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By Zhang Qi

For the most part, the flying piece is serious endangerment in the demolition blasting. To prevent the endangerment, a large number of materials are needed as the protection. Therefore, the determination and design way of the flying distance of piece in demolition blasting have been concerned extensively. Previously, the experienced or half experienced formula was adopted to calculate the distance of the flying pieces. The calculating values of the distances of flying pieces are not identical with the practice results. The problems concerning the design way of flying distance of pieces are researched in the paper.

Jan 1, 1994

Failure of rock materials is a process of crack propagation. Crack initiation takes place when the crack tip stress intensity K reaches a critical value called fracture toughness, K1C. The rock fracture toughness is known to be affected by the surrounding environment such as temperature, confining pressure and humidity. In order to examine the effect of humidity, a series of semi-circular bend tests were performed under various water vapour pressures in a rock material that is known to be anisotropic. Water vapour promotes stress corrosion of rock and therefore the fracture toughness was found to have a decreasing trend with increasing water vapour pressure. The rate of decreasing the fracture toughness depends on the microcrack density that promotes the migration of water vapour into the rock. Also in an anisotropic rock, the fracture toughness depends on the direction of crack in relation to the anisotropy of the rock material.

Dec 6, 2010

By Thomas A. Palmer

Free cyanide has been successfully determined in ground and surface water by isolation using a microdiffusion technique followed by a pyridine-barbituric acid photometric finish. The determinable free cyanide includes hydrocyanic acid, ionic cyanide, and the cyanide of weak complexes such as cadmium, lead, manganese, and zinc cyanide. Complexes of copper, iron, nickel, and silver are sufficiently strong so the dissociation into free cyanide does not occur at the microdiffusion pH 7. Cyanate, sulfide, and thiocyanate do not interfere. Samples containing as little as 0.005 mg/L are successfully analyzed. The relative standard deviation is <10%. Samples stored at pH >I2 in the dark are stable at least three weeks.

Jan 1, 1981

A knowledge of airway friction factor (K-factor) is necessary to designing mine ventilation systems for least cost and optimum effectiveness. The friction factor used must be accurate and reliable to estimate correctly roadway resistances and pressure sources for required flows. Though the resistance to flow offered by mine airways has been an object of study over the last half century, no accurate relation has yet been established from which the prediction of the resistance of a projected airway can be made. In Kentucky, only limited and incomplete data on local K-factors are available. Therefore, there is a need for field investigations to determine these values in-situ for existing mining conditions. The author describes a study concerning K-factor that was carried out in ten coal mines, located in eastern and western Kentucky. The results of these investigations are presented in both tabular and graphical form.

Jan 1, 1991

By Bartosiewicz H

A method for the determination of the gas content of coal seams is presented which improves upon existing methods. The method makes use of a gravitational technique for measurement of the gas desorbed. The amount of lost gas is estimated by determining an empirical relationship relating the desorption of gas with time for each sample separately. This is to replace the assumption that desorp- tion follows a square root law with time. Laboratory investigations have been conducted which indicate that the square root desorption law does not hold good for carbon dioxide. Results of investigations on various factors influencing the technique are presented. It is shown that co-efficients of the empirical equation are dependent upon the elapsed time and the period of observation. Data about gas pressure measurements is presented and it is concluded that gas pressure can be approxi- mated to 0.6 times the pressure below a column of water equal to the depth of cover. This estimate is good enough for adsorption tests to evaluate desorption co-efficients. The technique for repressurisation of the sample,

