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By Lyn Jones, Mike Bratty, Rick Lawrence, David Kratochvil

"The treatment of water is required at many mining operations to remove metals and prevent the discharge of contaminated water to the environment. In other cases, water treatment is used to provide better quality water for recycle to the processing plant, or to process bleed streams in hydrometallurgical operations in order to prevent deterioration in metallurgical performance or process equipment. BioteQ Environmental Technologies Inc. has developed and commercialized the BioSulphide® Process which can provide an alternative for these treatment needs and which can also be used for profitable metal recovery, particularly in cases where conventional metal winning techniques are not economical. The BioSulphide® Process is a high rate anaerobic biotechnology for on-site production of H2S from sulphur species, although for smaller flows and metal loadings, the use of chemical sulphide reagent might be more cost effective. Both new projects and existing commercial operations, used for removal and/or recovery of copper, nickel, and zinc, and which range in sulphide generating capacity from 50 kg/day to 3.7 tonnes/day, are discussed. Particular focus is placed on the results of operations at the Raglan Mine in Northern Quebec where dissolved nickel is removed from contaminated water at a high efficiency through the precipitation of nickel sulphide. Plant effluent is discharged directly to the receiving environment and the high-grade nickel sulphide product is combined with the nickel flotation concentrate produced at the mine. The plant at Raglan will replace the existing conventional water treatment plant and will eliminate the need for on-site storage of treatment plant sludge.INTRODUCTIONThe BioSulphide® Process, which produces low cost H2S for use in selective metal precipitation, offers a low capital cost alternative which can operate efficiently and cost-effectively within a wide range of flows and solution grades. Since the technology can be used to recover metals from solutions with low flows and metal grades, the technology is also applicable to environmental applications for water treatment, with the sale of recovered metals providing an offset to treatment costs. For environmental control, the technology has a distinct advantage in being able to meet strict effluent discharge criteria due to the very low solubility of metal sulphides. To date, BioteQ Environmental Technologies has designed and constructed three plants for metal sulphide precipitation, with another three projects in the advanced development stage."

Jan 1, 2006

Accurate geometric models of orebodies establish the framework for reliable mineral resource estimates that provide a basis for further exploration and mine planning, as well as for financial models that ultimately determine the economic viability of a deposit. Traditional, explicit geometric modelling techniques that are utilised for resource modelling by the general mining software packages, such as MineSight«, involve manually digitising interpreted ore outlines that must be carefully linked to create valid geometric solid models. An alternative, implicit modelling method, employed by LeapfrogTM software relies on a fast method of global interpolation, which offers several advantages over traditional modelling techniques. Although previous case studies have documented the relative efficiencies of the two approaches, the accuracy of the two methods has not been previously quantified and compared. This study quantifies the accuracy of solid models created using explicit and implicit methods, and compares the differences between the models. Solid models of the Doris Hinge vein gold deposit (located in the Hope Bay district, Nunavut, Canada) are constructed from preliminary and follow-up drilling data using both modelling techniques. The accuracies of the solid models generated using preliminary drilling data are determined by measuring the 3D distance between the surface of the models and the actual contact location defined by the follow-up drilling data. Additional comparisons based on volume, cross-sectional area and surface differences were made between both phase 1 solid models and solid models constructed from phase 2 drilling information. The overall results of this study find that the MineSight« and LeapfrogTM solid model accuracies are virtually the same, and that their volume, cross-sectional area, and surface differences are comparable. This study concludes that the implicit modelling technique generates accurate solid models that can be used in place of explicit models as ore shells for resource estimation in certain circumstances.

Jan 1, 2006

By Z. Trojanová

Mg micropowders generated by gas atomisation of a magnesium melt with argon were mixed and ball milled with ceramic nanoparticles prepared by laser-induced gas phase reaction. The materials were then hot extruded. Specimens were deformed in tensile as well as compression tests at temperatures between 20 and 300 °C at a constant initial strain rate. The flow stress is significantly influenced by the test temperature. The yield stress decreases with temperature. This decrease and the flat character of the stressstrain curves at elevated temperatures indicate possible contributions of softening processes. The materials studied exhibit high-damping characteristics. The results are analysed and possible mechanisms are discussed.

