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By Tadashi Aiura, Yasuhiro Miura

"A small amount(0.2mass%) of Scandium(Sc) was added to the 7.NOl and 5083 Al alloys as a refiner and stabilizer of microstructure, and the resulting microstructures were discussed in comparison with the effects of the conventional additives. The followings are summarized: 1) in the as-solidified structure, a ·decreased tendency of constitutional supercooling and increased solubility of Mg were recognized for the Sc-added 5083 alloy. Sc is a -better microstructure refiner for the 7N01 alloy than Zr, in a sense that it does not suppress the favorable effect of· coexisting Ti. 2) Sc effectively suppresses recrystallization both in the 5083 and 7N01 alloys. 3) The rod like primary Al3Sc crystals formed during solidification, as well as the fine dispersion of Al3Sc precipitates formed by subsequent heat treatment, can act as a strong recrystallization suppresser. IntroductionThe 7N01 and 5083 alloys are the most popular industrial Al alloys and they are widely' used for various structures because of their superior properties. Fine macro and micro structures of the materials are required for obtaining acceptable sec resistance,consistent appearance of anodized surface and good weldability, as well as good mechanical properties. In order to produce fine grain structures, transition metals, such as Cr, Zr, and Mn, have been conventionally added.It has been reported that Sc is an efficient refiner [l, 2] and can be an alternative for the conventional and also suppresses recrystallization in Al alloys [3,4]. Scandium is the lightest transition element and forms an equilibrium intermetallic phase. The equilibrium phase, Ll2-Al3Sc, is coherent with the matrix, and of _spherical shape. A fine dispersion of the spherical precipitates is obtained by quenching and aging after solutionizing annealing. The authors have already reported a part of the experimental results on the effect of Sc on the as homogenized microstructure of the 5083 alloy [5]. In the present study, the effects of Sc on the macro and micro structures of the industrial high strength Al alloys(7N01 and 5083) for extrusion are investigated, and the superior role of Sc as a grain refiner is shown"

Jan 1, 2000

By A. E. Dabbagh

Saudi Arabia’s mineral potential offers development target that compliment the national effort to diversify the income of this oil and gas economic based nation. Ma’aden, a joint stock company with paid-up capital of US$1 billion, has from its inception in 1997, actively developed in-house engineering and management skills to transform the Arabian shield’s mineral potential into such real projects. Gold mine operating facilities of 100,000 oz/yr underground and 50,000 oz/yr open pit are de-scribed, as well as 3 targets, two of which are underdevelopment; Al Hajar (3,000 tpd at 2.5 gpt Au)and Al Amar (5,000 tpd at 20 gpt Au). Emphasis is also on exploitation of phosphate rock and down-stream fertilizer products, based on the Kingdom’s107,000 sq. km. northern basin geological reserve. Al Jalamid, the prime target, represents 216 million tonnes of these P2O5 reserves. Saudis and expatriates, together, lead international engineering companies and contractors operating and developing these facilities.

Jan 1, 2000

By J. J. Gusek

Passive treatment of mine drainage using constructed wetlands has been employed on coal and metal mine sites since about 1985. The technology has advanced significantly since then; there are currently over 600 of these systems treating coal mine drainage in the Eastern U.S. at flow rates of hundreds of liters per minute. Passive treatment performance at three metal mines discussed in this paper has been positive for a wide variety of flows, water chemistry, and climates. The sites include a high-altitude underground copper mine, acidic seepage from a gold heap leach pad, and pumped effluent from an active underground lead mine in Missouri.

Jan 1, 2000

By C. Restarick, R. G. Robins, R. M. Taylor, I. Ennis

Lime addition to acid mine drainage waters (AMD), possibly accompanied by aeration, has been the basis for their remediation by precipitation of predominantly metal hydroxides. An efficient novel alternative technique causes precipitation of double M(II)-M(III) hydroxy sulfates which readily precipitate and are easily dewatered. When the Fe(II)/Fe(III) + Al(III) ratio of the AMD is appropriate, the Green Precipitate (GP) Process provides a more effective alternative to normal liming/aeration. The process can be adapted to give a continuous in-line treatment by the choice of suitable computer-controlled reactors designed to improve the liming efficiency, reduce scaling and control the rate of treatment. The processes are described in terms of the chemistry involved.

