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By Yan Fu, Chuanlin Fan, Xiujing Zhai, Yongfeng Chang, Binchuan Li

"The mechanism of the selective chlorination of nickel and cobalt in reduced limonitic laterite was investigated. Reduced ores were obtained from the reduction roasting of a limonitic nickel laterite. The thermal decomposition of related chlorides and the selective chlorination of the reduced ore were carefully studied using Differential Thermal analysis - Thermogravimetry (DTA-TG), X-Ray Diffraction and chemical leaching methods. In the temperature range of 300 - 500 °C, aluminum chloride hexahydrate was chosen as chloride agent. During the selective chlorination, reduced ore was partly chlorinated by hydrogen chloride generated from the thermal decomposition of chloride agent. Then the oxydrolysis of ferrous chloride re-generated hydrogen chloride was used to further the chlorination. Finally, iron was mostly rejected as hematite, while nickel and cobalt were selectively chlorinated. More than 91 %Ni , 90%Co and about 4%Fe in the chlorinated ore was extracted using a water leaching method.IntroductionLimonitic nickel laterite is an important nickel reserve, which is rich in iron in the form of goethite and has low contents of magnesium, aluminum, silicon, and other elements. Goethite is the main nickel-bearing mineral in the laterite [1]. Nickel is generally present in goethite in three modes: (a) associated with amorphous or poorly crystalline goethite, (b) weakly adsorbed to the crystalline goethite surface, and ( c) as lattice substituents [2]. In addition, cobalt in limonite was found to be associated with a manganese phase rich also in nickel [3]. These results indicate that the extractions of nickel and cobalt are highly dependent upon the degree of the decomposition of the nickel, cobalt-bearing minerals.For the selective extraction of nickel and cobalt from limonitic laterite, the ore is usually processed by hydrometallurgical methods, including high pressure acid leaching (HPAL) [4] or reductive roasting - ammonia leaching (Caron process). However, there are still some disadvantages in these processes, such as the expense of autoclaves and scaling problems in HP AL [ 4, 5], and relatively low overall metal recovery, large energy and reagent requirements for the Caron process."

Jan 1, 2011

By Gordon Lovegrove, Jeffrey Leob, Dwayne Tannant

It has long been known that the combination of aluminum (AL) powder to ammonium nitrate (AN) / fuel oil (FO) can greatly enhance fragmentation or ultimately reduce the number of blast holes in a pattern. Decades of research have meticulously provided optimal AL:AN:FO ratios showing dramatic increases in energy output levels, yet widespread use of aluminized ANFO (ALANFO) has yet to replace the use of ANFO in the blasting world today. This may be due to the perception that the upfront, increased cost of materials deters the selection of this advantageously modified explosive. Researchers have explored this question and promote ALANFO by pledge of massive reductions in day-to-day operational costs. However, in these analyses there is a complete disregard for the external costs of the material; the environmental effects and sustainability considerations of the product. A holistic social cost-benefit analysis of ALANFO shows that an admittedly high-cost explosive does indeed provide an output which contains a wealth of operational savings in typical blast patterns. However, the immediate, on-site costs and savings do not define the limitations of this analysis. A complete comparison of the externalities including the environmental and sustainability considerations of the aluminum by-product life-cycle, and the environmental impacts of both the refinement of ammonium nitrate prills and the acquisition of sufficient fuel oil are also assessed. A savings of $216,000 / year through the use of ALANFO in one particular case study was recalculated to an increase in drilling and blasting costs of $188,000 when the external costs of aluminum, ammonium nitrate, and fuel oil are included analysis. The results of this analysis are intended to improve contractors? selection of explosives by providing additional societal and environmental factors into the equation, in preparation for an exponential global shift to greener business operations, while allowing them to remain competitive.

