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By Douglas Valentim Fernandes Neves

O aço inoxidável austenítico 316 (316 SS) é um dos materiais metálicos mais utilizados em aplicações médicas devido à combinação de propriedades mecânicas e do baixo custo. No entanto, desgaste e corrosão estimulam mudanças permanentes no tecido humano que podem levar à perda do implante. O desenvolvimento de recobrimentos biocompatíveis e estáveis, que apresentem propriedades mecânicas adequadas, e que não sofram ruptura ou delaminação durante o uso, é uma solução muito promissora para melhorar o desempenho do 316 SS como biomaterial para implantes. Neste trabalho, uma liga intermetálica FeAlCr, que tem apresentado propriedades adequadas para a aplicação como biomaterial, foi utilizada como recobrimento sobre um aço inoxidável 316 de grau médico. O revestimento foi obtido utilizando-se a técnica magnetron sputtering por corrente contínua. Os parâmetros de deposição, como distância substrato - alvo e pressão de gás argônio foram mantidos fixos em 50 mm e 5 mTorr, respectivamente. As amostras foram preparadas com os seguintes valores de potência de sputtering: 50 W, 75W, 100 W e 150 W. A adesão dos filmes foi analisada por teste de scratch, enquanto a espessura e a taxa de deposição foram analisadas por perfilometria ótica. As características estruturais foram analisadas por microscopia eletrônica de varredura com EDS.

Aug 8, 2018

By Y. M. Jiang

A users friendly PC Computer Program has been developed to implement a systematic design of the powered support. The required input data are: (1) thickness, RQD, and compressive strength of the immediate roof; (2) mining height; and (3) type, thickness, and tensile strength of the main roof. Several important parameters for support selection under a given geological condition are generated through the implementation of the program, including type of support most favorable for the geologic condition, minimum inclination angle of the legs with respect to the horizontal axis, suitable setting load ratio of the front to rear leg for the 4-leg supports, optimum setting load, and support capacity.

Jan 1, 1989

By Philip Henry

THERE is a difference of opinion among engineers on the subject of depreciation in general, and still more on its application to any given case. The committee which was appointed by the American Society of Civil Engineers to make a report on Valuation of Public Utilities, states "There is no subject connected with valuation about which there are more diverse views than those relating to depreciation;" and in the discussion which took place upon the presentation of the preliminary report of this committee in January, 1914, that part of the report dealing with depreciation called forth more discussion than any other. From this discussion it was evident that the word " depreciation" was not always used in the same sense, so it is quite important that some definition be adopted. As this paper relates to the proper method of treating depreciation by corporations or individuals operating oil properties, both of which must make a return of annual net income to the government in connection with the income tax, it will be in order to adopt the definition of the Internal Revenue Bureau. Under date of Mar. 29, 1910, the Commissioner of Internal Revenue of the Treasury Department stated "Deduction on account of depreciation of property must be based on lifetime of property, its cost, value and use." Again, on Form 1035, "Return of Annual Net Income" for miscellaneous corporations (Section 2, Act of Congress approved Oct. 3, 1913), a deduction from gross income is allowed for "Total amount of depreciation for the year." This item is defined more particularly as follows: "The amount claimed under Item No. 5 (b) for depreciation should be such an amount as measures the loss which the corporation actually sustains during the year in the value of buildings, machinery, and such other property as is subject to depreciation on account of wear and tear, exhaustion, or obsolescence. The amount taken credit for on this account in order to be allowable should be so entered on the books as to constitute a liability against the assets of the corporation. The amount claimed under this item should not cover losses in the value of stocks and bonds. Decrease in the book value of securities owned, so far as such decrease represents a decline in the actual value of such securities, should be deducted under item 5 (a) of the return.

Jan 1, 1915

By I. A. Ettlinger

DEPRECIATION allowances have become firmly rooted in our income tax structure both by legislation and by court decisions. Secretary of the Treasury Morgenthau has recently stated before the Ways and Means Committee of the House: A taxpayer who did not provide for depreciation of assets used in his business could not long remain in business and the income tax should be levied on the assumption that he will provide for such depreciation. The 1934 Revenue Act has now been enacted, the depreciation provisions of the 1932 Revenue Act having been carried forward without change. However, there has arisen, in connection with the preparation of this new Revenue Act, a determination by the Treasury Department to make certain changes in the future administration of the depreciation allowances that will affect all corporations, and mining companies in particular.