Jan 1, 1982

By S. Shimaya, T. Maejima, M. Shimo

"The authors conducted the in-situ gas-tightness tests in a fractured rock at the Namikata underground LPG storage site in Ehime prefecture, Japan. The test consisted of two independent setups, a gas-tightness test that used boreholes, and a chamber-scale test that used a horizontal drift sealed with a concrete plug. In each test, the gas pressure was increased up to the onset of the measurable gas flow to obtain the maximum containment pressure. This paper discusses the hydraulic conditions for gas leakage initiation and the importance of the pore pressure measurement for monitoring the gas-tightness of the LPG storage cavern based on the test results.INTRODUCTIONJapanese first underground LPG storage plant was constructed by JOGMEC, the Japan Oil, Gas and Metals National Corporation, at Namikata in Ehime prefecture in granitic rocks (Kato et al., 2007). The “hydraulic sealing principle” (Åberg, 1977) that utilizes groundwater flow into an unlined cavern to prevent the leakage of gas through fractures in the surrounding rock mass was employed for storage of LPG. This paper describes the results of the in-situ tests performed at the Namikata Site to obtain information on fundamental gas-tightness characteristics of fractured rock. Two types of in-situ tests, a borehole gas-tightness test and a chamber gas-tightness test, were carried out near the storage caverns. Figure 1 shows the cavern layout of the Namikata underground storage plant and the test locations. The storage facilities consist of three caverns (W26m×H30m×L485m). The cavern crown lies at a depth of 150m below the sea level in Cretaceous granitic rock (Figure 1). Water curtain boreholes excavated from the water gallery tunnel at EL-125m level are located above and side of the caverns to prevent water drainage from fractures during the construction stage as well as during operation. The borehole tests were performed from a drilling adit excavated from the eastern end water gallery tunnel, while the chamber test was conducted at the southern edge of an exploratory drift extending from the central water gallery tunnel."

Jan 1, 2015

By A. Dunnett, N. J. Turner, J. Koyanagi, M. Ji

The analysis of rare earth element (REE) samples is a necessary part of the metallurgical process for rare-earth bearing ores, providing invaluable information during testing procedures. This requires a fast, multi-element technique, capable of analyzing a variety of matrices for all rare earth elements. X-ray Fluorescence spectrometry and Instrumental Neutron Activation Analysis are typically used for high concentrations of REE, but they have limitations for some process work applications due to an inability to measure all elements, longer analysis times, significant interferences and elevated detection levels. The work reported here uses new approaches with Inductively Coupled Plasma Mass Spectrometry (ICP-MS) in order to achieve high precision and accuracy within acceptable timeframes. A combination of aerosol dilution and Kinetic Energy Discrimination (KED) produce a process solution assay method that is robust enough to deal with changing sample matrices and concentrations, whilst maintaining low reporting limits and precisions of less than 5% Relative Standard Deviation (RSD). For high concentration metallurgical and geological samples, a sodium peroxide fusion digestion procedure was used, followed by ICP-MS analysis using extended dynamic range (EDR) and KED. Using these technologies, it has been demonstrated that the necessary support can be given to metallurgical process work for REE extraction.

Jan 1, 2014

By S. E. Phillipson

Underground mine mapping is a critical component of understanding the controls on ground instability. Many relatively localized examples of ground failure are associated with geologic features, such as faults, joints, compaction zones, or sedimentological transition zones. In contrast, long-running, directional roof falls are associated with regionally directed horizontal stress fields, which are induced by tectonic plate interactions in the earth?s crust. When stress-related features are distinguished from geological features, underground mapping can be an effective method for inferring the direction of horizontal stress at individual mines. Comparisons with data compiled in the World Stress Map confirm that underground mapping can be a valid method for determining the orientation of maximum principal horizontal stress at a variety of scales, ranging from individual mines to an entire mining district or coal basin. Comparisons are presented between the maximum horizontal stress directions inferred by MSHA?s Roof Control Division through underground mapping and the azimuths of maximum horizontal stress in the World Stress Map database for North America?s Pennsylvanian-aged Appalachian, Illinois, Black Warrior, and Arkoma Basin coal fields. The comparison indicates that azimuths are similar for both data sets, even where variations in the direction of horizontal stress are present. It is interpreted that inconsistencies in direction are attributable to near-surface affects such as deeply incised stream valleys, or to fault zones that represent heterogeneities in the crust.