Jan 1, 2011

By Mick Fritz, Gregory Poole

Construction blasting is always challenging when in close proximity to existing structures, but when you are next to a landmark like Sanford Stadium at the University of Georgia it can get intense. Blasting on this project was performed less than 100 feet from students studying in their dorms at Reed Hall. Some shots are only a few feet from the columns on the stadium that hold up the sky boxes where meetings were being held while blasting was being performed. If a shot goes vertical the rocks would go through the floor of the sky boxes.

Jan 1, 2011

By P. N. Anyalebechi

"The as-cast microstructure of two commercial-size ingots of aluminum alloy 3004 produced by the electromagnetic casting process was quantitatively characterized. This involved the quantitative determination of through-thickness and across-width variations in dendrite cell size, grain size, macrosegregation of alloying elements, interparticle spacing, and the types, volume fractions, and sizes of the constituent or second phase particles. More than ninety-five percent of the constituent phases in the ingots consisted of the A16(Mn,Fe) phase; the desirable a-Al 12(Fe,Mn)3Si phase was not detected in any of the ingots by Guinier X-ray diffraction analyses or electron probe X-ray microanalyses. A significant microstructural heterogeneity through the thickness and across the width of both ingots was observed. For example, macrosegregation, and the sizes of the constituent phase particles, dendrite cells, and grains increased concomitantly from edge to mid-width and from surface to center of the ingots. There was a -20% depletion (negative macrosegregation) of Mg and a +54-87% enrichment (positive macrosegregation) of Ti in the center of the ingots. With the exception of grain size, there was no significant microstructural difference between the two ingots examined. The causes and practical implications of the observed microstructural heterogeneity in the ingots are discussed.IntroductionThe first step in the fabrication of majority of wrought products of aluminum and its alloys is the casting of large ingots or billets of simple shapes (round or rectangular). The sizes of the ingots vary from 10 mm to 450 mm diameter or 25 mm to 780 mm thick. The quality of the finished products is established at the ingot casting stage. This is because the microstructural characteristics, such as secondary dendrite cell size or arm spacing, amount of alloying elements retained in solid solution, macrosegregation, and the characteristics of second phases, produced during casting cannot be reversed by subsequent processing. Up until twenty-five years ago, the effect of as-cast microstructure of large ingots on the structure and behavior of thin sheets (0.34 mm thick) during drawing and ironing processes was incorrectly assumed to be minimal or nonexistent. This was based on the erroneous notion that the thermal treatments and large reduction (>99.94%) and strain that the ingot undergoes during production of the sheets completely destroys the original ingot structure and its inherent heterogeneity. However, the effects of ingot structure can, a priori, be deduced from the observed effects of constituent phase particle size, type and volume fraction on recrystallization, development of texture during annealing and deformation, and earing. In fact, careful examination of the behavior of products produced from different size ingots or castings have shown that the original microstructure of the ingot has a direct impact on the properties and performance of the end products."

Jan 1, 2011

By P. N. Anyalebechi

"The effects of solidification rate, initial melt hydrogen concentration, and grain refining on porosity formation in aluminum alloy 2024 have been investigated with unidirectionally cooled laboratory-size ingots. The ingots were prepared from melts containing hydrogen concentration of 0.059-0.27 cm3/100 g and solidified at 0.2-37 °C/s. As expected, the amount of porosity, average pore size, and pore number density increased with increase in melt hydrogen concentration and decrease in solidification rate. However, the effect of solidification rate was greater at the very low melt hydrogen concentration (0.059 cm3/100 g). These results are consistent with reported effects of solidification rate and melt hydrogen content on porosity formation in other aluminum alloys. Interestingly, addition of grain refiner slightly increased the amount of porosity and the average pore size, especially at solidification rates above 1°C/s. IntroductionIn shaped castings and wrought products fabricated from ingots, billets, bars, or slabs of aluminum and its alloys porosity formation is a problem. This is because it compromises their tensile strength, fracture toughness, and fatigue properties [ 1-18]. The pores are usually the crack initiation and propagation sites [6,8,9] and the largest pores tend to dictate the fatigue life of the aluminum products [9,10,14]. Porous regions within an aluminum product probably yield first due to the reduced tensile load bearing capacity, causing the concentration of the strain near the voids which subsequently results in premature fracture. In aluminum alloy ingots, billets, bars and slabs porosity formation is particularly problematic because of its persistence through fabrication and potential for reappearance or exacerbation during subsequent thermal treatment processes before and/or after fabrication [19]. In fact, persistence of microporosity is a serious problem in large thick plates of wrought aluminum alloy products that must be rolled from correspondingly large direct-chill or electromagnetic cast ingots. Some of these thick plate products are machined into large aircraft components that are required in service to withstand multi-directional stresses and to possess high fatigue strength, fracture toughness, resistance to stress corrosion cracking, and strength in the short-transverse direction [1,20]."

