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By L Grigorov, G J. Jame, A V. Nguyen

The dewetting kinetics between a small air-liquid interface and a silica (negatively charged in water) planar surface in solutions of dodecylammonium chloride (cationic surfactant) has been investigated using the Scheludko cell and digital high-speed video microscopy. The gas-liquid interface was created at the bottom of a small silica capillary of the cell and then was moved towards the silica planar surface. After the rupture of the liquid films between the interfaces, the expansion of the gas-liquid-solid three-phase contact (TPC) line was observed and recorded using a digital high-speed video microscope system, operating at 1000 frames per second. The surface tension of the surfactant solution was measured using the pendant drop technique. The equilibrium contact angle was measured using the Scheludko-Minings method with a silica micro-sphere. The TPC radius was determined as a function of time and compared against the available hydrodynamic and molecular-kinetic models. The experimental data are described very well by the molecular-kinetic model for the TPC line motion. The hydrodynamic model is in agreement with the experimental data only for a short time after inception of the three-phase contact expansion.

Jan 1, 2005

By H. K. Work, G. H. Enzian

In the manufacture of steel for commercial purposes, the deoxidation practice used, i.e., the method and degree of deoxidation, is an important factor affecting the structure and mechanical properties of the finished steel. Deoxidation practice exerts a pronounced influence not only on the soundness of the ingots but also on the reaction of the steel to a number of mechanical and thermal treatments. The first mentioned effect of deoxidation is more or less obvious and was first demonstrated, though perhaps not fully appreciated, by Robert Mushet when, in 1856, he added speigeleisen to low-carbon bessemer blown metal. In 1861. Bessemer patented the addition of one pound per ton of silicon to his blown metal to "cause the metal to lie quietly in the mold." The second effect of deoxidation-—that is, the effect on the properties and behavior of the steel—is, one might say, more subtle, and certainly not as well understood as the first, although in many cases it is the more important consideration. This paper is limited to a discussion of only the second effect of deoxidation and: in particular, to the effect on the strain-sensitivity of low-carbon steels. General Discussion Originally it was thought that the function of a deoxidizer was to combine with the oxygen present in the steel as iron oxide and prevent its subsequent evolution as a gas. -More recently it has been realized that a deoxidizer does more than this. Frequent reference has been made to the effect of deoxidizers on the nitrogen in the steel, and some attention has also been paid to hydrogen. As a consequence of the above situation any study of deoxidation must be concerned with the gas content of the steel and the effect of the deoxidizer on the gases involved. The term "gas content" as used here refers to gases extracted from steel during melting in vacuum rather than to elements present in steel in the gaseous state. The extracted gases, at least in the case of oxygen and nitrogen, are generally accepted to be products of decomposition of oxides, nitrides, or other more complex compounds. The manner in which deoxidation affects the gas content of steel and the significance of gases in steel have been and still are subjects of considerable speculation. No attempt will be made here to give a complete discussion of the literature on this subject but a few references will be cited for purposes of illustration. N. Hamilton1 found a correlation between the oxygen content of alloy steel and the behavior of the steel during tube piercing. Davenport, Bain, and others associated oxygen with aging properties of steel while Köster5 and a number of others6-lo made similar claims for nitrogen. Daniloff, Mehl, and Hertyll stated that "deoxidation decreases the susceptibility of steels to aging directly

