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By F. A. Guo

Ultrafine-grained surface layers were obtained by surface mechanical attrition treatment (SMAT) in copper and titanium samples. The thermal properties of the deformed layers were characterized using a scanning thermal microscopy (SThM) that allows thermal conductivity to be mapped down to the submicrometer scale. A theoretical approach, based on this investigation, was used to calculate the heat flow from the probe tip to the sample and then estimate the thermal conductivities at different scanning positions. Experimental results and theoretical calculation demonstrate that SThM can be used as a powerful tool for the thermal property and microstructural analysis of ultrafine-grained microstructures.

Jan 1, 2006

By Shinroku Matsuzaki

Data the measurement sensor installed with spatial distribution on the blast furnace were successively accumulated online from the process computer to the database system over a long period. This is a new system that accurately considers the relation with the installation position of each sensor, and picture computerization of the measurement data was developed. The overall operation state of a blast furnace, which skilled operators can see in their mind?s eye, was objectively visualized as pictorial information.

Jan 1, 2006

By Ryosuke O. Suzuki

A combined process of electrolysis of CaO in the molten CaCl2 and of calciothermic reduction, so-called OS process, was applied to prepare metallic vanadium directly from V2O3. The fine metallic powder containing 1860 mass ppm oxygen was obtained using 0.5mol%CaO-CaCl2 melt for 10.8 ks at 1173 K. The oxygen level did not decrease further even when twice electricity was applied. Because the metallic vanadium could be electrochemically deoxidized to the level of 10 ppm oxygen from 1.48 %, the large amount of by-product, CaO, due to reduction and the large surface area of the fine particles are the reasons of high oxygen content in the reduced powder.

Jan 1, 2006

By Tom Goforth, Rongmao Zhou

The interest of seismologists in mining explosions has increased substantially with the construction of the International Monitoring System (IMS). The IMS supports the Comprehensive Nuclear Test-Ban Treaty by providing global data coverage from seismic, hydro acoustic, infrasonic, and radionuclide sensors that will detect a host of natural and man-made events at regional (<2000 km) distances. Ideally, the recorded data can be used to identify those events that have explosive characteristics and therefore might be clandestine nuclear tests. The regional observations assure the detection of mining explosions, and these must be properly identified to avoid false alarms of the monitoring system. Cooperation with the mining industry, including documentation of the firing programs, provides critical information necessary to characterize the seismograms.

Jan 1, 2006

By Vince Luongo

"INTRODUCTIONThe West Side Combined Sewer Overflow (CSO) Tunnel Project is located in Portland, Oregon and is part of the Willamette River CSO Control Project. The purpose of the West Side CSO Project is to reduce the frequency and volume of combined sewage overflows from the drainage areas on the west side of the Willamette River using the West Side CSO tunnel as a combined storage and conveyance facility. The sewage is then directed to the Pump Station on Swan Island, which is located on the east side of the Willamette River. From here the combined sewage is pumped through force mains that discharge into the existing Peninsular and Portsmouth tunnels.The West Side CSO tunnel has an inside diameter of 14-feet (4.27m) and is approximately 18,150-feet (5,532m) long. The tunnel slopes at a constant down gradient of 0.0018 from south to north over the entire length of its alignment.The tunnel passes beneath six existing bridges; Hawthorne Bridge, Morrison Bridge, Burnside Bridge, Steel Bridge, Broadway Bridge and Fremont Bridge. The general tunnel alignment follows beneath the Naito Parkway starting at Clay Street Shaft and connecting three other shafts on the west side of the Willamette River, Ankeny Shaft, Upshur Shaft and Nicolai Shaft. It then passes below the Willamette River and on to Swan Island to connect with the Confluent Shaft, which will combine flows from the West Side CSO and East Side CSO (not part of this contract) and then continues to the Pump Station Shaft.The Nicolai Shaft is the primary mining shaft from which two TBM’s were launched to construct the West Side CSO tunnel. The first TBM started mining south and terminated at the Clay Street Shaft. The second TBM started mining north below the Willamette River and terminated at the Swan Island Pump Station Shaft."