Jan 1, 2009

By S. E. Phillipson

Underground mine mapping is a critical component of understanding the controls on ground instability. Many relatively localized examples of ground failure are associated with geologic features, such as faults, joints, compaction zones, or sedimentological transition zones. In contrast, long-running, directional roof falls are associated with regionally directed horizontal stress fields, which are induced by tectonic plate interactions in the earth?s crust. When stress-related features are distinguished from geological features, underground mapping can be an effective method for inferring the direction of horizontal stress at individual mines. Comparisons with data compiled in the World Stress Map confirm that underground mapping can be a valid method for determining the orientation of maximum principal horizontal stress at a variety of scales, ranging from individual mines to an entire mining district or coal basin. Comparisons are presented between the maximum horizontal stress directions inferred by MSHA?s Roof Control Division through underground mapping and the azimuths of maximum horizontal stress in the World Stress Map database for North America?s Pennsylvanian-aged Appalachian, Illinois, Black Warrior, and Arkoma Basin coal fields. The comparison indicates that azimuths are similar for both data sets, even where variations in the direction of horizontal stress are present. It is interpreted that inconsistencies in direction are attributable to near-surface affects such as deeply incised stream valleys, or to fault zones that represent heterogeneities in the crust.

Jan 1, 2009

By H. Ankara

Determining the identicalness levels of the same model trucks working in open pit mine transportation system by means of statistical analysis methods is very significant in terms of availability analysis. In this study, the identicalness levels of two trucks picked randomly from the 170-short-tonne truck fleet working in open pit coal mine over one-year period were examined through a non-parametric test, Mann-Whitney U test for two samples. Time to failures (TTFs) and Time to Repairs (TTRs) of the trucks were analyzed with this test technique and then whether they were identical or not was determined. In order to determine whether the trucks identified to be identical at the end of this test displayed the same mining performances within the same open pit transportation system, the availability analysis of the identical trucks was carried out. As a result of the availability analysis, it was observed that the trucks had availability values that were very close to each other. It was also determined that Mann-Whitney U test could be employed together with availability analysis. Finally, it was observed that Mann-Whitney U test for two samples could yield rapid results in the performance analysis of complex systems like open pit mines.

Jan 1, 2010

By Michael J. Beus, Jan G. Patricio

INTRODUCTION The U.S. Bureau of Mines, Spokane Mining Research Center, has been conducting and documenting rock mechanics research in the Coeur d’Alene mining district for the past ten years (1, 2, 3, 4, 14, 15). A current project combines the information gathered from rock mechanics instrumentation, geologic structure, and analytic techniques to improve shaft and support design for the deep mines of the district (3). This project required knowledge of the anticipated loads and the physical properties of the rock mass to provide accurate input data for computer design models. Several techniques have been utilized to determine the physical parameters including the USGS (U.S. Geological Survey) solid inclusion probe, the CSIR (Council for Scientific and Industrial Research) biaxial and triaxial strain cells, and the CSM (Colorado School of Mines) dilatometer. This paper describes the determination of the in situ modulus of deformation in three mines over a period of three years and the evaluation of these results as they applied to this project. The need for in-situ rock mass properties such as the modulus of deformation has stimulated research and development of a large number of instrumentation techniques. One area of continuing interest involves various methods of radial borehole dilation. This concept was pursued by Menard (9) with an apparatus known as the pressure meter, which is used frequently in soil mechanics. Other developments in rock mechanics include the CPC (cylindrical pressure cell) by Panek (11) and the dilatometer by Rocha et.al. (13) in Portugal. The CSM dilatometer, which also utilizes this technique, was chosen for this project because it required a small amount of background study, was inexpensive, and could easily be combined with other experiments being planned for the test locations. Although no previous field applications to hard rock (compressive strengths greater than 20,000 psi) has been documented, the instrument was selected since good results have been achieved in granite, oil shale, and several coal measure rocks (11, 12).

