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Comparison of Industrial Cyanide Destruction Processes

Sep 13, 2010

By Johan Gjødvad, Catherine Aimone-Martin, Charles Dowding, Mathias Jern

A residential structure adjacent to a quarry in Ohio was instrumented to record structure motions, resulting wall strains and existing crack displacements in response to close-in blasting within 82 m (270 ft). The project is a cooperative effort among international experts representing the European Federation of Explosives Engineers (EFEE) and ISEE supported by more than 21 persons from eight different countries to compliment prior work performed at the Aitik Mine in northern Sweden. The focus of this study is to compare blast-induced vibration measurements relative to regulatory compliance limits as a percentage of allowable velocities among eight different countries for a one-story residential wood-frame structure with a brick-and-mortar exterior and full basement. Participating counties included Austria, France, Germany, Norway, Sweden, Switzerland, the United Kingdom (UK) and the United States (US). Geophones were placed on the foundation and in the ground in accordance with each country’s regulations to record peak velocities as a function of frequency or distance to blasting. This study extends the work performed at the Aitik Mine to include interior corner geophones to calculate global wall strains and micro-m (micro-in) displacement gauges mounted over an existing drywall crack to measure blast-induced dynamic crack responses and climatological influences on daily opening and closing of a crack. Structure responses were documented for 68 blasts conducted north of the structure from February through September 2023 of which 17 blasts were selected for detailed analyses. The highest in-ground PPVs recorded were 43 mm/s and 59 mm/s at the NE and SW corners, respectively. Measurements from these blasts plotted within each country’s limits provided a comparison of stringency among the counties. The percentage of compliance limits among counties ranged from an average of 114% for the US, UK, and Austria limits to the highest of 585% for Switzerland. Despite these high percentages of compliance for all countries, the global tensile strains induced by these blasts were at most only 12 μ-strains and occurred with the highest velocity blast that exceeded each county’s limit. This high percentage of compliance and low strain level demonstrates the restrictive nature of the regulations studied. Peak dynamic crack opening and closing during blasting averaged 20 -m (0.0008 in) while the 12-hour weather-induced crack displacement during the time period over which blasting occurred averaged 200 -m (0.008 in) and the largest 12-hr change in crack width was 356 -m. This low level of crack response validates the observation that the studied regulations have highly conservative limits for cracking potential of standard building materials.

Jan 21, 2025

By Jessica M. Wempen, Michael K. McCarter

"Differential Interferometric Synthetic Aperture Radar (DlnSAR), a satellite-based remote sensing technique, has potential application for measuring mine subsidence on a regional scale with high spatial and temporal resolutions. However, the characteristics of Synthetic Aperture Radar (SAR) data and the effectiveness of DlnSAR for subsidence monitoring depend on the radar band (wavelength). This study evaluates the effectiveness of DinSAR for monitoring subsidence due to longwall mining in central Utah using L-band (24 cm wavelength) SAR data from the Advanced Land Observing Satellite (ALOS) and X-band (3 cm wavelength) SAR data from the TerraSAR-X mission.In the Wasatch Plateau region of central Utah, which is characterized by steep terrain and variable ground cover conditions, areas affected by longwall mine subsidence are identifiable using both L-band and X-band DlnSAR. Generally, using L-band data, subsidence magnitudes are measurable. Compared to X-band, L-band data are less affected by signal saturation due to large deformation gradients and by temporal decorrelation due to changes in the surface conditions over time. The L-band data tend to be stable over relatively long periods (months). Short wavelength X-band data are strongly affected by signal saturation and temporal decorrelation, but regions of subsidence are typically identifiable over short periods (days). Additionally, though subsidence magnitudes are difficult to precisely measure in the central Utah region using X-band data, they can often be reasonably estimated.INTRODUCTIONDifferential Interferometric Synthetic Aperture Radar (DlnSAR) is a satellite-based remote technique that can be used to measure surface displacement over large regions with high spatial resolution. Under good conditions, displacements can be measured with centimeter to subcentimeter accuracy (Buckley, 2000; Massonnet and Feig!, 1998). DlnSAR also has high temporal resolution, and imaging periods typically range from 10 to 50 days (Rosenqvist, Shimada, and Watanabe, 2004; Roth, 2004). In the last two decades, the application of DlnSAR for mine subsidence monitoring has been demonstrated in coal basins in Europe, Australia, China, and the United States (Camec and Delacourt, 2000; Ge, Chang, and Rizos, 2007; Ge et al., 2008; Ismaya and Donovan, 2012; Ng et al., 2010; Perski, 2000; Perski and Jura, 2003; Popiolek and Krawczyk, 2006; Wegmuller et al., 2005; Wright and Stow, 1999; Zhao et al., 2014; Xinglin et al., 2014). Overall, these studies have demonstrated good data resolution, strong relationships between mine development and subsidence, and reasonable agreement between displacements measured by DinSAR and displacements measured by conventional surveys."