Jan 1, 2006

By Philip Dubbeling

Conventional dynamic sheetpiling techniques are ill-suited to urban development because of the emission of excessive noise and ground vibrations. Drilled shafts and slurry walls alleviate some of these environmental concerns but add additional problems due to large bulky machines, reliance on dusty concrete plants and urban trucking grief. To solve these problems, pre-fabricated sheetpiles are hydraulically jacked-in by reaction principle using a compact and lightweight press-in machine, a so called the "Silent Piler". Through scientific analysis, definition and systemization of press-in machines and methods, new construction concepts such as the one-step approach, implant structures, functional design and life cycle design have been developed to comply with new basic construction principles.

Jan 1, 2006

By N Hungerford, A Coote, S Doyle, D Henderson, F Della-Pasqua

A systematic, detailed airborne geophysical programme carried out in the Taupo Volcanic Region (TVR) in 2005 by Glass Earth NZ Ltd culminated in the identification of 21 epithermal gold targets. In this paper we present the follow up ground-truthing results from the first target drilled, Tahunaatara (TAH). &nbsp; The Tahunaatara target was identified by means of a multi-disciplinary integrated approach (ôdata interventionö) that defined and ranked the target as being highly prospective for epithermal gold mineralisation. A follow-up ground resistivity survey over the target area revealed the presence of a ôresistorö buried beneath an extensive cover of recent volcaniclastic material. Geochemical soil sampling carried out in conjunction with the resistivity survey yielded anomalous gold values. &nbsp; The host unit at TAH consists primarily of flow banded rhyolitic lavas, volcaniclastic deposits and tuffs of the Ohakuri Ignimbrite with small outcrops of silicified bedded breccias forming local topographic highs. Results from the first orientation drill hole show wide zones of intense silicification, clay alteration and mineralisation. Sulphide mineralisation is disseminated throughout the core in association with hydrothermal replacement and also occurs in association with quartz veins and infill in fractures (sulphide-only veinlets as opposed to quartz + sulphide veinlets). Textural evidence from drill core indicates that hydrothermal fluid flow was multi-staged with potential for multi-stage gold, and other elements. The presence of polymictic hydrothermal eruptive breccias indicates a hydrothermal vent system. &nbsp; Alteration varies from argillic to silicic, with pervasive adularia and vuggy silicification also present. Chlorite is minor and associated with quartz, illitic clay and adularia. Assay results currently available confirm the presence of anomalous gold values in association with zones of vuggy silica deposition and intense silicification.

Jan 1, 2006

By P Atkinson, M P. Simpson, J R. Kyle

BM37 is a bonanza-grade (&gt;30 ppm Au) ore shoot of the Maria Lode of the Karangahake adularia-sericite epithermal deposit in the southern Hauraki Goldfield. Samples from BM37 contain up to weight percent gold. The ore shoot is a vein that pinches and swells, but is typically tens of cm thick, and locally exceeds 0.5 m in true width. Gold occurs as irregular anhedral electrum grains that range up to 300 microns across and contain 38 to 59 wt&nbsp;per cent&nbsp;Au (ave. 52 wt per cent&nbsp;Au). Electrum occurs in sulphide-rich bands in association with pyrite, chalcopyrite, acanthite, galena, sphalerite, and local covellite. Lower grade samples contain local to rare mckinstryite [(Ag, Cu) 2S] and polybasite [(Ag, Cu) 16 (As, Sb) 2S11]. Pyrite from BM37 is nearly stoichiometric; it lacks the As that commonly occurs at up to percent levels in pyrite from other veins in the goldfield. Acanthite also contains low quantities of trace metals, and typically has less than 2.5 per cent&nbsp;Se. The vein shows complex textures. Bonanza grade sulphide-rich ginguro bands form discrete layers adjacent to the vein margins, and occur as breccia fragments encased by later massive to comb quartz with local quartz after platy calcite. Both the breccia fragments and ginguro bands are cross-cut by later quartz veins. Textures thus indicate that formation of the high-grade portions of BM37 resulted from one or more discrete events that differed markedly from the events that formed the bulk of the vein.