Jan 1, 1945

By Michael Tenenbaum, C. C. Brown

Numerous investigatiolls have been carried out to determine the total oxygen present in the basic open-hearth bath and the results of these studies have clearly defined the factors controlling the bath oxidation during the period prior to deoxidation. On the other hand, very little is known concerning any changes in total oxygen content that may occur during deoxidation, tapping and teeming. The need for such additional data is continually becoming more apparent, since there is no strict technical basis for selecting any particular deoxidation practice. Many steels are made for the same purposes and to the same chemical analyses by widely differing practices. Apparently, each practice is satisfactory. However, it would be desirable to establish more definitely the effects and relative merits of the individual practices. Such information could be used to give a definite foundation for evaluating various types of deoxidation. In order to approach this problem, a study was made of the changes effected in the total oxygen content of several grades of steel by representative open-hearth deoxidation practices. To carry out such studies, it was necessary that a reliable testing procedure for determining the oxygen content of the steel bath and the ingot mold be established. Before entering on any extensive testing program, consideration was given to the available methods of obtaining steel samples and analyzing for oxygen. Testing Procedures It has been shown5-9 that in solidified steel oxygen may ekist in combination with iron, manganese, silicon, aluminum, titanium, chromium and carbon, depending upon the amount of these elements in the sample. In molten steel, however, there has been no direct distinction of the various oxides. Accordingly, the total active oxygen in the molten steel bath is designated by the symbol 0. During deoxidation, various oxides may be present either in solution in the molten steel or as solid or liquid inclusions. Any sample taken from the molten steel for oxygen analysis will include both the dissolved and the mechanically included oxygen. Similarly, samples of the solid steel product will also include the two forms of Oxygen' Methods of Samplirzg the Molten Steel Bath In order to obtain a true oxygen analysis from liquid steel, this element must be completely retained in the solidified sample. Several methods have been proposed whereby this stabilization can be effected. As early as 1915, Kichlinelo proposed a method for testing molten steel, in which the oxygen combined with some added aluminum. The concentration of the resultant aluminum oxide was determined by chemical analysis. This method was

Jan 1, 1945

Perhaps the most significant development in China's base metal sector is the discovery of major copper porphyries in northern Jiangxi Province and the adjacent southern Anhui Province. At the center of the new exciting district is the proposed Dexing copper complex, located some 350 km east of Nanchang, the provincial capital of Jiangxi. This project represents China's first attempt to put together a major large-scale open-pit operation, comparable in magnitude to Arizona porphyry operations. With the aid of Fluor Mining and Metals, the Chinese plan to develop a 135-175 kt/d open-pit mine, a matching large-scale mill, and the infrastructure needed to accommodate the big operations. An operation of this magnitude would significantly reduce China's import requirements by some 75%. China imports of the red metal are running around 200 kt/a. Under the direction of the Ministry of Metallurgical Industry, the Chinese are currently operating a 10-kt/d mine and mill with equipment primarily of Chinese origin. Dexing engineers told ME that they are considering a possible scale-up to 20 kt/d. How this effort will ultimately jell with the major expansion program is largely a matter of conjecture. Fluor Mining and Metals received a $10-million contract in December 1978 to develop a preliminary engineering and design program. While the original plans called for a 175-kt/d capacity complex, the Chinese subsequently decided to scale it down somewhat. The current proposal is around a 135 kt/d, which would in- elude the existing operation, according to Dexing engineers. Completion of the engineering and design phase is expected by March 1980 and a go-ahead decision will likely be made at that time. The value of the engineering and construction contract is estimated between $800 million and $1 billion. At right, mined ore is dumped 150 m down the mountain to a holding pocket below for rail haulage to the processing plant. Below, a Chinese miner tackles the universal problem of hard toes in the pit with a jack leg. Reserves and Early History The Dexing mineralization consists of three principal ore bodies, including the Chushahung on the north mountain, and the Tungchang and Fuchiawu on the south mountain. Combined ore reserves are estimated by mine geologists at 1.7 Gt of 0.4-0.5% copper. As is characteristic of porphyries, the ore contains important associated values of molybdenum, rhenium, pyrite, gold, and silver. There is also some secondary calcocite and bornite with an oxidized capping. Historically, copper was recovered with iron from the pregnant solutions emanating from the Tungchang deposit as early as the Tang Dynasty (700 AD). Modern day exploration was conducted by the Bureau of Geology in 1956 and reserve figures were es-