Jan 1, 1977

By D. R. Tesarik, F. M. Jones, J. B. Seymour

As part of safety and stability studies at three underground mines in the United States, researchers installed earth pressure cells and embedment strain gauges in cemented rockfill to measure stress and strain changes as mining progressed and the rockfill was loaded. Data from these instruments were used to calculate the in situ modulus of the rockfill for two of the mines. A three-dimensional numerical model of a cemented rockfill cap was validated with data from extensometers anchored in the mine roof and sill; this model was then used to estimate deformation modulus at the third mine because the earth pressure cells and embedment strain gauges recorded negligible changes. Rockfill binder used at these mines ranged from 4 to 8 per cent of the dry components by weight, the water-to-cement ratio was from 0.42 to1.0, and the largest aggregate size in the three mixes ranged from 5 to12 cm (2 to 4.7 in). The range of the calculated in situ deformation modulus values was large, but as expected, it was bracketed by modulus values for cemented tailings and roller-compacted concrete with similar cement contents and water-to-cement ratios. Dans le cadre d’études sur la sécurité et la stabilité de trois mines souterraines situées aux États-Unis, les chercheurs ont installé des palpeurs de pression des terres et des extensomètres d’encastrement dans les remblais cimentés afin de mesurer les variations relatives à l’effort et à la déformation des terrains durant l’exploitation minière et le chargement du remblai. Les données recueillies à l’aide de ces instruments ont servi au calcul du module in situ du remblai dans deux de ces mines. Le modèle numérique tridimensionnel de la semelle d’un remblai cimenté a été validé à partir des données recueillies par les extensomètres ancrés dans la voûte et dans la semelle de ces mines; ce modèle a ensuite été utilisé pour estimer le module de déformation à la troisième mine, étant donné que les palpeurs de pression des terres et les tensiomètres enfouis avaient relevés des variations négligeables. La matière d’agrégation de l’enrochement utilisée dans ces mines comportait entre 4 % et 8 % des composantes sèches par poids; le rapport eau-ciment se situait entre 0,42 et 1,0; et la taille des agrégats les plus gros dans ces trois mélanges était de 5 cm à 12 cm (2 po à 4,7 po). L’écart entre les valeurs calculées des modules de déformation in situ était grand, mais comme on s’y attendait, cet écart a été compensé par les valeurs modulaires des résidus cimentés et du béton tassé au rouleau avec des teneurs en ciment et des rapports eau-ciment semblables. Als Teil der Sicherheits- und Stabilitätsstudien an drei Bergwerken in den Vereinigten Staaten von Amerika installierten Forscher Erddruckgeber und Einbindungsdehnungsmesser in zementierter Steinschüttung, um Spannungs- und Dehnungsveränderungen während der fortlaufenden Bergarbeiten und der Belastung der Steinschüttung zu messen. Daten von diesen Instrumenten wurden dazu verwendet, das In-Situ-Modul der Steinschüt-ung für zwei Gruben zu berechnen. Ein dreidimensionales numerisches Modell einer zementierten Steinschüttungsschwelle wurde mit den Daten von den im Grubendach und in der Schwelle verankerten Extensometern validiert; dieses Modell wurde dann dazu eingesetzt, um das Deformationsmodul in der dritten Grube zu schätzen, da die Erddruckgeber und Einbindungsdehnungsmesser nur geringfügige Messabweichungen feststellten. Das in diesen Gruben verwendete Steinschüttungsbindemittel variierte zwischen vier und acht Prozent an Trockenkomponenten nach Gewicht, der Wasser-Zementfaktor betrug zwischen 0,42 und 1,0 und die größte Zuschlagstoff-größe in den drei Mischungen schwankte zwischen fünf und zwölf Zentimetern. Die Reichweite der berechneten Werte des In-Situ-Deformationsmoduls fiel etwas breit aus, aber es fand erwartungsgemäß eine Klammerung der Modulwerte zwischen den Zemen-trückständen und dem durch Walzen verdichteten Beton mit ähnlichem Zementanteil und Wasser-Zementfaktor statt.