Jan 1, 2011

By Guan-zhou Qiu, Shui-shi Liu, Yu-feng Guo, Tao Jiang

"The preparation of high-quality synthetic ruitle from electric furnace titanium slag was systematically investigated by activation roasting followed by acid leaching process. The results showed that impurities such as Ca and Mg in titanium slag can be effectively removed and TiO2 grade of the product was markedly improved by the process. High-quality synthetic rutile containing 88.54% TiO2, 0.42% (CaO+MgO) was obtained under the conditions that roasted with 7.5%(wt) H3PO4 at 1000 oC for 2h, followed by two-stage leaching in boiling dilute sulfuric acid for 2h. Mechanism studies showed that anosovite solid solution and silicate minerals were reacted with phosphoric acid in the roasting process. As a result, titanium components in titanium slag turned into rutile (TiO2) and impurities were transformed into acid-soluble phosphate and quartz.IntroductionWith the gradual depletion of natural rutile and the rapid development of titanium industry in China, the natural rutile reserves cannot satisfy the requirement for production of titanium pigment and titanium sponge. Ilmenite is, therefore, becoming main raw material for titanium industry. However, because of its low TiO2 grade, it generally requires preconcentration to titanium-rich material such as titanium slag or synthetic rutile [1-3].Ilmenite resources are extremely rich in Pan-xi area of China, which account for 90.54% of total ilmenite reserves in China [4]. The titanium slag produced by electric smelting of ilmenite concentrate has high contents of Ca and Mg, and is not suitable as a raw material for chloride process and titanium sponge production. Therefore, upgrading titanium slag to prepare raw material suitable for chloride process and titanium sponge production has important significance for the development of China's titanium industry."

Jan 1, 2011

A major hazard to workers in underground mines is fire and the resulting contaminated air. Fire reaches miners thousands of yards away with carbon monoxide gas and other toxic fumes. The same ventilation system that furnishes fresh air to miners can also be the vehicle to carry contaminated air to remote locations. To reduce these problems, the U.S. Department of the Interior's Bureau of Mines entered into Contract H0242016, "Mine Shaft Fire and Smoke Protection System," with FMC Corporation, Santa Clara, California, to evaluate mine shaft fire and smoke hazards and to develop and demonstrate a low-cost, reliable mine shaft fire and smoke protection system that would be applicable to a majority of metal and nonmetal mine shafts, including raises and winzes, especially in deep mines.

Jan 1, 2011

By M. Dupuis

Recently, a new approach to controlling alumina feeding in a H.H. cell has been proposed [1, 2 and 3]. This approach, labeled In Situ aluminium cell control, is based on a correlation between the slope of the cell voltage during a no feed observation period and the dissolved alumina concentration in the bath. Once the dissolved alumina concentration has been estimated, a primary calibration surface uniquely relating the dissolved alumina concentration and the anode-cathode-distance (ACD) to the cell voltage is used to estimate the cell ACD. Once both the alumina concentration and the ACD have been estimated at the end of the observation period, a PID controller can be used to regulate the rate of alumina feeding using only the normalized cell voltage to calculate the error between the estimated dissolved alumina concentration and a target value. The In Situ aluminium cell control algorithm has now been tested with the Dyna/Marc [4, 5 and 6] cell simulator demonstrating that it should be possible to control a H.H. cell in this manner with less variation in the dissolved alumina concentration and other process variables producing a prediction of improved cell current efficiency and power efficiency.

