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By C. A. Young

Cyanide is a fast-acting, highly toxic substance but, at the same time, is deemed essential for sustaining life as well as our standard of living. In this manuscript, the facts about cyanide are presented beginning with a brief history and definition and ending with a discussion on cyanide alternatives. Other topics include speciation, physical characteristics, toxicity, manufacturing, cyanogenics, cyanide cycle, separation, destruction, and markets including those outside the mining industry. Emphasis, of course, is placed on gold production by leaching and how it is influenced by ore type, mineral characteristics and economics as well as its advantages and disadvantages.

Jan 1, 2001

By K. J. R. Ford, Botz. M. M.

Porphyry copper ores are frequently a source of low-grade gold ore, but gold in these ores is often associated with significant levels of cyanide-soluble copper. Cyanide leaching of such ores increases flowsheet complexity and operating costs, and requires thorough planning to satisfy environmental requirements for tailings disposal and mine closure. This paper presents a review of the chemistry of cyanide leaching of gold-copper porphyry ores, carbon adsorption phenomena and means of removing base metals from leach solution. The primary economic drivers behind the processing of such complex ores are also analyzed.

Jan 1, 2011

By Jose R. Parga

In mining operations, cyanidation is the ,predominant method by which gold and silver are recovered from their ores and it is recognized that cyanide consumption can be a major factor that contributes to the operating costs for such operations. Also after extraction and recovery of precious metals a certain amount of cyanide is delivered to the tailings pond and must be considered with respect is environmental problems due to the toxicity of cyanides. In this regard, the Air-Sparged Hydrocyclone (ASH) has been used as a reactor for the treatment of cyanide solutions in two ways; first for cyanide recovery by acidulation using the Mexican modification of the Mills-Crowe process and second for cyanide destruction by oxidation with the use of chlorine dioxide (ClO2). In both cases, excellent performance can be achieved using the high capacity ASH system.

Jan 1, 1998

By D. Kidby, A. Briggs

"Vitrokele ™ is a synthetic adsorbent, using chelating groups on large polystyrene beads, developed in Canada over 7 years ago, and first commercialised in 1985 to recover noxious metals from plating wastes.Pilot plant trials have been performed in Australia and Canada to demonstrate the recovery of cyanide and removal of metal cyanide complexes from gold plant effluent using Vitrokele1 M 912. The pilot plants comprise a simple adsorption train (similar to a CIP circuit) followed by complete elution facilities, so that loaded Vitrokele™ can be stripped and returned to the adsorption circuit.An account of these campaigns is provided, showing the reduction of total CN levels from over 200 ppm to less than 0.5 ppm and Cu levels from approximately 100 ppm to less than 0.3 ppm in treated tailings.Comparisons between pilot plant results and laboratory test data are given and probable future work on the process and its application to the gold mining industry is discussed.INTRODUCTIONThrough millions of years of evolution, life forms have developed specialised molecules with exceptionally high affinity and selectivity for various metals such as iron, cobalt, zinc and copper.In the early 80's professors at the Faculty of Medicine of McGill University engaged in research on the extremely efficient ways that living cells captured trace metals essential for life.As research progressed, it became evident that the special molecules used by biological systems to capture metals could be synthesized to capture selected metals with similar efficiency from water or other solutions.The technology was first commercialised in 1985 to recover noxious metals from plating wastes with compositions applying the special molecules (chelating groups) on vitreous particles (hence Vitrokele™). To date approximately three commercial Vitrokele™ plants have been installed for treating plating waters in Ontario and Quebec."

