposit. The latter discovery led LCMC to shift from a predominantly copper mine to a gold mine. The pre-Eocene Lepanto basement andesite and the middle Miocene Balili volcaniclastic sequence underlie the Mankayan Mineral District. They are intruded by tonalitic to gabbroic Bagon Intrusive followed by diorite-quartz diorite intrusions. Diatreme emplacement of late Miocene-early Pliocene Imbanguila dacite pyroclastics and porphyries took place much later. Faults in the district mostly form a conjugate fracture pattern dominated by north and northwest trending shears, east-west trending extensional fractures and few north-south trending fissures. Victoria is an epithermal gold-base metal rich quartz vein deposit. The veins occur along tensional structures and it is common to observe crustiform and banded features among the sulphides and gangue minerals. It is an open space infilling type of mineralisation. The Victoria vein systems are divided into zones based on continuity. In each zone are major veins and associated spits. Dacite pyroclastics and porphyries predominantly host the major veins with a few narrow veins hosted by the Balili volcaniclastics and the Lepanto metavolcanics. The veins generally trend east-northeast with 75 - 80 dips towards the south. The longest vein can be traced fairly continuously for a horizontal distance of about 600 metres. The vertical persistence of major veins exposed on three level drives has a range of 150 metres and can reach as much as 400 metres based on drill hole intercepts. The vein widths vary from two to eight metres. Right lateral movements of either the NW or NE shear faults could have produced the east trending tensional fractures. The development of ore shoot patterns was recognised and has been helpful to the mining operations. Cymoid loops with defined pinch and swell features are noted both laterally and vertically. Complementing the structural pattern is the distribution of gold values along veins where lateral and vertical continuity is also observed. Gold is associated with quartz, sphalerite, galena and chalcopyrite. In relatively high gold zones, the abundant sulphides are sphalerite and galena. In relatively high copper zones, there is an abundance of chalcopyrite and tetrahedrite. Galena is always associated with sphalerite but less in abundance. Chalcopyrite occurs either as separate bands from or associated with sphalerite-galena. Chalcopyrite and tetrahedrite appears contemporaneous with sphalerite and galena but in some portions the former cuts the latter sulphides. The predominant gangue minerals are quartz, carbonates and gypsum. Rhodochrosite is the predominant carbonate gangue. Few sulphides are found in the carbonates. Gypsum (anhydrite) is found cross-cutting early mineralisation. It carries very few sulphides. The alteration halos around veins are relatively narrow. In an outward sequence, the silicic alteration occurs very near the veins, followed by sericitic-argillic alteration then to propylitic zones. It is also common to observe veins bounded by propylitic alteration. Preliminary paragenetic studies show apparent three stages of mineralisation, the early-quartz (-gold) stage followed by a carbonate stage and a late-gypsum stage. The abundance of base metals relatively decreases towards the gypsum stage. The Victoria gold deposit could have some genetic associations with the Lepanto Cu-Au deposit and probably indirectly with the FSE porphyry system. It is relatively apparent that the Victoria quartz-gold-base metal veins could have occurred similarly as the quartz-gold roots overprinting the Lepanto enargite mineralisation. This overprinting signifies the waning stages of the entire hydrothermal system.

Jan 1, 1999

By E. B. Freidina

We have investigated a new electrochemical process for preparing lead-calcium alloys. Calcium metal, reduced fiom a molten chloride mixture, forms an alloy with liquid lead cathode. The addition of calcium carbonate to conventional CaC12-NaCl electrolyte enables us to avoid chlorine production on the anode and replace it with oxygen and carbon dioxide. The ternary system CaClz-NaC1-CaCO3 has a range of melt compositions, where the electrolysis can be held below 650°C. In order to prevent the side reaction of carbon deposition on the cathode we have separated the anolyte from the catholyte with alumina diaphragm. The factors, which affect the level of impurities and the current efficiency of the process, are discussed.