Jan 1, 2011

By S. Slottee

The technology of making and using ?paste? from mine tailings is increasingly well known by the minerals industry. The primary applications are water recovery and ?stacking? of tailings with minimal use of dams and ponds. This paper highlights some applications, other than water recovery and stacking, that have come to the attention of a paste thickener equipment supplier. As generated by thickeners, paste (also called ?thickened tailings?) is a non-settling, relatively high concentration, suspension of solids that can be pumped. Paste deposits with an angle of repose, allowing minimal use of dams. High solids concentration allows more water recovery at the paste thickener than is achieved in conventional and high rate slurry tailings thickeners. This paper is based on paste as produced in a flow sheet that includes a thickener, underflow pumps that are typically centrifugal, transfer pumps that can be centrifugal or positive displacement, and a distribution system at the deposition site. Examples of paste applications other than water recovery or stacking include: ?mine? an existing tailings pond by removing slurry, recovering coal or iron ore values, and return the new tailings to the pond as a paste that does not res-suspend; use paste to seal an existing tailings pond from leaking to groundwater or to an underground mine; extend the life of an existing tailings pond by thickening the tailings to paste; move an existing dry tailings impoundment to a new location by slurrying, pumping, paste thickening, and redeposit; minimize the size of a filter by paste thickening the feed; operate a paste thickener and filter in parallel on a tailings stream with re-mixing to achieve a high solids concentration. The use of paste tailings technology has been expanding over the last 15 years. The applications, both implemented and under consideration, are increasingly diverse and include all minerals tailings. Tailings handling designers should always consider a paste option to the conventional slurry solution.

Jan 1, 2011

By S. Constantinides

Over the past 100 years we have witnessed a revolution in permanent magnetic materials. Prior to 1932 electrical machinery depended upon steels for both the soft and the permanent magnet structures. Because permanent magnet steels were easily demagnetized, motors, generators, loudspeakers and similar devices often used the interaction between two electromagnets. Motors and generators were mostly of the induction type, depending for function upon induced fields. The discovery of Alnico in 1931 and its rapid commercialization presaged an expansion of the industrial revolution and today, permanent magnet structures are widely utilized. [ ] DEVELOPMENT OF PERMANENT MAGNETS Act 1: Early Days of Permanent Magnets Alnico, which stands for aluminum, nickel and cobalt, is a family of alloys with similar structure and processing requirements. Additional elements, such as copper and titanium, are present in minor amounts to optimize magnetic properties. Alnico is known by many trade names around the world including Alcomax, Hycomax, Ticonal, Nipermag, Koerzit, Oerstit, Nialco, etc(1,2,3). In addition to the generic name ?alnico?, it is usually appended with a number representing the magnetic grade.