Jan 1, 2016

By R. R. Cellan

There have not been many opportunities to date for comparison between laboratory and commercial neutralization rinse data. Homestake Mining Company's Santa Fe project is one such comparison. This paper discusses laboratory procedures and results from a 100' leach pad height simulation column neutralization rinse test and compares principal data with that achieved in actual commercial leach pad neutralization rinsing procedures. Principal comparisons include the rate of WAD cyanide neutralization, decrease in effluent pH, stabilization of dissolved silver and copper, and the quantity of dissolved gold recovered during rinsing.

Jan 1, 1996

By Leong, William. Chong, Kam Weng

Deep Vibro Techniques namely Vibro Compaction (VC) and Vibro Replacement (VR) are widely used in ground improvement to densify sands and strengthen cohesive soils. This paper describes the application of these techniques for the construction of 20 Ha Iron Ore Stockpile Yard with the maximum stockpile height of 14 m in Quang Ngai, Vietnam. The challenges of this project are to limit the stockpile allowable settlement and the surrounding pile’s lateral movement. The soil condition can be summarized as 12m – 18m thick of loose to medium dense SAND with qc around 5-18MPa and followed by 2.0 – 6.0 m thick soft clay with qc around 0.4 – 0.8MPa. Localized very dense sand layer was found. VR using stone columns were installed in soft clay layer while VC was adopted to densify sand layer. Additional shallow stone columns were built in sand strata to minimize pile top lateral movement. The post construction performance was verified by a large 6 m by 12 m plate load test (PLT). The predicted PLT deformation using Priebe’s improved properties for the VR will be presented and compared with the measured plate load test results.

Nov 1, 2022

By Brent W. Madsen

To assist in fulfilling the Bureau of Mines goals of maintaining adequate mineral supplies to meet national economic and strategic needs, and to minimize the environmental impacts associated with mineral-processing operations, a leaching-solvent extraction-electrowinning technique was compared with a leaching-cementation technique for processing low-grade copper ores. Large-scale laboratory column leaching tests (6 to 7 tonnes) were conducted on minus 37-cm chalcocitic ore using ferric sulfate leach solutions at 25° C. Two columns contained 11 percent minus 1.27-cm fines, and two columns contained 32 percent minus 1.27-cm fines. After 416 days of leaching ore samples containing 11 percent minus 1.27-cm fines, copper extraction was 48 and 51 percent for the leach-cementation and leach-solvent extraction-electrowinning procedures, respectively. When leaching ore samples containing 32 percent minus 1.27-cm fines, the leaching-solvent extraction-electrowinning technique extracted 60 percent of the copper after 568 days, whereas the leaching-cementation technique extracted only 48 percent of the copper. In the latter test, leach solution ponded on the ore, which reflected a decrease in ore column permeability. The decreased permeability was attributed to the generation of excessive amounts of iron salts during cementation; the salts precipitated on the fine ore particles and in the interstices, thus plugging the column. This decrease also lowered the available oxygen, resulting in poor aerobic bacterial activity which slowed the oxidation rate of ferrous ions to ferric ions. Sulfuric acid required to maintain a leachant pH of 2 was nearly halved when copper was recovered by solvent extraction and electrowinning rather than by cementation.

Jan 1, 1979

By Jowett A

To compare open circuit lead primary rougher results at Mount Isa Mines Ltd., eleven surveys were made over five weeks of plant operation with varying ore sources, including a specially hauled sample of 100% Black Star ore. Three of the surveys which represented extremes in performance were selected for sizing, cyclosizing and assaying for lead, zinc and iron. A comparison of the flotation kinetics has revealed the similarities (including common problems) and differences for the surveyed ores. The concepts of entrainment and collectorless flotability are used to aid interpretation of the kinetic data.