Jan 1, 1992

By Dean Lindsay, Inna Dymov, Mariam Melashvili, Jim Smolik, Chris Fleming

"This paper presents results from the proposed cyanide detoxification circuit for Seabridge Gold’s KSM project. The proposed flowsheet uses a two-stage CCD (counter-current washing/decantation) circuit to transfer the flotation products CIL(carbon-in-leach) barren solution to a SART process (Sulphidization, Acidification, Recycling of precipitate, and Thickening of precipitate) to recover copper and free cyanide from the copper cyanide complex. The SART barren solution is then treated by an AVR process (Acidification, Volatilization of HCN gas, and Reneutralization) to concentrate the cyanide that was liberated in SART for recycling to leach. The washed CIL barren pulp (the CCD underflow) is treated with the SO2 /Air process to oxidize residual cyanide.The goal of this complex flowsheet is to recover and recycle as much cyanide as possible and produce a final effluent containing less than 0.5 mg/L copper and CNWAD at the lowest cost. The SO2/air process is capable of achieving low residual CNWAD (<1 mg/L) in the final product, but the persistence of aqueous copper above the target level has been detected in the treated solution in some instances. The expected high concentrations of copper and cyanide in the KSM CIL barren ( >200 mg/L each species) and the difficulties this might create for the SO2 /air process was a key factor in the decision to consider including the washing, SART and AVR steps in the project flowsheet.The target concentrations of CNWAD and Cu were readily achieved after aging the SO2 /air treated pulp, as would occur in a tailing or polishing pond. This suggests no additional treatment will be required to sustain low levels of these species in the final plant effluent."

Jan 1, 2015

By M. Hames, K. Larmour-Ship, B. Grinbaum, E. Buchalter, R. Hackl, B. Wassink

Sodium cyanide continues to be the lixiviant of choice for gold dissolution. Many gold ore-bodies contain a significant amount of cyanide-soluble copper which increases the cost of processing due to high cyanide consumption and high cyanide destruction and disposal costs. Several cyanide destruction processes are in use today, however, there are just a few cyanide recovery plants operating. A solvent extraction process to recover cyanide has been developed which utilizes the organophosphorous extractants Cyanex 923, di-butyl-butyl-phosphonate (DBBP) or tri-n-butyl phosphate (TBP) in Bateman Pulsed Columns. Copper cyanide species are first converted to hydrogen cyanide (HCN) by acidification, with or without sulfide addition. HCN is extracted by the organic and stripped using a suitable base (eg. NaOH) resulting in a high strength cyanide solution (eg. NaCN) for recycle to the gold recovery process. Continuous pilot plant testwork on HCN extraction using a 40 mm diameter Bateman Pulsed Column demonstrated a cyanide recovery of greater than 99% with final levels of cyanide in solution of less than 10 ppm. These results illustrate the potential of this technology to recycle cyanide and to detoxify final effluent streams.

Jan 1, 2005

By P. A. Riveros, J. Binvignat, V. M. McNamara, D. Koren

The recovery of cyanide from a gold mill solution containing high levels of copper (400 mg/L to 900 mg/L) using the AVR process was evaluated. It was determined that acidification to pH 2 to 3 provides a suitable balance between HCN generation, copper precipitation and acid consumption. A short pilot plant campaign showed that ~75% of the feed WAD cyanide was recovered while the remainder precipitated along with copper upon acidification. The acid consumption averaged 3.5 g H2SO4 per litre of solution. The copper precipitate, consisting mostly of CuCN and CuSCN, was readily separated from the solution by gravity. The volatilization of HCN in countercurrent packed columns averaged 98.7% efficiency. Reabsorption of HCN was practically 100% in NaOH solutions and slightly lower in a lime slurry. Basic volatilizer design parameters applicable to a large-scale operation were determined, including the Henry’s Law constant and the mass transfer coefficient of HCN gas.

Jan 1, 1998

By H. Soto, J. Jara, F. Nava

A method has been developed to recover cyanide and copper from solutions containing copper complexes and thiocyanate. Copper is precipitated as copper thiocyanate or as copper cyanide depending on pH and the concentrations of thiocyanate and cyanide in the effluent. The copper precipitate assays over 50% copper and presents good dewatering characteristics. After settling it can be separated from the effluent by filtration. The solution containing the bulk of the cyanide is then oxidized with ozone to transform the remaining thiocyanate into cyanide. This results in a regenerated solution rich in free cyanide that can be recycled to the cyanidation process. Careful control of the pH of the solution is required. First, pH of the effluent is lowered to optimize the precipitation and oxidation stages, then the pH is restored to an alkaline value to regenerate the cyanide solution. Recoveries of over 96% copper and cyanide were obtained in laboratory tests using industrial solutions. With this procedure, cyanocidic gold/copper ores could be treated economically by heap leaching, since the cyanide consumed by the copper impurities could be regenerated at very low cost (most of the cost of cyanide regeneration would be compensated by the copper credits). In order to achieve this, a bleed of the barren solution could be treated by the proposed method, and then recycled to the leaching step. The volume of solution to be treated should be large enough to keep a cyanide/copper molar ratio higher than 3:1. This would assure that copper does not cause undue interferences in the leaching or the carbon adsorption stages. If the thiocyanate content is low, the oxidation stage can be avoided, and the solution can be recycled to the leaching stage directly after the solid-liquid separation stage.