Jan 1, 1999

By B. A. Kjarsgaard, C. J. Mwenifumbo

"Abstract - Natural gamma-ray measurements were made in the GSC Smeaton drillhole as part of the borehole geophysical classification of kimberlite pipe 169. In addition, forty samples of Cretaceous sediments (shales, siltstones, and sandstones) and thirty-five kimberlite samples, selected from the drill core, were analyzed for major and trace elements. These elements included potassium (K), uranium (U), and thorium (Th), which are the main naturally-occurring radioactive elements.Different phases of the kimberlite, and the Cretaceous sediments which show variations in the gamma-ray activity, can be easily delineated on the gamma-ray logs. The gamma-ray logs indicate that the radioactivity in the kimberlite derives mainly from Th, and, to a lesser extent, U. Most of the kimberlite units are enriched in Th and U relative to the Cretaceous sediments, and these radioelements are mainly hosted by accessory apatite and perovskite, and minor zircon. Potassium concentrations are low in the kimberlite. The higher K concentration in the sediments clearly distinguishes the Cretaceous sediments from the kimberlite.The U/K and Th/K ratios show important and distinct differences between the two major types of volcaniclastic kimberlite. Kimberlite lapillistones have higher U/K and Th/K ratios than the olivine crystal tuffs. Furthermore, standardized U/K and Th/K geophysical logs can be used to separate marine reworked olivine shoreface sands from other shallow marine sediments that contain kimberlitic detritus. The identification of different phases and/or stratigraphic facies of kimberlite on the basis of radioelement distributions means that gamma-ray spectrometry can assist exploration, particularly in regard to diamond grade distribution."

Jan 1, 1999

By Dimitrios Fillippou

Magnesium hydroxide is used in a number of industrial applications, from the neutralisation of acid effluents to the production of pharmaceuticals. High-quality magnesium hydroxide powders can be produced by hydrating slow-reacting magnesia in dilute magnesium acetate solutions. The process of magnesia hydration shows many similarities with a typical hydrometallurgical leaching operation; however, its kinetics are crucial not only for process design and control, but also for the production of powders with a desirable particle morphology. This article shows the results of an experimental work whereby industrial heavily-burned magnesia powders were hydrated in 0.01 to 0.1 mol/L magnesium acetate solutions at temperatures ranging between 333 and 363 K. Examination of the magnesium hydroxide produced and the analysis of the kinetic data suggest that the hydration of heavily-burned magnesia in magnesium acetate solutions is a dissolution-precipitation process controlled by the dissolution of magnesia particles. The activation energy was estimated to be 60 kJ/mol, while the reaction order with respect to magnesium acetate concentration was found to be about one.

Jan 1, 1999

The Yanacocha district hosts the largest and most significant acid-sulphate, high-sulphidation deposits in Per· with total production, reserves and resources of over 27 million ounces of gold. Several other smaller high-sulphidation systems are also recognised in the Cajamarca region including La Zanja, Sipßn, Tantahuatay, and San Nicolas. These each have reserves/resources of between 640 000 and 800 000 ounces of gold. Gold deposits in the Yanacocha district are hosted in an extensive volcanic field. Flow domes have intruded precursor pyroclastic rocks and flows that are interpreted as part of an earlier intermediate multi-vent volcanic complex. The larger, contiguous Yanacocha Norte - Sur and Encajon gold deposits are spatially associated with late-stage diatreme breccias. At La Zanja extensive acid-sulphate alteration is associated with the margins of the small San Pedro caldera (6 +4.5 km), nested within the larger, less well-defined La Zanja caldera (19 +24 km). The inner caldera is resurgent with abundant magmatism expressed as several flow dome complexes located on the caldera rim, and shallow level intrusive stocks. Gold mineralisation is associated with a WNW-trending structural corridor that transects the southern margin of the San Pedro caldera. On the eastern side of the La Zanja caldera there are a series of younger andesitic eruptive centres, some associated with acid-sulphate alteration and gold mineralisation. The Sipßn deposit occurs in one such centre with structurally-controlled gold associated with a NE-trending silicified structure developed within a sequence of andesitic tuffs. In conclusion, although a number of high-sulphidation deposits are recognised in northern Per·, their settings and styles of mineralisation are all quite different. Smaller deposits generally have strong and obvious structural controls. In the larger Yanacocha deposits the structural controls are less obvious, and mineralisation is disseminated in porous or strongly fractured and brecciated silica. Erosional levels are probably a significant factor, with disseminated mineralisation at higher levels, and structurally-controlled mineralisation in more deeply eroded deposits.

Jan 1, 1999

By C. Flores

The direct cementation of copper from a loaded D2EHPA 20 % vol. in kerosene using zinc, zinc-lead alloy and iron metallic powders was studied. Copper was loaded into the organic solvent from an aqueous copper sulfate solution. Results indicated that copper is reduced spontaneously with relatively fast reaction rates. The effects of several operating parameters such as water content in the organic system, initial copper concentration, reductant surface area, oxygen and nitrogen atmosphere, intensity of the agitation and temperature on the galvanic stripping of copper were studied. For a better understanding of the electrochemical reactions involved in the galvanic stripping, the dissolution of metallic copper in the organic solvent was also studied. Copper did not dissolve unless a small amount of water was present in the organic system. The results and possible reaction mechanisms are discussed.