Jan 1, 2006

By A. C. Neiva

An energy-dispersive x-ray fluorescence spectrometer was assembled with the aim of analysing alloys and corrosion products of artistic, ethnological and archaeological pieces. The spectrometer is semiportable and consists basically of an 60kV/1.5mA X-ray tube with W anode and a Si-drift X-ray detector with Peltier cooling, with no need of liquid nitrogen. It was used for the analysis of the alloys and occasional corrosion products of several metallic pre-Hispanic pieces of the Museum of Ethnology and Archaeology of the University of São Paulo. Special care was taken to account for the contribution of spurious radiation from both the Pb primary collimator and the Zr detector collimator. The main components of most alloys were Au, Ag and Cu, but Pb, Ca, Fe and other elements were also identified. The characterization of the alloys and corrosion products is important for the subsequent conservation of the collection.

Jan 1, 2006

By D. Seo, P. Au, X. Husang, D. Nagy

The production of single crystal (SX) turbine blades represents the current stateof- the-art in Ni-based superalloy design. With complex casting processes and alloy composition modifications, SX superalloys exhibit superior high temperature mechanical properties to their polycrystalline counterparts. Stresses and plastic deformation can occur in SX nickel-base superalloy engine components at various stages during their manufacture and use. For examples, stresses are created during initial solidification and also during solid state processing such as shot peening, grit blasting, blending, electrodischarge machining and welding. Stresses may also be created during service due to random events such as foreign object impacts. Subsequent exposure of SX to high temperatures during solution heat treatment and brazing repair can result in recrystallization which has been shown to be detrimental to both creep rupture strength and fatigue performance of the components. It is therefore the objective of this paper to understand the recrystallization behavior of two SX superalloys, PWA 1484 and 1483, subjected to pre-stressing and subsequent heat treatments.

Jan 1, 2006

By Robert Lee, Jeff Corace, Rob Cyr

Blasting in the heart of the historic Byward Market District of Canada’s capital, Ottawa, presents a unique set of challenges. The obvious difficulties arising on projects requiring blasting within 3 m (10 ft) of 125 year old buildings in various states of disrepair have been encountered and successfully dealt with countless times before. The complexities increase exponentially when tenuous property boundaries, unknown structural details, litigious histories and the need for encroachment agreements lead to individuals with competing interests all able to impact the same operation. Blasting on three projects in the Market was started in early 2005 after months of negotiation. Ultimately, the potential for the projects to proceed hinged on the ability to successfully disseminate blast data to the various stakeholders. As part of the agreements drawn up, property owners demanded immediate notification of the measured vibration levels with contract provisions including clauses such that any exceedance of the USBM criteria immediately triggered project shut down and complete blasting program redesign, and approval by all parties. With stakeholders located in various cities and, in some instances, on various continents, a conventional attended monitoring strategy would not satisfy the requirements. In response to the critical reporting need, Explotech Engineering Ltd. installed unattended monitoring stations around the sites, all incorporating wireless telemetry. After each blast, data was automatically transferred from the monitoring stations to a web-linked server via the wireless network, where it was immediately available to project stakeholders through a password protected website. The solution required a unique blend of data acquisition, telemetry, database, and security technologies, all married to produce a reliable system that was easy to maintain and use. While these types of systems were originally developed for use as permanent monitoring networks in operating mines and quarries, monitoring professionals are increasingly benefiting from the technology on temporary building projects that have typically been the realm of attended monitoring strategies. Globally, this has emerged as a solution to provide more timely access to data for stakeholders, and to minimize the legal exposure from multiple violations of vibration limits. As this trend is likely to continue, the regulated vibration control industry is likely to see a continued shift in technology development to leverage wireless networks and the Internet to continue to improve data transfer, archiving and distribution.

Jan 1, 2006

By Khaled Morsy

The studied mine extracts the Sewickley seam using room-and-pillar method. The overburden at study site ranges from 400 to 800 ft. Eight years earlier, the Pittsburgh seam was mined 80 ft underneath the Sewickley seam. Parts of the mains at the study site experienced problems of rib spalling associated with floor heave. Numerical modeling was used to explain the mechanism of ground control problems encountered at the mains of the upper seam. The modeling results show that the ground control problems encountered were caused by multiple seam interactions with the previously mined longwall panel of the lower seam. Based on the modeling results, a criterion to predict the probability of multiple seam interactions was proposed.