Jan 1, 1997

By A. V. Faiberg

Currently, the interest to conditioning of cyanide-bearing recycled solutions with high-grade of base metals, in particular, copper has significantly grown. This can be explained by two major factors. Firstly, there are strict regulations on cyanides amount in tails and higher cost of detoxification processes. This problem can be easily solved during the ore treatment using the conditioning of solutions and water recycling. Secondly, the presence of other metals minerals which react with cyanide during gold leaching resulting in high cyanide consumption. The presence of copper is a major problem. Many copper minerals react with cyanide with the formation of cyanide complexes-Cu(CN)2-, Cu(CN)32- and Cu(CN)43-. One mole of copper consumes 2-4 moles of free cyanide. Availability of cyanide-soluble copper minerals has deleterious effect on gold leaching (gold recovery, cyanide consumption, tails detoxification, efficiency of gold elution and electrowinning). The precipitation of copper from the solutions improves gold recovery by CIL. The removal and recycling of cyanide allowed the reduction of cyanide addition to the process. The recycling of spent cyanide-bearing solutions based on the removal of copper and the return of cyanide bound in complex compounds for leaching process is an optimal way of solving the problem of gold-bearing copper ores treatment. By using the technology, an adverse impact onto gold recovery process is eliminated and at the same time reducing the cyanide consumption. Today, processes and methods of high-grade copper leaching solutions conditioning before and after gold recovery have been developed, which combine two ways of copper recovery: as a saleable product and cyanide to recover gold and reduce total operating costs. They are Cutech, MNR, SART, Cyanomet, AuGment, Vitrokele, Hannah and Cyanisorb. At the same time, these technologies have not been studied enough and described in literature. Data on parameters and operating conditions as well as introduction is not available. The conditioning technology of recycled solutions developed by IRGIREDMET JSC allows copper to be recovered as high quality concentrate and at the same time free cyanide regeneration in the recycled solution which is amenable to gold leaching. This technology was commercialized at a mine in Kazakhstan in 2008. The removal and recycling of cyanide does not require additional cyanide and is cost-effective. More cost-efficiency is achievable through selling copper concentrates, closed water cycle without the detoxification of effluents and enhanced gold recovery by CIL and cathode quality.

Sep 1, 2012

By Charles H. Buclmam

"Environmental regulatory requirements for discharge of solutions and closure of operations for the gold mineral processing industry have been gradually lowered and in certain instances have been targeted to USEP A inorganic drinking water standards for dissolved ions in solution. The use of jar tests for water treatment process development is suitable for preliminary scoping work to be conducted in the research laboratory, as well as for optimization studies at the site of the treatment requirement. This paper will describe experimental methods which were performed using standard jar test equipment in efforts to produce solutions which meet USEP A inorganic drinking water standards after chemical treatment of cyanide solutions. The materials tested included gold bearing pregnant solutions from heap leaching operations, gold plant barren solutions from the Merrill-Crowe zinc cementation gold recovery process and gold heap leach wash solutions after carbon-in-column gold recovery. Experiments included cyanide destruction with sodium hypochlorite and arsenic and selenium co-precipitation coupled with mercury precipitation.IntroductionCyanide leaching solutions are used to selectively dissolve metallic gold from commercially viable mineral deposits. The heap leaching process involves stacking of gold bearing ores on specially designed solution containment pads and percolating alkaline cyanide solutions through the ore to dissolve the gold. Pregnant solutions containing the dissolved gold are collected and sent through a gold recovery process. After selective recovery of the gold, the barren solutions are recycled to the gold extraction process after adjustment of the solution alkalinity and available cyanide concentrations."

