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By M BSckstr÷m

Acid rock drainage (ARD), commonly found in vicinities of sulfidic mines, possess properties capable of widely affecting the surrounding environment by acidification and heavy metal pollution. In most ARD treatments, various alkaline sources are used to neutralise the acid produced. Utilisation of highly alkaline fly ashes instead of raw materials is a cost-effective alternative, which lately have become increasingly popular. In laboratory batch experiments, neutralising capacity of fly ash was studied during 20 days. ARD was added to the fly ash once a day, for each increment the liquid to solid ratio (L/S ratio) was increased. At an early stage of the experiment (day 6, L/S ratio 12), the concentration of barium in solution unexpectedly increased by a factor of 50 (from 200 to 10 000 ¦g+l-1). This high concentration also sustained the following two days (L/S ratios 14 and 16) before dropping to the original level. pH showed a slight increase during these observations (pH 12.4 - 12.7). The phenomenon was also observed in a parallel and identical series. In addition to barium, aluminium and strontium clearly increased in the same manner, however not as much as barium. Furthermore, concentrations of chromium and molybdenum noticeably decreased at these distinct L/S ratios (12, 14 and 16). The behaviour of barium and subsequently strontium, aluminium, chromium and molybdenum is only partially understood. The decrease of chromium and molybdenum is suggested to be due to incorporation into the interlayer regions of hydrocalumite (Ca4Al2(OH)12(OH)2+6H2O), replacing the hydroxide groups, which also explains the increase in pH. Moreover, the increase of barium, strontium and aluminium could be attributable to dissolution of the silicate mineral celsian (Ba,Sr(Al2Si2O8)). Alternatively, barium and strontium increase could be explained by dissolution of a Ba,Sr(SO4)-solid solution and aluminium increase by dissolution of hydrocalumite or ettringite.

Jan 1, 2008

By Walt Meglasson

The Kaiser Aluminum Company Smelter, one of several in the Pacific Northwest, was built in 1942 and operated by the Olin Company during World War II and then purchased by Kaiser Aluminum after the war. At its height, the facility employed over 350 workers and was capable of producing 73,000 tons of aluminum per year. It was closed in 2000 through a combination of rising electrical and labor costs, and the inability to compete with more up-to-date foreign facilities.

Jan 1, 2008

By Guozhu Ye, Mikael Larsson, Eric Burström, Sten Ångström

"Increased use of scrap in steelmaking including scrap use in BOF has a high economic and environmental potential in terms of increased productivity, energy saving and reduced emission of CO2. Preheating and surface cleaning of steel scrap is a concept developed by MEFOS in a four year research program funded by MISTRA, Swedish Foundation of Strategic Environmental Research. The process concept consists of four major steps: 1) Combustion of ASR or other waste fuel and composing of the gas composition. 2) Scrap heating and cleaning in a shaft where the coated zinc is removed as ZnCl2 and scrap is heated to about 600 ºC. 3) Dust separation for recovery of metal zinc. 4) Gas cleaning. This paper will describe the process concept and highlight the major results from preliminary trials around the scrap heating and cleaning shaft.IntroductionSteel is often coated to increase the corrosion resistance. Share of coated and galvanized steel in the world marked is steadily increasing. This results in increased amounts of scrap with different types of coatings. Use of galvanized scrap in EAF plant results in an EAF dust with high content of zinc ferrite and many other impurities like Pb, Hg, Cd and halide. EAF dust is classified as hazardous waste in most of the developed countries and the steel plant has to pay for external treatment for zinc recovery. For use in BOF plant this will result in a BOF dust containing typically 1-5%Zn making it impossible for recycling to the blast furnace.Different approaches for surface cleaning have been investigated in past. Dapper et al. [1] examined the possibility to evaporate Zn, Ni, Cr, Sn from coated materials using chlorine. Chlorinated rinsing of non iron oxides and metals using HCl from combustion of PVC was discussed by Fray [2]. Further studies by Tee and Fray [3-5] have been concentrated on the possibility to vaporize coatings with an air and chlorine gas mixture. The O2:Cl2 ratio in the gas mixture was found to have great importance for control of the process. To avoid the chlorination of iron, this ratio should be kept at a level of 10:1.Scrap pre-heating up to about 600 ºC is a well known method and this alone could save up to 100 kWh per ton steel. The technology has been established since many years and efficient processes were developed in the 90’s. However, no process has fully gained the expected energy savings as the large quantity of the exhaust gas has to be reheated to over 1000 ºC again to destroy the hazardous components like dioxins."