Jan 1, 2006

By G. Barrasso

REACH was proposed by the EU Commission in October 2003 and stands for the Registration Evaluation, Authorisation and Restriction of Chemicals. It requires that all substances identified as persistent, bio-accumulative and toxic, whether the risk of those chemicals being released is real or perceived, require registration prior to them being allowed to be imported into the European Union. An internal investigation by the metals industry indicates that almost all primary raw materials streams would be classified as hazardous due to the potential health or environmental hazard properties of one or more of their ingredients. REACH uses a wide definition for chemicals and metals and as such its implications greatly impact the entire supply chain of the metals industry. The process of registration would require the producer/ importer to produce a dossier. Initiatives along the same lines as the EU REACH are also coming up in other parts of the world. REACH requires registration of at least four substances manufactured by the aluminium industry: aluminium metal, including powder, aluminium oxide, and aluminium hydroxide. The proposed legislation permits the affected companies to band together to form a consortium to develop certain aspects of the registration application. The aluminium industry has established a consortium and testing is currently underway.

Jan 1, 2006

By Donald P. Tuchman, Robert P. Vinson, Steven J. Page, Linda J. McWilliams, Gerald J. Joy, Steven E. Mischler, Jon C. Volkwein

The National Institute for Occupational Safety and Health (NIOSH), through an informal partnership with industry, labor, and the Mine Safety and Health Administration, has developed and tested a new type of instrument known as the personal dust monitor (PDM). The dust monitor is an integral part of the cap lamp that a miner normally carries to work and provides continuous information about the amount of respirable coal mine dust in the breathing zone of that individual. Testing was conducted on 25 prototype instruments in the laboratory to verify the instruments’ accuracy as received from the manufacturer and after a period of underground use. The laboratory testing verified previous work; there is a 95% confidence that the individual PDM measurements were within ±25% of reference measurements. In-mine testing determined the precision, durability, and miner acceptance. Data from the mines showed a field precision of 0.078% relative standard deviation for the PDM and 0.052% for the recognized standard—the coal mine dust personal sampler unit. The PDM had about 90% availability for collecting valid information in over 8,000 hr of underground use. Anecdotal comments by miners indicated that they found the PDM more convenient to wear for sampling than currently used instruments because of the integration of the sampler into the normally worn cap lamp. The means of the instruments’ pre- and postmine accuracy verification test values were statistically equivalent. Additional data were collected to measure the equivalency of the PDM to the U.K. Mining Research Establishment sampler, as required by U.S. law. However, analysis of the data was more complex than originally anticipated because the variance with increasing concentration required use of a more sophisticated statistical model. Explanation of and results from this work will be the subject of a second publication. Under the broad range of test conditions covered in this work, the PDM functioned as well as the current sampler in terms of availability for use, accuracy, precision, and miner acceptance.

Jan 1, 2006

By M. H. Colebrook

Nickel laterites contain about 70% of all continental or terrestrial nickel resources; therefore the recovery of nickel from lateritic ores has large economic significance. The processing of lateritic ores involves the preparation and movement of concentrated aqueous suspensions. However due to complex characteristics and non-Newtonian properties, ranging from shear-thinning to shear-thickening and from thixotropic to rheopectic, a basic understanding of the flow behaviour must be developed. This understanding will assist in the development of new plants and the operation of existing plants. The work in this paper involves the characterization of three ore types from the Vermelho ore deposit to categorize them as rheologically simple to complex. Rheological testing was also conducted on pure mineral samples that represent the main minerals in these samples. The results show that the rheological properties of the ore types can be related to the surface properties and physical characteristics of the main mineral constituents.

Jan 1, 2006

By F. Chiesa

The permanent mould process, which is a favoured process for producing premium quality aluminium casting, is rarely used to produce magnesium alloy parts. This may be attributed different factors such as: the reservation with which the automotive industry considers using magnesium in structural castings; also the relative hot shortness of most magnesium alloys when compared to aluminium A356/357 is another factor. A third reason stems from the fact that the "heat content" of magnesium is much less than that of aluminium, resulting in the difficulty, for a relatively slow process such as permanent mould (versus pressure die casting), to reach a mould dynamic equilibrium temperature sufficiently high to avoid premature freezing and misruns. The present work will address this problem by carrying out controlled cycling of a laboratory mould, poured with aluminium and magnesium alloys. The influence of insulation of the mould and artificial electric heating on the run-in mould temperature will be determined experimentally. A thermal model will be sought for these thermal devices that will allow to predict the thermal behaviour of moulds of different geometry before a single casting is poured. The model will be tested on an industrial casting in a workshop environment.