Jan 1, 1997

By K. R. Coulter

"Good morning gentlemen. I am very pleased to have this opportunity to tell you a few of the things that happen within a completely unrelated activity, the electroplating industry, except that it does consume metals and has some slight similarity of problems so far as cyanide is concerned.First, just a few general terms about the industry. It is a relatively unsophisticated industry technically, and in many instances there are serious problems in obtaining staff that can operate the various systems that are currently available for destroying cyanide or precipitating metals.I would suggest to you that if you are investigating any system that you consider very seriously the personnel that are actually going to run it. The installation people; probably have some idea what it is all about but the operators must be chosen for their ability and not because they just happen to be available.We perhaps have another area in common. There is very little money for capital expenditures that produce no immediate return or even eventual return on the investment.The industry is largely made up of ""Jobbers"" who are strictly electroplating. There is another group in which the electroplating is captive as in large companions where it is a convenience operation. Also there are specialists, who do other things besides plating but it is a very major part of their operation. This applies to the automotive parts industry.Cyanide applications in the plating industry will be for copper, zinc, cadmium, silver, brass, and gold. Cyanide waste solutions come from those solutions adhering to the plated parts, and from the occasional discharge of the plating bath solutions. Also, in a related industry, the heat treating people with cyanide case hardening have some high concentrations of cyanide to dispose of. Concentrations of cyanide that we treat are 2500 parts per million or higher especially in wastes from heat treating. Solution volumes might be as low as 100 gallons per hour in a well run, carefully operated rinsing system. It may be as high as 3000 gallons per hour where dilution occurs."

Jan 1, 1973

By A. G. Roach

IT IS generally stated that the gold ores of Nova Scotia are free-milling, and for the most part this is true. However, there is a certain proportion of the gold finely disseminated throughout the sulphides, notably arsenopyrite, and this gold is definitely not recoverable as &apos;free-milling&apos; gold by amalgamation. The proportion of free-milling gold to total gold seems to vary widely in different localities in the Province and is lowest in deposits of the fissure-vein type. The problem of recovery of these relatively recalcitrant values is usually one of economics, in some plac.es a simple gravity concentrate being of such low tenor that its extraction and subsequent disposal will not bear the costs involved. In other cases, such a high percentage of values escapes from the mortars and plates that concentration is definitely indicated. The size of the mining operation is also an important factor. In the large majority of cases, however, some concentrating step is warranted, even if the resulting concentrate is stock-piled until sufficient has accumulated to justify further treatment.

Jan 1, 1940

By JIAQI JIN, Joe Milbourne, Maoming Fan

Gold is very important to support the financial system, and to be used in industries of the jewelry, high-tech fields such as electronics and aerospace, etc. Gold is mainly extracted from three types of ores: primary ore (vein gold), placer (alluvial gold) and associated ore. Cyanide was widely used in gold ore flotation to depress gangue minerals and leaching/cyanidation. The process of extracting gold from gold ore, its separation and flotation concentrate, specifically through a technique called cyanidation or cyanide leaching. This method, which has been dominant since the 1970s, utilizes a dilute solution of cyanide to dissolve gold from the ore. While effective, the use of cyanide raises environmental and safety concerns due to its high toxicity. Cyanide spills can have severe environmental consequences. This has led to the exploration of alternative, environmentally friendly reagents. This paper discusses processing results using the alternative flotation depressants such as sodium sulfite (Na2SO3), etc. to produce a goldrich flotation concentrate for sale to a smelter or as feed to an alternative leaching agent. and methods to extract gold from ore without relying on cyanide.