Jan 1, 2000

By Charles Deacon

The mining industry is constantly taking greater cognisance of their operating costs as a strategy to counter the effects of falling commodity prices. As a result, optimal operating efficiency is more important than ever. One such operation is that of blasting. Considering the relative increasing costs of explosives and accessories it is desirable to optimise the number of blast-holes fired by maximising their individual output. This achievement may now only be possible following the advent of higher technologies in the form of modified explosives and electronic detonators. This paper reviews and introduces some techniques of blast monitoring, types of operations where each is most suited, resulting modifications to blast designs, and identifies some pitfalls to watch out for when analysing the results.

Jan 1, 2000

By G. J. Koons, J. L. Uhrie

Field density studies carried out at the Phelps Dodge Chino Mine have found that truck-induced compaction is limited to the upper 2.4 meters (8 feet) of an individual lift. Hydraulic properties of material compacted to field densities were determined in a laboratory setting and saturated flow models were then run, simulating the effect of compacted zones within a stockpile. Modeling shows that compaction can effectively prevent solution flow through large portions of the stockpile, implying that great care must be taken to ensure that ripping is carried out to a full depth of at least 2.4 meters (8 feet) across the entire stockpile to achieve uniform solution flow. Uniform solution flow will result in maximum leach recovery.

Jan 1, 2000

By W. J. Nokleberg, B. A. Bouley, T. K. Bundtzen

Central Alaska contains a wide variety of pre-, syn-, and post -accretionary mineral deposits that are related to the growth and evolution of the north-west North American continental margin. Withinpre-accretionary terranes, the Devonian-Carboniferous, carbonate platform-hosted MVT zinc-lead deposits of the Kandik and Reef Ridge districts in central Alaska, and the Devonian-Mississippian volcanogenic massive sulfide (VMS) polymetallic deposits of the Bonnifield, and Delta mineral belts of eastern Interior Alaska have received the most exploration interest to date. Syn-accretionary rift related, mafic and ultramafic sill swarms and zoned plutons of the Kluane-Nikolai igneous belt are currently being explored for Ni-Cu-Co-PGE deposits. Syn-accretionary granitoid complexes in the PurcellMountains, Illinois Creek, and Sitylemenkat areas have been explored for uranium-REE-gold, and tin-silver mineralization respectivelyPost-accretionary granitoid intrusions and associated volcanic fields that range in age from mid-Cretaceous to early Tertiary contain significant gold-silver-polymetallic resources in the East Central Alaska, Hogatza, and Kuskokwim Mineral belts. Collectively the three main post-accretionary plutonic/volcanic belts of central Alaska are part of the Tintina Gold Province, where exploration since 1990has identified about 848 tonnes gold.

Jan 1, 2000

By M. G. Lipsett

"Mining properties are becoming increasingly remote, a challenging situation for operating and maintaining equipment. Logistics of transporting workers and materials can be alleviated by having timely, accurate information of equipment location and operating condition, and by automating some activities. This paper discusses an infrastructure for remote operations, with strategies for communicating different types of data, and a design method so that systems can interact with either an operator or another system. A remotely operated excavator prototype is described, with on-board performance and diagnostic monitoring systems now used on production equipment. IntroductionSyncrude Canada Ltd. operates an openpit oil sands mine near Fort McMurray, Alberta. For twenty years, draglines and bucketwheel reclaimers have fed conveyors that transport dry oil sand to an extraction and upgrading plant. In converting to a truck and shovel operation, Syncrude has developed slurry pipelines and bitumen froth pumping to allow more remote leases to be mined more than 30 km from the base plant.There are organizational and resourcing challenges in operating and maintaining equipment in three nearby, but separate, mines. The logistics of transporting workers and materials to production and support equipment become more difficult, and operations and maintenance personnel and facilities become more distributed. Supervising mine operations will rely even more on having timely, accurate information about equipment location and operational status.Syncrude is typical of an open-pit operation. Voice communications are the preferred way to exchange information for making immediate decisions about operations and maintenance. A large number of narrowband FM broadcast radio channels keep teams of miners working together. Haul truck drivers, shovel operators, and dispatchers talk on one channel while maintainers coordinate activities with the control tower on another. Cellular phones have become popular for supervisors who have to talk with planners and engineers in offices without radios."