Jan 1, 1934

By S. Castro, L. Uribe

Seawater can be considered as a particular process water with a high concentration of NaCl (about 0.5- 0.6 mole/L) and high concentration of hydrolyzing metal cations (mainly, Mg2+ and Ca2+ ions). Micro-flotation tests, induction time measurements, and zeta potential measurements have been used to investigate the effect of these ions on the natural floatability of molybdenite. The results demonstrate that molybdenite is strongly depressed in the alkaline pH range over which hydrolysis products of Mg2+ and Ca2+ ions are formed. At pH 10, colloidal magnesium hydroxide seems to be responsible for molybdenite depression in seawater and in Mg2+ solutions. This is also supported by the measurements of the effect of Mg2+ ions on the zeta potential of molybdenite. The mechanism of depression of molybdenite with Ca2+ ions is different, and depression takes place in the pH range were Ca(OH)+ complexes are formed, below the pH of precipitation of calcium hydroxide. Adsorption of the cationic hydroxy species and/or hetero-coagulation of the positive charged colloidal hydroxide on the negative charged molybdenite particles seem to be the main mechanisms involved.

Jan 1, 2014

By S. Castro

Molybdenite flotation is strongly depressed at pH higher than 9.5 in the flotation of Cu-Mo ores in sea water. Chemically sea water contains mainly Na+ and Cl- ions, but also some secondary ions, such as SO42-, Mg2+; Ca2+, HCO3-; etc., which are not necessarily indifferent for the flotation of molybdenite. The natural floatability of molybdenite in sea water and in NaCl solutions containing different secondary ions is investigated by micro-flotation tests. The tests indicate that the floatability of molybdenite in alkaline media in 0.6 M NaCl solutions is not affected by the presence of anions, such as, SO42- and HCO3-, at concentrations similar to those occurring in sea water. However, a strong depression of molybdenite at pH ranging from 9.5-10.0, is produced by the alkaline earth metal cations (Ca2+ and Mg2+ ions), dissolved in distilled water or in 0.6M NaCl solutions. It was found that effect of Mg2+ions is significantly stronger than Ca2+ ions. Effect of both ions is attributed to hydrolysis and adsorption of MOH+ hydroxy-complexes. This is followed by subsequent precipitation of hydrophilic colloidal hydroxides at the molybdenite/solution interface, and in bulk solution.

Sep 1, 2012

By S. K. Kawatra, T. C. Eisele

Microorganisms, such as the bacteria Thiobacillus ferrooxidans, have been reported to depress pyrite flotation (Elzeky and Attia, 1987; Atkins, 1990). However, the depen¬dence of the depression on the type of organism or on suspension pH is still being determined. In this study, the relative effectiveness of various microorganisms (chemolithotrophic bacteria, chemoorganotrophic bacteria and yeast) over the pH range of 2 to 12 was studied. Screen¬ing tests using microflotation showed that every microorgan¬ism tested was capable of depressing naturally hydrophobic pyrite at acidic pH. Larger-scale experiments with both mineral pyrite and coal pyrite using Thiobacillus ferrooxidans and Saccharomyces cerevisiae as depressants, showed that these microorganisms are very effective depressants for mineral pyrite at acid pH, but they are largely ineffective at neutral and alkaline pH, where the mineral pyrite surface is not naturally hydrophobic. The flotation response of the coal pyrite was completely different from the mineral pyrite. The coal pyrite was most floatable near neutral pH, with the floatability decreasing in acidic or alkaline solutions. De¬pression of the coal pyrite by yeast was not selective between the pyrite and the associated coal under the experimental conditions.