Jan 3, 1980

By A. Mehinrad, F. Rafia

"The Dez River flows from the Zagros Mountains into the great Khuzestan plain, Southwest of Iran. The 203 m high Dez Dam is a double curvature thin concrete arch dam, with a Pulvino, founded on thick bedded to massive conglomerate of Bakhtiary Formation, mainly horizontal and very less jointed at the dam site. Construction work was completed in 1963, creating a reservoir with a total storage volume of 3’315 million m3. The dam body, with some 350’000 m3 volume and (W/H=1.1/1.0), is the dominant feature of the project.Geological and geotechnical studies at the dam site started in 1957 and continued during the whole period of dam construction. Simultaneously, two extensive programs of laboratory testing were carried out in New York and Milan.Most of the results were recorded in the project design documents and in two very well-known papers of Talobre et. al. (1964) and Dodds (1966), however, no detail results are available for most of tests.In order to estimate geomechanical parameters of the rock mass foundation for numerical modeling of the dam body and its foundation, reassessment of the in-situ and laboratory test results using the recent rock mechanics methods was required.This paper explains how the outcomes of those tests, performed more than 50 years ago, were reevaluated and how the definitions and parameters presented in the project reports were re-interpreted using the recent rock mechanics concepts and definitions. Also, the results of classification of Bakhtiary conglomerate using GSI system and application of Hoek & Brown failure criterion for estimating rock mass parameters have been described.INTRODUCTIONThe Dez River flows from its headwaters in the Zagros Mountains into the great Khuzestan plain. Just before entering the plane, the river passes through a narrow, steep gorge that is about 17 km long. The Dez Dam is located at the entrance to this gorge, some25-km upstream of the city of Dezful and 150-km upstream from the provincial capital Ahwaz (Figure 1)."

Jan 1, 2015

By M. M. C. Lima, L. C. S. Solimani, M. A. Quintela

Galvanized steel scrap is recycled to B OF converters where zinc escapes from the bath and is captured by the gas control system, appearing in BOF sludge. As BOF sludge contain high iron content, it could be recycled, but due to its zinc content, it is disposed in landfills. In this study techniques were evaluated for zinc layer removal from scrap by sulfuric acid leaching. The effects of coating weight, temperature, time and sulfuric acid concentration were evaluated for three different galvanized scrap. The results showed that the behavior of each galvanized scrap was different. Nevertheless zinc removal efficiency was more than 80% with low dissolved iron in the leached solution.

Jan 1, 2011

By F. G. Prado

The technology for the extraction of zinc from zinc residues, such as zinc ashes, drosses and metallurgical flue dusts, by way of ammonium chloride solutions is well established, at least at the laboratory and bench scale levels. (3, 4) Zinc is soluble in ammonium chloride solutions in the form of zinc diammine chloride. Its solubility depends upon the concentrations and temperatures employed. The procedure and the equipment required are simple, and they can be applied either to small or large operations. As a by-product, zinc diammine chloride is produced with extremely low impurities in quantities which are stoichiometrically proportional to the zinc removed. The technology has been applied experimentally to galvanized steel residues. The dezincing results, including removal performance, energy and reagents required, and by-products are summarily presented in this paper.

Jan 1, 1992

By J. Grogan

Leaching of galvanized steel coatings allows the steel substrate to be used as a zinc-free scrap source to steel and iron furnaces. In this study the behaviors of sulfuric acid leaching solutions are investigated. The ranked significance of the variables are shown to be acid concentration > temperature > zinc concentration. Examination of the leaching mechanism finds the rate-limiting step to be the cathodic hydrogen reduction reaction. This rate is not only influenced by acid concentration, but also by the hydrogen reduction exchange current density. Dezincing leaching rates are improved by taking advantage of the higher exchange current density of the iron substrate versus the zinc coating. This is accomplished in practice by increasing the exposed interfacial zinc:iron surface area through shredding. Also, a leach control mechanism is proposed through online monitoring of the zinc-iron couple mixed potential.

By A. V. Tarasov

The proposed process is based on creating a controlled frothed layer of molten slag, in which fine particles of carbonaceous reductant and raw material to be processed are mixed with emulsified iron. Frothing of the slag layer without external blowing occurs as a result of intensive evolution of gaseous reduction products. The froth reaction process is maintained due to the heat of an electric arc in the slag layer. When the metal bath is heated by the arc to 1400- 1 500°C, the low temperature of the slag surface of about 1200-1 300°C is maintained due to low thermal conductivity of slag froth preventing heat loss. In order to maintain the required slag froth level and control the process temperature, air tuyeres are installed above the slag bath; blowing air serves also for oxidation of zinc in fumes and for its transportation. High adsorption and thermal insulating properties of slag froth ensure virtually complete elimination of dust and mist entrainment along with low heat losses. The main macrokinetic regularities of the carbon thermal reduction of zinc-containing slag melts have been studied under frothing conditions. The mechanism of formation of gas-slag emulsion has been identified under the conditions of reaction [C]+[O]=CO occurring locally at the slag-metal interface. It has been demonstrated that under the froth reduction conditions the zinc removal rate from the melt increases on the average by 3 to 5 times. Based on the physical and chemical data obtained, basic principles of the dezincing technology have been developed for different intermediate oxide iron-containing products produced in the process of ferrous and non-ferrous metals production.