Jan 1, 2003

By Carlos A. Prato, Federico Pinto

"ABSTRACTThe design of drilled shafts often incorporates large factors of safety, for which settlements under service loads are highly influenced by the initial elastic stiffness. In the case of groups of drilled shafts with typical spacing, the elastic shaft-soil-shaft interaction dominates the behavior even for loads close to the bearing capacity, for which the initial stiffness is a key parameter in the design. This paper describes typical trends in results obtained by means of different approaches currently available in the literature for the evaluation of the initial stiffness of a single shaft. An experimental technique that provides a rapid and inexpensive means for the evaluation of the initial stiffness is described, and the results obtained for typical cases are compared with analytical predictions.IntroductionThe behavior of drilled shafts under axial loads is generally governed by the initial stiffness, as the factors of safety considered in design are often large, due to a superposition of conservative assumptions on soil properties and expected loads. In the case of shaft groups, the initial elastic stiffness plays a major role together with the elastic group effects, as nonlinearities tend to localize around the shafts and have a lesser effect than elastic deformations on adjacent elements (e.g., Leung et al., 2010). An accurate characterization of the initial stiffness is thus warranted for the analysis of drilled shafts and shaft groups under service loads.Initial stiffness of shafts may be estimated on the basis of soil stiffness and structural properties of the element by means of numerical methods (e.g., Pinto and Prato, 2006), as well as analytical methods (e.g., Randolph and Wroth, 1978). The soil stiffness may be determined by means of geophysical tests (e.g., Spectral Analysis of Surface Waves, SASW, Stokoe et al., 1994), or correlations with Standar Penetration Test (SPT) blowcounts or Cone Penetration Test (CPT) resistances (e.g., Sabatini et al., 2002).The initial stiffness may also be measured on drilled shafts by means of load tests. Static load tests (SLT), however, have some limitations on measuring small deflections, for which the initial stiffness is often extrapolated by means of large strain measurements (e.g., Chin, 1970), where the SLT measurements are more accurate."

Jan 1, 2014

By S Hapugoda

Iron ore oxide and oxyhydroxide minerals such as haematite (eg various types of martite and microplaty haematite), different forms of goethite, magnetite, hydrohaematite and kenomagnetite were analysed using optical microscopy, scanning electron microscopy (SEM) and electron probe microanalysis (EPMA) techniques, to determine the type and proportion of deleterious elements present and the chemistry of associated gangue minerals. The aim was to characterise elements potentially deleterious for agglomeration and steelmaking, eg sulfur, phosphorus, aluminium and silicon and correlate their distribution with mineral texture and association, to provide feedback on downstream processing performance and product quality.Examples of characteristic mineral associations are shown from various genetic styles of iron ores, including magnetite banded iron formation (BIF), BIF-derived martite-goethite and skarn-type magnetite ores.A number of examples are presented demonstrating the benefits of the use of combined techniques of reflected optical microscopy, SEM and EPMA data to reliably identify ore and gangue minerals and their associations in different types of iron ores.

Jul 11, 2011

By L Dixon, J Carter, K Auyong

Fourier transform infrared (FTIR) spectroscopy and other near infrared (NIR) tools have been used in the bauxite industry for many years. Infrared spectroscopy exploits the differences in chemical composition and lattice structure to produce a characteristic response. Spectral devices, such as those from ASD Inc and the HyLoggerTM, provide qualitative mineralogical data targeted towards hydrated minerals detected in the near and short wave infrared region. The FTIR spectrum extends into the mid and thermal infrared range and can therefore respond to the presence of silicates and oxides, in addition to hydrates and carbonates.The key to successful utilisation of infrared spectra, however, is the interpretation methodology. In this study, FTIR spectra were calibrated against quantitative X-ray diffraction data for the determination of the mineralogy of iron ore. A full pattern profiling machine learning technique was utilised for the calibration, and the assessment of the regressions determined from an independent validation set. The abundance of key minerals – hematite, goethite, kaolinite and quartz – were determined and the results correlated against X-ray fluorescence assays and loss on ignition data. The results of the study indicate that spectral techniques using a full-pattern profiling machine learning approach and artificial neural networks can be used successfully to obtain objective and quantitative mineralogical data to support field observations and analytical results for iron ore resource modelling. A comparison of this technique to the cost, quality and timeliness of other quantitative mineralogy tools is also made.CITATION:Carter, J, Auyong, K and Dixon, L, 2017. Determination of iron ore mineralogy using Fourier transform infrared spectroscopy and machine learning, in Proceedings Iron Ore 2017, pp 519–528 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By D. R. Piteau, A. MacG. Robertson