Jan 1, 2006

By Preston C. Holloway

Transformational roasting involves the heating of a material along with specific additives to induce mineralogical changes in the starting material. By controlling the chemical composition, roasting atmosphere, temperature and time of reaction, the mineral transformations induced during roasting can be engineered to control the distribution of valuable, or harmful, metals and to produce new mineral assemblages that are more amenable to conventional methods of metals recovery or to environmentally safe disposal. To date, this type of process has only been applied to the recovery of a limited number of metals, but current research is looking to expand the application of these techniques to the recovery of metals from a wider range of materials. An introduction to these techniques is presented along with preliminary results from their application to metals recovery from zinc bearing wastes, such as zinc ferrite leach residues and carbon steel electric arc furnace dust.

Jan 1, 2006

By S. Hardy

The paper describes state of the art non-linear analyses of the pile groups that were employed during the raising of the 133m high triumphal arch which forms the centre piece of the new Wembley stadium in North London. The deformation behaviour of these piles groups was critical during the lifting process, due to the slendemess of the arch structure. The issue was made more critical by the high profile nature of the project. The results of Class A (Lambe (1973)) predictions of the pile group movements are compared with observed displacements and rotations which were accurately measured on site. To illustrate the importance of soil non-linearity on pile group behaviour, comparison is also made with pile group analyses which assume a linear soil stiffness.

Jan 1, 2006

By E. Krause

The oxidation of Fe(II) with S(IV) and oxygen can be used advantageously in leaching systems requiring both Fe(III) and sulfuric acid; e.g., heap leaching of sulfide-containing ores or concentrates. The oxidation of Fe(II) with SO2/air is several orders of magnitude faster than with air alone; rates of up to ?20 g/L&apos;h were observed at 25°C. The reaction proceeds via an intermediate orange-red mixed-valence Fe(II)/Fe(III) sulfite complex, which is present at an essentially constant concentration throughout most of the oxidation process. The oxidation rate of Fe(II) is approximated by the formula -d[Fe(II)]/dt = k [S(IV)] [02]0&apos;3. The concentration of the mixed-valence complex, and thus the iron oxidation rate, decreases with increasing acidity. Certain impurities, such as SCN- and thiourea, negatively affect the rate. The oxidation reaction 2Fe2 + SO2 + 02 4 2Fe3+ + S042- is accompanied by the side reaction H20 + SO2 + 1/202 4 H2SO4. The side reaction becomes particularly important at low temperatures and whenever the oxygen mass transfer is insufficient with respect to the rate of addition of S(IV). Thus, effective oxygen mass transfer is essential for achieving high oxidation rates with minimal acid formation. The activation energy was estimated as 141 kJ/mol over the temperature range 10-35°C.

Jan 1, 2006

By O. Acaroglu

Selection of the most suitable roadheaders (boom type tunnelling machines) for the galleries/tunnels to be excavated in certain rock and under known project conditions is important for avoiding problems during application. This research utilized a multiple attribute decision-making method and studied how this will be applied for the selection of boom-type excavation machines. The Cayirhan Coal Basin was used for selecting roadheaders using the analytical hierarchy process, which is one of the multiple attribute decision-making methods. To conclude, this study reveals that decision-making methods can be used in the process of selecting roadheaders for the excavation of galleries. Keywords: roadheaders, multiple attribute decision-making, analytical hierarchy process.

Jan 1, 2006

By K. Kawagishi, J. Ang, A. Sato, H. Harada

"We have recently proposed a new ""EQ Coating"" bond coat system to solve the problem of secondary reaction zone (SRZ) formation caused by bond coats applied on the hot section components of modem jet engines. A viable EQ coating alloy was previously found for a representative znd generation superalloy, TMS-82+. It would be ideal if the same could be done for a representative 5th generation superalloy, TMS-173. In this paper, we will show that the coating with the best oxidation resistance in the EQ system of TMS-173, although possessing considerably better resistance than TMS-173, did not have sufficient oxidation resistance. In order to improve the oxidation resistance of the EQ coating for TMS-173, we have ventured into ""Pseudo-EQ coatings"". A diffusion couple between the Pseudo-EQ coating and TMS-173, after 300hrs at 1100°C, had a 0-15µm IDZ, but no SRZ. A diffusion couple between a conventional coating and TMS-173 formed a 80-150 µm SRZ. After a 1 hr oxidation test at 1100°C, the PseudoEQ coating formed a thinner oxide layer than the EQ coating, but still contained NiO and spinel. Aerospace"