Jan 1, 2002

Jan 1, 1992

Jan 1, 1987

By Alice Arana, David M. Cacoilo, Joel L. Volterra

"To make space for the new South Ferry Station in lower Manhattan, engineers and contractors carved out a new tunnel beneath three operating subway tunnels and tangentially to yet another tunnel. Creating the space required the design and construction of complex temporary excavation support and underpinning systems and the design and installation of real-time monitoring systems. Construction for the new station and tunnel was mainly cut-and cover in a mixed-face area of soil and rock approximately 2,000 linear ft long, 60 ft wide and up to 70 ft deep. Close coordination between the design/build team and the project owner, the Metropolitan Transportation Authority (MTA), was critical.With the construction of this $400 million project, the MTA and New York City Transit (NYCT) are correcting the numerous physical and operational deficiencies of the existing station and improving the lives of millions of commuters. Built in 1905, the original South Ferry Station is on the IRT Broadway–Seventh Avenue Line of the New York City Subway and is the southern terminal of the #1 subway service, which forms a loop to return uptown. The station has a sharply curved single platform on the outside of the outer track of a two track loop. This platform is short and does not allow the rear five cars of a normal 10-car subway train to load or unload. In addition, once the train stops at the station, commuters wait while retractable floor grates bridge the gap created between the platform and the subway car doors, and then they have only one exit from the station. Spray nozzles keep the tracks lubricated to reduce the train wheels’ friction caused by the tight curve. The sharp curvature of the loop and the inability to use half of the subway car doors slow train operation. With the new ADA-accessible station, 10-car trains will be able to open all doors, and additional entrances, escalators and elevators will greatly reduce travel times."

Jan 1, 2008

By Bernard H. Hertlein

"When the Deep Foundations Institute (DFI) was founded, quality assurance and quality control (QA/QC) of foundation construction was rudimentary. Nondestructive testing (NDT) was a nascent technology, known to very few people, and very limited in its capabilities and applications. In the four decades since the DFI became a reality, NDT researchers and practitioners have taken advantage of technological advances to improve those existing testing and analysis techniques, and to create new ones that have all contributed to the engineering body of knowledge. This has enabled contractors to improve the quality and reliability of their products, and engineers to design more efficient foundations.Through its regular series of seminars, publications and annual meetings, the DFI has been vitally important in educating the deep foundations industry about the capabilities and benefits of NDT methods. In turn, NDT results have helped the industry identify problems in deep foundation construction, determine the causes of those problems, and improve design constructability and construction practices to increase the quality, reliability and efficiency of all types of deep foundations. This presentation reviews the evolution of several important NDT methods, and the contributions that they have made to foundation quality.THE BEGINNINGSThe Deep Foundations Institute (DFI) was incorporated in 1976 in the State of New Jersey as a 501(c)(6) non-profit association. The DFI is a consensus organization of Contractors, Engineers, Owners and Suppliers involved with the design and construction of all types of deep foundations. The purpose of the DFI was and still is to improve the planning, design and construction of deep foundations by educating all those involved, sharing best practices, and promoting the adoption of new technologies that improve quality, productivity or safety.This is well expressed in the current DFI Mission Statement: To bring together multi-disciplined individuals and organizations to find common ground and create a shared vision and a consensus voice for continual advancement in the deep foundations industry.At the time the DFI was born, nondestructive testing for verifying the quality and integrity of deep foundations was in its infancy, its growth constrained by the technology, or lack thereof. Some visionary engineers of the time understood the physics of the potential methods, and therefore the possible capabilities, but were frustrated by the lack of technology to work with. Electronic equipment was mostly analog, and the few digital data acquisition systems that were available had such slow sampling rates that they were incapable of recording rapid event sequences or short duration events such as those used in modern integrity tests. For example, Jean Paquet, a leading research engineer at the French National Construction Institute, (Centre Experimentale de Recherche et d’Etudes du Batiment et des Travaux Publics, or CEBTP) patented the frequency-based analysis procedure for the Transient Dynamic Response (TDR) method, aka Sonic Mobility or Impulse Response, in 1974, but it was not until 1977 that analog data acquisition systems became fast enough to turn his theory into a reality."