Jan 1, 2011

By Richard L. Bullock

Believe it or not, mine evaluation and feasibility studies are as old as the industry itself. In the first recorded writing on mining by Agricola (1556), he gave several clues as what to look for in evaluating a mine, to determine if it was economically feasible. Below is the guidance from Agricola, with my interpretation of what he would include today. Now a miner, before he begins to mine the orebodies must consider seven things, namely: ? The situation (the geography/topography). ? The conditions (the geologic/mineralogic and mining conditions). ? The water (availability, hydrology and ownership). ? The roads (plus the railroads, power lines, all other infrastructure). ? The climate (the weather-rainfall/environment). ? The right of ownership (the land and legal entitlement). ? The neighbors (the social environmental concerns of the area). It is amazing how much of his guidance has not changed in 455 years. Yet Agricola gives no guidance on determining the correct cost, or determining the correct commodity pricing. But he does give a few words of caution on the related ethics involved on buying mineral properties: ?A prudent owner, before he buys shares, ought to go to the mine and carefully examine the nature of the vein, for it is very important that he should be on his guard lest fraudulent sellers of shares should deceive him.? Three hundred years later (1866), to further amplify this point, in the most famous thing that Mark Twain never said, as an introduction to a lecturer to an audience of gold-miners at Red Dog, CA, the famed author/humorist allegedly described a mine as ?a hole in the ground owned by a liar? (Farrar & Rinehart, 1935). So, one might conclude that between these two dates, the mining industry did little to improve its reputation. Unfortunately, since Mark Twain allegedly made those remarks, we have not done near enough to gain accountability for the mineral industry.

Jan 1, 2011

By R. Dillinger

In the environmentally conscious social atmosphere today, reclamation in surface mines has become a main issue to the public and the regulatory committees. In response to this increased attention, many regulatory committees have begun to enact more stringent regulations on surface mining operations. Operations across all spectrums of the industry have seen changes. Recently and most visibly the mountain top removal mines have seen several new regulations focusing on environmental protection. Specifically regulatory committees have emphasized a focus on the methods of reclamation and recovery of layers suitable for vegetation. These layers are the most visible once the operation has concluded. Also, these layers have the most human interaction (farming, hunting, and house development). Often times the new regulations enacted are shifting from a performance base to a standards base. The key differentiator being a performance base dictates the final result while a standards base dictates the method to achieve the result. The very nature of many regulations (especially those that are standards based) not only challenges the physical limitations of the equipment used today, they come with a financial impact. For the purpose of this paper, the model will be a surface coal operation, utilizing draglines as primary overburden movers. The coal seam is ten feet thick, the overburden ninety five feet thick, the pits are 150 feet wide, and the dragline is a Bucyrus Erie 1570.

Jan 1, 2011

By Run Huang, Xuewei Lv, Lei Lei, Guibao Qiu, Chenguang Bai

"The TiO2-rich slag and pig iron can be produced from ilmenite concentrate by the electric furnace process. In this study, ilmenite concentrate was reduced in a vertical furnace equipped with a weighting data acquisition system. The effects of reducing agent (carbon) amount on the iron reduction were studied. The phase transformation, morphology and chemical compositions of reduced samples were investigated by X-ray diffractometry (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS), respectively. It was found that the reductive degree of ilmenite concentrate increased with the increase of reducing time. The phases of reduced samples were mostly iron, rutile, Ti3O5 and Fe2TiO5. The mass loss percentage increased with increasing the carbon amount from 8% to 12%. When the carbon amount exceeded 12%, the mass loss percentage decreased with the increasing of carbon amount.IntroductionIlmenite and rutile are the main raw materials for producing titania pigment and titanium metal. With the development of the titanium industry, huge amounts of titanium resources are needed. As sources of high-grade titania mineral decrease worldwide, more attention should be paid to the processes involving low grade mineral such as ilmenite ore. In ilmenite, MgO and CaO are the gangue parts. Therefore, the ilmenite refining becomes more and more popular. In the previous studies, the methods of ilmenite refining are electric furnace smelting, direct acid leaching, selective chlorination and thermal reduction [1]. Electric furnace smelting method is widely used in the titanium industry, however, which consumes a great deal of energies and has a high CO2 emission. Its essence is to remove iron oxides and obtain a high titania slag. So the thermal reduction of ilmenite concentrate is an important step in titanium industry, which can decrease carbon reagent consumption and save energy.Over the past several decades, many studies have been carried out on the mechanism and kinetics of the reduction of different ilmenite ores, which are as follows: The carbothermal reduction of Panzhihua ilmenite initiated at about 860 oC. In the temperatures ranging from 900 oC to 1400 oC, the reaction rate was changed like a shape of “M”. That was to say that the reaction rate increased with the growth of temperature at first, then decreased, afterward increased again and at last the reaction was arrested [2]. The Mohammad A.R group [3, 4] showed that the carbothermal reduction of primary ilmenite concentrate was faster in hydrogen and initiated at a lower reduced temperature than in argon and helium. The reduction in argon and helium had about the same rate and extent. Titanium oxycarbide started at 1000°C in hydrogen. The conversion of primary ilmenite concentrate to metallic iron and titanium oxycarbide at 1200 °C was completed in 300 minutes. Monoxide as the reductant to reduce ilmenite had been studied intensively by a few research groups [5, 6]. The rate and the degree of reduction depended on the formation of a metallic shell of iron which inhibited the transfer of CO to the reaction zones; titanium had a strong effect on the mechanism and rate of reduction of iron oxides. Wang and Yuan [7] studied the reductive kinetics of the reaction between a natural ilmenite and carbon. At temperature below 1100°C, chemical reaction was the rate controlling step, at 1100 to 1250°C mixed controlling was rate controlling step, above 1250°C diffusion through the product layer controlled the reaction. Zhang [8] investigated the reduction of natural, sintered and preoxidized ilmenite concentrates in hydrogen methane mixtures. Preoxidation and sintering of ilmenite concentrates changed their phase composition and caused a sharp decrease in specific surface area of raw materials and an increase in carburization temperature. Sintering also increased the metallization temperature of iron."