Jan 1, 2000

By Shigehito Deki

"A new wet process has been developed for the synthesis of various kinds of oxide thin films on various kinds of substrates, even which have complex surface morphology, from aqueous solution. The process was named as the LPD, Liquid Phase Deposition, method, which has some advantages over the conventional dry processes. This process can be applied to an on-site synthesis of advanced materials in the thin film technology. In this paper, some current topics on the synthesis of the composite thin oxide films by the LPD method, are presented.IntroductionGenerally, metal oxide thin films have been made by different preparative processes such as r.f. sputtering, chemical vapor depositon, CVD, laser ablation and sol-gel method, etc [1-3]. Each method has it own advantages and disadvantage. In some cases, the process is not suitable for the preparation of thin film on substrate with large surface area or complex surface morphology, and makes the deposition apparatus complicated and expenisve. By using Liquid Phase Deposition, LPD, method which overcomes some of those problems, metal oxide or hydroxide thin film can be formed on the substrate with large surface area and complex surface morphology, which are immersed into the aqueous solution only at ambient temperature and under atmosphere without any special equipments and high energy. And also, multicomponent oxide thin films can be formed readily by mixing solutions containing the objective metal ions, because it is performed in the aqueous solution which is typically a homogeneous mixing system. This process utilizes ligand-exchange, hydrolysis, equlibrium reaction of metal-fluoro complex species, MF x (x-2n>-, and F consumptive reaction. In the aqueous solution, MFx<x-2n>-is hydrolyzed with water to release F ions by a ligand exchange equilibrium reaction as following;"

Jan 1, 2000

By Martin J. Kenwright

Within the famous Harrods department store, a new lift shaft has been constructed, servicing a depth of 22m below ground level as well as the existing 6 storeys of the store. The shaft will connect with a new goods tunnel which is to be excavated beneath the shop, as well as new floor space above ground level which has resulted from the infilling of a previously existing lightwell within the store. The construction of the deep shaft while maintaining uninterrupted use of the store by the Client led to a number of innovative solutions being undertaken. Empirical assessments were made of settlements anticipated from the construction process, which took place within a congested environment of existing foundations. Various elements were designed and installed to mitigate the effects of the inevitable ground movement on the surrounding overlying structure, which supported sensitive high quality finishes and mechanical and electrical installations. The reinforced concrete lining of the shaft was contained within a cofferdam of minipiles. The minipile placement accuracy (1 in 150) was vital as it could not interfere with the subsequent tunnelling works. As the scheme progressed this became even more critical since the minipiles were needed as support for parts of the permanent works. This paper describes:- the high quality placement and control of the minipiled cofferdam, the methods employed in assessing ground movements and the techniques used to mitigate against the effects of these movements.

Jan 1, 2000

By H. Sis, S. Chander

The pressure filtration behaviors of dispersed and flocculated alumnae slurries at high percent solids were investigated with the objective of determining the effect of surfactant type and concentration on slurry properties. A high-purity alumina powder was used as a model solid. Dispersion of the alumina was controlled by pH and by surfactants that are known to act as electric and steric stabilizers. The effects of both ionic and nonionic sutfactants were investigated. Surface charge measurements of the slurries were carried out by an electrokinetic sonic amplitude (ESA) method to better understand the mechanisms. The effect of surfactant type and concentration on the kinetics of pressure filtration and cake properties are discussed.