Jan 1, 1978

By J. W. van der Merwe, A. Palazzo

"Owing to the corrosiveness of the untreated brackish cooling water typically used for steel mills (and other environments), it is important to treat the water and monitor corrosion in such systems. Generally, corrosion rates are monitored with corrosion probes inserted into a pipeline or vessel. This has been standard practice for many years, and is widely accepted in industry. Typically, two kinds of probes are used - electrical resistance and linear polarization resistance (LPR) probes.In this study, the effectiveness and accuracy of the LPR technique was evaluated by comparing the electrochemical measurements with the results of mass loss tests using corrosion coupons. The corrosivity of the environment, a synthetic brackish water, was varied by varying the calcium hardness and alkalinity, and to simulate actual plant conditions temperatures of 35°C and 45°C were used. In addition to the corrosion rate measurements, the iron concentration was measured, as well as the imbalance from the probe.The corrosion rates obtained by LPR were from 57% lower to 385%higher than those from the immersion tests. Most probe measurements were higher than the immersion results, and 50% of the probe results were50% or more higher than the immersion results. The best correspondence between the two methods was obtained at low calcium levels, except for one measurement that was 93% higher than the coupon results. There was no clear correlation between parameters such as temperature and total alkalinity and the difference between the results. It would therefore appear that LPR measurements can differ significantly from immersion results, and LPR results should therefore be used with caution in industrial applications."

Jan 1, 2015

By A. J. Brown

This paper presents an economic evaluation of resin ion exchange and solvent extraction for the purification and concentration of uraniferous solutions derived from sulphuric acid leaching operations. Capital and operating costs are related to the uranium tenors of pregnant solutions. The conclusions drawn herein apply only to cases where resin and liquid ion exchange are technically feasible process alternatives. It is shown that solvent extraction is economically favoured for pregnant solutions at tenors greater than 0.90 gpl U3O8. Pregnant solutions with tenors below 0.35 gpl U3O8 are best treated by resin ion exchange. Between these concentrations, the economics are marginal and the favoured process is indistinguishable within the limits of accuracy of this study.

Jan 1, 1979

By Tracy Brettmann, Shailendra Endley, Jason Leary, Shashank Valluru

"Augered Cast-in-Place (ACIP) piles have long been used for deep foundation support in sands due to their high capacity and speed of installation. Very little information exists on the effects on capacity if the auger needs to be withdrawn from the hole prior to grouting. This condition can occur due to various reasons including grout plug ups, equipment issues, and grout supply delivery problems. It can become a major problem for the project team if this happens during production because the capacity of that pile is then in question, potentially resulting in re-design, installation of replacement piles and/or schedule delays. This paper compares the results of two high capacity test piles installed into a dense sand where one test pile was installed by first completely withdrawing the auger from the hole after drilling to the pile tip depth and the other test pile was installed utilizing conventional industry standard methods. Identical load tests were then performed on both piles to compare the effects of the two different installation procedures. The load test results were surprisingly similar in this case although the grout take required for the test pile installed in the pre-drilled hole was significantly higher to produce a similar grout return depth.IntroductionAugered Cast-in-Place (ACIP) piles are used extensively along the Texas Gulf Coast due to their combination of high capacity and speed of installation resulting in one of the most cost effective deep foundation systems relative to other options. Soil conditions in this region typically consist of alternating layers of sand and clay in the upper several hundred feet. ACIP piles are routinely installed to depths of over 100-ft to achieve the required capacity depending on the site specific soil conditions and therefore typically extend through and tip into sand layers. Occasionally, due to various reasons like equipment issues and plug-ups, the auger is withdrawn from the hole without grouting. Significant sand in the soil profile could lead to questions about the effect of the auger withdrawal on the pile capacity and load deflection relationship.This paper summarizes the results of two identical pile load tests performed on adjacent piles of the same length with the main difference being one was installed using the standard installation procedure and the other was installed by first completely withdrawing the auger from the hole after drilling to the pile tip depth. The load test results were then evaluated using load transfer analyses to estimate the effect of the withdrawal of the auger on the load-deflection characteristics and capacity."