Jan 1, 2011

By E. Carvajal I

Large diesel engines provide the mining industry the substantial power and torque needed to move large amounts of material efficiently. But the stresses generated by such power and torque necessitate complex maintenance programs to ensure the utmost operating capabilities are not compromised. Of all its available sensors, the Exhaust Temperature differential between the right and left banks can provide the most valuable indicator of the overall operating condition and potential degradation of a large diesel engine. BHP Billiton Escondida Mining has implemented real-time remote monitoring, diagnostics, reporting, and tracking of Exhaust Temperature differential using Modular® technology. As a result of the processes and procedures put into place surrounding their MineCare maintenance management system, Escondida has proactively replaced over 300 injectors, resulting in an increase of 4% in Engine availability.

Jan 1, 2011

By Ahmad-Bitar¸ Riyad N., Shadia J. Ikhmayies

"CdSi-xTex thin films with O<x<0.3 were prepared on glass substrates by the annealing of CdS:In thin films produced by the spray pyrolysis technique. The annealing was performed in nitrogen atmosphere at 400 --,C in the presence of Te vapor. The compositions of the films were determined by energy dispersive X-ray detection (EDAX) measurements. Scanning electron microscopy (SEM) was used to investigate the morphology of the films. The transmittance of the films was measured at room temperature in the wavelength range 400-1100 nm and used to produce the absorbance of the films. The first derivative of the absorbance was used to estimate the optical bandgap energy Eg by using the minima in the first derivative. The relation between the bandgap energy and the fraction x was found to fit with a parabola and bandgaps in the range 2.196: =Eg: =2.480 e V were obtained. Urbach tailing in the bandgap was also investigated.IntroductionPolycrystalline thin film CdS/CdTe solar cells are promising candidates for low cost and high efficiency photovoltaic applications. The fabrication process of these cells involves the deposition of a p-type CdTe absorber layer on top of an n-type CdS one which acts as a window. The efficiency of the solar cell is affected by the method of preparation of both layers [1, 2].Interdiffusion processes taking place at the CdS/CdTe interface have largely been realized to significantly affect the device performance [3] by changing the bandgap of both CdTe and CdS which modifies the spectral response of the solar cell [ 4]. The formation of a mixed crystal or a graded layer causes a reduction in the lattice mismatch at the CdS/CdTe junction [5] which is about 9% [ 6] and then a reduction in the number of interfacial states and recombination centers, thus enhancing the solar cell performance [7, 8]. A complete understanding of the properties of the intermixed layers CdSxTe1-x that usually constitutes the interfacial region in the CdS/CdTe solar cell is essential. According to our knowledge, a lot of research was devoted to the investigation of the diffusion of S into CdTe [3-5, 9]; but little on the direct investigation of the diffusion of Te into CdS [6]."