Jan 1, 1999

By Edgar Urbaez

Production scheduling is one of the most important factors affecting mine planning. A program -Mine Scheduler -that aids mining engineers with the setup of an optimum open pit production scheduling algorithm has been developed. A mathematical model for open pit scheduling that optimizes the Net Present Value of the cash flows was formulated. A simulated data is formulated as a Mixed Integer Linear Programming (MILP) problem. What's Best by Lindo Systems is used as the MILP solver in Microsoft Excel. The implementation of the algorithm focuses on problem setup, allowing users to easily evaluate, simplify, and develop the model that best fits their production scheduling.

Jan 1, 1999

Kudremukh Iron Ore Company Ltd, a wholly owned Government of India Enterprise, was established in the year 1976 to develop mine and plant facilities to produce 7.5 Mtpa of high-grade iron ore concentrate at Kudremukh. The mine and plant facilities were commissioned in 1980. In view of high demand for iron oxide pellets in iron and steel industry worldwide and as a diversification activity, a pelletisation plant of 3.0 Mtpa capacity was commissioned in the year 1987 at Mangalore for production of high-quality blast furnace and direct reduction grade pellets for export. The pellet plant capacity has been increased to 3.5 Mtpa by technological improvement which included installation of roll press for quality and productivity improvement. In addition, the pellet capacity is being increased to 4 Mtpa by the addition of Shaft Pelletising Furnace plant.

Jan 1, 1999

By Rita Michael

"The Marmara Ironworks was not the earliest ironworks in Ontario, but it was distinguished from other early works in a number of ways. It was established on an ambitious scale as a self-sufficient and, for the time, sophisticated community. In effect it was an iron plantation on the scale and scope of those at Hopewell, Pennsylvania and Saugus, Massachusetts(1). It was, besides, the only one of the few early ironworks in Upper Canada which operated almost to the end of the nineteenth century, albeit in fits and starts, and which used magnetic ores rather than bog iron ores (limonite). Furthermore it is the only works which has produced archaeological interest over a number of years. The ironworks is on the east bank of the Crowe River near Highway 7, on Lots 7 and 8, Concession 4, Marmara Township, Hastings County, Ontario. It is the property of the Village of Marmara, and the extant remains encompass about 2. 5 acres of the original 2000 or so which made up the original grant. The mineral riches of the Canadian Shield had been known since the days of the Jesuit missionary-explorers. A consortium headed by Alexander Henry and the Duke of Gloucester planned to exploit the copper near Sault Ste. Marie during the last part of the eighteenth century, but nothing came of the venture(2). This attempt may have grown out of Lord Dorchester's suggestion that private enterprise be encouraged in order that the iron ore which ""abounds"" in Canada might be exploited(3). John Graves Simcoe, the first Lieutenant Governor of Upper Canada was also anxious to see iron working develop. Simcoe was eager to encourage many enterprises, among which ""the development of iron mines""(4) - Governor Gore had been approached by John Mason for help with his ironworks in Norfolk County (5). Three Americans had applied for permission and support to erect an ironworks on the Gananoque River at the falls to become known as Furnace Falls. They were granted 1000 acres of land in fee simple to encourage their endeavor(6). Sir Peregrine Maitland, only a few months after taking up his duties as Lieutenant Governor in 1818, intended to visit the ""bed of iron ore on the Crow River"" (7) - Maitland was to provide a good deal of support, both moral and substantive, to Charles Hayes when he came to Canada in 1820."

Jan 1, 1999

Raw materials account for over 60 per cent of the cost of hot metal production in classical blast furnaces and the principal cost component is cost of coke. Dependence on coke is a traditional weakness of blast furnace ironmaking and while efforts have been made to evolve alternative ironmaking technologies which do not use coke, such as direct reduction, smelting reduction, and the more recent method of making iron carbide, blast furnaces continue to be the most efficient means of producing bulk hot metal even today. Coal injection, to the extent of 150 - 200 kg/t of hot metal, has been one of the major innovations made in blast furnaces to decrease cost and to reduce the dependence on coke. This has, however, given rise to more stringent coke property requirements (which often means more expensive coke) - a `tail spin' of Sorts!