Jan 1, 2006

By Vojteh Leskov?ek

The tribological load is the load on forging tools resulting from the relative motions between the plastically deformed workpiece and the die. In comparison to many other forming processes hot die forging has an especially disadvantageous tribological system. The advantages of the application of hard coatings, which are well known for cutting tools, are to a much lesser extent explored for casting, extrusion, molding and forging tools. Increasing the lifetime of these tools is an important task in surface engineering because of the complex loading conditions and often complicated tool geometry. The plasma-assisted chemical-vapor-deposition (PACVD) technique is well suited to depositing hard coatings onto large dies and molds. The aim of this study is to present and discus results obtained on a duplex PACVD hard coating in an industrial application like the hot forging of automotive parts. A new generation of vacuum-melted and remelted (VMR) hot-work tool steels has been developed; these can reach a hardness of 58 HRc, and have a fracture toughness at this hardness equivalent to that of standard hot-work tool steels at 45 HRc. This offers one of two advantages: the steels can be used at the higher hardness to provide resistance to wear or deformation, or, when used at a hardness of 47?49 HRc for hot forging, to provide temper resistance, nitriding behavior and adhesive wear resistance. The results presented here are from a preliminary investigation. The experimental results indicate that the introduction of a proper duplex PACVD hard coating will lead to an improved wear resistance and a longer lifetime for the hot-forging dies. Furthermore, by using a hard, low-friction coating excellent anti-sticking properties can be obtained. At this stage of the investigation it is also necessary to carry out pilot trials to determine the wear resistance and the tool life in practice.

Jan 1, 2006

By David J. Blackwell

The challenge; to design production facilities and in particular separation equipment which have the ability to deal effectively with the ever changing composition of well fluids, over the life time of the field in which it is operating, ensuring maximum uptime of the asset coupled with consistently effective separation. Design engineers are, however, continually confronted with a dilemma when selecting materials of construction for Oil/Gas separation equipment, since they are generally obliged to select an acceptable material of construction, based on ?predicted? operating conditions, at the lowest acceptable cost. Consequently many designs are somewhat basic and do not take into account the constantly varying dynamics of the well fluids being released into the separator. As oil fields mature, oil companies endeavour to maximize revenue by maintaining oil and gas throughputs. This often results in an associated increase in water and sand volumes and, in order to maintain efficient separation, an increase in operational temperature and pressure; subjecting the equipment to operational conditions for which it was never designed. In reality, therefore, the limitations and constraints placed upon new construction design often result in Maintenance Engineers having to solve the ensuing problems in difficult ?in-field? environments. Should refurbishment or upgrade be required then the status of the platform and that of the vessel during shutdown will dictate how this is achieved. Hotwork on the vessel is generally not preferred due to the requirement for post weld heat treatment and re-classification of the pressure vessel, not to mention the added risk in terms of safety. Unfortunately, until recently, there have been few alternatives to conventional ?hotwork? repair and protection systems, especially since the performance of cold curing polymer based repair and coating systems, for use in oil and gas process equipment, has, until recently, been limited by their resistance to temperature and pressure in immersed conditions. In line with the continued development of high temperature / high pressure oil and gas fields however, recent breakthroughs in polymer technology can now offer both repair and protection solutions which are able to function effectively at temperatures up to 180°C in immersed conditions combined with resistance to the destructive forces of explosive decompression from pressures in excess of 90 bar. This paper will look at recent work that has been undertaken to determine the suitability of modern polymer based repair and protection systems as an alternative to hotwork; thus enabling newly designed and upgraded internals to be cold bonded into position and further protected with temperature resistant coatings, in order to minimize the downtime of the asset and further to protect the vessel internals from the Erosive Corrosive environment.

Jan 1, 2006

By A. J. Sideris

It is known that Mg can act as a catalyst/solvent in the high pressure high temperature diamond synthesis. However, above pressure levels of the order of 7 GPa, and temperatures from 1700 ? 1800oC, it was not possible yet to use Mg for the industrial production of diamond. A possible alternative is the use of MgNi based alloys. However, owing to the great Mg reactivity, it was consider, so far, a difficult task to deal with such alloys. The present work presents successful results regarding the production of MgNi alloys, with different composition, at high pressure conditions. The behavior of the alloys and their microstructural characterization is analyzed.

Jan 1, 2006