Jan 1, 2011

By Adriana de Aquino Soeiro da Silva, Joao Alves Sampaioa, Luiz Carlos Bertolino, Francisco Manoel Garrido, Marta Eloisa Medeiros

"Brazil has a large agricultural potential and its production success is related to the chemicaland physical soil characteristics. Therefore, the demand in the use of a great quantity offertilizers to compensate the low amount of nutrients in the soil includes about 40% of foodproduction costs. In order to develop economical alternatives to traditional fertilizers, rockswith potential use in agriculture will be studied. In this work the potassium rock, a greensandslate, will be chemically and structurally characterized for the development of a potassiumthermophosphate. This alternative fertilizer will be obtained based on a fusion of a ponderedmixture of potassium, magnesium and phosphate rocks to be applied in the Brazilianagriculture. Preliminary characterization results indicate that the greensand slate presents ahigh percentage of glauconite, quartz and micas.Keywords: Potassium thermophosphate, alternative fertilizers, greensand slate.IntroductionBrazil has a great agricultural potential and its production success is closely related to thesoil's chemical and physical characteristics. However, the country's soils present lownutrients content and high acidity due to weather conditions. Thus, the use of a high amountof fertilizers makes up for the soils' lack of nutrients and accounts for 40% of food productioncosts. Therefore, research on obtaining new alternative fertilizers is a constant worry due tothe increase on food demand [ 1].The lack of raw material for the preparation of NPK fertilizers in Brazil is a concern and theissue of potassium fertilizers a priority. Such a fact is because in 2008 only 608.000 tons ofKCl were produced, corresponding to just 10% of the Brazilian necessity. Thus, the use ofrocks as agricultural nutrients can contribute to reduce the need for industrial fertilizers.This way, the development of a new agricultural raw material originated from a rock thatalready exists in the country's soil is of great importance for the mineral and agriculturalsectors."

Jan 1, 2011

By R. Strandahl

As one of the largest private utilities globally, E.ON currently operates hard coal fired power stations in with a total installed capacity of some 20.000 MW: These thermal power plants consume domestic coals but are increasingly dependent on imported seaborne traded coal (in 2009 approx. 17 million t). Knowing that the company’s reputation and credibility depends in part on how E.ON lives up to the responsibilities along the entire energy value chain, E.ON takes a collaborative approach with the various suppliers. Hence, E.ON’s responsible policy also applies to the procurement of coal; the utility launched in 2009 a comprehensive Corporate Responsibility program with special focus on supply-chain audits. One of the first coal audits focussed on the Cerrejón coal mine in North Eastern Colombia. The authors will share the key learning’s and experience from the Colombian audit jointly conducted with an independent auditor and E.ON experts from the Corporate CR and E.ON Energy Trading.

Jan 1, 2011

By U. Paschedag, H. Bussmann

"Bucyrus manufactures the most comprehensive product portfolio of mining equipment worldwide. Its mission is to have a positive, lasting effect on our world. Bucyrus makes sustainable development a fundamental way of doing business through economic, environmental and social initiatives that support, educate and benefit our employees, customers, shareholders and other stakeholders. Our participation in GRI (Global Reporting Initiative), a network-based organization that has pioneered the most popular sustainability reporting framework will be discussed as well as examples will be given on each major field of engagement. Two examples from surface machinery are most fuel efficient haul trucks as well as the Highwall mining system which allows access to coal reserves which are lost not making use of this kind of system. Two examples from underground machinery are Bucyrus’ automated plow systems for the mining of medium and thin coal seams with minimum rock and Bucyrus’ intelligent CST drive system for high-powered armored face conveyors (AFCs) for efficient use of energy."