Jan 1, 2017

By Derrick Dasenbrock

Two DFI committees independently organized two complimentary panel sessions for the recent American Society of Civil Engineers' (ASCE) Geo- Risk 2023 "Advances in Theory and Innovation in Practice" Conference in Arlington, Virginia, July 23-26. The Geo- Institute (GI) specialty conference welcomed more than 200 professionals and students interested in risk from around the world to the Washington, D.C., area for three full days of plenary keynote lectures, papers and no-paper sessions. The GI Risk Assessment and Management Technical Committee organized the event, which is the third in a series planned on a 6-year cycle. The previous two events were in 2011 in Atlanta and 2017 in Denver.

Sep 1, 2023

By Rob van Dorp

"AbstractThe Monitoring & Instrumentation Committee (MIC) of DFI Europe has the objective to support DFI members in concern of risk management of geotechnical matters, where monitoring and instrumentation have added value.Work of the CommitteeA study by the committee showed that there are already several existing (national) guidelines. They all have their strengths and limitations and their focus may vary a little per country due to local regulations and typical local building activities, but the main question remains what added value another new guideline would have. More likely it would add to the confusion instead of providing overview.Companies with larger experience in geotechnical monitoring (often larger consultancy firm, contractors or clients) are already quite familiar with its benefits do not really need a new guideline in how to design and effectively apply sophisticated geotechnical monitoring systems for special projects.Therefore the aim of the MIC is to focus a little more towards smaller organizations - that are less familiar with monitoring and instrumentation - and the more ‘regular’ type of project that they are mainly involved in. The MIC wants to create a tool which helps them to create risk awareness, to understand the benefits of geotechnical monitoring and to provide them information about how and where to find the right partners and equipment to setup and apply appropriate monitoring systems for their projects.Monitoring and instrumentation benefits are for example:• Risk control during construction stage;• Costs reduction in design and construction (taken limitation of geotechnical aspects into account).• Prevent of unnecessary delays in construction work• Increasing general awareness of geotechnical risks and possibilities of monitoring.The cost of monitoring compared to the cost of failure and/or the savings that can be achieved play a role in the work of the committee. DFI members benefit from the shared knowledge by the MIC on monitoring and instrumentation within their process of risk management."

Jan 1, 2014

Jan 1, 1988

By Andy Boeckmann

In early 2021, DFI formed a Foundation Reuse Task Force due to concurrent and coincidental discussions of this topic during meetings of the Subsurface Char- acterization for Deep Foundations and Testing and Evaluation committees. Interested members from both commit- tees, as well as of the Sustainability Com- mittee, joined forces to form the task force. The task force mission is to promote foundation reuse by leveraging experi- ence among DFI members and collabo- rating across pertinent committees. General goals of the task force are to identify, assess and reduce risks associated with reuse; to educate owners and decision-makers about reuse; and to improve the investigation, design, construction and testing practices associated with reuse. One of the first orders of business for the task force was to organize a roundtable discussion of foundation reuse for DFI's 46th Annual Conference on Deep Foundations in Las Vegas. Last fall's discussion was framed as a continuation of the successful "Horses for Courses" session of SuperPile '21, which also focused on foundation reuse. However, whereas the SuperPile session focused on technical content, the annual conference panel on October 13, 2021, was envisioned as a less technical conversation that emphasized audience participation while addressing approaches to decisions about foundation reuse issues. The roundtable consisted of five panelists: • • • Bryan Hartnagel, Ph.D., state bridge engineer, Missouri DOT (MODOT) Tom Bradley, project director, Stanhope, London Hilary Shields, senior geotechnical engineer, Arup, London Jim Mackey, vice president/chief marketing officer, McGee Group, London Susan White, attorney, Benesch, Cleveland The roundtable was moderated by Andy Boeckmann, Ph.D., P.E., a senior engineer who works in Dan Brown and Associates' Missouri and Illinois offices, and is an article co-author.