Feb 22, 2026

By Roger L. Beals, George A. Tweedy

I. INTRODUCTION. THE results of the cyanide-operations, given in detail in the following paper, show the progress that is being made at the Minas del Tajo. The old pan-amalgamation process, in operation up to and including 1905, while paying a profit on high-grade ores, was no longer able to treat profitably the ores in sight at that time, hence an alteration in the process was imperative. The success of this alteration is eloquently expressed by the following data Pan- Amalgamation. Cyanidation. 1905. 1907. 1903. Tons treated, . . 51,387 53,983 69,300 Value per ton (U. S. currency),. $10.75 $8.39 $8.28 Extraction, per cent., 65.00 88.50 S7.45 Extraction, per ton. .- $7.00 $7.4.; $7.24 Total cost, per ton treated, 6.50 4.311 4.01 Profit, per ton treated, . . 0.50 3.07 3.23.;

Feb 1, 1910

By Courtney A. Young

Cyanide is a fast-acting, highly toxic substance but, at the same time, is deemed essential for sustaining life as well &apos;as our standard of living. In this manuscript, the facts about cyanide are presented beginning with a brief history and definition and ending with a discussion on cyanide alternatives. Other topics include speciation, physical characteristics, toxicity, manufacturing, cyanogenics, cyanide cycle, separation, destruction, and markets including those outside the mining industry. Emphasis, of course, is placed on gold production by leaching and how it is influenced by ore type, mineral characteristics and economics as well as its advantages and disadvantages.

Jan 1, 1998

By C. G. McLachlan

Abstract This paper deals with the application of the cyanide process to recover gold from a pyrite concentrate produced by means of differential flotation. This concentrate before cyanidation contains from 0.09 oz. to 0.14 oz. gold per ton, of which only about 60 per cent is recoverable. The rest is so fine that it remains interlocked in the pyrite and therefore is not acted on by the cyanide. The concentrate also contains about 15 per cent pyrrhotite and 0.4 per cent chalcopyrite, both of which are cyanicides. The cyanicidal effect of the pyrrhotite is inhibited by preacracing the pulp with lime, and maintaining a high lime alkalinity during cyanidation. The effect of the chalcopyrice is reduced as far as possible by removing those particles which are free by means of a further flotation step immediately prior to cyanidation. This involves the flotation of some very fine material. After nullifying as far as possible these two cyanicides, the concentrate is cyanided directly, i.e., without being roasted. This leaves the pyrite available for subsequent sale as a source of sulphur dioxide and sulphuric acid, and the entire residue of the cyamde plant, amounting to about 500 tons per day, 1s now being disposed of in this way. Prior to deciding on direct cyanidation, a number of laboratory roasting tests were made. These showed chat, 1f proper control were exercised, a better recovery of gold could be effected from the roasted product than by the direct method of treatment. The tests also showed that the capital cost o the plant would be much higher than that needed for the procedure adopted. The possibility of subsequently selling the pyrite for its sulphur content would also have been eliminated. Introduction A previous paper has described in considerable detail the application of the flotation process to improve gold recovery from Noranda&apos;s milling ore, and in so doing has covered the production of an auriferous pyrite concentrate. The present paper deals with the recovery of gold by cyanidation from that concentrate. This gold, though intimately associated with the pyrite, can, for metallurgical purposes, be considered as all occuring in the native state.

Jan 1, 1946

By C. G. McLachlan

Professor H.E.T. Haultain: To me from time to time the urge comes to say the agreeable thing as well as the disagreeable in commenting on the work of others. It is a prerogative of age. I don&apos;t apologize. To myself I justify my action as based on a long experience of the matters with which I deal, and I like to tell myself that I have a certain responsibility in such matters on account of my detached position. This Noranda article is a very fine contribution concerning Canadian milling, and I am surprised that no word of commendation or thanks has appeared concerning it in the BULLETIN. There is altogether too much written in these days by men rushing into print, concerning laboratory work, that has not been tied into, nor has resulted in application in the field. The authors of this paper have not rushed into print. The preparation of this paper was evidently an uncongenial task. If the authors had been that way inclined, it could have spread over several lengthy papers. It is an important article because it represents an enormous amount of work in the laboratory and the mill, extending over a period of sixteen years, and resulting in fine metallurgical and economic results with a very difficult and involved problem. It is a fine article because it is so well prepared and presented. It deals with an unusual ore condition, but there is much in it of use to every cyanide millman. It leaves very little room for criticism, though there may be differences of opinion in regard to some of the chemistry phases with which I am not conversant. I am struck by the enormous amount of persistent, painstaking, conscientious research work involved, and in the careful, sincere way in which the methods and difficulties have been described. Persistence and sincerity are the key note of the effort. It should have a good educational effect on the rising generation of millmen, and it should continue for long as a work of reference, and a spur to others. There has been an important by-product, the training and development of the young men engaged in the work. Three of them became superintendents of important mills. One was sought for important work in Africa, another has joined a large research organization in the United States.