Jan 1, 2017

By The Hollinger Mill Staff

ALTHOUGH cylindrical grinding mills have long been used, there is wide divergence of opinion as to what constitute best operating conditions. Questions such as mill diameter, diameter-length ratio, revolutions per minute, type and size of grinding media, volume of charge, circulating load, pulp level, pulp consistency, liner design, and size of feed, have all been given serious consideration by competent scientific investigators as well as by operators. While many laboratory and plant tests have been made that would seem to justify certain definite conclusions, there is a dearth of definite data giving actual results obtained when a grinding mill working between fixed limits is operated at its maximum capacity under varying conditions as to ball load, circulating load, speed, etc. In tests conducted recently at the Hollinger, extending over a period of thirteen months, to determine the best operating conditions for a ball-mill 6 ft. 6 in. diameter inside the liners, some very interesting facts have been ascertained. This paper is presented in the desire to make public the results of these tests and not with the idea that the last word has been spoken in regard to grinding. We feel, however, that these facts justify certain definite conclusions and hope that, by the fullest and frankest criticism and discussion, the essentials necessary for the correct design and operation of grinding mills will become better known.

Jan 1, 1937

By The Hollinger Mill Staff

MR. E. L. Longmore (l), in presenting this paper at the Annual General Meeting, suggested that it was neither desirable nor necessary to read any but the briefest portion of the paper. He wished to emphasize that the scale of the milling operations at the Hollinger not only provided several units in continuous operation to ensure that the test work was being carried on under normal conditions, but also provided a large and competent staff to supervise such an extensive experiment and to criticize intelligently the recorded results. He wished to acknowledge the enthusiastic co-operation of the group of assistants whose excellent work was responsible for the confidence with which the conclusions could be presented. The following data were given as a supplement to the published paper. Following conclusion of the test work described in the paper, the size of the balls fed to the mill was changed from 3-in. diameter to 2Yz-in. Within a short time, a gradual rise in the tonnage rate took place and, as no other condition had been changed, the increased tonnage was credited to the changed character of the ball load. At present, the average daily tonnage for the mill with low discharge is 1,507 tons, an increase of 77 tons over the 1,430 tons ground when feeding a 3-in. ball. A similar increase in tonnage should be credited to the high-discharge test, if the 2;Y2-in. ball had been used at that time. This would raise the 1,117 tons ground at that time to a new figure of 1,177 tons. From a study made to determine those factors influencing the rate of pulp flow through the low-discharge mill, it became evident that the ball screen used on the high-discharge mill must have been restricting the flow through the mill, although this was not recognized at the time. Accord-ingly, it was decided to repeat the high-discharge run. Additional length was added to the 21-in. ring grizzly originally used, and the length of the reverse spiral was increased. The end of the grizzly was left open so that, if necessary, excess pulp might flow out. A coarse mesh 3 ft. by 3 ft. flat screen was provided to catch stray balls.

Jan 1, 1937

By Yuexin Han

The characteristics of comminuted hematite products using a high pressure grinding roller (HPGR) and conventional jaw crusher (JC) were comparatively studied by screening, optical microscope, scanning electron microscope (SEM) and Brunauer, Emmett and Teller (BET) techniques. Major properties investigated included product size distribution, particle cracks, specific surface areas and pore volumes. Results showed that in a closed-circuit operation with a screen opening of 3.2 mm, the HPGR and JC gave a similar P80, but the HPGR achieved a more uniform size distribution, more fines and a higher crushing efficiency. Three modes of cracks were identified, namely transgranular cracks, innergranular microcracks and intergranular microcracks. Transgranular cracks originated from shearing breakage. Innergranular and intergranular microcracks were generated by HPGR via the two main nonrandom breakage forms, preferential breakage and interfacial breakage, depending on their respective ability to endure stresses when mineral phases (particles) were loaded against each other. The BET values for the same-size fractions showed that HPGR products gave higher specific surface areas and more pore volumes than JC products. This indicates that HPGR-crushed products are easier to grind because of their high porosity and extra cracks.