Jan 1, 2008

By Michael Schmalzel

Freeport-McMoRan Copper & Gold, Inc. (FMI) will soon begin copper production from the Dos Pobres and San Juan deposits near Safford, Arizona. Ore reserves total 615 M tons grading 0.36% copper, predominantly as chrysocolla. Copper extraction will be by leaching with sulfuric acid. Fluor Canada Ltd. provided EPCM services to design an ore handling and conventional SWEW facility capable of producing a nominal 240 million pounds per year of cathode copper. The ore handling facility will process 114,000 tons per day of ore through three-stage, open-circuit crushing followed by agglomeration and product placement on the permanent leach pad. Stacking of ore on the leach pad will utilize Terra Nova Technologies' "Super Portable" mobile stacking system. The stacking system fleet consists of 13 self- propelled, crawler-mounted mobile conveyor units, each with 72-inch-wide belting and a capacity of 6,800 tons per hour, including ten 250-foot-long portable conveyors, a horizontal feed conveyor, a 285-foot-long horizontal conveyor and a 220-foot-long radial stacker. PROJECT BACKGROUND Project History The Safford Leach Project is located in the Safford mining district in Graham County, Arizona, approximately eight miles northeast of the town of Safford and 170 miles east of Phoenix. The 3,360-acre property is located in the Gila River Valley, immediately south of the Gila Mountains, at elevations between approximately 3,000 and 5,400 feet above sea level. The Safford Leach Project is comprised of the Dos Pobres and San Juan deposits, two of five known copper ore deposits in the Safford mining district.

Jan 1, 2008

By Edward Jacobsen, Patrick J. Lydon

"The ongoing expansion of the Oak Creek Power Plant in Oak Creek, Wisc., includes a tunnel bored in rock that connects to four vertical intake shafts approximately 1.5 miles (2.4 km) offshore in Lake Michigan. In 2004, Case Foundation Company was awarded a lump sum contract to install these intake shafts. In spite of delays that shortened the May to September construction season by up to 50%, four shafts and liner assemblies were drilled in 2005 and 2006. The shafts were connected to the tunnel in 2007 by mining upward to reach the lower portion of each liner and then removing its internal bulkheads so that lake water fl owed into the tunnel. The project is one of the largest private construction projects ever undertaken in Wisconsin. The expansion adds 1,230 megawatts of generation. In addition to the tunnel and offshore work, there will be 16 miles (26 km) of railroad track and 6 million cubic yards (4,600,000 m3) of earth work. The 27 ft (8.2 m) diameter tunnel, drilled some 150 ft (46 m) below the surface of Lake Michigan, originates onshore at a pump house. A structural slurry wall was constructed as the foundation for the pump house. The tunnel passes to the south near the current water intake before bearing east toward the new offshore intake shafts, which are 12 ft (3.6 m) diameter by 108 ft (33 m) long steel liner assemblies. These were grouted in place from approximately 3 ft (1 m) above the crown of the intake tunnel and then to 20 ft (6 m) below the lake bottom.Site GeologyOffshore. The plant site is north of the Racine-Milwaukee county line in an area affected by glacial activity. The soil conditions encountered at each shaft location were consistent, with noticeable variations occurring in the top of rock elevations that sloped downward from the innermost to the outermost shaft."