Jan 1, 1946

By T. H. Oxnam

INTRODUCTION. THE predominating value of the ores now being treated by the Palmarejo and Mexican Gold Fields, Ltd., is silver, although some gold is also carried. The present method of treatment consists of wet-crushing and concentrating, followed by the cyanidation of the unroasted sands and slimes. The sands are treated by leaching and the so-called accumulated slimes by a system of agitation and decantation. It is only within very recent years that the cyanidation of unroasted silver-ores has been commercially successful. In fact, at the time operations were begun at the cyanide-plant at Chinipas, February, 1902, I knew of no other leaching-plant treating similar ores successfully. The cyanide treatment of the Palmarejo ores differs but little from the ordinary practice in cyaniding gold-ores; and perhaps but little, if any, new information concerning the metallurgy of silver is to be gleaned from it. PALMAREJO MINE. The Palmarejo mines are located in the southwestern part of the State of Chihuahua, Mexico, on the foothills of the Sierra Madre mountains, at an elevation of 3,200 feet. The mills, 12. miles distant, are situated on the Chinipas river, near the town of Chinipas, which is about 150 miles northeast of Agiabampo, on the Gulf of California. Supplies are shipped via this port as this route is the best and most direct to the property. The ore-bodies in the Palmarejo mines have been deposited. along a series of rock-fractures, caused by an intrusion of eruptive rock. The most important of these fractures or fissures, both in width and value, are the Prieta and Blanca veins, which.

Jul 1, 1905

By Mark R. Lamb

THE various methods of treating pulp in air-agitation tanks offer problems for experiment and study which are fascinating as well as practical. The usual method heretofore has been to fill each tank in turn, agitate the mixture the required period and then discharge the treated pulp into a storage-tank, from which it. is drawn to the filter as required. A later method is to run the pulp from the tube-mill, classifier, thickener, or settler into the first of a set of tanks, and thence continuously or in series through the remaining tanks, finally drawing off the pulp to a continuous filter, or to a pulp-storage tank if the filter is of the intermittent type. It is this method which I propose to discuss here in a preliminary way, with the idea of going exhaustively into the examination of the results of a series of experiments in a later paper. It may be of interest to note that the design of a cyanide-plant has recently been completed in which the estimated cost of the agitation-tanks, storage-tanks, and pumps was 30 per cent higher for the charge-agitation arrangement than for the series plan. The first question in studying the series method is, "What is the actual period of treatment undergone by the pulp?? One first supposes that by chance some of the pulp may get through with little or no treatment, while other portions may stay in the tanks a needlessly long period. The former is not probable or even possible, and the latter is, practically, true to only a limited extent. The greater the number of tanks the greater is the percentage of chance that all the pulp will be treated equally. Without going into the mathematical analysis of the problem (which is of little value, since it is based on problematical premises), its important terms may be clearly grasped by thinking of, or " visualizing," the conditions when,

Jan 1, 1910

By D R. Chalmers

Coal dust explosions have occurred in coal mines across the world. The Mitsui Miike Coal Mine disaster in 1963 was an example of how this hazard was not managed effectively, resulting in the loss of 458 lives and hundreds of people sustaining permanent brain injury from carbon monoxide poisoning. Management of the risks for this hazard have been well documented and have been implemented in modern coal mines. A recent trend in some mines has seen the abolition of barriers on roadways on the basis that the risks are being managed by the current controls. These controls include stone dust application, trickle dusters, dust analysis and dust removal. This paper explores the science behind such controls and questions the need for barrier protection on belt roads.CITATION:Chalmers, D R, 2013. Cybulski revisited - Lessons on dust, in Proceedings The Australian Mine Ventilation Conference , pp 165-168 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 1, 2013