Jan 1, 2000

By Yongjun Peng, Yufan Mu, Rolf A. Lauten

"Chalcopyrite, a major source of copper, is commonly found associated with iron sulfides, particularly pyrite. The separation of chalcopyrite and pyrite by flotation is difficult due to the galvanic interactions between pyrite and chalcopyrite during grinding and flotation. Galvanic interactions may cause oxidation and dissolution of chalcopyrite, copper activation of pyrite and the formation of hydrophilic iron hydroxide coating. The overall effect may change the floatability of the components and lead to the misplacement of pyrite into chalcopyrite concentrate. The objective of this study was to investigate the effect of lignosulfonate-based biopolymers on the depression of pyrite in the flotation of chalcopyrite with xanthate as collector and the mechanism responsible for the selective depression of pyrite. The flotation results showed that biopolymers depressed the flotation of both copper-activated pyrite and chalcopyrite in single mineral flotation although to different extents. In the flotation of mixed mineral systems, biopolymers significantly depressed pyrite flotation but had a less influence on chalcopyrite flotation. The selective depression of pyrite by biopolymers was due to the preferential adsorption of biopolymers on copper-activated pyrite surface. Galvanic interactions between pyrite and chalcopyrite surfaces promoted copper activation on pyrite. Presence of cuprous ions on pyrite surface favored biopolymer adsorption by the formation of a complex between the cuprous ions and biopolymer molecules. The same galvanic interactions also facilitated chalcopyrite oxidation leading to the formation of hydrophobic polysulfide that enhanced the hydrophobicity on chalcopyrite surface. The biopolymer structure controlled the depression effect. The results showed that the biodegradable biopolymers are promising depressants for pyrite.INTRODUCTIONCopper sulfide minerals, such as chalcopyrite (CuFeS2), bornite (Cu5FeS4), chalcocite (Cu2S) and covellite (CuS), are the major mineral source for copper. They are often found finely interlocked with iron sulfides, especially pyrite (FeS2) (Owusu, Brito e Abreu, Skinner, Addai-Mensah, & Zanin, 2014). Pyrite, as the most abundant sulfide mineral, is perceived as gangue in most cases and should be removed from the associated sulfides to minimize its contamination of the copper concentrate (Owusu, Addai-Mensah, Fornasiero, & Zanin, 2013; Wang & Forssberg, 1991). The commonly used strategy to remove pyrite is flotation (Wang & Forssberg, 1991)."

Jan 1, 2016

By Saul J. Escalera

Mechanisms involved in the depression of the sulfides: pyrite, chalcopyrite, galena and sphalerite with potassium permanganate have been investigated. Flotation tests were conducted using potassium amyl xanthate, Z-6, and pine oil in the absence and presence of potassium permanganate at around pH = 6. 5 naturally yielded by the sulfides in the pulp. On the basis of crystal chemistry considerations, the amount of xanthate adsorbed by the sulfides depends on the amount of sulfur and metal ions present on the surface; thus, the avidity of the sulfides for xanthate should increase in the order: sphalerite C chalcopyrite 4 galena 4 pyrite, and the ease of depression response to the permanganate action should be in the same order. Depression of the sulfides in the system occurs primarily due to the removal of the collector ions by the permanganate ions to form manganese dioxide and dixanthogen according to the reaction: 3 M(RX)2 + 2 Mn04 + 4 H20 2 ? MnO2 + 3(RX-XR) + 3 M+2 8OH where M represents the metal ion, RX the xanthate ion and (RX-XR) the dixanthogen molecule. Results seem to indicate that the permanganate ions play a triple role in the system: (1) they convert xanthate ions into dixanthogen, (2) they further oxidize the mineral surface and (3) if present in excess, they may oxidize the xanthate beyond the dixanthogen stage with the formation of CO2, H20 and SO4. All sulfides, except for chalcopyrite, showed a depression response in the order predicted regardless of the order of addition of xanthate and permanganate reagents. Chalcopyrite did not depress as easily; this behavior may be due to the avidity of the colloidal MnO2 to adsorb Cu+2 ions on its surface, this would destabilize the colloid making it coalesce with the formation of a layer of precipitated MnO2 on the surface of the mineral. The presence of this layer would prevent further action of the permanganate ions on chalcopyrite.

Jan 1, 1970

By Paul M. Tyler

MARKETWISE the year 1935 was rather a good one for most of the rare and minor metals; as a class they climbed out of the depression much faster than the common metals. The diamond market, too, was better than it had been for years, attributable only in part to investment buying, as there was a genuine pick-up in consumer demand. Wars and rumors of war tended to speed up purchases of certain metals, but consumption for peaceful purposes was the principal factor. Significant was the important role played by new industrial uses. New discoveries during the year were disappointingly few, considering the broad extent of this research frontier. Scientific developments were far from being at a stand-still, of course, but the dominant note was the cashing in on research consummated in former years. With even a moderate upturn in general business a surprising number of laboratory ideas donned overalls and found jobs in industry.