Jan 1, 2008

By James W. Marold

Tunnel and shaft plugs have been designed to assist in construction of new and rehabilitation of existing tunnels and shafts. Tunnel plugs have been used to provide construction access for side by side tunnels, separation of raw and treated water, and to allow operation of one tunnel during construction of a nearby tunnel. Shaft plugs have been used to seal up surface openings to tunnels and to prevent seepage of water to the surface through adjacent tunnels or shafts. The design construction details of tunnel and shaft plugs are provided. Typical examples of tunnel and shaft plugs are provided.

Jan 1, 2008

By Stephen A. Orr

Underground mining is a dynamic art and science with a diverse set of design, production, and economic criteria that must be considered before selecting an optimal method to extract the ore. While all methods can be technically classified as either self-supported, supported, or caving, the multitude of subsystems and existing variations bear witness to the fact that each orebody is unique and, as such, justifies an individual approach to optimize mineral extraction. In this sense, underground mining is an art. The ability to evaluate the unique characteristics of each ore body and utilize sound engineering principles to design the optimal system constitutes effective method selection. The task by no means ends at this juncture, however. Subsequent implementation requires an ability for modification. Very rarely are all the facts available to make a concrete decision prior to development of the resource. As a result, the risk of a wrong decision can never be eliminated. This requires a significant degree of flexibility with each method. Each unit of exploration, development, or exploitation work contributed to a deposit enhances knowledge of the ore body. The best mining methods are those that correctly account for the known parameters but provide an allowance for change at minimal cost and adapt to unanticipated conditions.

Jan 1, 2008

By Gregory Molinda

NIOSH has recently completed a study of the interaction between polyurethane (PUR) and coal mine roof in order to determine the mechanism of reinforcement, in both highly fractured rock and unfractured rock. Four case studies of PUR rein­forcement are presented. At a West Virginia site, a borehole camera revealed the location of roof voids and guided the PUR injection. By injecting polyure­thane into a zone from 0.6 to 1.8 m (2?6 ft.) high in the roof, a roof beam was created and ongoing intersection falls were halted. In another highly fractured roof in a western Pennsylvania mine, a total of 5.8 cm (2.3 in.) of rubbleized rock was found in a zone up to 3 m (10 ft.) into the roof. Untargeted PUR injection filled approximately 1/2 of the fractures. These two case studies showed that it is not necessary to fill up 100% of the void space to create stability. In the other two field sites, polyurethane was injected into weak, but unfractured roof. Post-injec­tion video monitoring showed that weak bedding planes were hydraulically wedged open and polyure­thane injected along bedding. The reinforcement value of this injection method is limited because of the wafer-thin layer of PUR introduced along bedding, and the lack of a PUR ??webbing?? which would serve as a structural framework to provide strength. It was determined that video inspection prior to PUR injection can aid in identifying the fracture zones to target, and minimize ??blind?? pumping and loss of PUR.

Jan 1, 2008

By I. Kylmakorpi

In non-ferrous metal smelting, when the concentrate entering the furnace contains high levels of moisture, energy requirement for heating and drying increases and large volumes of exhaust are produced. To solve this problem, rotary dryers and flash dryers using direct heating, and also steam dryers using indirect heating have all been used for drying concentrate. The focus of this paper is to present the development and current applications of the Kumera Rotary steam dryer. The advantages of this technology are numerous, including reduced heating requirements, environmental friendliness, operation reliability and minimum maintenance needs; making it a top choice for drying concentrate.