Jan 1, 2006

By Yong-Moo Cheong

When the zirconium pressure tube(PT) is in contact with the calandria tube(CT) in the pressurized heavy water reactor(PHWR), the temperature gradient between the inner and outer wall of the PT results in a thermal diffusion of hydrogen(deuterium) and hydride blisters are formed on the outer surface of the PT. Since Zr-2.5Nb pressure tubes have a high risk for the formation of blisters during their operation in a PHWR, there is a strong incentive to develop a method for the non-destructive detection of the blisters grown on the tube surfaces. However, because there is little mismatch in an acoustic impedance between the hydride blisters and zirconium matrix, it is not easy to distinguish the boundary between the blister and the zirconium matrix with the conventional ultrasonic methods. This study has focused on the development of an ultrasonic method to detect the hydride blisters formed on Zr-2.5Nb pressure tubes. Hydride blisters were grown on the outer surface of a Zr-2.5Nb pressure tube using a cold finger attached to steady state thermal diffusion equipment. Ultrasonic velocity ratio method as well as conventional ultrasonic parameters with an immersion technique was developed to detect small hydride blisters on the Zr-2.5Nb pressure tubes.

Jan 1, 2006

By H. Kotzé

Ticor SA began with a detailed feasibility study in 1995. The Hillendale mine (situated between Richards Bay and Empangeni) and mineral separation plant were approved in 2000. The smelter, just outside Empangeni, consists of two 36 MW DC arc furnaces that were commissioned in 2003. Experiences gained during the initial commissioning of the furnaces proved valuable in later commissioning work, as shown by the increase in ramp-up rates. The capacity of the plant is 250 kt/a TiO2slag and 145 kt/a of pig iron.

Jan 1, 2006

By V. C. Pandolfelli, L. Paulino, C. E. Zangiacomi

The continuous improvement in aluminum industry over the last years has increased metal output at lower cost. The potlining plays an important role in this regard due to high cost involved and more recently in its environmental aspects. In order to increase potlife and thus minimize the aluminum cash cost, a systemic approach is needed, through investigating the main cathode failure mechanisms by using a pot autopsy as a powerful tool, and then making the necessary chances to achieve extended potlife. In addition, preheating and pot start-up may also damage the cathode if not performed with an appropriate technique or even if the lining materials are not specified correctly, among other factors. All these aspects will be presented and discussed in this paper. Increased potlife, especially now that the current is reaching values up to 300kA, will allow aluminum plants to match their goals more efficiently at lower costs.

Jan 1, 2006

By F. Patisson

One of the major issues with multiparticle reactors is to handle their multiscale aspect. For modeling, it usually comes to coupling a reactor model (describing the phenomena at the macroscopic scale) with a so-called grain model (simulating the behavior of a single grain or a particle). An interesting approach proposed by H.Y. Sohn (1978) is to use the law of additive reaction times in order to calculate, approximately but analytically, the reaction rate of a particle in the reactor model. Its great advantage, compared to a numerical grain model, is to drastically reduce the computation time, particularly in the case of complex reactor models. This is the approach we retained for modeling the moving bed furnace, a counter-current gas-solid reactor used in the nuclear fuel-making route for producing uranium tetrafluoride from uranium trioxide. The numerical model we developed is 2-dimensional, steady-state and based on the finite volume method. It describes solid and gas flow, convective, conductive and radiative heat transfers, and six chemical reactions involved in the process. The law of additive reaction times is used to calculate analytically the rate of the three principal gas-solid reactions at every discrete point in the reactor. We have demonstrated the validity of this approach by comparing its results with those calculated from a numerical grain model. Also detailed in the paper are the main results of the moving bed furnace model itself and the possibilities of optimizing the process revealed by the calculations.

Jan 1, 2006

By J. N. Van der Merwe

The research described in the paper was aimed at providing standardized information of cases of failed and intact coal pillars in the form of databases to researchers. It also offered the opportunity to take stock of the pillar stability situation in coalmining and to review the impact of the application of the safety factor formula for pillar design. It was found that the physical parameters of coalmining have not changed substantially over the last four decades. However, changes in the controllable parameters like pillar width, pillar width-to-height ratio and percentage extraction have all moved toward the more conservative side. Scrutiny of the database indicates that of all the failures recorded, only 23 occurred in panels that were mined after 1969, when one can assume that the safety factor formula was fully applied. If the pre-1969 practices had been continued, at least 144 collapses would have been expected. There has thus been a substantial reduction of pillar collapse cases, justifying the cost paid for the formula, which has shown to be in the region of 600 million tons of coal. It is evident that that are distinct differences in the natures of the failures among different coalfields. This justifies the attempts to derive seam or coal field specific strength formulae and is a topic that should be pursued.