May 1, 2012

By Seth H. Hamblin, John E. Regan, Dimitrios Palantzas

"Through reliability-based calibration of larger pile load test databases, recent developments of the Load Resistance Factor Design (LRFD) methods, which include geotechnical load and resistance factors for deep foundations design, have advanced the state of practice for geotechnical engineering. These load test databases upon which the current geotechnical load and resistance factors have been developed are limited, however, and do not provide sufficient data to support the development of resistance factors for uplift (tension) pile capacity. As such, some recommended resistance factors for uplift capacity estimation methods are simply derived by reducing the recommended resistance factors for piles in compression by a factor of 0.10.The results of three (3) tension loading tests performed to failure on 508 mm (20- in) square precast, prestressed concrete piles, driven though granular soil in southeastern Massachusetts, are presented and compared to static pile capacity calculations and dynamic analyses performed using the Pile Driving Analyzer (PDA) during installation. These results are presented along with current recommended LRFD resistance factors for driven piles under uplift (tension) loading conditions. These comparisons offer an assessment of the applicability and limitations of current resistance factors methods for piles under uplift loading and may be useful additions to the existing database for future calibrations of LRFD resistance factors for driven prestressed concrete piles in sand.IntroductionIn 2010, two (2) natural draft cooling towers were constructed by Kiewit (Kiewit) Construction Company of Woodcliff Lake, New Jersey at the Brayton Point Power Station in Somerset, Massachusetts. These massive 500 foot tall, 400 foot diameter cooling towers were designed to convert the existing “open loop” system into a “closed loop system” thereby dramatically reducing the thermal impact to Mt. Hope Bay.Based on design guidance from the German VBG Design Code and the Massachusetts State Building Code (MSBC), tension (i.e. uplift) and lateral loads due to wind loads and design seismic events represented the critical loading conditions.Weighing approximately 190,000 kips upon completion, the cooling tower loads are transferred to 44 foundation nodes (i.e. pile caps) evenly spaced along ring beams which run the circular perimeter of each tower base. Each pile cap node was designed to resist a 2,000 ton compression load, 200 tons in tension (i.e. uplift), and 600 tons in the lateral direction."

Jan 1, 2015

By J. D. Noll, J. A. Organiscak, A. B. Cecala

Significant strides have been made in optimizing the design of filtration and pressurization systems used on the enclosed cabs of mobile mining equipment to reduce respirable dust and provide the best air quality to the equipment operators. Considering all of the advances made in this area, one aspect that still needed to be evaluated was a comparison of the efficiencies of the different filters used in these systems. As high-efficiency particulate arrestance (HEPA) filters provide the highest filtering efficiency, the general assumption would be that they would also provide the greatest level of protection to workers. Researchers for the U.S. National Institute for Occupational Safety and Health (NIOSH) speculated, based upon a previous laboratory study, that filters with minimum efficiency reporting value, or MERV rating, of 16 may be a more appropriate choice than HEPA filters in most cases for the mining industry. A study was therefore performed comparing HEPA and MERV 16 filters on two kinds of underground limestone mining equipment, a roof bolter and a face drill, to evaluate this theory. Testing showed that, at the 95-percent confidence level, there was no statistical difference between the efficiencies of the two types of filters on the two kinds of mining equipment. As the MERV 16 filters were less restrictive, provided greater airflow and cab pressurization, cost less and required less-frequent replacement than the HEPA filters, the MERV 16 filters were concluded to be the optimal choice for both the roof bolter and the face drill in this comparative analysis case study. Another key finding of this study is the substantial improvement in the effectiveness of filtration and pressurization systems when using a final filter design.

Aug 1, 2016

By V. E. Ross

A comparison was made of three methods for determining the contributions of true flotation and entrainment during batch flotation tests. In the first method size-by-size recoveries are measured in both the presence and the absence of a collector, a frother being present in both tests. In the second method the mass of solids and water recovered after a chosen time of flotation is varied by changing the rate of froth removal and the depth of the froth. The third method uses a transfer factor to describe the classification of solids and water, and hence the changes in the composition of the pulp, during a single flotation test. Batch flotation tests were carried out with artificial mixtures of pyrite and gangue, the amount of floated material recovered being calculated according to each of the three methods. The discrepancies betweeen the calculated amounts are analysed in terms of the assumptions that are made for the various methods and the most suitable conditions for the application of each method are identified