Jan 1, 2008

By Jim Sarvinis, Mark Berkley, David Clarry, Jason Berzansky

"Technologies developed to sequester CO2 or use CO2 for enhanced fossil fuel recovery are currently being utilized across the globe. Taxation regimes and CO2 credit trading are becoming drivers for a number of projects. Some mining companies have also identified ancillary opportunity to sequester CO2 in their by-products; recent work in the alumina industry is a prime example. In addition to process plant emissions, mining companies are becoming increasingly aware of their overall carbon footprint, including CO2 generated during the production of utility power. New power plant designs, in various stages of development, include CO2 separation and sequestration techniques. This paper summarizes the state-of-the-art for these technologies; including integrated gasification combined cycle (IGCC) power plants. A concept to use the gasification products as reductant in metallurgical processes is also described. The relevance of technology from power plant designs with post-combustion capture to the processing of off-gas generated in metallurgical facilities is also reviewed.IntroductionGlobalization and international economic growth have led to an increase in energy demand worldwide, and a corresponding increase in greenhouse gas (GHG) emissions. In 2005, 81% of global energy supply came from fossil fuels [1]; and while alternative energy technologies are emerging, it will require many decades to curb society’s fossil fuel dependence. Given the global concern of climate change and its scientific relationship with anthropogenic carbon dioxide (CO2), there is at present great interest in the development of techniques to reduce emissions of CO2. While most of these efforts are related to power generation and energy efficiency, the development of technologies for CO2 capture may offer opportunities in reducing emissions from industrial processes."

Jan 1, 2008

By Zhigeng Xu

Pressure leach of a Yunnan marmatite concentrates with adding coal as the elemental sulfur disperser was investigated. The experimental results show that the coal with carbon content higher than 70% is incapable of dispersing elemental sulfur from minerals and cannot improve the leaching of zinc. The coal with low carbon content (lignite coal) can act as excellent sulfur-disperser in the pressure leaching at 423K. The mechanism of lignite coal as sulfur disperser was further discussed by ultraviolet, infra-red spectrum and mass spectrum.

Jan 1, 2008

By Jerry Pyatt

Lead has been used by mankind since before the Egyptian pyramids were built. Its durability provides for a continuum of innovation. As the largest integrated lead producer in the Western Hemisphere, The Doe Run Co. is committed to locating, mining, processing and sup-plying lead in ways that are responsible and sustainable. It takes ingenuity and resolve to successfully operate in the heavy industry field today. Doe Run is committed to applying responsibility through sustainability, lean manufacturing, safety, environmental stewardship, education and workforce development, and com-munity support.

Jan 1, 2008

By Norm Disley, Kingsley Hortin, Gertjan Bekkers

As part of the expansion of the Kidd Creek Mine to 2,682 meters (8800 feet) below surface, two largediameter 3000kW (4000HP) booster fans were installed at the 6000 level. Shortly after commissioning the fans, significant damage to the fan bearings were observed, forcing several shutdowns for repairs, which were very disruptive to the mine’s production process.

Jan 1, 2008

By J. Yianatos

The collection zone residence time distribution (RTD) of mechanical self-aerated flotation cells was characterized for liquid and solid per size class (-45 mm, +45-150 mm and +150 mm). It was found that a single large industrial cell with a volume of 130 to 250 m3, now used in plant operations, can be well represented by an LTST (large and small tank-in-series) model plus dead time. From a scale-up point of view, results showed a similar mixing behavior for industrial cells ranging from 130 to 250 m3. Also, single mechanical cells showed a similar mixing pattern (RTD) when compared to large pneumatic flotation columns. It was confirmed that for practical purposes, the mixing condition in a flotation bank of three or more cells in series can be well described by the classical N tanks-in-series model.