Jan 1, 2006

By Doug Tesarik

Researchers from the National Institute for Occupational Safety and Health1 (NIOSH), together with employees from The Doe Run Company, are monitoring and evaluating the stability of a pillar retreat section at the Fletcher Mine, a lead/zinc, room-and-pillar mine near Bunker, MO. Cemented rockfill is being used to provide roof support as high-grade, remnant ore pillars are mined. Earth pressure cells and deformation meters placed in backfill panel pillars monitor stress change and vertical deformation, respectively, as nearby ore-bearing pillars are extracted. Similarly, biaxial stressmeters and borehole extensometers are used to monitor mining-induced stress change and deformation, respectively, in long-term support pillars. Data from these instruments indicate that when ore-bearing pillars were mined, stress was redistributed from support pillars to a backfill panel pillar. The data also indicate that the backfill and support pillars have remained stable for two years after pillar extraction was completed in the area. This research demonstrates the importance of using reliable instruments to document the geomechanical behavior of pillars and backfill. Gaining a better understanding of roof support and stress redistribution mechanisms is a fundamental part of NIOSH's goal to reduce and/or predict rockfalls, which are still among the leading causes of injuries in metal/nonmetal underground mines.

Jan 1, 2006

By M Armstrong, S J. Coward, A Galli

Mine management is often expected to make rapid evaluation decisions at different stages of projects based on limited and uncertain data. The challenge is exacerbated by having to distil technical complexity into a financial model that is usually designed to produce only one or two key indicators, eg net present value (NPV), internal rate of return (IRR). Mining is a complex environment with many sources of uncertainty ranging from sampling to economics. In order to optimise investment decision-making, an appropriately structured evaluation framework must be utilised. An evaluation framework should be designed to encapsulate and integrate the complexity across the evaluation cycle, ie sampling, resource estimation, mine planning and treatment, and financial and economic modelling. This complexity is diverse and ranges from sampling support, scale effects to understanding the impact of variability, uncertainty and flexibility on operational efficiency and economic viability. These complexities, combined with time and capital constraints, usually do not allow all facets of evaluation to be integrated into the model. The model must strike a balance between simplified estimation techniques and sufficient incorporation of aspects of the project that will make a material difference to the investment decision. This paper demonstrates the impact of the scale of measurement on the valuation of a mineral project. Comparisons are made between global estimation averages using a top-down approach and local estimates using a bottom-up approach. Three sampling campaigns were conducted on a virtual orebody to compare the relative NPV accuracies. Stochastic forward models were run on foreign exchange rates and are compared with the results from a fixed foreign exchange rate model.

Jan 1, 2006

By Richard F. Sliwoski

The Virginia State Capitol was designed by Thomas Jefferson and constructed in 1785. The Capitol is of great historic and architectural significance to not only the Commonwealth of Virginia but to the nation. It is the oldest operating Capitol in the U.S. and required a total restoration/renovation as well as an expansion to continue to remain functional. Site conditions dictated that the expansion (a new visitor center) be placed underground on the south side of the Capitol building, requiring a 40-foot deep excavation approximately 5 feet from the Building. Because of its historic significance, every measure had to be taken to ensure the safety and function of the Capitol during construction. The construction techniques that were used to make the deep excavation and protect the historic Capitol included a tied back concrete slurry wall, jet grouting, compensation grouting, and instrumentation monitoring. This paper describes the history of the Capitol building, the techniques that were employed for construction of the deep excavation, results of the latest movement monitoring, and factors contributing to meeting the restrictive movement goals.

Jan 1, 2006

By K. Nielsen

The Norwegian tunnelling industry has made remarkable improvements both with regard to productivity and cost efficiency over the last 30-40 years. This development has been made possible by continuous improvement driven by innovation. Based on a generic description of the innovation process and the innovation system, the paper has used the development of modern tunnel drilling in the Norwegian tunnelling industry to discuss the characteristics of its innovation system with a focus on human capital issues and knowledge management.

Jan 1, 2006

By Louis W. Cope

Mongolia is known in western countries as the location of rich dinosaur fossil fields. However, the country is even richer in mineral resources. The Ministry of Industry and Trade reports 6,000 mineral occurrences of 80 metals and minerals. Mongolia has already attracted much foreign investment in the mining sector. Mining is the country’s largest industry. It is responsible for 17 percent of the gross domestic product, 65 percent of industrial output and 57 percent of export earnings.