Dec 1, 1991

By BARONJUPTNER VON JONSTORFF, Andrew A. Blair, GUNNAR DILLNER

IT is a well-known fact that the results of different analysts, when operating on the same identical sample of steel or iron, are far from concordant, and it not infrequently happens that great annoyance and trouble in the commercial community are occasioned by these discrepancies. Attempts have been made at various times to investigate the causes of such differences and to obtain more reliable methods of analysis. The most important of these was made by the British Association in 1889: The following gentlemen, with Sir W. Roberts-Austen as Chairman, and Professor T. Turner as Secretary, were constituted as a committee to investigate the question, viz.: Sir F. A. Abel, Mr. Edward Riley, Mr. G. J. Snelus, Mr. John Spiller, Professor J. W. Langley, and Professor Tilden. Average .samples of steel were prepared in America under the superintendence of Professor J. W. Langley. The steels, in the form of turnings, were divided and distributed to sub-committees in Great Britain, America, France, Germany, and Sweden. In Sweden Professor Åkerman acted as Secretary to the Swedish committee. The Government Department of Tests was appointed in Germany; Mr. Ferd. Gautier in France; the British Association Committee in England; Messrs. William

Mar 1, 1905

By M. J. Sapko

From 2001 to 2007, the Pittsburgh Research Laboratory (PRL) of the National Institute for Occupational Safety and Health (NIOSH) conducted studies to develop alternative methodologies to full-scale explosion testing for deter-mining the ultimate strength of mine seals. As a result, the PRL developed and proposes an alternative seal-strength evaluation method based on a hydrostatic pressure-loading concept. The researchers suggest pressure loading a seal using water to twice the expected dynamic design load. The hydrostatic chamber test offers a means of validating seal designs, establishing appropriate resistance functions and determining the ultimate strength of seals through testing to failure. This article contrasts the full-scale explosion and hydrostatic testing of mine seals using a simple dynamic system model and principles.

Jan 1, 2008

By Jeffrey Meissner, Mike Waldron, Charles Dowding

Most studies of crack response have focused on opening and closing of a crack in the plane of the wall in which the crack occurs. Crack movement also occurs perpendicular or normal to the plane of the wall. This paper will examine and compare the in-plane and out-of-plane (normal) response of cracks in two different residences near limestone quarries. In two locations, sensors that measure in-plane and normal displacement were installed side-by-side on the same crack, allowing direct comparison of the two modes of response. In a third location, a perpendicular pair of displacement sensors was installed in a corner of a room to observe the bidirectional response of the structure at a corner. Both long-term and dynamic data were recorded with the same sensors; temperature, humidity, and air over pressures were also recorded to compare blast and weather effects. Measurements show that ratios of out of plane to in plane response to dynamic events can vary. However, the ratios of out of plane (normal) response to vibratory events to that of climatological change is still as small as the ratio for in plane crack responses.

Jan 1, 2010

By Y. C. Kim, W. L. Meyer, W. Cai

Although the first published optimum pit limit design algorithm by Lerchs-Grossmann dates back to 1965, the majority of the open-pit mines in the US has not as yet adopted such a rigorous optimization algorithm. Instead, the floating cone approach initially developed by Kennecott Copper in 1961 is still used today for various reasons. However, shortcomings with the floating cone algorithm, particularly for precious metal deposits with erratic mineral distributions, have provided a renewed interest in optimizing algorithms. This paper compares the performance of the floating cone algorithm with the rigorous optimization algorithm of the Lerchs-Grossman's graph theory and the newly developed maximum network flow algorithm by Hanson (1986). The maximum flow algorithm is a modified version of the logic as initially advocated by Johnson in 1968. Comparisons are made for three different deposits in terms of the total profits generated and the computation times involved. The results of the comparison show that both algorithms produced higher total profitability pits than the floating cone in all three deposits, although the increase in profits never exceeded 1 % of the base design obtained using the floating cone. Between the graph theory and maximum flow, graph theory produced consistently higher profits. The current version of maximum flow, however, cannot be modified to produce the optimum pit. Nevertheless, the authors prefer the maximum flow over the graph theory, simply because it is easy to program as well as to explain.

Jan 1, 1987