Jan 1, 2008

By Timothy Barton

The uniaxial compressive strength (UCS) is the most fundamental measurement used in geotechnical rock characterization for mine design. While there are standardized procedures for how to conduct UCS tests, there are no firm guidelines as to when to conduct them. However, it is well known that the strengths of at least some rocks can change during the time between when the core first comes up out of the hole and when it is prepared and tested in the lab. The goal of this NIOSH (National Institute for Occupational Safety and Health) study was to evaluate UCS changes occurring in a broad range of weak coal measure rocks over a one-year time span. The study found the highest moisture contents were measured when the core was fresh, immediately after it was taken from the hole. The specimens then dried rapidly over the next few weeks. Subsequently, sample moisture contents decreased slightly in the winter and increased in the summer in response to the ambient changes in humidity. The measured UCS of the core also changed during the year, apparently in response to changes in the moisture content. The UCS values from the dry, winter months were, on average, 60% higher than the values obtained when the core was fresh, and the summer UCS was approximately 11% lower than the winter UCS. These findings have implications for the use of UCS as an input parameter for both empirical and numerical mine design methods. UCS values of unprotected core tested weeks to months after drilling can be significantly stronger and indicate stronger roof sequences than warranted. In order to obtain the most representative and reliable UCS value, it is necessary to test the core, or wrap and seal it, at the drill site shortly after recovery.

Jan 1, 2008

By Mark H. Hashiguchi

Examination of tensile bar surfaces shortly after destructive testing was conducted to search for clues that would aid in optimization of mechanical properties, especially tensile strength, yield strength and elongation to fracture. Cu-Ni-Si-Cr alloy bars in the as-cast, forged, rolled and extruded conditions were examined. Low ductility bars (<4% Elongation) showed dramatically different features than the fracture surfaces of high strength - high ductility bars (7 to 10% Elongation). Analysis of the fracture surfaces at 15X to 2000X and use of Energy-Dispersive X-Ray Spectroscopy (EDS) identified Ni-Si and Ni-Si-Cr precipitates of varying sizes and morphologies. Thermo-mechanical processing techniques to control the size and distribution of these precipitates show promise in improving the properties and performance of this alloy system and appear to correlate with improvements in the fracture surface morphology.

Jan 1, 2008

By Jacolien P. Wyethe

Zincor uses a Roast-Leach-Electrowinning circuit to process zinc sulphide concentrates. It also processes zinc oxide fume, originating from a slag smelting operation in the Democratic Republic of the Congo (DRC). Zincor achieved an average zinc recovery of 90.3% during the period January 2006 to May 2007. The bulk of the losses occurred in the iron and lead silver residues, both as soluble and un-dissolved losses. The un-dissolved losses in the iron residue constituted around 33% of the total zinc lost from the circuit, and were largely attributed to the presence of zinc-ferrite in the calcine used for neutralization during iron removal. As part of Zincor?s continuous improvement programme, the un-dissolved zinc losses in the iron residue were targeted by: the partial replacement of calcine with zinc oxide fume (from the DRC); and the preferential use of ?low-ferrite content calcine? as neutralizing agents in the iron removal circuit. These initiatives, coupled with other operational factors, resulted in a marked improvement in recovery to 92.6% during June to December 2007. The zinc oxide fume, directly fed to the circuit, required investigation of the halide rejection capacity of the Zincor circuit. Rejection of chloride via the magnesium bleed operation was considered adequate. Fluoride was mainly rejected via the iron (~70%) and lead silver (~27%) residues. Fluoride rejection via the lead silver residue varied significantly, probably as a result of variations in the sparingly soluble CaF2 content in the feed. The mechanism for fluoride rejection in the iron residues is uncertain. The fluoride rejection capacity of the Zincor iron residue (comprising of mainly jarosites, schwertmannite and ferrihydrite) at 2 ? 4 mg/L F in solution, was estimated at 0.14 ? 0.19 kgF/tFe residue.

Jan 1, 2008

By George Harrison

A great many labor leaders and others advocate shot-firers as the acme of relief for all the dangers connected with solid shooting, and where large quantities of powder are used in one blast in coal mines. Legislative bodies in several mining States have enacted laws providing for shot-firers in mines under such circumstances, the blasting to be done at night after the miners have left the mine. With all due respect to the opinions and honesty of purpose of these advocates of shot-firers, it is evident that a great many of them are not considering this important question in the broad sense it deserves and should be considered.