Feb 1, 2022

By Manjeet Chowdhry, Qingxia Liu, Phillip Choi, Zhenghe Xu

Computational chemistry methods, such as density functional theory (DFT), are powerful tools to quantify reagent-mineral interactions encountered in sulphide mineral flotation. A quantitative relationship between theoretically calculated parameters based on chemical structure of collectors and their reactivity with different metals/minerals can provide valuable insights for design and development of more powerful and tailor-made reagents offering enhanced metal/mineral selectivity. DFT calculations at B3LYP/6-311++G(3df,3pd) level were employed to elucidate the reactivity of neutral sulphide collector reagents, including thionocarbamates (TC), thioureas (TU), xanthogen-formates (XF), dialkyldithiocarbamates (DTC) and dialkyltrithiocarbonates (TTC) with different heavy metal ions (Cu2+, Zn2+ and Pb2+) in solution. The extent of delocalization of lone pair electrons of heteroatoms (attached directly to C in C=S) over C=S group was found to be the dominant factor in determining the collector’s reactivity. Order of reactivity was established as: TU > TC > XF > DTC > TTC. All the collectors showed superior affinity towards copper followed by lead. Unidentate binding was observed through sulphur atom except for xanthogen-formate for which bidentate binding mode was observed. Effect of nature of substituent groups at N and/or O atom on reactivity of thionocarbamate and thiourea was also investigated. The results obtained through DFT calculations are consistent with the experimental data reported in literature.

Jan 1, 2015

By Gregory Molinda

Historically, coal miners have known that roof shales can deteriorate in contact with humid mine air, causing massive roof falls and injuries from falling rock. It is critical to recognize rocks prone to weathering and to adequately support these rocks in order to ensure the long-term stability of the openings. In a recent study, NIOSH has used a wet/dry cycling test to determine the moisture sensitivity of over 800 specimens of roof rock from 25 U.S. coal mines. Fireclays and some gray shales are the most moisture-sensitive. Rocks with disturbed bedding, in contrast to flat-bedded rocks, are also more sensitive to water. Black shales are relatively un-reactive to moisture and serve to protect more reactive gray shales above. Mines that have roof rocks with moisture-sensitivity indexes above 40% can experience slaking roof conditions, and many require high coverage surface controls. Three case studies are presented in which the moisture-sensitivity index is correlated to roof conditions underground, and can be used to indicate long term deterioration. Engineering measures are described to control moisture-sensitive roof. In one case, roof screen not only reduces injuries from rock fall but also is shown to reduce roof falls. Keywords: coal mining, roof control, slaking, roof support, rock falls

Jan 1, 2008

By H. R. Manouchehri

The importance of the grinding environment and its effect on sulphide minerals flotation behavior has been known for many years. The grinding environment may play a role in controlling fine and coarse particle flotation along with dissociation of different chemical species in grinding environment. Dissociation of different chemical species and ions within the process water may result from changing the grinding environment. The mining and mineral processing industry undertakes activities that may impact on water resources. These include use and storage of chemical storm-water management, process water management, mine dewatering and management of tailings. In mineral flotation understanding and controlling water quality is paramount important not only because of its effect on flotation but also with respect to control the quality of the water which is released to the environment. Releasing of different anionic and/or cationic chemical species in the process water results from the interactions among different mineral within the ore, process water, and the milling environment. In fact grinding mill acts as an electrochemical reactor which affects the flotation performances of different value minerals as well as the quality of the tailing products. An increasing in antimony content in process/discharge water at Boliden?s Tara processing plant in Ireland to above limitation level was reported in April 2010 which needed to be controlled. An increase up to 6 times of the permitted level was reported which needed an immediate action to control due to environmental considerations. Therefore attempts were made to detect why this higher amount of Sb is released and how to control and minimize its release to the process/reclaim water. This paper discusses how/why Sb content in process/reclaim water was increased by changing the mill electrochemistry and the strategies were taken into considerations to control it. Different strategies, including electrochemical controlling of the milling section, Fenton process, using Bauxsol in treating the process water, etc., have been considered and tested which are described herein. All strategies taken into consideration for solving the problem were successful which indicated good understanding of the issue and good decision making. Furthermore, for each solution the capital and operational costs were roughly estimated. Accordingly, the Sb content in process/discharge water was controlled to a value lower than allowed limitation, i.e., 1 ppm. Keywords: antimony, water contamination, mill electrochemistry, ag milling, grinding media, eh-ph, sulfide minerals, fenton process, bauxsol, lime addition

Sep 1, 2012