Jan 1, 1936

By David R. Hargis

Large-scale groundwater withdrawals are necessary to depressurize a confined aquifer system allowing the dry open-pit mining of the overlying phosphate ore. The extent of the existing and planned groundwater development led to the establishment by the State of North Carolina of Capacity Use Area No. l. Groundwater use in the Capacity Use Area is regulated by a permitting system. A two-dimensional finite-difference ground- water flow model was developed for North Carolina Phosphate Corporation. The aim of the model is to aid the Corporation in matters relating to permitting by serving as a predictive tool. The model can be used to project regional water level impacts resulting from various scenarios of depressurization pumping.

Jan 1, 1983

The Martha deposit is an economic giant epithermal gold deposit, with mined and unmined resources of more than 218 000 kg (7 Moz) Au. The Au-Ag, base metal sulphide-bearing quartz lodes in the Martha deposit form an extensive braided pattern within hydrothermally altered andesite wall rock. There are five main quartz lodes: 1.      Martha, 2.      Welcome, 3.      Edward, 4.      Empire, and 5.      Royal.   Information from historic mine plans and reports has been used to determine the depth distribution of economic ore within the Martha deposit. Economic ore (average of 10 g/t Au) in the Martha underground mine was at a maximum width and strike length between a vertical depth of 160 and 350 m. Below this depth the quartz-sulphide lodes continue, but the grade declined to sub-economic grades (< 4g/t Au) at about 575 m depth and economic ore shoots were localised, mainly on the hangingwall side of the lodes. Samples from exploration drill holes indicate that this decrease is associated with a depth zonation from electrum-bearing Zn-Pb-Cu-Ag sulphide ore (average 10 g/t Au) to sub-economic (< 2 g/t Au) electrum-poor Zn-Pb sulphide mineralisation.

Jan 1, 2006

By Shi Shuaixing Zhang Yuejun, Fan Xuesai Zhangming

"For the traditional principle of flotation cell design, or in the perspective of some researchers, the mixing effect of impeller for flotation cell is not only to suspend the particles off the bottom, but also to mix slurry well to achieve a uniform system. But for some special processing conditions, the depth profile of slurry concentration and particle size demonstrates an obvious difference. In the part around of the impeller in the cell, the slurry concentration is much higher than the part below the lip.For the vanadium titano-magnetite flotation process, distinguished with high concentration and large coarse particle size fraction, even though the concentration is very high, it can reach good gas dispersion, which is a fundamental principle for flotation cell design and application. The gas dispersion is not a challenge in the high slurry concentration environment, not only in the vertical direction, but in the cross section. Different levels (the distance from the lip is 400mm, 700mm, 1200mm, 1700mm, 2200mm, 2700mm) slurry in the flotation cell is sampled and analyzed. The slurry concentration of the 3 levels(1700mm, 2200mm, 2700mm) is about 55%, but the slurry concentration decreases from 55% to 25% sharply towards the lip.Therefore, a new understanding and viewpoint is presented, that the uniform system of slurry is not always reasonable for all of the flotation process. For some special process, if the coarse particles are needed to agitated well and transported to the upper cell, the quiescent zone in the upper cell will be destroyed and enhance the detachment probability for the coarse particles. The difference of slurry concentration and particle size fraction benefits the air dispersion and coarse mineral particles recovery.1.INTRODUCTIONNowadays, flotation is the most widely used separation process in the mineral processing industry. The importance of flotation technology in the global economy is significant. A rough estimate of the quantity of crushed ore treated by flotation is about nine billion tons per year, and the portion of base metals processed using this method is approximately 95% (Brewis, 1996)."