Jan 1, 2000

By A. E. Lewis

The emphasis of this paper is on the characterization and testing of the slag produced by a secondary lead refinery. This work forms part of a broader investigation aimed at reducing loss of valuable product from the process as well as minimizing the environmental impact of the process wastes. It was this work that led to a critical examination of the standard waste classification tests. Characterization of the slag was carried out using a number of complementary techniques. In the broader context, the slag characterization aided in identifying process deficiencies and thus was a critical tool in suggesting potential for process optimization. For this study, the slag characterization provided a relatively comprehensive picture of the composition and properties of the slag, which facilitated understanding the behaviour of the slag under batch test conditions. On the basis of quantity of hazardous components alone, the slag is hazardous according to South African Acceptable Risk Limits (ARL). However, when both the quantity and the leach potential of the hazardous components is taken into account, standard waste tests carried out by three independent agencies indicate that the slag should not be classified as hazardous according to local regulations. Also, according to United States Environmental Protection Agency (US EPA) limits, which are independent of the quantity of the waste, the slag would not be classified as hazardous. The standard waste tests used by the independent agencies was the Toxicity Characteristic Leach Procedure (TCLP), a test which was developed by the US EPA to classify hazardous wastes. One of the requirements of this batch test is that it should be quick, simple to carry out and that the results should be reproducible. Previously, the applicability of the TCLP test to mineral processing and metallurgical wastes has been challenged on a number of points. Additional testing of the slag was carried out using both the TCLP and the Synthetic Precipitation Leach Procedure (SPLP) recommended by the American National Mining Association as being more appropriate for mineral processing wastes. The particular physical and chemical characteristics of the secondary lead slag highlighted additional limitations of both the TCLP and SPLP tests as standard laboratory batch procedures. Keywords: environmental protection, secondary lead processing, slag, leach testing, TCLP, SPLP, ARL, hazardous waste, batch tests

Jan 1, 2000

By A. T. Iannacchione

From 1990 to 1996, 16 states reported 92 injuries from falls of roof, rib or face in the more than 90 underground stone mines in the United States (Fig.1). Missouri, Pennsylvania and Kentucky accounted for 48% of the total number of injuries (Fig. 2). Of this total, 11 miners were killed. Of the 11 fatalities, 10, or 91%, were associated with unrecognized loose or failed rock within the roof beam. Additionally, unrecognized roof beam failures resulted in a majority of the falls of ground injuries occurring in underground US stone mines from1990 to 1996. This number is not large in magnitude. But a workforce of fewer than 2,000 miners makes for a high fatal-accident rate. The severity of the typical fall-of-ground injury is, in general, very high. About three-fifths of all roof, face and rib fall injuries were designated by the US Mine Safety and Health Administration (MSHA) as some kind of lost time accident. MSHA assigns each accident a severity value from one to six. A one represents a fatality, a two, a permanent disability and three, a lost time accident (Fig. 3).

Jan 1, 2000

By K. Hanumantha Rao, K. S. E. Forssberg, H. R. Manouchehri

This paper summarizes the practical considerations of the various electrical separation methods used in mineral processing. The effective factors related to mineral characteristics and equipment attributes are described and analyzed with reference to conventional industrial applications of the electrical methods. Some new aspects of electrical methods application and their potential for mineral beneficiation, apart from the mineral systems that have been successfully beneficiated, are also presented. In addition, wet dielectric separation, which now appears to be promising, is briefly cited.

Jan 1, 2000

By P. A. Treasure

The EMEW® cell has been developed to overcome a number of inherent limitations in conventional electrowinning technology, particularly the high cost and restricted process windows characteristic of conventional hardware. The technology has been widely demonstrated to achieve high performance for various metals under chemical conditions well outside the limits required for efficient operation of conventional cells. This process flexibility offers significant opportunities for cost savings. in recovery of zinc from primary and secondary sources. The EMEW® technology is now available on a fully engineered basis, as a versatile commercial alternative to conventional electrowinning hardware. Application of the EMEW® cell for recovery of secondary zinc material offers significant advantages to the recycling industry. For example, a selective caustic leach can be used where there are high levels of iron or other contaminants in the target material. The reagent requirement is minimal as most of the caustic is regenerated in the bell and zinc dust that may be required for electrolyte purification is produced in the cell. A high purity zinc powder or cathode is produced in the cell. In the case of acidic zinc electrolytes, the cell is capable of operating over a much wider range of operating conditions than a conventional cell.