Jan 1, 2006

By Giovanni Principi

The activity of the ?Hydrogen Group? of Padova University, addressed to the study of materials for solid state hydrogen storage, is illustrated. Various Mg-based materials have been considered and are being studied: a) MgH2 and 0.5% mol Nb2O5 mixture ball milled under argon atmosphere; b) Mg-Ni-Fe intermetallic compounds prepared by short time ball milling of ribbons obtained by melt spinning and by long time ball milling of a mixture of MgH2, Ni and Fe powders; c) MgH2 ball milled in argon with Mm-Ni-Al (Mm = La-rich mishmetal) and Zr-Cr-Fe catalyst alloys. All the samples have been structurally characterized by X-ray diffraction (Rietveld refinement) before and after hydrogen absorption/desorption cycling and tested with a Sievert apparatus as regarding their thermodynamic and kinetic properties.

Jan 1, 2006

By A. Noël, R. Lapierre, M. Provencher

"Modem aluminum smelters are facing significant operating cost pressure. Key methods used by smelters to manage this pressure are automation and production-information systems to optimize processes, manage quality, anticipate problems and reduce operating costs. In 2002, Aluminerie Alouette Inc. began its Phase II Expansion project, and retained the joint venture of SNC-Lavalin and Hatch (SLH) as its engineering, procurement and construction management (EPCM) team. Alouette had the distinction of being one of the most efficient aluminum smelters in the world. Alouette already understood the importance of systems integration in project delivery. For Phase II, key objectives were identified to ensure ""a state of the art"" integrated architecture that would support Alouette's production goals to integrate the existing facilities with the expansion, to form a single efficient facility and meet project schedule and budget targets. Achieving those objectives within the context of a large project often creates major challenges due to the nature of the traditional EPCM delivery model, which relies on several vendors and third-party-systems integrators. In this case, an integrated Alouette-SLH team was made responsible for all aspects of the systems integration, taking over the task from most suppliers. The integrated team was responsible for delivering an automation system and plant-wide-production IT system for the new facilities while accommodating migration for the existing systems. Through the use of rigorous methodology and advanced state of the art technology, the IT and automation strategy led to significant value creation and is recognized today as one of the key factors of the project's success. The primary results were: fast and efficient start-up of facilities, due to quality programming and implementation; a plant able to operate as a single entity; automation and IT systems delivered before time and under budget; standard programming methods implemented throughout the plant; and reduced and simplified maintenance."

Jan 1, 2006

By M. Stephton, L. A. Cornish, R. Süss, N. B. Maledi, J. H. Potgieter, L. Chown

In today?s gas turbines, the emphasis is on saving energy and reducing the amounts of pollutants emitted. This can be attained only by designing alloys with higher melting points and the capability to retain mechanical integrity at increased temperatures. The development of nickel-based superalloys (NBSAs) has reached its limit, as the alloys are operating at critical temperatures close to their melting points. Further increase in the operating temperatures will result in dissolution of the strengthening phases and even melting. Recent trends are towards developing materials that are adequately strong but have much higher melting points and corrosion resistance than the NBSAs that are currently in use. Studies conducted on Pt alloys with similar structure to the NBSAs have presented mechanical results that are promising. This has led to further development of these alloys as a replacement for NBSAs. The operations of gas turbines are usually limited by hot corrosion, which could lead to catastrophic failures. Increased temperatures have an adverse effect on the corrosion of the alloys by making the environment more aggressive. Hence, during a material selection process, the corrosion behaviour of any selected material for a highly specialized application such as gas turbines needs to be assessed. Generally, coatings are applied to combat degradation by salt deposits, hence coated and uncoated NBSAs were selected as benchmark alloys. Corrosion mechanisms and kinetic studies of the Pt alloys were conducted. High temperature hot corrosion (HTHC) tests were conducted at 950°C for540 hours. Analysis of the corrosion products was conducted using a Raman spectrometer, scanning electron microscope with energy dispersive X-ray spectroscopy (EDS) optical microscopy, and X-ray diffraction study of the phases that formed. Both coated and uncoated NBSAs failed under the test conditions. Samples were covered with a porous non-adherent greenish layer which is characteristic of NiO. Pt alloys displayed superior corrosion properties compared with the benchmark alloys.

Jan 1, 2006