Jan 1, 2011

By M. M. Valenta

A number of challenges face platinum concentrator plant operators. These challenges include the increase in operating costs, the increase in smelter cost for the processing of concentrate, the shortage and cost of power, and the tightening of specifications on concentrate quality by the toll-smelting operations. Over the years the focus has moved from extracting the platinum group metals (PGM) from the Merensky Reef to the UG2 reef. This has a number of advantages, including the higher ?basket price? for UG2 concentrate, reduced mining cost per unit volume as a result of the higher density of UG2, and the reduction in overall concentrate tonnage to be smelted. In many cases the Merensky ore has been fully exploited and it makes sense for the focus to shift to the UG2 ore that can be accessed through the Merensky shaft infrastructure. The presence of relatively high levels of chromite in UG2 concentrate is, however, a major disadvantage due to the problems associated with smelting such a concentrate in conventional submerged arc furnaces. In addition to increasing the specification on the minimum PGM grade of concentrates, smelters have had to impose strict specifications on the levels of chromite in the concentrate. The threat of high penalties has forced concentrators to change their modus operandi, often resulting in a significant loss in recovery. The final concentrate grades and PGM recoveries are shown to vary significantly throughout the industry. The reasons for this include varying ore mineralogy and different operating philosophies. This would therefore imply that the opportunity exists to optimize the operations by considering fundamental aspects such as the PGM mineralogy and the application of appropriate technologies. By returning to the fundamentals of flotation and applying the findings of detailed process reviews, it has been possible to increase the concentrate PGM grade, reduce the concentrate chromite grade, and in some cases increase the recovery of PGM to concentrate. This paper presents case studies where this approach has been used to successfully optimize concentrator performance, resulting in lower operating cost and higher PGM production. Keywords Process optimization, platinum concentrator, milling, flotation, grade, recovery

Jan 1, 2011

By Jim Sarvinis, Rory Hynes, Elizabet Cruz, Kerry McKenna, Maytinee Vatanakul

"Energy efficiency improvements achieved using heat recovery processes offer benefits to both the business case and environmental impact of metallurgical facilities. Global demand drives the development of lower and lower grade ore bodies. This trend results in higher energy intensity and consequently increased waste heat. Waste heat boilers and Organic Rankine Cycle (ORC) processes are becoming cost competitive methods of utilizing this waste heat.This study analyzes heat recovery from available sources to produce power using, • High grade: waste heat boiler and steam turbine generator. This system will produce electricity, and/or process steam.• Low grade: ORC to produce electricity. The cycle is well adapted to low- moderate temperature heat sources.Processes used in metallurgical plants, such as hot exhaust streams, cooling and condensers could benefit from application of these systems.The study demonstrates:• The energy and cost saving potential of waste heat recovery technologies,• The environmental benefit.IntroductionIn recent decades, process intensification has resulted in increased productivity from unit operations such as kilns, fluidized bed reactors and smelting furnaces and decreased unit operating costs. In the coming decades, the industry’s challenge will be to continue this trend while at the same time decreasing the consumption of fossil fuels and further reducing the environmental impact of its processes.The U.S. Department of Energy reports that available waste heat sources in industry, which is approximately seven quadrillion BTU (~7,400 PJ/y), exceeds the current production of all renewable power sources combined. In Canada there are about 2,300 PJ/y of available waste heat, with the pulp and paper, metallurgy, chemical/petrochemical and oil refining industries the main players. Natural Resources Canada (NRCan)9 has estimated that about 25% of that heat could be recoverable using existing technologies, which in turn, represents a reduction of 27 Mt/y of Green House Gas (GHG) emissions, plus considerable water savings due to lower water cooling requirements and less fossil fuel consumption."

Jan 1, 2011