Strength, permeability, and deformational properties of a rock mass are influenced and often controlled by the geological discontinuities within the mass. These properties are often determined by physical tests conducted within and on portions of the rock mass under consideration. Any extrapolation of these test results to other portions of the rock mass assumes that a similar pattern of discontinuities, having similar properties, exists throughout the region of extrapolaion. A survey in which various joint properties of interest are measured may be conducted to sample the joint population of the mass. Suitable data manipulation and handling techniques are developed to permit the definition of the joint population of the rock mass. The validity of the extrapolation of test results may then be assessed.

Jan 1, 1974

By J. A. S. Tenorio, K. S. Barros, D. C. R. Espinosa

In the last decades, authors have been focused in the development of a cyanide-free bath for the electroplating industry of brass due to the risks that involves the use of cyanide and they have been evaluated the electrodialysis as an alternativemethodforthetreatmentoftheeffluentgeneratedinthistypeofindustry because ofthe limitationscaused bythe chemical precipitation. Hence, thepresent paperaimedtodeterminethelimitingcurrentdensityoftheeffluentgeneratedinthe free-cyanide electrodeposition of copper and zinc using EDTA as chelating agent for the treatment of the effluent by electrodialysis. The synthesized solutions were preparedwith copper sulfate andzinc sulfate indifferent conditionsofpH (10–12) and proportion of cupric ions (30%, 50%, 70%). According to the results, the increase of pH and the cupric ions proportion caused an increase in the limiting current density because of the larger amount of anionic species in solution and the consequent difficult to achieve the concentration polarization phenomenon. (cid:1) (cid:1) (cid:1)

Mar 1, 2018

By Aniruddha Sengupta, Rana Chattaraj, G. R. Reddy, Raj Banerjee

"Earthquake induced liquefaction in saturated granular soils is an important phenomenon which causes severe damage to life and property. In the present study, dynamically induced liquefaction of saturated Kasai River sand is studied in 1-g shake table to assess its liquefaction potential. In the shake table, the soil was subjected to sinusoidal motions of amplitude 0.35g at a frequency of 2Hz. A numerical model using FLAC 2D (Itasca 2005) was performed to simulate the shaking table tests. Reasonably good agreement between the experimental and the numerical results has been observed. Moreover, wavelet analysis has been conducted to identify the occurrence of liquefaction in sand and to correlate the observations found from the experiments. The nonlinear curves used to represent shear strain dependency of stiffness of the Kasai River sand was obtained from cyclic tri axial tests.INTRODUCTIONThe term Liquefaction is used in conjunction with a variety of phenomena that involve soil deformations due to cyclic disturbance in saturated soil under undrained conditions. The generation of excess pore water pressure is the hallmark of all liquefaction related phenomena and the reduction in the volume or the tendency of cohesionless soil to densify during undrained loading condition as prevails during an earthquake is also well known. Use of shaking table tests to understand liquefaction of soils has been demonstrated by several researchers (Ye et al. 2013; Ha et al. 2011). Mohajeri and Towhata 2003 and Towhata et al. 2006 carried out 1-g shaking table tests on soil models prepared in laminar box to study the rate dependent behavior of liquefied soils. Ueng et al. 2010 used a biaxial laminar shear box mounted on shaking table to study the settlements in saturated clean deposits of sand and related the volumetric strain in liquefied sand to the relative density for various shaking durations and earthquake magnitudes. Maheshwari et al. 2012 reported increase in liquefaction resistance of reinforced sand through shaking table tests and concluded that the type and amount of reinforcement in the soil layer has influence on its liquefaction potential.The objective of the present study is to compare the behavior of dry and saturated Kasai River sand when subjected to seismic shaking. The Kasai River separates two growing cities, Medinipur and Kharagpur in the state of West Bengal in India. A number of road and railway bridges exist over the river connecting the two cities. The area being in Seismic Zone III, that is, a zone with moderate probability of earthquake, it is important to characterize the behavior of the Kasai River sand during a possible earthquake event especially when a number of bridges are existing over it. Small scale laboratory model tests and numerical analyses using a commercial finite difference algorithm called FLAC2D (Itasca 2005) have been utilized to study the difference in behavior of dry and liquefied Kasai River sand during dynamic loading conditions."