Jan 1, 1999

By Mayfield P. L J, Honeyands T. A

BHP's two million tonne per annum nominal capacity Hot Briquetted Iron (HBI) plant at Port Hedland in the Pilbara region of Western Australia is based on FINMET¦¦ direct reduction technology. The FINMET¦¦ process produces direct reduced iron (DRI) by reacting fine iron ore with reformed natural gas in a series of fluid bed reactors and then hot briquetting this DRI into dense, high quality iron briquettes. The Port Hedland HBI project represents a major investment in the chemical processing of Australian minerals to higher value products prior to export to Asian markets. This paper describes the FINMET" process and technical aspects of the high-quality HBI product, and provides an update of the current status of the project.

Jan 1, 1999

The rush for alternate iron-units in the last few years spurred a true outbreak of new alternate iron units projects many of them incorporating new process in what can be classified as the.most fruitful and innovative technology outburst, in the steel industry, in decades In a recent paper we focused on what would be, in our opinion, the ultimate targets of the use of alternate iron-units by mini-mills: 1. to improve quality, 2. to reduce cost, 3. to increase plant productivity, and 4. to improve `supplyability'. With these objectives in mind liquid hot-metal, among all possible scrap substitutes, has been proven to be by far the best. This conclusion stems from many different authors who have reviewed the `value in use' of hot-metal against other alternate iron units and measured its impact on steel-shop productivity and cost (Figure 1).

Jan 1, 1999

By W. G. Davenport

A survey of world copper refining tankhouse .practices has been carried out. This paper compiles the results and examines changes in operating practices .since the similar 1987, 1991 and 1995 surveys. Continuing trends are the installation of ISA Process and Kidd Process stainless steel cathode technology, polymer concrete cells, anode preparation machines and automatic cranes. Instrumentation and automatic control are increasing, particularly for addition agent optimization; solvent extraction .and ion exchange techniques are being increasingly applied for electrolyte purification. The overall consequences of these changes have been 'improved cathode purities and enhanced tankhouse productivities.

Jan 1, 1999

By Fritz J. Klingler

From site demolition, to design, to construction, Detroit's new Tiger Stadium project is required to be completed within a short 2 ½ years from award of the design-build contract. Such extreme schedule requirements together with somewhat difficult ground conditions at the site, resulted in several challenges in the design and construction of the deep foundation system for the stadium. During the geotechnical investigation, an intermittent water bearing sand layer was encountered overlying the hardpan at the site. As a result, some concern developed regarding the potential for collapse of caisson bells within this layer, as well as the potential for flooding of the caissons during drilling. Although sand and/or ground water was encountered within about half of the caissons, standard drilling and belling methods were used, and adverse conditions were controlled in almost all cases through expeditious drilling, inspection and concreting of the caissons. This paper will present a summary of the ground conditions, design and specification requirements, and construction methods used to successfully install the caissons for this project.

Jan 1, 1999

By Ken Mills

Dartbrook Mine (Australia) works the Wynn seam, which has a moderate propensity for spontaneous combustion. Prior to any mining a commitment was made to place a segregation barrier pillar between longwall blocks 4 and 5. This was to segregate goaves and improve management controls in the event of a spontaneous combustion event within previous longwall goaves. An alternative to the segregation barrier known as a Consolidated Barrier was developed; firstly as a concept, then computer modelled and finally field tested. It consists of a wider than normal chain pillar with concrete Mega-Seals placed in cut-throughs. Permeability and stress measurements were conducted in the surrounding coal of the seal. Remote monitoring took place as the longwall face approached and then passed by the seal. Results indicate that as the longwall retreats past the seal, horizontal stress increases. The additional stress leads to an increase in confinement and a subsequent reduction in permeability.

Jan 1, 1999

By Gary Brendel

India produces about 70 Mt/a (77million stpy) of coal ash (fly ash and bottom ash) from burning about 200 Mt/a (220 million stpy) of coal for electric power generation. The average ash content is 35%. In contrast, the United States produces about 70 Mt/a (77 million stpy) of coal ash from burning 800 Mt/a (880million stpy) of coal for power generation. Its average ash content is less than 10%. In 1998, GAI Consultants Inc.(GAI) embarked on a federally funded, multiyear project to assist the government of India in solving its growing coal-ash management problem.

Jan 1, 1999