Jan 1, 2000

By R. B. Rao, B. Das, J. K. Mohanty, D. S. Rao

Physical, mineralogical and geochemical characterization, along with some beneficiation approach to pre-concentrate the Ni content of the chromite overburden material of the Sukinda Valley, India, have been carried out in detail. Mineralogically, the overburden consists of geothite, quartz, hematite, magnetite and secondary silicates in varying proportions. A specific Ni mineral phase is absent in this material with the Ni and Fe being mostly enriched in finer fractions. Distribution of Ni and Fe in various size fractions and increase of Ni with increase in Fe (goethite content) indicate that goethite is the major Ni-bearing mineral phase. Quantitative estimation of goethite from chemical analysis and weight loss data indicates that the goethite quantity varies from 40% to 90%. Electron microprobe analysis (EPMA) indicates that Nirich and Ni-poor goethite are present in the overburden material. A sequential dissolution study indicates that more than 50% of the Ni are present within the goethite lattice as a lattice substitution. The results of pre-concentration studies (size classification, gravity, flotation and magnetic separation) indicate that Ni is richer in finer fractions. Further, the enrichment of Ni content is limited to 1.1% with 50% recovery by classification followed by hydrocyclone separation of the below 53 m m fraction.

Jan 1, 2000

By Philomene Verlaan

This study examines the possible relationships between compositional variability in non-hydrothermal manganese nodules and large-scale environmental parameters. In the central SW Pacific (145-180° W and 20-O° S) the level of primary productivity, the rates and proportions of carbonate, silica and organic matter supply to the sediments, and the position of the seafloor relative to the Calcium Carbonate Compensation Depth (CCD) appear to directly influence nodule composition. Four zones of nodule composition are apparent. These zones correlate fairly well with the level of primary productivity in surface waters, as estimated by satellite-based measurement of chlorophyll content. The observed correlations between surface productivity and nodule composition are consistent with the contention that the dominant source of several transition metals in these deposits (i.e , Mn, Ni, Cu. and Zn) is provided by removal of fine-grained particulate matter from the water column by biological means. Subsequent decay of organic matter in sediments augments the content of these metals in the nodules through oxic and sub-oxic diagenesis. The opposite behavior of Fe and Co content may in part result from mineralogical and dilution effects.

Jan 1, 2000

By Z. Zhang, R. G. Reddy

The viscosities of industrial lead slags with various compositions were measured as a function of temperature. It was found that viscosities of lead slags decreased with increasing temperature, and the plots of ln(11) vs. 104tr followed a linear relation over the reported ranges of temperature. Using the data of this study and available other related data from the literature, a viscosity expression was developed as a function of composition and temperature. The calculated results using this viscosity expression are in good agreement with the measured data. The composition dependency of viscosity of lead slags is discussed.

Jan 1, 2000

By David R. Beadman

This paper discusses how modern techniques of design and construction were used to create the deep stations for the Copenhagen Metro. The deep stations are located in small squares within the city adjacent to many old and sensitive buildings. The architectural design provides a large open atrium to allow natural light to reach the column free platforms to give the citizens of Copenhagen a feeling of safety and security and encourage them to use the Metro. The design and construction contract was undertaken using the relatively new and untried Eurocodes. The resulting stations set new standards of design for underground metros and have pushed forward the frontiers of what is appropriate construction practice to protect the existing and enhance the future environment.

Jan 1, 2000

By Charles Pol Vuillier

Piling work for modification to the Charles Grimes Bridge in Melbourne, Australia required piles to be installed through 15 to 20 m thickness of very soft to soft silty clay overlying 10 m of stiff clays and sands in turn overlying siltstone. The presence of an old sewer founded at depth in the soft clays demanded that vibrations be kept to a minimum. Two pile type were used by Vibro-pile (Australia) to provide the client with the most economical piling price. The two pile types were CFA piles of 750mm diameter founded in the weathered rock and a full displacement concrete injected screw pile developed by Vibro-pile called the "Z" pile, founded on the rock. The development and features of the "Z" pile are briefly discussed, including the perceived applications and advantages of the pile type. On board instrumentation comprising a computer was used to monitor all aspects of the construction. The rig instrumentation provided an important quality control measure that gave confidence in the pile installed. Pile performance was proved on the cast in situ piles by dynamic load testing methods. Initially tests performed with a 120 kN drop hammer, which was not capable of mobilising the required loads. The performance was then satisfactorily proved by using a drop hammer of 20 tonne mass delivering blows drop heights of 1.5m. Low strain integrity tests on a number of piles were also used to confirm the structural integrity of the piles.

Jan 1, 2000