Jan 1, 2015

By John L. H. Patterson

Handheld XRF has become the favorite way of measuring the content and identity of alloys in the field. This is because of the very portable nature of the instrumentation and its simple operation. However, these analyzers have been unable to determine the concentration of the light elements like Mg and Si due to the very low energy of the x-rays produced by these elements. In the past accessories such as vacuum and He flush have given some analyzers the ability to determine these light elements with modest detection limits. The introduction of the Silicon Drift Detector (SDD) into this class of instrumentation has added a new level of analysis capability to portable XRF instrumentation. X-ray fluorescence is achieved by exciting a sample with a beam of x-rays, which in recent portable equipment are generated by a small tube. This results in the emission of characteristic x-rays from the sample under test. By measuring the energy of each x-ray it is possible to determine what element generated it. By counting the number of x-rays at each energy it is possible to determine the concentration of each element. The detection limit for each element is dependent upon the number of x-rays which reach the detector. As the number of x-rays increases the detection limit will improve. One of the major factors in an x-ray reaching the detector is the energy of the x-ray. As the energy of an x-ray increases the probability of that x-ray reaching the detector increases. The energy of an x-ray is inversely proportional to the atomic number (AN) of the element generating the x-ray. For example, an iron x-ray (AN=26) is 6.40 keV while an aluminum x-ray (AN=13) is 1.49 keV. As the energy decreases, the detection of the x-ray becomes less and less probable because the x-ray may be absorbed by the windows which are part of the instrument and detector or the air in the path between the sample and detector. In SiPIN based portable XRF analyzers, the lowest element which is detected with acceptable detection limits is normally considered to be Ti (AN=22). The detection limits for 60 second measurements on typical SiPIN XRF analyzer are given in Table I. Thus, portable analyzers have not been useful for measurement of aluminum and titanium alloys as major components of these alloys are Mg (AN=12), Al (AN=13) and Si (AN=14).

Jan 1, 2009

By Alvin J. F

Tin in ores containing 0&#183;025 to 1&#183;5 per cent tin can be determined polarographically by the reduction of the chlorostannite ion at the dropping mercury electrode in 2M hydrochloric acid solution containing 15 per cent ammonium chloride. The tin is separated from interfering elements by distillation as the tetrabromide and collected from the distillate by co-precipitation with aluminium hydroxide. The method can detect 0&#183;01 per cent tin in ore.INTRODUCTIONAn iodimetric method, suitable for routine analysis of titrating tin in concentrations down to 1 per cent, has been available for some years (Low, Weinig, and Schoder, 1939).As concentrations fall below 1 per cent tin, there is increasing difficulty in obtaining a distinct end point due to large amounts of iron and silica normally present after fusion of the ore. Since concentrations of tin down to 0&#183;02 per cent are significant in ore dressing products it was necessary to examine methods to determine such low concentrations, and to adapt these to tin ores containing a wide variety of other minerals.EXPERIMENTALDigestion and separationCassiterite, the principal tin mineral, is refractory but readily attacked by a sodium peroxide flux to yield soluble sodium stannate. In a recognized procedure, a sample of ore is mixed with up to 15 g of sodium peroxide in an iron crucible and swirled over the full heat of a Meker burner for 7 min. The fusion is leached with water and acidified.This solution then contains tin, silica, and other soluble...

Jan 1, 1962