Jan 1, 2018

By Svetlana Nikitina

While many question "sustainability" as an intellectual field on the grounds that it is too broad and "undisciplined," we are able to achieve a good balance between breadth of coverage and depth of inquiry in our team-taught seminar "The Grand Challenges: Sustainable Development for the 21st Century" offered to first year students at Worcester Polytechnic Institute. We strike this balance between breadth and depth by a) problematizing key sustainability issues in class discussions; b) by explicitly exploring the lenses of different disciplines (the historical context, the scientific facts, the engineering interventions and the philosophical foundations of unsustainable behaviors); and c) by offering our students opportunities to pursue a targeted project on specific sustainability issues (vertical gardening, metals recycling on college campus) through which they gain depth of understanding as well as practical exposure to all components of the problem, which puts them on the path of seeking effective solutions.

Jan 1, 2010

By Luis Haro Chávez

"El presente trabajo describe el proyecto del depósito de relaves aplicado a una presa de taludes en Asnapampa a través del método Paddock en la quebrada del mismo nombre. El método consiste en la construcción de una presa por dos etapas, siguiendo las elevaciones progresivas y manteniendo el eje central de la presa. Cabe precisar que esta metodología solo es aplicable en zonas donde las altas temperaturas permiten una evaporaciónrápida del agua de relaves. En este sentido, es factible la construcción de este depósito de relaves emplazándolo en la quebrada del mismo nombre y a orillas del rio Marañón, puesto que el nivel de balance de aguas es mínimo, y el potencial de licuefacción no está presente. Asímismo, las obras de defensa ribereña permitirán asegurar su estructura ante el fenómeno de erosión y socavamiento y se podrá recuperar terreno al río para incorporar mayor área disponible para el depósito, redundando en mayor capacidad de almacenamiento."

Jul 31, 2003

By Alfred Bodenlos

"El presente texto describe los depósitos de los metales no preciosos de la Cordillera Negra, que es el ramal más accidentado de los Andes en el departamente de Ancash. La mayor parte de estos depósitos contienen minerales de zinc y plomo, pero algunos incluyen minerales de cobre, así como de antimonio. La plata ocurre con el plomo y en algunos sitios con minerales de cobre y en un depósito los sulfuros de plata, se forma el mineralprincipal. El oro está presente en muchos de los depósitos, pero en cantidades insignificantes que carecen de valor."

May 1, 1957

By Alfred Bodenlos

El presente artículo describe la historia geológica pre-cretácica de la Cordillera Negra. En algunos intervalos predominaron los pantanos que dieron lugar a la formación de carbones. Luego, en el Valanginiano superior, la región estuvo sumergida, depositándose calizas delgadas. Los tufos que yacen sobre la secuencia de elásticos indican que hubo actividad volcánica a fines de este intervalo. Parte apreciable de los depósitos marinos del Cretácico medio está formado por calizas bituminosas obscuras.

Jul 1, 1957

By Alfred Bodenlos

"El presente texto señala los acontecimientos geológicos en la Cordillera Negra y la deposición de travertino por las fuentes termales todavía activas al oeste de la población de Ticapampa. Los minerales fueron depositados principalmente como rellenos de fisuras, siendo cavernosos y en partes bandeados y sus temperaturas conocidas de formación varían desde baja hasta moderada, lo cual, además de su textura porosa, sugiere que están comprendidos entre las clases epitermal y mesotermal, según sistema propuesto por Lindgren. "

Sep 1, 1957

By Alfred Bodenlos

El presente texto señala los depósitos de zinc y plomos encontrados en los cateos del flanco noroeste del cerro Huancapetí, perteneciente a la Cordillera Negra. En el flanco noroccidental del cerro Huancapetí, hay varias vetas que han sido exploradas por pequeños cateos, cuyas altitudes van desde 4480 hasta 4670 metros. Para llegar a esas vetas solo hay caminos malos que cruzan la cumbre de la cordillera al sur del área de la mina Huancapetí. De otro lado, en 1947 la única mina en actividad era la de Wilson, alcanzando 10 toneladas de concentrados al mes escogidos a mano, así como la mina San Idelfonso, la Improvisada, Mariscal y los cateos Señor de la Soledad y Fernandiita.

Nov 1, 1957

By Alfred Bodenlos

El presente texto señala los depósitos de plomo, zinc encontrados en la mina Huallpac, Macón, Cerro Plumisa; los cateos del área de la laguna Shagallán, Uchco, cateo del cerro Cieren y la mina Buena Casma y Mangán, pertenecientes a la Cordillera Negra, ubicado en Ancash, Perú.

Jan 1, 1958