Jan 1, 2008

By E L. Kotova

Completeness of extraction of a mineral from ore depends on many reasons. First of all it is a function of quality of disintegration of ore. It is supposed that two basic factors: character of structure and texture of the ore aggregate and a disintegration technique influence the quality of the mineral aggregate destruction, æopeningÆ of its internal boundaries. In this paper, the problem of technological mineralogy from the point of view of genesis of the mineral aggregate, its typomorphical features and methods of their quantitative description are discussed. The purpose of this research is to provide information for technologists. It should enable the development of a rational flexible scheme of disintegration of ore with full extraction of a useful component, without its losses and without unnecessary expenses of energy. For achievement of this purpose the mineralogical information should have ½number and a measure+. By the authors, the technique of the quantitative analysis of fabric of the mineral aggregate based on several models û thermodynamic, crystallographic and geometrical is offered and discussed. The leading role in the quantitative analysis of a fabric of ore belongs to internal bounders. But internal bounders of the mineral aggregate by bounders or faces of the mineral individuals or mineral grains are formed. Their geometry, orientation concerning own (mineral grain) crystallographic lattices, orientation and distribution in space of the ore aggregate are proportional to the energy accumulated at origin and the further growth. These characteristics of mineral individuals are consequences of conditions of their formation. That is why the named triad of models is used. From crystallography it is known that faces of different stability and mobility form borders of crystals. They also contain different quantity of energy. Mineral grains also are faceted by different energy borders. They form intergrowths with each other according to a principle of balance or unbalance. That is why in addition to traditional parameters of the description of a fabric of the mineral aggregate (mode and grainmetrical composition) it is necessary to add new. For example, length and the square of intergrowthing bounders of mineral individuals differentiated (in couples), crystallographic symbols of borders, their roughness and so forth. Consequently, solving a problem of the geometrical characteristic of borders, we define also its power characteristic. In this paper experience of application of our technology in studying ores of one of deposits of Urals Mountains is presented. For realisation of these types of the analysis technologies of measurement, the program of calculation and the devices, which are carrying out the analysis in a semi-automatic mode, are possessed. Structure and texture of rock or ore aggregate reflect its formation and transformation conditions. It is important to understand that disintegration energy cannot be more than aggregation energy, the energy of intergrowths formation. The square and orientation of mineral individuals borders vary at pressures or stresses of mineral aggregate evolution. These phenomena often cause selective increase in the square of borders at constant average grain size, ie the granulation. Granulation presents the increase in quantity of mineral individuals while their modal share remains constant. At the same time their average mineral grains size. Some mineral individuals increase in size at increased pressure. When lithostatic or lateral pressure drops the majority of mineral grains increases in volume at the cost of intersticial or film solutions or fine grains. These are only special examples of the ontogenesis of the mineral aggregate. They illustrate our statement that all changes in fabric of the mineral aggregate are a reaction on varying external (ie geological) conditions. It is possible to consider that structurisation of totality of mineral individuals as a whole is a process of adaptation of the mineral aggregate, which forms and exists in varying force and energy fields. Differential and integrated geometry of total internal boundaries of the mineral aggregate serves as adaptation mechanism of the mineral grains system. Boundaries form intergrowths of the mineral aggregate. Thus, it is possible to consider that the most informative parameters of the stereometric analysis for restoration of the ontogenesis of the mineral aggregate are the following. First of all, it is a quantitative estimation of the volumetric shape of the ore mineral in crystallographic coordinates, a total area of borders of all mineral grains in the aggregate, the specific square of their boundaries, the specific square of intergrowth boundaries of the ore mineral separately with grains of each minerals of the matrix of the mineral aggregate as well as traditional grainsmetric and modal composition. For realisation of these types of the analysis technologies of measurement, the program of calculation and the devices that are carrying out the analysis in a semi-automatic mode are possessed.

Jan 1, 2008

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Jan 1, 2008